CN108264263A - A kind of shell base novel dry powder fire prevention decorative material for internal wall exploitation and its application - Google Patents
A kind of shell base novel dry powder fire prevention decorative material for internal wall exploitation and its application Download PDFInfo
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- CN108264263A CN108264263A CN201810374182.7A CN201810374182A CN108264263A CN 108264263 A CN108264263 A CN 108264263A CN 201810374182 A CN201810374182 A CN 201810374182A CN 108264263 A CN108264263 A CN 108264263A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Abstract
A kind of shell base novel dry powder fire prevention decorative material for internal wall, specifically, the material includes：The oyster shell whiting of 50 100 parts by weight；The rubber powder of 1 30 parts by weight；The thickener of 0.1 30 parts by weight；The fire retardant of 0.1 20 parts by weight；The thermal insulating filling of 0.1 20 parts by weight；The pigment of 0.1 5 parts by weight；The Whiting filler of 1 50 parts by weight；And 0.1 20 parts by weight auxiliary agent.The material of the present invention have the advantages that fire prevention, it is environmentally friendly, be easy to carry about with one and at low cost.
Description
Technical field
The present invention relates to fire prevention decorative material for internal wall, and in particular to a kind of shell base novel dry powder fire prevention inner wall decoration material
Material.
Background technology
Nearly 2 years explosive fire accident Frequent Accidents, caused by casualties and property loss it is countless.In order to meet people
To beautiful pursuit, modern times finishing interior is generally all decorated with a coating.This coating is not prevented fires typically or easily
Fuel wood matter, and toxic and harmful gas can be decomposited under high temperature.While people are met to beautiful pursuit, a weight is also become
Big security risk.Be applied to flammable substrates surface, to change material surface combustion characteristics, retardance fire spread rapidly or
It is applied on building element, to improve the sapecial coating of the fire endurance of component, claims fireproof coating.The statistical number of fire control and disaster rescue
Burn lethal ratio very little from the point of view of, in the scene of a fire, and the lethal ratio of flue gas is up to 75%-80%.Accordingly, it is outer in the industry to have
People meets fireproof coating the safety after fire and queries, it is believed that its combustion product is not to fleeing from the personnel and fire fighter in the scene of a fire
It is a serious injury, while very big environmental pollution will be caused.
Oil paint is in the majority in the market in recent years, such coating using organic solvent as decentralized medium, coating mainly into
It is divided into organic molecule ingredient, such coating is inflammable, and organic solvent and organic matter are easy to volatilize.Not only pollute the environment and
And the health of damage people.The C-N-P or C-N- that most expanding fire-proof paint fire retardants (CN106957586A) use
P-Cl systems use the chemical substances such as a large amount of melamine, ammonium polyphosphate, ammonium borate, chlorinated paraffin, have been decomposited after heated
Malicious pernicious gas, such as NH3、HCl、NOX, CO etc..
Influence of the solid waste to environment has been to be concerned by more and more people, by various solid waste recyclings
The research direction new through becoming Material Field.With the fast development of China's mariculture industry, shell is to the dirt of coastal area environment
Dye influence is increasing, and shell pollution has become one of coastal area environmental problem urgently to be resolved hurrily.
In conclusion this field there is an urgent need for it is a kind of with fire-proof function, shell base at low cost, with now with the current function it is new
Type fire prevention decorative material for internal wall.
Invention content
The purpose of the present invention is prepare it is a kind of with fire-proof function, shell base at low cost, with now with the current function it is new
Type fire prevention decorative material for internal wall.
First aspect present invention prepares a kind of shell base novel dry powder fire prevention decorative material for internal wall, specifically, the material
Material includes：
In another preferred example, the thermal insulating filling is selected from the group：Expanded perlite, expanded vermiculite, hollow glass are micro-
Pearl, sepiolite, aerosil or combination.
In another preferred example, the Whiting filler is selected from the group：Talcum powder, dry powder, titanium dioxide or combination.
In another preferred example, the auxiliary agent is selected from the group：Plasticizer, stabilizer, waterproofing agent, anti-blushing agent, wetting point
Powder, mould inhibitor or combination.
Wherein, the material is also comprising silicate, phosphate or combination.
In another preferred example, the rubber powder is selected from the group：Vinylacetate and ethylene copolymer rubber powder, vinylacetate
With ethylene and higher aliphatic vinyl acetate ternary polymerization rubber powder, vinylacetate and higher aliphatic vinyl acetate copolymerization rubber powder, vinegar
Vinyl acetate homopolymerization rubber powder or combination.
In another preferred example, the rubber powder is dispersion vinylacetate and ethylene copolymer rubber powder.
In another preferred example, the thickener is selected from the group：Cellulose, carboxymethyl cellulose, hydroxypropyl methylcellulose
Element, phosphorylated cellulose, chitin, chitosan, gellan gum, xanthans or combination.
In another preferred example, the thickener is phosphorylated cellulose.
In another preferred example, the fire retardant is inorganic salts fire retardant.
In another preferred example, the inorganic salts fire retardant is selected from the group：Magnesium hydroxide, zinc borate, aluminium hydroxide, three
Aoxidize two antimony, silicon antimony oxide, borate, modified barium metaborate or combination.
In another preferred example, the oyster shell whiting includes：
By the oyster shell whiting 5-45 parts by weight of resolution calcining；
Without the oyster shell whiting 45-85 parts by weight of resolution calcining.
In another preferred example, the oyster shell whiting by resolution calcining includes：
1000-2000 mesh clears up calcined shell powder 5-25 parts by weight；
800-1000 mesh clears up calcined shell powder 5-20 parts by weight；
600-800 mesh clears up calcined shell powder 1-20 parts by weight.
In another preferred example, the oyster shell whiting without resolution calcining includes：
600-800 mesh is without resolution calcined shell powder 5-30 parts by weight；
400-600 mesh is without resolution calcined shell powder 10-50 parts by weight；
300-400 mesh is without resolution calcined shell powder 1-15 parts by weight.
The second aspect of the present invention provides a kind of new coating, and the preparation of the new coating includes step：
(a) material described in first aspect present invention is taken to mix in proportion, adds in water at the construction field (site)；(b) it stirs
It mixes,
Wherein, the weight part ratio of the material and water is 1：1.5-2.2.
It should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the invention and have in below (eg embodiment)
It can be combined with each other between each technical characteristic of body description, so as to form new or preferred technical solution.As space is limited, exist
This no longer tires out one by one states.
Specific embodiment
The present inventor after extensive and in-depth study, researches and develops a kind of shell with fire-proof function and environment protection health for the first time
Base novel fire prevention decorative material for internal wall.The fire prevention decorative material for internal wall is dry powder paint, easy to carry, can be showed at the construction field (site)
With now matching；It is compounded and prepared using different meshes oyster shell whiting, structure is finer and close in coating film forming procedure；The calcining resolution shellfish of addition
On the one hand shell powder can absorb heat in hot conditions decomposition and have certain inhibition exhaust gas dust effect, on the other hand clear up shellfish
Shell powder can be partially converted to calcium carbonate as time went on, further make metope densification and hard；Main component is inorganic salts, is contained
There is minimal amount of rubber powder, be not likely to produce electrostatic and with preferable fire retardant performance；Modified cellulose and biological polyoses plus
Enter, further improve material cohesion；With porous structure, there is absorption pernicious gas, purify the effect of eliminating atmosphere peculiar smell, and
And indoor air humidity can be adjusted；The fire prevention decorative material for internal wall is free of toxic and harmful gas, can be after brushing
When move in, on this basis complete the present invention.
Term
In the present invention, unless stated otherwise, term " dispersion vinylacetate and ethylene copolymer rubber powder ", " cellulose ",
" carboxymethyl cellulose ", " hypromellose ", " phosphorylated cellulose ", " gellan gum " and " xanthans " and this field are skilled
It is identical that personnel are familiar with meaning.
As used herein, term " shell base novel dry powder fire prevention decorative material for internal wall " or " material " are used interchangeably, and are referred to
A kind of shell base novel dry powder fire prevention decorative material for internal wall described in first aspect present invention.
Shell base novel dry powder fire prevention decorative material for internal wall
A kind of shell base novel dry powder fire prevention decorative material for internal wall of the present invention, typically, the material includes：
In another preferred example, the material is also comprising silicate, phosphate or combination.
In another preferred example, the thermal insulating filling is selected from the group：Expanded perlite, expanded vermiculite, hollow glass are micro-
Pearl, sepiolite, aerosil or combination.
In another preferred example, the Whiting filler is selected from the group：Talcum powder, dry powder, titanium dioxide or combination.
In another preferred example, the auxiliary agent is selected from the group：Plasticizer, stabilizer, waterproofing agent, anti-blushing agent, wetting point
Powder, mould inhibitor or combination.
In another preferred example, the rubber powder is selected from the group：Vinylacetate and ethylene copolymer rubber powder, vinylacetate
With ethylene and higher aliphatic vinyl acetate ternary polymerization rubber powder, vinylacetate and higher aliphatic vinyl acetate copolymerization rubber powder, vinegar
Vinyl acetate homopolymerization rubber powder or combination.
In another preferred example, the rubber powder is dispersion vinylacetate and ethylene copolymer rubber powder.
In another preferred example, the thickener is selected from the group：Cellulose, carboxymethyl cellulose, hydroxypropyl methylcellulose
Element, phosphorylated cellulose, chitin, chitosan, gellan gum, xanthans or combination.
In another preferred example, the thickener is phosphorylated cellulose.
In another preferred example, the fire retardant is inorganic salts fire retardant.
In another preferred example, the inorganic salts fire retardant is selected from the group：Magnesium hydroxide, zinc borate, aluminium hydroxide, three
Aoxidize two antimony, silicon antimony oxide, borate, modified barium metaborate or combination.
Oyster shell whiting
A kind of shell base novel dry powder fire prevention decorative material for internal wall of the present invention, wherein the oyster shell whiting includes：
By the oyster shell whiting 5-45 parts by weight of resolution calcining；
Without the oyster shell whiting 45-85 parts by weight of resolution calcining.
In another preferred example, the oyster shell whiting by resolution calcining includes：
1000-2000 mesh clears up calcined shell powder 5-25 parts by weight；
800-1000 mesh clears up calcined shell powder 5-20 parts by weight；
600-800 mesh clears up calcined shell powder 1-20 parts by weight.
In another preferred example, the oyster shell whiting without resolution calcining includes：
600-800 mesh is without resolution calcined shell powder 5-30 parts by weight；
400-600 mesh is without resolution calcined shell powder 10-50 parts by weight；
300-400 mesh is without resolution calcined shell powder 1-15 parts by weight.
A kind of new coating
A kind of preparation of new coating includes step：
(a) material as described in the present invention is taken to mix in proportion, adds in water at the construction field (site)；With
(b) it stirs,
Wherein, the weight part ratio of the material and water is 1：1.5-2.2.
Invention advantage
1st, it is fully applicable in inner wall decoration, there is fire prevention and advantage at low cost.
2nd, shell base novel fire prevention decorative material for internal wall is dry powder paint, is easy to carry about with one.
When the 3rd, being constructed using shell base novel fire prevention decorative material for internal wall, decentralized medium is water, and based on oyster shell whiting
Raw material is wanted, there is superior fire line.
4th, without toxic and harmful gas.
5th, there is breathing damping, antibacterial bacteriostatic, adsorption cleaning, eliminate peculiar smell, prevent light pollution, preventing electrostatic, noise reduction every
The advantages that sound is easy to repair, and service life is long.
6th, material can absorb heat and generate with the dust for inhibiting flue gas under the high temperature conditions.
7th, calcium carbonate can be partially converted to using the oyster shell whiting of resolution calcining, oyster shell whiting as time went in material, into
One step promotes metope densification and hard.
8th, the main component of material is inorganic salts, is not likely to produce electrostatic, is easy to arrange and repair.
9th, modified cellulose and microbial polysaccharide are added in material, further improves material cohesion.
10th, oyster shell whiting has porous structure, which has the function of adsorption cleaning eliminating atmosphere peculiar smell.
11st, using superfine oyster shell whiting is ground in material of the invention, oyster shell whiting is good with rubber powder compatibility, so as to reduce glue
Powder usage amount improves fire retardant performance.
12nd, material of the invention is used in compounding using different meshes oyster shell whiting, and structure more causes during making material filming
It is close.
With reference to specific embodiment, the present invention is further explained.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.Test method without specific conditions in the following example, usually according to conventional strip
Part or according to the normal condition proposed by manufacturer.Unless otherwise stated, otherwise percentage and number are calculated by weight.
According to standard GB12441-2005《Finishing fire retardant paint》It is tested, wherein the resistance to combustion time is burnt by big plate
Method measures, flame propagation ratio is measured by combustion tunnel method, mass loss and carbonization volume are measured by cell combustion method, adorns
Face type fireproof coating technical indicator is as shown in table 1.
Table 1
| Serial number | Project | Technical indicator | Defect classification |
| 1 | Resistance to combustion time/(min) | ≥15 | A |
| 2 | Flame propagation ratio | ≤21 | A |
| 3 | Mass loss/(g) | ≤5.0 | A |
| 4 | Be carbonized volume/(cm3) | ≤25.0 | A |
According to standard GB18582-2008《Limits of harmful substances in indoor hardware fitting interior wall coating》Harmful substance is contained
Amount is detected, and limits of harmful substances is as shown in table 2.
Table 2
Embodiment 1
50 parts of oyster shell whiting, 10 parts of redispersable latex powder, 0.5 part of hydroxypropyl methyl cellulose, 5 parts of fire retardant are heat-insulated to fill out
10 parts of material, 20 parts of Whiting filler, 1 part of pigment, 0.1 part of stabilizer, 0.2 part of mould inhibitor.Coating at the construction field (site) by with water 1:
1.8 quality proportionings are stirred, and are brushed.
Embodiment 2
50 parts of oyster shell whiting, 10 parts of redispersable latex powder, 0.5 part of hydroxypropyl methyl cellulose, 10 parts of fire retardant are heat-insulated to fill out
10 parts of material, 20 parts of Whiting filler, 1 part of pigment, 0.1 part of stabilizer, 0.2 part of mould inhibitor.Coating at the construction field (site) by with water 1:
1.8 quality proportionings are stirred, and are brushed.
Embodiment 3
50 parts of oyster shell whiting, 5 parts of sodium metasilicate, 8 parts of redispersable latex powder, 0.8 part of phosphorylated cellulose, 5 parts of fire retardant, every
Hot 10 parts of filler, 20 parts of Whiting filler, 1 part of pigment, 0.1 part of stabilizer, 0.2 part of mould inhibitor.Coating at the construction field (site) by with
Water 1:1.5 quality proportionings are stirred, and are brushed.
Comparative example
30 parts of oyster shell whiting, 40 parts of redispersable latex powder, 0.8 part of hydroxypropyl methyl cellulose, 5 parts of fire retardant are heat-insulated to fill out
10 parts of material, 20 parts of Whiting filler, 1 part of pigment, 0.1 part of stabilizer, 0.2 part of mould inhibitor.Coating at the construction field (site) by with water 1:
2.0 quality proportionings are stirred, and are brushed.
The finishing fire retardant paint technical indicator testing result of embodiment and comparative example is as shown in table 3.
Table 3
| Inspection project | Resistance to combustion time/(min) | Flame propagation ratio | Mass loss/(g) | Be carbonized volume/(cm3) |
| Standard requirement | ≥15 | ≤25 | ≤5.0 | ≤25 |
| Embodiment 1 | 16 | 21 | 4 | 21 |
| Embodiment 2 | 18 | 22 | 4 | 20 |
| Embodiment 3 | 21 | 21 | 3 | 22 |
| Comparative example | 12 | 28 | 8 | 29 |
The finishing fire retardant paint limits of harmful substances of embodiment and comparative example is as shown in table 4.
Table 4
The performance test results：It is compared compared with embodiment 1, embodiment 2 with embodiment 3, comparative example fire resistance period is short, flame propagation
Ratio is big, mass loss is big and carbonization volume is big, and fire resistance is poor.And the shell base novel dry powder fire prevention inner wall decoration of the present invention
Material is dry powder paint, is easy to carry about with one, and has fire prevention, nontoxic and at low cost advantage.
All references mentioned in the present invention is incorporated herein by reference, independent just as each document
It is incorporated as with reference to such.In addition, it should also be understood that, after reading the above teachings of the present invention, those skilled in the art can
To be made various changes or modifications to the present invention, such equivalent forms equally fall within the model that the application the appended claims are limited
It encloses.
Claims (10)
- The decorative material for internal wall 1. a kind of shell base novel dry powder is prevented fires, which is characterized in that the material includes：
- 2. material as described in claim 1, which is characterized in that the material is also comprising silicate, phosphate or combination.
- 3. material as described in claim 1, which is characterized in that the oyster shell whiting includes：By the oyster shell whiting 5-45 parts by weight of resolution calcining；Without the oyster shell whiting 45-85 parts by weight of resolution calcining.
- 4. material as claimed in claim 3, which is characterized in that the oyster shell whiting by resolution calcining includes：1000-2000 mesh clears up calcined shell powder 5-25 parts by weight；800-1000 mesh clears up calcined shell powder 5-20 parts by weight；600-800 mesh clears up calcined shell powder 1-20 parts by weight.
- 5. material as claimed in claim 3, which is characterized in that the oyster shell whiting without resolution calcining includes：600-800 mesh is without resolution calcined shell powder 5-30 parts by weight；400-600 mesh is without resolution calcined shell powder 10-50 parts by weight；300-400 mesh is without resolution calcined shell powder 1-15 parts by weight.
- 6. material as described in claim 1, which is characterized in that the rubber powder is selected from the group：Vinylacetate and ethylene It is copolymerized rubber powder, vinylacetate and ethylene and higher aliphatic vinyl acetate ternary polymerization rubber powder, vinylacetate and higher aliphatic Vinyl acetate copolymerization rubber powder, vinylacetate homopolymerization rubber powder or combination.
- 7. material as described in claim 1, which is characterized in that the thickener is selected from the group：Cellulose, carboxymethyl are fine Tie up element, hypromellose, phosphorylated cellulose, chitin, chitosan, gellan gum, xanthans or combination.
- 8. material as described in claim 1, which is characterized in that the fire retardant is inorganic salts fire retardant.
- 9. material as claimed in claim 8, which is characterized in that the inorganic salts fire retardant is selected from the group：Magnesium hydroxide, Zinc borate, aluminium hydroxide, antimony oxide, silicon antimony oxide, borate, modified barium metaborate or combination.
- 10. a kind of new coating, which is characterized in that the preparation of the new coating includes step：(a) material as described in claim 1 is taken to mix in proportion, adds in water at the construction field (site)；With(b) it stirs,Wherein, the weight part ratio of the material and water is 1：1.5-2.2.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810374182.7A CN108264263B (en) | 2018-04-24 | 2018-04-24 | Shell-based dry powder fireproof interior wall decorative material and application thereof |
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| CN201810374182.7A CN108264263B (en) | 2018-04-24 | 2018-04-24 | Shell-based dry powder fireproof interior wall decorative material and application thereof |
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| CN108264263B CN108264263B (en) | 2021-01-26 |
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| CN110358333A (en) * | 2019-08-09 | 2019-10-22 | 岭南师范学院 | A kind of shell powder paint and preparation method thereof |
| CN111040477A (en) * | 2019-11-27 | 2020-04-21 | 惠州学院 | Dry powder coating with lasting antibacterial and mildew-proof effects and preparation method thereof |
| CN115340322A (en) * | 2022-08-25 | 2022-11-15 | 安徽中科思沃生物科技有限公司 | Shell powder-based light sound insulation exterior wall coating and preparation method thereof |
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| CN110358333A (en) * | 2019-08-09 | 2019-10-22 | 岭南师范学院 | A kind of shell powder paint and preparation method thereof |
| CN111040477A (en) * | 2019-11-27 | 2020-04-21 | 惠州学院 | Dry powder coating with lasting antibacterial and mildew-proof effects and preparation method thereof |
| CN115340322A (en) * | 2022-08-25 | 2022-11-15 | 安徽中科思沃生物科技有限公司 | Shell powder-based light sound insulation exterior wall coating and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN108264263B (en) | 2021-01-26 |
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