CN108264681A - Salt affected soil cultivation degradable mulch - Google Patents

Salt affected soil cultivation degradable mulch Download PDF

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Publication number
CN108264681A
CN108264681A CN201711372876.9A CN201711372876A CN108264681A CN 108264681 A CN108264681 A CN 108264681A CN 201711372876 A CN201711372876 A CN 201711372876A CN 108264681 A CN108264681 A CN 108264681A
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CN
China
Prior art keywords
affected soil
salt affected
soil cultivation
parts
degradable mulch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711372876.9A
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Chinese (zh)
Inventor
王胜
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Weifang Yourong Industry Co Ltd
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Weifang Yourong Industry Co Ltd
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Priority to CN201711372876.9A priority Critical patent/CN108264681A/en
Publication of CN108264681A publication Critical patent/CN108264681A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • A01G13/0275Films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2403/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2403/04Starch derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • C08J2405/04Alginic acid; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/11Esters; Ether-esters of acyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/39Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates

Abstract

The invention discloses a kind of salt affected soil cultivation degradable mulch, including being made of the raw material of following parts by weight:30~60 parts of ethylene acrylic, 20~40 parts of modified starch, 10~20 parts of sodium alginate, 0.5~5 part of photosensitizer, 0.5~1.5 part of plasticizer, 0.5~1.5 part of heat stabilizer, 0.5~1 part of graphene.The present invention is fast with degradation speed, the advantages of intensity is high since the Plastic-film disintegration speed is fast, does not pollute arable land, the structure of salt affected soil is not interfered with, is avoided and is aggravated to salt affected soil structural damage, is conducive to the growth of plant in the improvement and salt affected soil of salt affected soil.

Description

Salt affected soil cultivation degradable mulch
Technical field
The present invention relates to ground membrane technology more particularly to a kind of salt affected soil cultivation degradable mulch.
Background technology
As mulch uses on a large scale, a large amount of mulch fragments can remain in the soil.At present majority peasant households using Nondegradable plastics film, because bright day illuminance is good, durable, extremely efficient in preserving heat.But nondegradable plastics film is difficult point Solution, can not only destroy soil texture, influence plant growth and lead to the underproduction, can also cause Heavy environmental pollution.And salt affected soil Physicochemical property itself it is poor, salt affected soil structure is destroyed, hard when sticking dry when wet, ventilation, it is permeable bad, in salt affected soil Nutrient be largely lost in, such as using nondegradable plastics film, then can the salt affected soil above problem can be further aggravated, in this way The growth of plant causes greatly to influence in improvement and salt affected soil for salt affected soil.
Invention content
The technical problems to be solved by the invention are to provide a kind of destruction that can avoid aggravating to salt affected soil, are conducive to The salt affected soil cultivation degradable mulch of the growth of plant in the improvement of salt affected soil and salt affected soil.
In order to solve the above technical problems, the technical scheme is that:Salt affected soil cultivation degradable mulch, including by The raw material of following parts by weight is made:30~60 parts of ethylene acrylic, 20~40 parts of modified starch, 10~20 parts of sodium alginate, light Quick dose 0.5~5 part, 0.5~1.5 part of plasticizer, 0.5~1.5 part of heat stabilizer, 0.5~1 part of graphene.Graphene equally may be used Play the role of photosensitizer, convenient for the degradation of this degradable mulch.The production of this salt affected soil cultivation degradable mulch uses Conventional mulch film production method is produced.
The photosensitizer for cerium stearate, ferric stearate, N, N- dibutyl dithiocaarbamates iron, manganese stearate and N, One or more of N- nickel dibutyl dithiocarbamates.
The plasticizer is tributyl citrate, tributyl 2-acetylcitrate, dioctyl phthalate, ethylene glycol and third One or more of triol.
The heat stabilizer is one or more of zinc stearate, hydrotalcite and calcium stearate.
Further include 0.5~1.5 part of 0.5~1 part of raw material solubilizer, the antioxidant including following parts by weight.
The antioxidant is more than one of tea polyphenols, natural plant polyphenols, tris phosphite and triphenyl phosphite.
The solubilizer be in pentalyn, rosin glycerides and maleficent acid rosin resin it is a kind of with On.
By adopting the above-described technical solution, the beneficial effects of the invention are as follows:This salt affected soil cultivation degradable mulch Fast with degradation speed, the advantages of intensity is high, since the Plastic-film disintegration speed is fast, does not pollute arable land, does not interfere with saline and alkaline The structure of soil avoids and aggravates to salt affected soil structural damage, is conducive to plant in the improvement and salt affected soil of salt affected soil The growth of object.
Specific embodiment
With reference to embodiment, the present invention is further explained.In the following detailed description, it is only retouched by way of explanation Certain exemplary embodiments of the present invention are stated.Undoubtedly, those of ordinary skill in the art will recognize, without departing from In the case of the spirit and scope of the present invention, the described embodiments may be modified in various different ways.Therefore, The description of embodiment is regarded as illustrative in nature, and is not intended to limit the scope of the claims.
Embodiment one:
Salt affected soil cultivation degradable mulch, including being made of the raw material of following parts by weight:60 parts of ethylene acrylic changes 40 parts of starch of property, 20 parts of sodium alginate, 5 parts of ferric stearate, 1.5 parts of tributyl citrate, 1.5 parts of hydrotalcite, 1 part of graphene.
Embodiment two:
Salt affected soil cultivation degradable mulch, including being made of the raw material of following parts by weight:30 parts of ethylene acrylic changes 20 parts of starch of property, 10 parts of sodium alginate, N, 0.5 part of N- dibutyl dithiocaarbamates iron, dioctyl phthalate 0.5 Part, 0.5 part of calcium stearate, 0.5 part of graphene.
Embodiment three:
Salt affected soil cultivation degradable mulch, including being made of the raw material of following parts by weight:45 parts of ethylene acrylic changes 30 parts of starch of property, 15 parts of sodium alginate, N, 2.5 parts of N- nickel dibutyl dithiocarbamates, 1 part of tributyl 2-acetylcitrate, 1 part of zinc stearate, 0.75 part of graphene, 0.75 part of pentalyn, 1 part of tris phosphite.
Example IV:
Salt affected soil cultivation degradable mulch, including being made of the raw material of following parts by weight:30 parts of ethylene acrylic changes 20 parts of starch of property, 10 parts of sodium alginate, N, 0.5 part of N- dibutyl dithiocaarbamates iron, dioctyl phthalate 0.5 Part, 0.5 part of calcium stearate, 0.5 part of graphene, 0.5 part of rosin glycerides, 0.5 part of triphenyl phosphite.
Basic principle, main feature and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (7)

1. salt affected soil cultivation degradable mulch, which is characterized in that including being made of the raw material of following parts by weight:Ethylene, propylene Acid 30~60 parts, 20~40 parts of modified starch, 10~20 parts of sodium alginate, 0.5~5 part of photosensitizer, 0.5~1.5 part of plasticizer, 0.5~1.5 part of heat stabilizer, 0.5~1 part of graphene.
2. salt affected soil cultivation degradable mulch as described in claim 1, it is characterised in that:The photosensitizer is stearic acid Cerium, ferric stearate, N, in N- dibutyl dithiocaarbamates iron, manganese stearate and N, N- nickel dibutyl dithiocarbamate More than one.
3. salt affected soil cultivation degradable mulch as described in claim 1, it is characterised in that:The plasticizer is citric acid One or more of tributyl, tributyl 2-acetylcitrate, dioctyl phthalate, ethylene glycol and glycerine.
4. salt affected soil cultivation degradable mulch as described in claim 1, it is characterised in that:The heat stabilizer is tristearin One or more of sour zinc, hydrotalcite and calcium stearate.
5. the salt affected soil cultivation degradable mulch as described in claim 1,2,3 or 4, it is characterised in that:Further include solubilising 0.5~1 part of agent, 0.5~1.5 part of antioxidant.
6. salt affected soil cultivation degradable mulch as claimed in claim 5, it is characterised in that:The antioxidant is more for tea Phenol, natural plant polyphenols, tris phosphite and triphenyl phosphite more than one.
7. salt affected soil cultivation degradable mulch as claimed in claim 5, it is characterised in that:The solubilizer is rosin season One or more of Doutrate, rosin glycerides and maleficent acid rosin resin.
CN201711372876.9A 2017-12-19 2017-12-19 Salt affected soil cultivation degradable mulch Pending CN108264681A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711372876.9A CN108264681A (en) 2017-12-19 2017-12-19 Salt affected soil cultivation degradable mulch

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711372876.9A CN108264681A (en) 2017-12-19 2017-12-19 Salt affected soil cultivation degradable mulch

Publications (1)

Publication Number Publication Date
CN108264681A true CN108264681A (en) 2018-07-10

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4337181A (en) * 1980-01-17 1982-06-29 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable starch-based blown films
CN1239725A (en) * 1999-06-22 1999-12-29 沈阳南阳经贸集团有限公司 Polynary degradable resin composition and its preparation process
CN104292600A (en) * 2014-09-22 2015-01-21 井冈山大学 Humic acid/EVA (ethylene-vinyl acetate) resin blending-modified degradable solid mulching film
CN104497365A (en) * 2014-12-16 2015-04-08 潍坊华潍新材料科技有限公司 Bentonite/ starch composite degrading material produced by melt intercalation and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4337181A (en) * 1980-01-17 1982-06-29 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable starch-based blown films
CN1239725A (en) * 1999-06-22 1999-12-29 沈阳南阳经贸集团有限公司 Polynary degradable resin composition and its preparation process
CN104292600A (en) * 2014-09-22 2015-01-21 井冈山大学 Humic acid/EVA (ethylene-vinyl acetate) resin blending-modified degradable solid mulching film
CN104497365A (en) * 2014-12-16 2015-04-08 潍坊华潍新材料科技有限公司 Bentonite/ starch composite degrading material produced by melt intercalation and preparation method

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Application publication date: 20180710

RJ01 Rejection of invention patent application after publication