CN108261910A - A kind of washing ammonia desulfuration equipment - Google Patents

A kind of washing ammonia desulfuration equipment Download PDF

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Publication number
CN108261910A
CN108261910A CN201810275933.XA CN201810275933A CN108261910A CN 108261910 A CN108261910 A CN 108261910A CN 201810275933 A CN201810275933 A CN 201810275933A CN 108261910 A CN108261910 A CN 108261910A
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CN
China
Prior art keywords
layer
water pipe
cooling water
tower
cooling
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Pending
Application number
CN201810275933.XA
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Chinese (zh)
Inventor
钟璐
胡小吐
刘勇
杨颖欣
胡静龄
薛学良
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Guangdong Jiade Environmental Protection Technology Co Ltd
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Guangdong Jiade Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Guangdong Jiade Environmental Protection Technology Co Ltd filed Critical Guangdong Jiade Environmental Protection Technology Co Ltd
Priority to CN201810275933.XA priority Critical patent/CN108261910A/en
Publication of CN108261910A publication Critical patent/CN108261910A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention is a kind of washing ammonia desulfuration equipment, including the prewashing tower connected by interface channel and absorption tower, the prewashing top of tower is provided with kiln gas air inlet, kiln gas gas outlet is provided at the top of the absorption tower, being disposed with aerosol cohesion along smoke movement direction inside the prewashing tower washes layer, spraying layer, circulating cooling layer.Flue gas is handled using the present invention, on the basis of spraying layer cooling, one layer of circulating cooling layer is superimposed, mass-and heat-transfer effect is carried out between increase and flue gas, improve the abjection ability of back segment electrostatic precipitator, is the deep purifying processing to flue gas.

Description

A kind of washing ammonia desulfuration equipment
Technical field
The present invention relates to ammonia desulfuration equipments, and in particular to a kind of washing ammonia desulfuration equipment.
Background technology
Increase aerosol cohesion water wash system in the prewashing tower of ammonia desulfuration equipment, the basic function of aerosol washing system is logical It crosses using aerosol two-fluid spray system, clear water atomization is generated into a large amount of droplets, is significantly increased and aerosol subtle in flue gas Contact probability, so as to improve desulfurization dust-removing efficiency.
CN204933781U discloses a kind of air atomization spray gun, including inner sleeve, is arranged on inner sleeve wherein one end Air cap and connection be arranged on the water inlet pipe and air inlet pipe of inner sleeve the other end, the inner sleeve with air cap It stretches into desulfurizing tower, is additionally provided with adjusting retaining mechanism, adjusting locking in the middle part of the inner sleeve between desulfurizing tower Mechanism includes being fixed at ring flange at the top of desulfurizing tower, is fixed on ring flange and externally threaded company is offered in outside wall surface Female connector, collet and lock nut.However, although this method discloses the spray gun that may be used in aerosol, but wash system It is not high that bulk cargo puts efficiency of dust collection.
CN205731707U discloses a kind of ammonia desulfuration equipment with aerosol coacervation water wash system device, specifically discloses Spray gun, prewashing tower, water circuit system and air-channel system are connected between the aerosol coacervation water wash system and desulfurizing tower by interface channel It connects, the spray gun is distributed in the tower top, Ta Nei and interface channel of prewashing tower, and the tower top sets two spray guns, is set in tower One spray gun, interface channel one spray gun of interior setting;The nozzle of two spray guns of the tower top is placed in prewashing tower downward.So And the method use excessive water resource, meanwhile, it cannot slowly become slant acidity after the water resource and smoke reaction that use, It cannot recycle.Therefore, it not only pollutes the environment, but also also creates a large amount of waste.
Therefore, the prior art lacks a kind of relative energy-saving environmental protection, water-saving washing ammonia desulfuration equipment.
Invention content
To solve the above problems, the present invention provides a kind of washing ammonia desulfuration equipment, it can not only pass through atomized water and cigarette Mass-and heat-transfer effect is carried out between gas, further reduces flue-gas temperature, makes the aerosol particle object of the water vapour and remaining in flue gas It is condensed on water mist particle, droplet is made to grow up, to further improve demisting efficiency, and use recirculated cooling water and spray equipment Cooperation, can be with using water wisely and environmental protection.
Concrete scheme of the present invention is as follows:
A kind of washing ammonia desulfuration equipment, including the prewashing tower connected by interface channel and absorption tower, the prewashing tower Top is provided with kiln gas air inlet, is provided with kiln gas gas outlet at the top of the absorption tower, along flue gas inside the prewashing tower The direction of motion is disposed with aerosol cohesion washing layer, spraying layer, circulating cooling layer.
In the actual production process, pending flue gas is generally the larger situation of the exhaust gas volumns such as coal-burning power plant, standard Exhaust gas volumn is generally 30000-50000Nm3/ h, and flue-gas temperature is 130 DEG C or so.Therefore, only only spraying cooling, cooling Time is short, and cooling capacity is limited, and cooling efficiency is in contrast than relatively low.Therefore, on the basis of spraying layer cooling, superposition one Layer circulating cooling layer, carries out mass-and heat-transfer effect between increase and flue gas, significantly reduce the temperature of flue gas, for absorption below Tower, which is further processed, provides very big facility.
Preferably, the circulating cooling layer connects successively with cooling water tank, cooling water pump cycle.
Preferably, the circulating cooling layer includes cooling water pipe and water pipe fixing device, the water pipe fixing device The cooling water pipe is fixed on to the inner wall of the prewashing tower.
Preferably, the circulating cooling layer includes the flow slowing down net being arranged on around the cooling water pipe tube body, institute Flow slowing down net is stated as porous wire netting.Porous wire netting not only can also slow down spray liquid with reducing smoke flowing velocity Water velocity, not only increase the gas heat exchanger time of flue gas and cooling water pipe, also increase the gas heat of flue gas and spray liquid Swap time further increases the cooling effect of flue gas.
Preferably, the cooling water pipe is from top to bottom multilayer equidistant placement, quadrature arrangement between upper and lower two layers is described Cooling water pipe shares 10-20 layers, and the ratio between the distance between every layer and the caliber of the cooling water pipe are 1:1-3.This arrangement side Formula, space availability ratio is high, good cooling results.
Preferably, on the flow slowing down network arrangements and under be disposed with three layers, top layer's screen size is 2.00- 4.00mm, that is, 5 mesh to 10 mesh, middle layer screen pore size are 2.00-0.850mm, that is, -20 mesh of 10 mesh, top layer's sieve Pore size is 0.850-0.300mm, that is, -50 mesh of 20 mesh.Screen size is very few, the air resistance that comparison can be brought high, and Screen size is excessive, will not bring relatively good slowing effect.Therefore, screen size is reduced successively using three layers, it can band Carry out proper slowing effect, advantageously promote makings heat transfer.
Preferably, length of the cooling water pipe in prewashing tower inner height direction is the 1/4-1/3 of prewashing tower height degree.Only Guaranteed certain height, had not only interfered with the pattern of prewashing tower entirety, but also can guarantee the time of contact of flue gas and cooling water, into And ensure the efficiency of cooling.
Preferably, the spraying layer is connected with Sprayer Circulation water pump cycle, the flow set of the Sprayer Circulation water pump For 10-20m3/ h, the flow set of the cooling water pump is 10-100m3/ h, the volume of the cooling water tank is 100-1000m3。 30000-50000Nm is generally according to standard fume amount3/ h, and flue-gas temperature is 130 DEG C or so, according to actual condition, design Rational technological parameter ensure that air-flow cooling effect.
Preferably, the interface channel inner upper is provided with spray gun.
Preferably, the spray gun includes gun shot and nozzle, the nozzle is welded on one end of gun shot, the nozzle Angle with gun shot is 90-180 °, and the nozzle is equipped with 3-20 spray orifice, and the spray orifice is evenly distributed on nozzle, described The diameter range of spray orifice is 0.1-3mm;The other end of the gun shot is equipped with air hose and water pipe, the air hose and water pipe Aperture ratio is 1:0.8~1.2, a diameter of 20-100mm of the air hose.
Beneficial effects of the present invention:
1. the present invention on the basis of spraying layer cooling, is superimposed one layer of circulating cooling layer, mass transfer is carried out between increase and flue gas Heat transfer effect greatly improves flue gas cooling effect so that prewashing tower slurries spray carries out at low temperature, reduces ammonium sulfite Volatilization, it is possible to reduce the generation of aerosol;
2. cooling water pipe and air-flow speed reduction screen cooperate, the heat exchanger time of air-flow and liquid is increased, is further carried High cooling effect;
3. the present invention increases specific surface using spray gun atomization technique atomized water, increase what is collided with each other with microfluidic aerosol intergranular Frequency simultaneously occurs to agglomerate coalescence phenomenon, molecule is made to become larger particles, these particles are easy to the electric demisting in back segment It is removed in device, it is more preferable than increasing one layer of slurries spraying effect newly in prewashing tower, it is energy saving.
4. the present invention is not only more environmentally-friendly efficient, but also water resource is greatly saved.
Description of the drawings
Fig. 1 apparatus main body structure diagrams;
Fig. 2 Section A-A sectional views.
Reference numeral:Prewashing tower 1, absorption tower 2, kiln gas air inlet 3, kiln gas gas outlet 4, aerosol cohesion washing layer 5, Spraying layer 6, circulating cooling layer 7, Sprayer Circulation water pump 8, circulating chilled water water pump 9, cooling water tank 10, spray gun 11, interface channel 12, Cooling water pipe 13, flow slowing down net 14, water pipe fixing device 15.
Specific embodiment
The specific embodiment of the present invention is described further below:
A kind of washing ammonia desulfuration equipment, as depicted in figs. 1 and 2, including 1 He of prewashing tower connected by interface channel 12 Absorption tower 2,1 top of prewashing tower are provided with kiln gas air inlet 3, and 2 top of absorption tower is provided with kiln gas gas outlet 4, aerosol cohesion washing layer 5, spraying layer 6, circulating cooling layer 7 are disposed with along smoke movement direction inside the prewashing tower 1. The circulating cooling layer 7 connects successively with cooling water tank 10, the cycle of cooling water pump 9.The spraying layer 6 and Sprayer Circulation water pump 8 Cycle connection.12 inner upper of interface channel is provided with spray gun 11.The circulating cooling layer 7 includes 13 He of cooling water pipe The cooling water pipe 13 is fixed on the inner wall of the prewashing tower 1 by water pipe fixing device 15, the water pipe fixing device 15.It is described Circulating cooling layer 7 includes the flow slowing down net 14 being arranged on around 13 tube body of cooling water pipe, and the flow slowing down net 14 is Porous wire netting.
Preferably, the cooling water pipe 13 is from top to bottom multilayer equidistant placement, and quadrature arrangement between upper and lower two layers, institute It states cooling water pipe 13 and shares 10-20 layers, the ratio between the distance between every layer and the caliber of the cooling water pipe 13 are 1:1-3.It is this Arrangement, space availability ratio is high, good cooling results.
Preferably, on the flow slowing down net 14 arrangement and under be disposed with three layers, top layer's screen size is 2.00- 4.00mm, that is, 5 mesh to 10 mesh, middle layer screen pore size are 2.00-0.850mm, that is, -20 mesh of 10 mesh, top layer's sieve Pore size is 0.850-0.300mm, that is, -50 mesh of 20 mesh.Screen size is very few, the air resistance that comparison can be brought high, and Screen size is excessive, will not bring relatively good slowing effect.Therefore, screen size is reduced successively using three layers, it can band Carry out proper slowing effect, advantageously promote makings heat transfer.
Preferably, length of the cooling water pipe in prewashing tower inner height direction is the 1/4-1/3 of prewashing tower height degree.Only Guaranteed certain height, had not only interfered with the pattern of prewashing tower entirety, but also can guarantee the time of contact of flue gas and cooling water, into And ensure the efficiency of cooling.
Preferably, the spraying layer is connected with Sprayer Circulation water pump cycle, the flow set of the Sprayer Circulation water pump For 10-20m3/ h, the flow set of the cooling water pump is 10-100m3/ h, the volume of the cooling water tank is 100-1000m3。 30000-50000Nm is generally according to standard fume amount3/ h, and flue-gas temperature is 130 DEG C or so, according to actual condition, design Rational technological parameter ensure that air-flow cooling effect.
Preferably, the spray gun includes gun shot and nozzle, the nozzle is welded on one end of gun shot, the nozzle Angle with gun shot is 90-180 °, and the nozzle is equipped with 3-20 spray orifice, and the spray orifice is evenly distributed on nozzle, described The diameter range of spray orifice is 0.1-3mm;The other end of the gun shot is equipped with air hose and water pipe, the air hose and water pipe Aperture ratio is 1:0.8~1.2, a diameter of 20-100mm of the air hose.
The direction of motion of absorption tower 2 along the kiln gas is disposed with washing tower tray, packing layer, spraying layer, electric demisting Device, wet electrical dust precipitator.The washing tower tray is eddy flow gas cap tower tray.Described filler layer is ceramic packing.Wash tower tray, filler The absorption tower washing layer of layer, spraying layer composition, realizes low concentration clear water three-level circulating water wash, to the ammonia and sulfuric acid of flue gas entrainment Ammonium is washed, and can substantially reduce flue gas entrainment, water washing device and packing layer, is improved desulphurizing ability, is reduced aerosol It generates, strengthens the trapping to subtle aerosol and washing, increase grain size, promote the removal efficiency to aerosol.Refer to patent one The water washing device (CN 206343056U) of kind high efficiency removing aerosol.Before the electrostatic precipitator is arranged on wet electrical dust precipitator It face can be with smooth air-flow;Wet electrical dust precipitator includes the cellular electroconductive frp anode tube of regular hexagon, titanium pole discharge lines and height Pulased power supply unit is pressed, the output terminal connection titanium pole discharge lines of high-voltage pulse electric source device, the high-voltage pulse power source is base pressure The high voltage power supply that superimposed pulse voltage integrates, titanium pole discharge lines are located at the center of anode tube.It refers to patent one kind and is based on arteries and veins Rush the new and effective wet type electric precipitator (205887177 U of CN) of power supply.
Flue gas is handled using the present invention, on the basis of spraying layer cooling, is superimposed one layer of circulating cooling layer, increase and flue gas Between carry out mass-and heat-transfer effect, be conducive to the absorption to subtle aerosol, coacervation, grain size increase, improve back segment electrostatic precipitator Abjection ability is the deep purifying processing to flue gas.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula is changed and is changed.Therefore, the invention is not limited in specific embodiment disclosed and described above, to the one of invention A little modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, it although is used in this specification Some specific terms, but these terms are merely for convenience of description, do not limit the present invention in any way.

Claims (10)

1. a kind of washing ammonia desulfuration equipment, including the prewashing tower connected by interface channel and absorption tower, the prewashing tower top Portion is provided with kiln gas air inlet, is provided with kiln gas gas outlet at the top of the absorption tower, which is characterized in that in the prewashing tower Portion is disposed with aerosol cohesion washing layer, spraying layer, circulating cooling layer along smoke movement direction.
2. the apparatus according to claim 1, which is characterized in that the circulating cooling layer successively with cooling water tank, cooling water Pump circulation connects.
3. the apparatus of claim 2, which is characterized in that the circulating cooling layer includes cooling water pipe and water pipe is consolidated Determine device, the cooling water pipe is fixed on the inner wall of the prewashing tower by the water pipe fixing device.
4. device according to claim 3, which is characterized in that the circulating cooling layer includes being arranged on the cooling water pipe Flow slowing down net around tube body, the flow slowing down net are porous wire netting.
5. device according to claim 3 or 4, which is characterized in that the cooling water pipe is the equidistant cloth of multilayer from top to bottom Put, quadrature arrangement between upper and lower two layers, the cooling water pipe shares 10-20 layers, the distance between every layer with the cooling water pipe The ratio between caliber be 1:1-3.
6. device according to claim 4, which is characterized in that be disposed with three under on the flow slowing down network arrangements Layer, top layer's screen size are 2.00-4.00mm, and middle layer screen pore size is 2.00-0.850mm, and top layer's screen size is 0.850-0.300mm。
7. device according to claim 3 or 4, which is characterized in that the cooling water pipe is in prewashing tower inner height direction Length is the 1/4-1/3 of prewashing tower height degree.
8. the apparatus of claim 2, which is characterized in that the spraying layer is connected with Sprayer Circulation water pump cycle, institute The flow set for stating Sprayer Circulation water pump is 10-20m3/ h, the flow set of the cooling water pump is 10-100m3/ h is described cold But the volume of water tank is 100-1000m3
9. device according to claim 1 or 2, which is characterized in that the interface channel inner upper is provided with spray gun.
10. device according to claim 9, which is characterized in that the spray gun includes gun shot and nozzle, the nozzle weldering It is connected on one end of gun shot, the angle of the nozzle and gun shot is 90-180 °, and the nozzle is equipped with 3-20 spray orifice, described Spray orifice is evenly distributed on nozzle, and the diameter range of the spray orifice is 0.1-3mm;The other end of the gun shot is equipped with air hose And water pipe, the aperture ratio of the air hose and water pipe is 1:0.8~1.2, a diameter of 20-100mm of the air hose.
CN201810275933.XA 2018-03-30 2018-03-30 A kind of washing ammonia desulfuration equipment Pending CN108261910A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108619880A (en) * 2018-07-24 2018-10-09 中电环保科技发展有限公司 A kind of drying garbage flue gas processing device and its technique

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103575132A (en) * 2012-07-20 2014-02-12 广州市华德工业有限公司 Efficient heat exchange tube fin for filler coupling coil evaporative condenser
CN107213732A (en) * 2017-05-26 2017-09-29 北京哈宜节能环保科技开发股份有限公司 Vapor, TDS and SO in wet desulfurization flue gas3Removal methods and device
CN107469580A (en) * 2017-09-30 2017-12-15 广东佳德环保科技有限公司 A kind of wet flue gas desulfurizing and hydrargyrum-removing dust removal integrated plant and technique
CN208229653U (en) * 2018-03-30 2018-12-14 广东佳德环保科技有限公司 A kind of washing ammonia desulfuration equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103575132A (en) * 2012-07-20 2014-02-12 广州市华德工业有限公司 Efficient heat exchange tube fin for filler coupling coil evaporative condenser
CN107213732A (en) * 2017-05-26 2017-09-29 北京哈宜节能环保科技开发股份有限公司 Vapor, TDS and SO in wet desulfurization flue gas3Removal methods and device
CN107469580A (en) * 2017-09-30 2017-12-15 广东佳德环保科技有限公司 A kind of wet flue gas desulfurizing and hydrargyrum-removing dust removal integrated plant and technique
CN208229653U (en) * 2018-03-30 2018-12-14 广东佳德环保科技有限公司 A kind of washing ammonia desulfuration equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108619880A (en) * 2018-07-24 2018-10-09 中电环保科技发展有限公司 A kind of drying garbage flue gas processing device and its technique

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