CN108264858A - A kind of new A B glue being bonded for acryl plates and preparation method thereof - Google Patents
A kind of new A B glue being bonded for acryl plates and preparation method thereof Download PDFInfo
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- CN108264858A CN108264858A CN201810140756.4A CN201810140756A CN108264858A CN 108264858 A CN108264858 A CN 108264858A CN 201810140756 A CN201810140756 A CN 201810140756A CN 108264858 A CN108264858 A CN 108264858A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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Abstract
The invention discloses a kind of for new A B glue of acryl plates bonding and preparation method thereof.AB glue of the present invention is A, B two-component type acryl plates bonded adhesives, by component A and B component in mass ratio 10:1 is mixed to get.The present invention improves compatibility between the glue and acryl plates, cementability by selecting the matrix of polymethyl methacrylate, methyl methacrylate, styrene copolymer, cross-linked modifier as component A；The functional additive of polymerization inhibitor, stabilizer, antioxidant, ultra-violet absorber, vulcanization accelerator, curing accelerator, fire retardant for component A is selected, improves the stability, adhesive strength, weatherability of the glue；Selective polymerization initiator, plasticizer, thixotropic agent are B component main body, improve the curing rate of the glue, stability, adhesive strength, weatherability.
Description
Technical field
The present invention relates to a kind of new A B glue for acryl plates bonding and preparation method, advantage to be：Preparation side
Method is simple, hardening time is short, bonding after bubble-free, adhesive strength is big, thermal stability is high, yellowing resistance is good, be easy to, adapt to it is large quantities of
Amount production.It is bonded especially suitable for acryl plates, has for application fields such as building, advertisement, traffic, medicine, illumination, industry
There is very high practical value.
Background technology
Acryl plates have impayable high luminosity, and good toughness, not cracky, beautiful smooth, prosthetic is strong, quality
Soft, bright in luster, service life is long, and the individual character that can meet different tastes is pursued.Therefore, acryl plates are widely used in building
Build (show window, sound insulation door and window, dome skylight, telephone booth etc.), advertisement (lamp box, signboard, direction board, Display Rack etc.), traffic (train, vapour
Door-windows such as vehicle etc.), medicine (baby incubator, various surgical medical utensils etc.), civilian (bathroom facility, craftwork, makeup
Product, stent, aquarium etc.), industrial (instrument and meter surface plate and protecting cover etc.), illumination (fluorescent lamp, pendent lamp, street lamp cover etc.).It is sub-
The bonding of gram force plank is a key link in acrylic process for manufacturing product, and it is as clear as crystal how to show acrylic product
Characteristic, embody acrylic craftwork sense of worth, to the maximum extent improve acrylic craftwork class and taste, be bonded skill
Art plays very important effect.The bonding of acryl plates is mainly by of both bonding agent applicability itself and bonding skill
It influences.
At present, mainly there is the acryl plates bonding agent of two types on domestic and international market：One kind is single component adhesive,
Such as chloroform；One kind is two-component bonding agent, such as neoprene stick, epoxy resin.In general, the bonding agent of two-component is (i.e.
AB glue) it is that bonding is realized by curing reaction, the bonding agent of one-component is the final volatilization of a solvent and realization is bonded.Single group
Part bonding agent curing rate is fast, can meet the technological requirement of bulk article production, but the product after being bonded is also easy to produce bubble, resistance to
Time property is poor, so as to directly affect the external beautiful and product quality of acrylic product.Two-component bonding agent adhesive effect is preferable, glues
Connect that rear bubble-free, intensity is big, good weatherability, but it is complicated for operation, difficulty is big, hardening time is long, it is difficult to adapt to produce in enormous quantities
Requirement.The present invention is aiming at acryl plates two-component bonding agent hardening time length, complex process, difficulty currently on the market
It adapts to produce in enormous quantities, it is impossible to meet the requirement of performance and invent.
Invention content
For the above-mentioned problems in the prior art, the object of the present invention is to provide a kind of adhesive strength is big, weatherability
Well, stability is high, hardening time is short, the simple production process new A B glue and preparation method for acryl plates bonding,
To solve deficiency of the current acryl plates two-component bonding agent in aspect of performance such as hardening time, production technologies.
A kind of new A B glue for acryl plates bonding, the AB glue is A, B two-component type acrylic board
Material bonded adhesives, it is characterised in that by component A and B component in mass ratio 10:1 is mixed to get：Wherein,
Component A is made of the component of following parts by weight：
B component is made of the component of following parts by weight：
A kind of new A B glue for acryl plates bonding, it is characterised in that the esters polymer in component A
For polymethyl methacrylate；Esters monomer is methyl methacrylate；Styrene copolymer is butadiene-styrene copolymer
Object, Methyl Methacrylate-Butadiene-Styrene Copolymer, acrylonitrile-butadiene-styrene copolymer, polystyrene fourth two
One or more of alkene copolymer, Styrene-Butadiene-Styrene Block Copolymer.
A kind of new A B glue for acryl plates bonding, it is characterised in that the polymerization inhibitor in component A is pair
Hydroxyanisol, 2- tert-butyl hydroquinone, 2,5 di tert butyl hydroquinone p-tert-Butylcatechol, N- nitrosos-N-
Phenylhydroxylamine aluminium, 2- tert-butyl -4,6- xylenols, 2,4- dinitro -6- sec-butyl phenols, TRI N BUTYL PHOSPHATE, 4- oxygen
One or more of generation -2,2,6,6- tetramethyl -4- piperidines, 4- hydroxyl -2,2,6,6- tetramethyl piperidine -1- oxygen radicals；
Stabilizer is disodium ethylene diamine tetraacetate, sodium versenate, tetrasodium ethylenediamine tetraacetate, disodium ethylene diamine tetraacetate
Magnesium, calcium disodium chelate, disodium ethylene diamine tetraacetate manganese, ethylenediamine tetraacetic acid disodium zinc salt, disodium ethylene diamine tetraacetate
One or more of copper, disodium ethylene diamine tetraacetate iron.
A kind of new A B glue for acryl plates bonding, it is characterised in that the antioxidant in component A is neighbour
Tert-butyl phenol, p-tert-butylphenol, 2- tert-butyl-4-methyl-Phenols, 6- tertiary butyl -2- methylphenols, 6- tertiary butyl -3- first
Base phenol；4- tertiary butyl -2,6- xylenols, 6 t butyl 2,4 dimethyl phenol, 2,4- DI-tert-butylphenol compounds, 2,5-
DI-tert-butylphenol compounds, 2,6 di t butyl phenol, 2,5- di-tert-butyl-4-methy phenols, 2,6- di-t-butyl -4- methylbenzenes
Phenol, 4,6- di-t-butyl -2- methylphenols；2,4,6- tri-butyl-phenols, 2 allyl 4 methyl 6 tert butyl phenol, 2-
Sec-butyl -4-TBP, 4- sec-butyls -2,6 di t butyl phenol, 4- nonyls -2,6 di t butyl phenol, 2,6- bis-
Tertiary butyl -4- ethyl -phenols, 2,6- di-t-butyl -4- normal-butyls phenol, 2,6- di-t-butyls-α-methoxyl group-paracresol, 4- hydroxyls
Methyl -2,6 di t butyl phenol, 2,6- di-t-butyls-alpha, alpha-dimethyl amino-p-cresol, 4,4 '-isopropylidene bis-phenol, 2,2 '-it is bis- -
(- 4 hydroxy phenyl of 3- methyl) propane, 4,4 '-dihydroxybiphenyl, 4,4 '-dihydroxy -3,3 ', 5,5 '-four-tertiary butyl biphenyl, 2,
2 '-methylene-bis--(4- methyl-6-tert-butylphenols), 4,4 '-methylene-bis--(2- methyl-6-tert-butylphenols), 2,2 '-
Methylene-bis--(4- ethyl -6- tert-butyl phenols), 2,2 '-methylene-bis--(4- methyl -6- cyclohexylphenols), 2,2 '-Asia
Methyl-bis--[4- methyl -6- (Alpha-Methyl cyclohexyl) phenol], 2,2 '-methylene-bis--(6- α-methylbenzyls paracresol), 4,
4 '-methylene-bis--(2,6- DI-tert-butylphenol compounds), 4,4 '-methylene-bis--(2-TBP), 2,2 '-ethylidene-bis--
(4- methyl-6-tert-butylphenols), 4,4 '-ethylidene-bis--(2- methyl-6-tert-butylphenols), 4,4 '-ethylidene-bis--(2,
6- DI-tert-butylphenol compounds), 4,4 '-butylidene-bis--(6- tertiary butyls-metacresol), 4,4 '-isobutylidene-bis--(bis- tertiary fourths of 2,6-
Base phenol), 4,4 '-thiobis-(3 methy 6 tert butyl phenol), 2,2 '-thiobis-(4- methyl-6-tert-butylphenols),
4,4 '-thiobis-(2- methyl-6-tert-butylphenols), 4,4 '-thiobis-(5- methyl -2-TBP), 4,4 '-it is thio
Bis- [the β-(3,5- di-t-butyl -4- hydroxyls of double-(2,6 di t butyl phenol), 2,2 '-thiobis-(4- octyl phenols), hexylene glycol
Base phenyl) propionic ester], double-(3,5- di-tert-butyl-hydroxy phenyl propionic acid propionyl) hydrazine, double-(3,5- di-t-butyl -4- hydroxyls
Base benzyl) thioether, 2,2 '-sulfurous ethyl glycol bis- [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic ester], triethylene glycol be double-
3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, 1,3,5- trimethyls -2,4,6- three-(4 '-hydroxyl -3 ', 5 '-two
Tertiary butyl) benzene, three [2- (3,5- di-tert-butyl-hydroxy phenyls) propiono oxygen ethyl] isocyanates, four (bis- tertiary fourths of 3,5-
Base -4- hydroxy-phenylpropionic acids) pentaerythritol ester, 1,3,5- tri- (3,5- di-tert-butyl-4-hydroxyl benzyls) guanamine, 4,6-
(1H, 3H, 5H), 1,1,3- tri--(2- methyl -4- hydroxyl -5- tert-butyl-phenyls) butane, (2,6- dimethyl -4- uncles of 1,3,5- tri-
Butyl -3- hydroxybenzyls) guanamine, 4,6- (1H, 3H, 5H), it is bis- [3,3- is bis--(3 '-tertiary butyl -4 '-hydroxybenzyl) fourth
One or more of acid] glycol ester.
A kind of new A B glue for acryl plates bonding, it is characterised in that the additive in component A is poly-
Ethylene powder wax, polytetrafluorethylepowder powder wax, polypropylene powder wax, ethene-vinyl acetate copolymer powder wax, polyamide powder
One or more of wax；Ultra-violet absorber is septichen phenyl ester, 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzo three
Nitrogen azoles, 2,4 dihydroxyl benzophenone, ESCALOL 567,2-hydroxy-4-n-octoxybenzophenone, 2-
(2 '-hydroxyl -3 ', 5 '-two tertiary phenyl) -5- chlorobenzotriazoles, -5- chlorobenzenes are simultaneously by 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls)
Triazole, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol), single benzoic acid resorcinol, 2,2 '-thiobis (4-
T-octyl phenol oxygroup) nickel, (2 '-n-butoxyphenyl) -1,3,5- of 2,4,6- tri- triazines, hexamethylphosphoramide, 2- (2 '-hydroxyls
Base -5 '-t-octyl phenyl) benzotriazole, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary amyl phenyl) benzotriazole, 2- (2- hydroxyl -3,
Bis- (bis (alpha, alpha-dimethylbenzyl) base) phenyl of 5-) benzotriazole, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary phenyl) -5- chlorobenzotriazoles, 2-
(2 '-hydroxyl -4 '-benzoxy phenyl) -5 chloro- 2H- benzotriazole, 2- (bis- (2,4- the 3,5-dimethylphenyls) -1,3,5- three of 4,6-
Piperazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazines -2) -5- n-hexane oxygroups phenol, benzoic acid (2,2,
6,6- tetramethyl -4- hydroxy piperidines) ester, bis- (2,2,6,6- tetramethyl -4- hydroxy piperidines) esters of decanedioic acid, nitrogen base three [acetic acid (2,
2,6,6- tetramethyl -4- hydroxy piperidines) ester], N, N '-bis- (2,2,6,6- tetramethyl-piperidyls) hexamethylene diamine, phosphorous acid three (1,2,
2,6,6- pentamethyl -4- hydroxy piperidines) ester, bis- (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) esters of decanedioic acid, 2- ethyls -2-
One kind or several in bis- (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) esters of (4- hydroxyl -3,5- three-levels butyl benzyl) malonic acid
Kind.
A kind of new A B glue for acryl plates bonding, it is characterised in that the vulcanization accelerator in component A
For four (3- mercaptobutyric acids) pentaerythritol esters, N, N '-diphenylguanidine, 2- benzothiazolyl mercaptans, hexa, curing
Tetrabutyl thiuram, tetra-benzyl thiram disulfide, tetramethylthiuram monosulfide, tetramethylthiuram disulfide, curing
Thiuram, tetra-sulfurized pair (1,5- pentylidene) thiuram, four isobutyl group thiuram of curing, a four isobutyl group autumns of vulcanization
Lan Mu, tetramethylthiuram monosulfide, the double pentamethyl thiurams of six vulcanizations, tetra-sulfurized pair (1,5- pentylidene) thiuram, two neighbours
Toluene, N- tertiary butyls -2-[4-morpholinodithio time sulphonyl, N, N- dicyclohexyls -2-[4-morpholinodithio time sulphonyl, N, N- dicyclohexyls -2-
Benzothiazole sulfenamide, N- oxygen diethylidene thiocarbamoyl-N'- oxygen diethylidenes sulfenamide, N, N- diethyl-two
Sulfo-amino benzothiazole, dibenzothiazyl disulfide, zinc 2-mercaptobenzothiazole salt, diethyldithiocar bamic acid
Lanthanum, diethyl thiocarbamic acid tellurium, ferric dimethyl dithiocarbamate, zinc dimethyl dithiocarbamate, dibenzyl
Nabam, NB sodium dibutyl dithiocarbamate, bismuth dimethyl dithiocarbamate, dimethyl disulfide are for ammonia
Base copper formate, zinc dibenzyl dithiocarbamate, zinc diisobutyldithiocarbamate, dibutyl dithiocaarbamate
Zinc, zinc diethyl dithiocarbamate, zinc-ethylphenyl dithiocarbamate, zinc dialkyl dithiophosphate, dialkyl group
One or more of zinc dithiophosphate, N, N'- di-n-butyls thiocarbamide, diethyl thiourea, N, N '-rhenocure CA.
A kind of new A B glue for acryl plates bonding, it is characterised in that the curing accelerator I in component A
For N, N- bis- (2- hydroxypropyls) open-chain crown ether, N, N- bis- (2- ethoxys) open-chain crown ether, N, N- dimethyl open-chain crown ether,
N, accelerine, N, N- diethylanilines, N, N- dicyanoethyls methylaniline, N- methyl-N-2- hydroxyethylanilines, N- first
Base-N-2- ethoxys open-chain crown ether, one or more of N, N- diisopropyl ethyl amines；Curing accelerator II is isooctyl acid
Zinc, cobalt naphthenate, cobalt iso-octoate, vanadium phosphate, cobalt naphthenate, manganese naphthenate, copper naphthenate, lauric acid copper, cobalt laurate, bay
One or more of sour nickel, lauric acid manganese, lauric acid iron；Cross-linked modifier for trimethylol-propane trimethacrylate,
One in ethoxylated trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, triallyl isocyanate
Kind is several；Fire retardant is one or more of aluminium hydrate powder, aluminium oxide powder.
A kind of new A B glue for acryl plates bonding, it is characterised in that the polymerization initiator in B component
For dibenzoyl peroxide, cumyl hydroperoxide, cyclohexanone peroxide, methyl ethyl ketone peroxide, peroxidating 2- ethylhexyls acid
Tert-pentyl ester, peroxidating 2- ethylhexyls tert-butyl acrylate, 1,1 '-bis- (t-amyl peroxy) hexamethylenes, 1,1 '-bis- (tertiary butyl mistakes
Oxygen) -3,3,5- trimethyl-cyclohexanes, peroxidating acetic acid tert-pentyl ester, peroxide acid tert-amyl acetate, peroxidating 3,3,5- trimethyls
Hecanoic acid t-butyl ester, peroxidized t-butyl perbenzoate, 3,3- bis- (t-amyl peroxy ethyl butyrates), bis- (t-butyl peroxy) fourths of 3,3-
Acetoacetic ester, cumyl peroxide, di t-amyl peroxide, di-t-butyl peroxide, peroxidating tertiary pentyl, the tertiary fourth of peroxidating
Base, dicetyl peroxydicarbonate two (2- ethylhexyls) ester, bis- (4- tert-butylcyclohexyls) peroxy dicarbonates, dicetyl peroxydicarbonate
Double 14 esters, two carbonic ester of peroxidating two (cetyl), di-cyclohexylperoxy di-carbonate, lauroyl peroxide, azo
One or more of bis-isobutyronitrile.
A kind of new A B glue for acryl plates bonding, it is characterised in that the plasticizer I in B component is benzene
Formic acid esters, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, triethylene-glycol dibenzoate, 2,2,4- tri-
Methyl-1,3- pentanediols-isobutyric acid-benzoic ether, 1,2,3- glyceryl tribenzoates, 1,2,3- glycerine lists lactate three
Benzoic ether, pentaerythritol tetrabenzoate, dibutyl phthalate, diisobutyl phthalate, phthalic acid two
Monooctyl ester di-sec-octyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisononyl phthalate
One or more of；Plasticizer II is diethylene glycol, hydroabietyl alcohol, polyvinyl alcohol, 2- ethyl -1,3- hexylene glycols, the third two
It is alcohol, ethylene glycol, hexadecanol, neopentyl glycol, polyethylene glycol, Decanol, 1,4- butanediols, 1.3 butanediols, polypropylene glycol, just pungent
One or more of alcohol；Thixotropic agent is one or more of aerosil, polyamide powder wax, organobentonite.
The preparation method of the new A B glue for acryl plates bonding, it is characterised in that include the following steps：
1) preparation of component A：
A press rate of charge, by esters polymer, esters monomer, styrene copolymer, polymerization inhibitor, stabilizer, antioxidant and
Additive under 70~90 DEG C of environment uniform stirring 1~4 hour to being uniformly mixed and be completely dissolved to obtain mixture；
B is again by ultra-violet absorber, vulcanization accelerator, curing accelerator I, curing accelerator II, cross-linked modifier and resistance
Combustion agent is added under 25~40 DEG C of environment in the mixture obtained by a steps, uniform stirring 1~4 hour, is uniformly mixed and complete
It discharges after dissolving, obtains component A；
2) preparation of B component：
A presses rate of charge, by polymerization initiator, plasticizer I, the II mixture uniform stirring 0.5~1 of plasticizer in B component
Hour is complete to dissolving, and obtains mixture；
Thixotropic agent is added in the mixture obtained by a steps by b, and uniform stirring 0.5~1 hour discharges after mixing,
Obtain B component；
3) preparation of new A B glue is using mass ratio as 10：Component A and B component are uniformly mixed by 1 proportioning, obtain new A B
Glue.
By using above-mentioned technology, compared with prior art, beneficial effects of the present invention are as follows：
1) in component A of the invention, by being copolymerized with polymethyl methacrylate, methyl methacrylate, phenylethylene
Object, cross-linked modifier are matrix, so as to play the compatibility, the cementability purpose that increase between the glue and acryl plates；Component A
In added using polymerization inhibitor, stabilizer, antioxidant, ultra-violet absorber, vulcanization accelerator, curing accelerator, fire retardant as functionality
Add agent, so as to play the stability, adhesive strength, the weatherability purpose that increase the glue；In B component with polymerization initiator, plasticizer,
Based on thixotropic agent, so as to play the curing rate for increasing the glue, stability, adhesive strength, weatherability purpose；
2) present invention is by selecting polymethyl methacrylate, methyl methacrylate, styrene copolymer, crosslinking to change
Matrix of the property agent as component A improves compatibility between the glue and acryl plates, cementability；Select polymerization inhibitor, stabilization
Agent, antioxidant, ultra-violet absorber, vulcanization accelerator, curing accelerator, the functional additive that fire retardant is component A, are improved
Stability, adhesive strength, the weatherability of the glue；Selective polymerization initiator, plasticizer, thixotropic agent are B component main body, improve the glue
Curing rate, stability, adhesive strength, weatherability.
Specific embodiment
The invention will be further described with reference to embodiments, but protection scope of the present invention is not limited to that.
Specific embodiment
Embodiment 1
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component：
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 2
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A is the same as embodiment 1.
B component：
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 3
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A is the same as embodiment 1.
B component：
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 4
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A is the same as embodiment 1.
B component：
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 5
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 6
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 7
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 8
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 9
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 10
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 11
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Embodiment 12
In the present embodiment, a kind of new A B glue and preparation method for acryl plates bonding, A, B component composition are with weight
Amount score is calculated as：
Component A：
B component is the same as embodiment 1.
In use, A, B component in mass ratio 10:1 mixing.
Performance test
1. tensile shear strength：It is performed by GB/T 7124-2008, test test piece is stainless steel test piece.
2. just consolidate the time：Component A 1.0g, B component 0.1g are weighed on clean glass plate or non-sticky paper, it will with instruction stick
Two components are uniformly mixed, and start timing since mixing, after observation mixing glue start to smolder, heat release, it is as first the time required to writing down
Gu the time.
3. component A viscosity is tested using rotary viscosimeter.
4. thermal stability：Component A 100g is stored into 72h at 80 DEG C, the sample of no gelatin phenomenon is determined as thermal stability
It is good, there are gelatin phenomenon or the sample of partial gel phenomenon to be determined as that thermal stability is poor.
The performance test results are as follows：
| Embodiment | Just consolidate the time (min) | Rotary viscosity (mPa.s) | Shear strength (MPa) | Thermal stability |
| Embodiment 1 | 25 | 84500 | 23.1 | It is good |
| Embodiment 2 | 23 | 84500 | 23.1 | It is good |
| Embodiment 3 | 22 | 84500 | 23.1 | It is good |
| Embodiment 4 | 20 | 84500 | 23.1 | It is good |
| Embodiment 5 | 15 | 84500 | 23.1 | It is good |
| Embodiment 6 | 26 | 58500 | 24.2 | It is good |
| Embodiment 7 | 28 | 43000 | 23.7 | It is good |
| Embodiment 8 | 28 | 41500 | 30.7 | It is good |
| Embodiment 9 | 29 | 15500 | 29.6 | It is good |
| Embodiment 10 | 22 | 87000 | 28.8 | It is good |
| Embodiment 11 | 22 | 87500 | 31.4 | It is good |
| Embodiment 12 | 22 | 88000 | 27.1 | It is good |
| Commercial product | 30 | 75000 | 22.3 | Difference |
From upper table test result understand this patent product have viscosity it is adjustable, just admittedly the time is controllable, tensile shear strength is high,
The advantages that stability is good, hence it is evident that better than presently commercially available product.
Claims (10)
1. a kind of new A B glue for acryl plates bonding, the AB glue is A, B two-component type acryl plates bonded adhesives,
It is characterized in that by component A and B component in mass ratio 10:1 is mixed to get：Wherein,
Component A is made of the component of following parts by weight：
B component is made of the component of following parts by weight：
2~6 parts of polymerization initiator, 80~95 parts of plasticizer I
0.3~0.7 part of plasticizer II, 5~9 parts of thixotropic agent.
2. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Esters polymer is polymethyl methacrylate；Esters monomer is methyl methacrylate；Styrene copolymer for butadiene-
Styrol copolymer, acrylonitrile-butadiene-styrene copolymer, gathers at Methyl Methacrylate-Butadiene-Styrene Copolymer
One or more of styrene-butadiene-copolymer, Styrene-Butadiene-Styrene Block Copolymer.
3. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Polymerization inhibitor is p-hydroxyanisole, 2- tert-butyl hydroquinone, 2,5 di tert butyl hydroquinone p-tert-Butylcatechol, N-
Nitroso-N-Phenylhydroxylamine aluminium, 2- tert-butyl -4,6- xylenols, 2,4- dinitro -6- sec-butyl phenols, the positive fourth of tricresyl phosphate
One kind in ester, 4- oxo -2,2,6,6- tetramethyl -4- piperidines, 4- hydroxyl -2,2,6,6- tetramethyl piperidine -1- oxygen radicals
It is or several；Stabilizer is disodium ethylene diamine tetraacetate, sodium versenate, tetrasodium ethylenediamine tetraacetate, ethylenediamine tetrem
Acid disodium magnesium, calcium disodium chelate, disodium ethylene diamine tetraacetate manganese, ethylenediamine tetraacetic acid disodium zinc salt, ethylenediamine tetrem
One or more of acid disodium copper, disodium ethylene diamine tetraacetate iron.
4. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Antioxidant is o-tert-butylphenol, p-tert-butylphenol, 2- tert-butyl-4-methyl-Phenols, 6- tertiary butyl -2- methylphenols, 6-
Tertiary butyl -3- methylphenols；4- tertiary butyl -2,6- xylenols, 6 t butyl 2,4 dimethyl phenol, bis- tertiary fourths of 2,4-
Base phenol, 2,5- DI-tert-butylphenol compounds, 2,6 di t butyl phenol, 2,5- di-tert-butyl-4-methy phenols, bis- tertiary fourths of 2,6-
Base -4- methylphenols, 4,6- di-t-butyl -2- methylphenols；2,4,6- tri-butyl-phenols, 2- pi-allyl -4- methyl-6-terts
Butylphenol, 2- sec-butyls -4-TBP, 4- sec-butyls -2,6 di t butyl phenol, 4- nonyl -2,6- di-t-butyls
Phenol, 2,6- di-t-butyl -4- ethyl -phenols, 2,6- di-t-butyl -4- normal-butyls phenol, 2,6- di-t-butyls-α-methoxyl groups -
Paracresol, 4 hydroxymethyl 2,6 di t butyl phenol, 2,6- di-t-butyls-alpha, alpha-dimethyl amino-p-cresol, 4,4 '-isopropylidene are double
Phenol, 2,2 '-bis--(- 4 hydroxy phenyl of 3- methyl) propane, 4,4 '-dihydroxybiphenyl, 4,4 '-dihydroxy -3,3 ', 5,5 '-four-uncle
Butyl biphenyl, 2,2 '-methylene-bis--(4- methyl-6-tert-butylphenols), 4,4 '-methylene-bis--(2- methyl-6-tert butyl
Phenol), 2,2 '-methylene-bis--(4- ethyl -6- tert-butyl phenols), 2,2 '-methylene-bis--(4- methyl -6- cyclohexyl benzenes
Phenol), 2,2 '-methylene-bis--[4- methyl -6- (Alpha-Methyl cyclohexyl) phenol], 2,2 '-methylene-bis--(6- α-methylbenzyls
Paracresol), 4,4 '-methylene-bis--(2,6- DI-tert-butylphenol compounds), 4,4 '-methylene-bis--(2-TBP), 2,2 '-
Ethylidene-bis--(4- methyl-6-tert-butylphenols), 4,4 '-ethylidene-bis--(2- methyl-6-tert-butylphenols), 4,4 '-Asia
Ethyl-bis--(2,6 di t butyl phenol), 4,4 '-butylidene-bis--(6- tertiary butyls-metacresol), 4,4 '-isobutylidene-bis--
(2,6 di t butyl phenol), 4,4 '-thiobis-(3 methy 6 tert butyl phenol), 2,2 '-thiobis-(4- methyl-6-terts
Butylphenol), 4,4 '-thiobis-(2- methyl-6-tert-butylphenols), 4,4 '-thiobis-(5- methyl -2- tert-butyl benzenes
Phenol), 4,4 '-thiobis-(2,6 di t butyl phenol), 2,2 '-thiobis-(4- octyl phenols), the bis- [β-(3,5- of hexylene glycol
Di-tert-butyl-hydroxy phenyl) propionic ester], double-(3,5- di-tert-butyl-hydroxy phenyl propionic acid propionyl) hydrazine, double-(3,5-
Di-tert-butyl-4-hydroxyl benzyl) thioether, the bis- [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid of 2,2 '-sulfurous ethyl glycol
Ester], double -3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester of triethylene glycol, 1,3,5- trimethyls -2,4,6- three-(4 ' -
Hydroxyl -3 ', 5 '-di-t-butyl) benzene, three [2- (3,5- di-tert-butyl-hydroxy phenyls) propiono oxygen ethyl] isocyanates, four
(3,5- di-tert-butyl-hydroxy phenyls propionic acid) pentaerythritol ester, 1,3,5- tri- (3,5- di-tert-butyl-4-hydroxyl benzyls) equal three
Piperazine -2,4,6- (1H, 3H, 5H), 1,1,3- tri--(2- methyl -4- hydroxyl -5- tert-butyl-phenyls) butane, (2,6- bis- of 1,3,5- tri-
Methyl -4- tertiary butyl -3- hydroxybenzyls) guanamine, 4,6- (1H, 3H, 5H), it is bis- [3,3- is bis--(3 '-tertiary butyl -4 '-hydroxyl
One or more of benzyl) butyric acid] glycol ester.
5. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Additive for polyethylene powders wax, polytetrafluorethylepowder powder wax, polypropylene powder wax, ethene-vinyl acetate copolymer powder wax,
One or more of polyamide powder wax；Ultra-violet absorber is septichen phenyl ester, 2- (2 '-hydroxyls -5 '-methyl
Phenyl) benzotriazole, 2,4 dihydroxyl benzophenone, ESCALOL 567,2- hydroxyl -4- n-octyloxies
Benzophenone, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary phenyl) -5- chlorobenzotriazoles, 2- (2- hydroxyl -3- tertiary butyl -5- methylbenzenes
Base) -5- chlorobenzotriazoles, 2,2' methylene bis (4- t-octyl -6- benzotriazole phenol), single benzoic acid resorcinol, 2,
2 '-thiobis (4- t-octyl phenol oxygroup) nickel, (2 '-n-butoxyphenyl) -1,3,5- of 2,4,6- tri- triazines, hexamethyl phosphinylidyne three
Amine, 2- (2 '-hydroxyl -5 '-t-octyl phenyl) benzotriazole, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary amyl phenyl) benzotriazole,
2- (bis- (bis (alpha, alpha-dimethylbenzyl) base) phenyl of 2- hydroxyls -3,5-) benzotriazole, 2- (2 '-hydroxyl -3 ', 5 '-two tertiary phenyl) -5- chlorine
Benzotriazole, -5 chloro- 2H- benzotriazole of 2- (2 '-hydroxyl -4 '-benzoxy phenyl), 2- (bis- (the 2,4- dimethyl benzenes of 4,6-
Base) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazines -2) -5- n-hexane oxygroups phenol,
Bis- (2,2,6,6- tetramethyl -4- hydroxy piperidines) esters of benzoic acid (2,2,6,6- tetramethyl -4- hydroxy piperidines) ester, decanedioic acid, nitrogen
Base three [acetic acid (2,2,6,6- tetramethyl -4- hydroxy piperidines) ester], N, N '-bis- (2,2,6,6- tetramethyl-piperidyls) hexamethylene diamine,
Phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, decanedioic acid are bis- (1,2,2,6,6- pentamethyl -4- hydroxy piperidines)
Ester, bis- (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) esters of 2- ethyls -2- (4- hydroxyl -3,5- three-levels butyl benzyl) malonic acid
One or more of.
6. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Vulcanization accelerator is four (3- mercaptobutyric acids) pentaerythritol esters, N, N '-diphenylguanidine, 2- benzothiazolyl mercaptans, hexa-methylene
Tetramine, tetrabutylthiuram disulfide, tetra-benzyl thiram disulfide, tetramethylthiuram monosulfide, tetramethyl autumn
Lan Mu, tetraethylthiuram disulfide, tetra-sulfurized pair (1,5- pentylidene) thiuram, four isobutyl group thiuram of curing, a sulphur
Change four isobutyl group thiurams, tetramethylthiuram monosulfide, the double pentamethyl thiurams of six vulcanizations, tetra-sulfurized pair (1,5- pentylidene)
Thiuram, two adjacent toluene, N- tertiary butyls -2-[4-morpholinodithio time sulphonyl, N, N- dicyclohexyls -2-[4-morpholinodithio time sulphonyl, N, N-
Dicyclohexyl -2-[4-morpholinodithio sulfenamide, N- oxygen diethylidene thiocarbamoyl-N'- oxygen diethylidenes sulfenamide, N,
N- diethyl-dithiocarbamates benzothiazole, dibenzothiazyl disulfide, zinc 2-mercaptobenzothiazole salt, two sulphur of diethyl
For carbamic acid lanthanum, diethyl thiocarbamic acid tellurium, ferric dimethyl dithiocarbamate, dimethyl dithiocarbamic acid
Zinc, dibenzyl aminodithioformic acid sodium, NB sodium dibutyl dithiocarbamate, bismuth dimethyl dithiocarbamate, diformazan
Base aminodithioformic acid copper, zinc dibenzyl dithiocarbamate, zinc diisobutyldithiocarbamate, two sulphur of dibutyl
For carbaminate, zinc diethyl dithiocarbamate, zinc-ethylphenyl dithiocarbamate, dialkyl dithiophosphoric acid
Zinc, zinc dialkyl dithiophosphate, N, N'- di-n-butyls thiocarbamide, diethyl thiourea, one kind in N, N '-rhenocure CA or
It is several.
7. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in component A
Curing accelerator I be N, N- bis- (2- hydroxypropyls) open-chain crown ether, N, N- bis- (2- ethoxys) open-chain crown ether, N, N- dimethyl
Open-chain crown ether, N, accelerine, N, N- diethylanilines, N, N- dicyanoethyls methylaniline, N- methyl-N-2- hydroxyl second
Base aniline, N- methyl-N-2- ethoxys open-chain crown ether, one or more of N, N- diisopropyl ethyl amines；Curing promotes
Agent II for zinc Isoocatanoate, cobalt naphthenate, cobalt iso-octoate, vanadium phosphate, cobalt naphthenate, manganese naphthenate, copper naphthenate, lauric acid copper,
One or more of cobalt laurate, lauric acid nickel, lauric acid manganese, lauric acid iron；Cross-linked modifier is trimethylolpropane tris
Methacrylate, ethoxylated trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, triallyl are different
One or more of cyanate；Fire retardant is one or more of aluminium hydrate powder, aluminium oxide powder.
8. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in B component
Polymerization initiator is dibenzoyl peroxide, cumyl hydroperoxide, cyclohexanone peroxide, methyl ethyl ketone peroxide, peroxidating 2-
Ethylhexyl acid tert-pentyl ester, peroxidating 2- ethylhexyls tert-butyl acrylate, 1,1 '-bis- (t-amyl peroxy) hexamethylenes, 1,1 '-it is bis-
(t-butyl peroxy) -3,3,5- trimethyl-cyclohexanes, peroxidating acetic acid tert-pentyl ester, peroxide acid tert-amyl acetate, peroxidating 3,
3,5- trimethylhexanoates, peroxidized t-butyl perbenzoate, 3,3- bis- (t-amyl peroxy ethyl butyrates), the bis- (uncles of 3,3-
Butyl peroxy) ethyl butyrate, cumyl peroxide, di t-amyl peroxide, di-t-butyl peroxide, peroxidating tertiary pentyl,
Tert-butyl peroxide, dicetyl peroxydicarbonate two (2- ethylhexyls) ester, bis- (4- tert-butylcyclohexyls) peroxy dicarbonates, mistake
Aoxidize two carbonic acid double 14 esters, two carbonic ester of peroxidating two (cetyl), di-cyclohexylperoxy di-carbonate, peroxidating 12
One or more of alkane acyl, azodiisobutyronitrile.
9. a kind of new A B glue for acryl plates bonding according to claim 1, it is characterised in that in B component
Plasticizer I is benzoic ether, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, triethylene-glycol dibenzoic acid
Ester, 2,2,4- trimethyls -1,3- pentanediols-isobutyric acid-benzoic ether, 1,2,3- glyceryl tribenzoates, 1,2,3- the third three
Alcohol list lactate tribenzoate, pentaerythritol tetrabenzoate, dibutyl phthalate, diisobutyl phthalate,
Dioctyl phthalate di-sec-octyl phthalate, diisooctyl phthalate, dinonyl phthalate, adjacent benzene two
One or more of formic acid dinonyl；Plasticizer II is diethylene glycol, hydroabietyl alcohol, polyvinyl alcohol, 2- ethyls -1,3-
Hexylene glycol, ethylene glycol, hexadecanol, neopentyl glycol, polyethylene glycol, Decanol, 1,4- butanediols, 1.3 butanediols, gathers at propylene glycol
One or more of propylene glycol, n-octyl alcohol；Thixotropic agent is aerosil, in polyamide powder wax, organobentonite
It is one or more of.
10. a kind of preparation method according to any new A B glue being bonded for acryl plates of claim 1-9,
It is characterized in that including the following steps：
1) preparation of component A：
A presses rate of charge, by esters polymer, esters monomer, styrene copolymer, polymerization inhibitor, stabilizer, antioxidant and addition
Agent under 70~90 DEG C of environment uniform stirring 1~4 hour to being uniformly mixed and be completely dissolved to obtain mixture；
B is again by ultra-violet absorber, vulcanization accelerator, curing accelerator I, curing accelerator II, cross-linked modifier and fire retardant
It is added under 25~40 DEG C of environment in the mixture obtained by a steps, uniform stirring 1~4 hour, be uniformly mixed and is completely dissolved
After discharge, obtain component A；
2) preparation of B component：
A presses rate of charge, by polymerization initiator, plasticizer I, the II mixture uniform stirring of plasticizer 0.5~1 hour in B component
It is complete to dissolving, obtain mixture；
Thixotropic agent is added in the mixture obtained by a steps by b, and uniform stirring 0.5~1 hour discharges, obtains after mixing
B component；
3) preparation of new A B glue is using mass ratio as 10：Component A and B component are uniformly mixed by 1 proportioning, obtain new A B glue.
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Cited By (6)
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| CN108976143A (en) * | 2018-08-17 | 2018-12-11 | 苏州联胜化学有限公司 | Color inhibition amide waxe and preparation method thereof |
| CN109054661A (en) * | 2018-07-17 | 2018-12-21 | 江苏道明胶粘剂有限公司 | A kind of high-adhesive-strength AB two-component type acrylic acid structure glue and preparation method |
| CN111002689A (en) * | 2019-12-20 | 2020-04-14 | 深圳市太阳雨展示制品有限公司 | Glue coating process for acrylic plate |
| CN111040677A (en) * | 2019-12-31 | 2020-04-21 | 宁波大榭开发区综研化学有限公司 | Flame retardant, flame-retardant adhesive composition, flame-retardant adhesive tape and preparation method thereof |
| EP3712184A1 (en) * | 2019-03-18 | 2020-09-23 | MKT Metall-Kunststoff-Technik GmbH & Co. KG | Fastening system comprising a curing component with at least one benzoate |
| CN112223464A (en) * | 2020-10-15 | 2021-01-15 | 桃江县鑫龙阳光木业胶板厂(普通合伙) | Wood modifier and preparation method thereof |
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| CN109054661A (en) * | 2018-07-17 | 2018-12-21 | 江苏道明胶粘剂有限公司 | A kind of high-adhesive-strength AB two-component type acrylic acid structure glue and preparation method |
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| CN111002689A (en) * | 2019-12-20 | 2020-04-14 | 深圳市太阳雨展示制品有限公司 | Glue coating process for acrylic plate |
| CN111040677A (en) * | 2019-12-31 | 2020-04-21 | 宁波大榭开发区综研化学有限公司 | Flame retardant, flame-retardant adhesive composition, flame-retardant adhesive tape and preparation method thereof |
| CN111040677B (en) * | 2019-12-31 | 2021-11-12 | 宁波大榭开发区综研化学有限公司 | Flame retardant, flame-retardant adhesive composition, flame-retardant adhesive tape and preparation method thereof |
| CN112223464A (en) * | 2020-10-15 | 2021-01-15 | 桃江县鑫龙阳光木业胶板厂(普通合伙) | Wood modifier and preparation method thereof |
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