CN108264300A - A kind of construction material concrete of environmental protection and preparation method thereof - Google Patents

A kind of construction material concrete of environmental protection and preparation method thereof Download PDF

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Publication number
CN108264300A
CN108264300A CN201711345830.8A CN201711345830A CN108264300A CN 108264300 A CN108264300 A CN 108264300A CN 201711345830 A CN201711345830 A CN 201711345830A CN 108264300 A CN108264300 A CN 108264300A
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China
Prior art keywords
parts
concrete
environmental protection
admixture
construction material
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CN201711345830.8A
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Chinese (zh)
Inventor
张如才
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Anhui Jiaxing Metal Materials Co Ltd
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Anhui Jiaxing Metal Materials Co Ltd
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Priority to CN201711345830.8A priority Critical patent/CN108264300A/en
Publication of CN108264300A publication Critical patent/CN108264300A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

Abstract

The invention discloses a kind of construction material concrete of environmental protection and preparation method thereof, including being prepared by the raw material of following parts by weight:85 100 parts of ferrous aluminate cement, 20 30 parts of admixture, 10 25 parts of coarse aggregate, 15 35 parts of diatomite, 10 15 parts of nanoclay, 18 25 parts of polyimide fiber, 10 20 parts of silicon dioxide modified acrylic ester, 20 25 parts of fatty glyceride, 10 15 parts of ammonium hydrogen carbonate, 10 20 parts of wollastonite powder, 5 10 parts of composite expanding agent, 8 15 parts of stabilizer and appropriate amount of water.The present invention is effectively matched using ferrous aluminate cement, admixture, coarse aggregate, diatomite, nanoclay, polyimide fiber, silicon dioxide modified acrylic ester, fatty glyceride, ammonium hydrogen carbonate, wollastonite powder, composite expanding agent, stabilizer, surface, internal fissure caused by the unstructuredness reason such as concrete temperature, drying shrinkage can be effectively prevented, the concrete also has higher shock resistance and anti-permeability performance, it has a safety feature, service life is long.

Description

A kind of construction material concrete of environmental protection and preparation method thereof
Technical field
The present invention relates to concrete for making technical fields, and in particular to a kind of construction material concrete of environmental protection and its preparation Method.
Background technology
In recent years, high strengthening becomes one of trend of modern concrete technology development.The research of high-strength concrete, exploitation work Larger progress is achieved, the intensity of high-strength concrete is gradually increased, performance constantly improve, and is obtained in many fields Extensive use.But as the complication of building structure, high-rise building are increasing, high-strength concrete can not meet construction need Will, the main trend that super high strength concrete will develop as concrete.Countries in the world start to carry out super high strength concrete Theoretical research and engineer application.
Super high strength concrete is a kind of good structural material, it possesses high intensity and excellent endurance quality, can Effectively to lower dead load, increase building using space, and compared to other materials, there is relatively low cost, with The development of China's high-rise building, for super high strength concrete demand also in growth gradually.As modern architecture is towards height Stratification, large span, lightweight, ruthless area development(Cold district, varieties in saline-alkali areas)Requirement to concrete strength is also got over Come it is higher, therefore carry out develop high-strength high-performance concrete have important practical significance.
Deficiency for the poor thermal insulation property for improving normal concrete, building inside/outside closed structure need to add insulating layer.Tradition Thermal insulation material is organic insulation material, and environmental pollution is serious and inflammable, easy to aging, durability is poor when making, and various regions are protected Warm architectural engineering repeated fire incident, and organic insulation material will soon be melted in fire, and smog is big, toxicity is big, very Difficulty is puted out a fire to save life and property, and harm is serious.The fire safety problem of wall heat insulation material is not solved, the Energy Conservation Project in Construction in China will have great Fire hazard, this causes inorganic heat insulation material substitution organic insulation material to become the certainty of historical development and scientific and technological progress.2009 The Nian9Yue20 Ministry of Public Security and the firmly portion's of building joint promulgate public affairs [2009] No. 46 texts of logical word《Civil buildings outer heat preservation system and exterior wall dress Decorations fire prevention temporary provisions》, specific requirement is proposed to civil buildings wall thermal insulation material combustibility rank and fireproof construction.Root According to regulation, the whole exterior walls of civil buildings must use A-grade non-ignitable heat insulating material, and there is an urgent need to not only energy saving but also with resistance in market Fire the building space enclosing structure material, product and its system of contour performance.
Foam concrete is as novel inorganic fireproofing insulation material, and generally existing density is big, and intensity is low and heat insulating ability is too late The defects of organic material, but synthesis is compared, it is still the best replacement of organic combustible material.At present, foam concrete In the application of every field there is no being widely used to promote, mainly due to dry density and compression strength problem.Because foam Coagulation filling's dry density and compression strength index are mutually contradictory, are unity of contradictions bodies.And domestic main research is weight Point is solved under the precondition for reducing foam concrete dry density, how to improve its compression strength and balance foam coagulation Other performances of soil.
Invention content
To solve the above problems, the present invention provides a kind of construction material concrete of environmental protection and preparation method thereof.
To achieve the above object, the technical solution taken of the present invention is:
A kind of construction material concrete of environmental protection and preparation method thereof, including being prepared by the raw material of following parts by weight:Iron aluminium 85-100 parts of acid salt cement, 10-25 parts of coarse aggregate, 15-35 parts of diatomite, 10-15 parts of nanoclay, gathers 20-30 parts of admixture 18-25 parts of imide fiber, 10-20 parts of silicon dioxide modified acrylic ester, 20-25 parts of fatty glyceride, ammonium hydrogen carbonate 10- 15 parts, 10-20 parts of wollastonite powder, 5-10 parts of composite expanding agent, 8-15 parts of stabilizer and appropriate amount of water.
Further, a kind of construction material concrete of environmental protection, including being prepared by the raw material of following parts by weight:Iron aluminium 86-99 parts of acid salt cement, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, 11-14 parts of nanoclay, gathers 21-29 parts of admixture 19-24 parts of imide fiber, 11-18 parts of silicon dioxide modified acrylic ester, 21-24 parts of fatty glyceride, ammonium hydrogen carbonate 11- 14 parts, 12-18 parts of wollastonite powder, 6-9 parts of composite expanding agent, 9-14 parts of stabilizer and appropriate amount of water.
Further, the admixture for sodium bentonite, iron ore waste residue, superfine quartz sand mixture.
Further, the coarse aggregate is the mixture of illite, perlite, pyrophyllite, expanded vermiculite.
Further, a kind of preparation method of the construction material concrete of environmental protection, includes the following steps:
S1,86-99 parts of ferrous aluminate cement, 21-29 parts of admixture, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, nanometer are glued Native 11-14 parts through high temperature flour mill, grinding obtains powder, through high-temperature calcination, then puts into blender plus water is stirred; To mixture A;
S2, by 19-24 parts of polyimide fiber, 11-18 parts of silicon dioxide modified acrylic ester, 21-24 parts of fatty glyceride, 11-14 parts of ammonium hydrogen carbonate is added in another blender, stirring while adding;It is stirred, added steady with the speed of 500-900r/min Determine 9-14 parts of agent to continue to stir 30-50min, obtain mixture B;
S3, it step S1 is obtained to mixture A and step S2 obtains mixture B mixing, add in 12-18 parts of wollastonite powder, composite expanded 6-9 parts of agent is thoroughly mixed;Concrete is made.
Further, a kind of construction material concrete of environmental protection, including being prepared by the raw material of following parts by weight:Iron aluminium 88 parts of acid salt cement, 28 parts of admixture, 18 parts of coarse aggregate, 18 parts of diatomite, 13 parts of nanoclay, 19 parts of polyimide fiber, 15 parts of silicon dioxide modified acrylic ester, 23 parts of fatty glyceride, 13 parts of ammonium hydrogen carbonate, 13 parts of wollastonite powder, composite expanding agent 7 Part, 11 parts of stabilizer and appropriate amount of water.
The present invention is using ferrous aluminate cement, admixture, coarse aggregate, diatomite, nanoclay, polyimide fiber, two Silica modified acrylate, fatty glyceride, ammonium hydrogen carbonate, wollastonite powder, composite expanding agent, stabilizer effectively match, energy Surface, internal fissure caused by the unstructuredness reason such as concrete temperature, drying shrinkage are enough effectively prevented, which also has Higher shock resistance and anti-permeability performance, suitable for mine operation, have a safety feature, good waterproof performance, and service life is long;Price Cheap, simple production process is suitble to large-scale production;By proportion optimizing and rational stabilizer is added, is overcome traditional The defects of regenerated aggregate concrete slump is difficult to control, and intensity is low;The resistance to compression of concrete, anti-folding, tensile strength are increased, is increased Corrosion resistance, rustless property, waterproof, seepage control performance are added.
The structure that concrete one-piece casting of the present invention forms is than the common insulation construction for gluing, hanging, the modes construction such as smearing It is more safe and reliable on the whole, other insulation energy-saving systems can effectively be avoided protective layer cracking easily occur and taken off with finish coat Situation about falling, while can also prevent that heat-insulation system from being wiped off by strong wind and rainwater is oozed to exterior wall inner surface.
Fatty glyceride has higher activity and is porous structure, under the selected moderate dosage of the present invention, with Higher activity improves the later strength of concrete;Meanwhile fatty glyceride plays the work of storage reservoir in concrete With, be conducive to improve inside concrete relative humidity, reduce the self-constriction of super high strength concrete.
Specific embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight:85-100 parts of ferrous aluminate cement, admixture 20-30 Part, 10-25 parts of coarse aggregate, 15-35 parts of diatomite, 10-15 parts of nanoclay, 18-25 parts of polyimide fiber, silica change It is 10-20 parts of acrylate of property, 20-25 parts of fatty glyceride, 10-15 parts of ammonium hydrogen carbonate, 10-20 parts of wollastonite powder, composite expanded 5-10 parts of agent, 8-15 parts of stabilizer and appropriate amount of water.
A kind of construction material concrete of environmental protection, including being prepared by the raw material of following parts by weight:Ferrous aluminate cement 86-99 parts, 21-29 parts of admixture, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, 11-14 parts of nanoclay, polyimides it is fine 19-24 parts of dimension, 11-18 parts of silicon dioxide modified acrylic ester, 21-24 parts of fatty glyceride, 11-14 parts of ammonium hydrogen carbonate, silicon 12-18 parts of ashes, 6-9 parts of composite expanding agent, 9-14 parts of stabilizer and appropriate amount of water.
The admixture is sodium bentonite, the mixture of iron ore waste residue, superfine quartz sand.
The coarse aggregate is illite, the mixture of perlite, pyrophyllite, expanded vermiculite.
A kind of preparation method of the construction material concrete of environmental protection, includes the following steps:
S1,86-99 parts of ferrous aluminate cement, 21-29 parts of admixture, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, nanometer are glued Native 11-14 parts through high temperature flour mill, grinding obtains powder, through high-temperature calcination, then puts into blender plus water is stirred; To mixture A;
S2, by 19-24 parts of polyimide fiber, 11-18 parts of silicon dioxide modified acrylic ester, 21-24 parts of fatty glyceride, 11-14 parts of ammonium hydrogen carbonate is added in another blender, stirring while adding;It is stirred, added steady with the speed of 500-900r/min Determine 9-14 parts of agent to continue to stir 30-50min, obtain mixture B;
S3, it step S1 is obtained to mixture A and step S2 obtains mixture B mixing, add in 12-18 parts of wollastonite powder, composite expanded 6-9 parts of agent is thoroughly mixed;Concrete is made.
Embodiment 1:
A kind of preparation method of the construction material concrete of environmental protection, includes the following steps:
S1, by 88 parts of ferrous aluminate cement, 28 parts of admixture, 18 parts of coarse aggregate, 18 parts of diatomite, 13 parts of nanoclay through high temperature Flour mill, grinding obtain powder, through high-temperature calcination, then put into blender plus water is stirred;Obtain mixture A;
S2, by 19 parts of polyimide fiber, 15 parts of silicon dioxide modified acrylic ester, 23 parts of fatty glyceride, ammonium hydrogen carbonate 13 parts add in another blender, stirring while adding;It is stirred with the speed of 550r/min, adds 14 parts of stabilizer and continue to stir 35min obtains mixture B;
S3, step S1 is obtained mixture A and step S2 obtain mixture B mixing, add in 13 parts of wollastonite powder, composite expanding agent 7 Part is thoroughly mixed;Concrete is made.
Embodiment 2:
A kind of preparation method of the construction material concrete of environmental protection, includes the following steps:
S1, by 99 parts of ferrous aluminate cement, 29 parts of admixture, 24 parts of coarse aggregate, 34 parts of diatomite, 14 parts of nanoclay through high temperature Flour mill, grinding obtain powder, cross 220 mesh sieve, then put into blender plus water is stirred;Obtain mixture A;
S2, by 24 parts of polyimide fiber, 18 parts of silicon dioxide modified acrylic ester, 24 parts of fatty glyceride, ammonium hydrogen carbonate 14 parts add in another blender, stirring while adding;It is stirred with the speed of 900r/min, adds 14 parts of stabilizer and continue to stir 50min obtains mixture B;
S3, step S1 is obtained mixture A and step S2 obtain mixture B mixing, add in 18 parts of wollastonite powder, composite expanding agent 9 Part is thoroughly mixed;Concrete is made.
Embodiment 3:
A kind of preparation method of the construction material concrete of environmental protection, includes the following steps:
S1, by 86 parts of ferrous aluminate cement, 21 parts of admixture, 11 parts of coarse aggregate, 16 parts of diatomite, 11 parts of nanoclay through high temperature Flour mill, grinding obtain powder, cross 200 mesh sieve, then put into blender plus water is stirred;Obtain mixture A;
S2, by 19 parts of polyimide fiber, 11 parts of silicon dioxide modified acrylic ester, 21 parts of fatty glyceride, ammonium hydrogen carbonate 11 parts add in another blender, stirring while adding;It is stirred with the speed of 500r/min, adds 9 parts of stabilizer and continue to stir 30min obtains mixture B;
S3, step S1 is obtained mixture A and step S2 obtain mixture B mixing, add in 12 parts of wollastonite powder, composite expanding agent 9 Part is thoroughly mixed;Concrete is made.
The present invention is using ferrous aluminate cement, admixture, coarse aggregate, diatomite, nanoclay, polyimide fiber, two Silica modified acrylate, fatty glyceride, ammonium hydrogen carbonate, wollastonite powder, composite expanding agent, stabilizer effectively match, energy Surface, internal fissure caused by the unstructuredness reason such as concrete temperature, drying shrinkage are enough effectively prevented, which also has Higher shock resistance and anti-permeability performance, suitable for mine operation, have a safety feature, good waterproof performance, and service life is long;Price Cheap, simple production process is suitble to large-scale production;By proportion optimizing and rational stabilizer is added, is overcome traditional The defects of regenerated aggregate concrete slump is difficult to control, and intensity is low;The resistance to compression of concrete, anti-folding, tensile strength are increased, is increased Corrosion resistance, rustless property, waterproof, seepage control performance are added.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, several improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. a kind of construction material concrete of environmental protection, which is characterized in that including being prepared by the raw material of following parts by weight:Iron aluminium 85-100 parts of acid salt cement, 10-25 parts of coarse aggregate, 15-35 parts of diatomite, 10-15 parts of nanoclay, gathers 20-30 parts of admixture 18-25 parts of imide fiber, 10-20 parts of silicon dioxide modified acrylic ester, 20-25 parts of fatty glyceride, ammonium hydrogen carbonate 10- 15 parts, 10-20 parts of wollastonite powder, 5-10 parts of composite expanding agent, 8-15 parts of stabilizer and appropriate amount of water.
2. the construction material concrete of a kind of environmental protection according to claim 1, which is characterized in that including by following parts by weight Raw material be prepared:86-99 parts of ferrous aluminate cement, 21-29 parts of admixture, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, 11-14 parts of nanoclay, 19-24 parts of polyimide fiber, 11-18 parts of silicon dioxide modified acrylic ester, fatty glyceride 21-24 parts, 11-14 parts of ammonium hydrogen carbonate, 12-18 parts of wollastonite powder, 6-9 parts of composite expanding agent, 9-14 parts of stabilizer and appropriate amount of water.
3. the construction material concrete of a kind of environmental protection according to claim 1, which is characterized in that the admixture is sodium base Bentonite, iron ore waste residue, superfine quartz sand mixture.
4. the construction material concrete of a kind of environmental protection according to claim 1, which is characterized in that the coarse aggregate is Erie Stone, perlite, pyrophyllite, expanded vermiculite mixture.
5. the preparation method of the construction material concrete of a kind of environmental protection according to claim 1, which is characterized in that including such as Lower step:
S1,86-99 parts of ferrous aluminate cement, 21-29 parts of admixture, 11-24 parts of coarse aggregate, 16-34 parts of diatomite, nanometer are glued Native 11-14 parts through high temperature flour mill, grinding obtains powder, through high-temperature calcination, then puts into blender plus water is stirred; To mixture A;
S2, by 19-24 parts of polyimide fiber, 11-18 parts of silicon dioxide modified acrylic ester, 21-24 parts of fatty glyceride, 11-14 parts of ammonium hydrogen carbonate is added in another blender, stirring while adding;It is stirred, added steady with the speed of 500-900r/min Determine 9-14 parts of agent to continue to stir 30-50min, obtain mixture B;
S3, it step S1 is obtained to mixture A and step S2 obtains mixture B mixing, add in 12-18 parts of wollastonite powder, composite expanded 6-9 parts of agent is thoroughly mixed;Concrete is made.
6. the construction material concrete of a kind of environmental protection according to claim 1, which is characterized in that including by following parts by weight Raw material be prepared:88 parts of ferrous aluminate cement, 28 parts of admixture, 18 parts of coarse aggregate, 18 parts of diatomite, nanoclay 13 Part, 19 parts of polyimide fiber, 15 parts of silicon dioxide modified acrylic ester, 23 parts of fatty glyceride, 13 parts of ammonium hydrogen carbonate, silicon 13 parts of ashes, 7 parts of composite expanding agent, 11 parts of stabilizer and appropriate amount of water.
CN201711345830.8A 2017-12-15 2017-12-15 A kind of construction material concrete of environmental protection and preparation method thereof Pending CN108264300A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746994A (en) * 2016-12-19 2017-05-31 芜湖浩权建筑工程有限公司 A kind of superhigh intensity building concrete and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746994A (en) * 2016-12-19 2017-05-31 芜湖浩权建筑工程有限公司 A kind of superhigh intensity building concrete and preparation method thereof

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