CN108260233A - A kind of graphene superconductive far infrared heat generating pastes - Google Patents

A kind of graphene superconductive far infrared heat generating pastes Download PDF

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Publication number
CN108260233A
CN108260233A CN201810068930.9A CN201810068930A CN108260233A CN 108260233 A CN108260233 A CN 108260233A CN 201810068930 A CN201810068930 A CN 201810068930A CN 108260233 A CN108260233 A CN 108260233A
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parts
graphene
heat generating
powder
far infrared
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CN201810068930.9A
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黄治鸿
夏有良
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Shandong Zhongyiene Innovative Materials Technology Co., Ltd.
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Huanggang Crane Mdt Infotech Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic

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Abstract

The invention discloses a kind of graphene superconductive far infrared heat generating pastes, the formula of raw material by weight is as follows:50 70 parts of graphene, 20 30 parts of graphite, 20 30 parts of organic carrier, 12 16 parts of synthetic resin, 12 16 parts of magnetic rubber, 12 16 parts of metal mixed powder, 59 parts of environment-friendly type thermostable conductive adhesive, 35 parts of corrosion-resistant agent, 35 parts of antistatic agent, 35 parts of catalyst, 13 parts of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl.The present invention is raw material by graphene, and is properly added graphite, and the comprehensive performance for enabling to the heat generating pastes is good, and resistance is moderate, and heating power is big, can effectively enhance the electric conductivity for going back heat generating pastes, so as to ensure the service life of slurry.

Description

A kind of graphene superconductive far infrared heat generating pastes
Technical field
The present invention relates to technical field of graphene more particularly to a kind of graphene superconductive far infrared heat generating pastes.
Background technology
The manufacture and application of graphene are a new industries, which has excellent mechanics, electricity, calorifics Can, there will be important application in terms of energy storage, conduction, heat conduction, mechanics enhancing.Our company is mainly in high quality thin graphene Mass produce technology of preparing exploitation and the conduction based on high quality thin graphene, heat conduction, the powder of stored energy application, slurry The series of products such as material, coating, ink.Major customer concentrates on the energy storage enterprises such as lithium electricity, super capacitor, conductive, antistatic polymerization Object composite material is developed and processing enterprise, and the photoelectric devices heat conduction and heat radiation such as mobile phone, computer electronic device and LED, laser should With enterprises such as enterprise, polymers anti-corrosive paint enterprise, catalyst carrier materials.Meanwhile high quality thin graphene powder product Also it is at home and abroad used widely in the scientific research market of institution of higher education, scientific research institutions.
At present, graphene industry is also in one, and product development has just started, but show huge with application and marketing Big potentiality, it is contemplated that after several years, rapid growth trend will occur in whole market.The extensive market demand and potentiality, indicate graphite Alkene associated materials will be an industry with considerably long life cycle.Currently with graphene generate slurry, longevity Life is insufficient.For this purpose, we have proposed a kind of graphene superconductive far infrared heat generating pastes.
Invention content
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, to solve mentioned above in the background art ask Topic.
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 50-70 parts of alkene, 20-30 parts of graphite, 20-30 parts of organic carrier, 12-16 parts of synthetic resin, 12-16 parts of magnetic rubber, metal mix Close 12-16 parts of powder, 5-9 parts of environment-friendly type thermostable conductive adhesive, 3-5 parts of corrosion-resistant agent, 3-5 parts of antistatic agent, catalyst 3-5 Part, 1-3 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
Preferably, graphene, graphite, organic carrier weight ratio be 55-65:23-27:23-27.
Preferably, synthetic resin, magnetic rubber, metal mixed powder weight ratio be 13-15:13-15:13-15.
Preferably, environment-friendly type thermostable conductive adhesive, corrosion-resistant agent, antistatic agent weight ratio be 6-8:3.5-4.5: 3.5-4.5。
Preferably, the weight ratio of the hard ester group ammonium chloride of catalyst, double hydroxyethyl bis-hydroxypropyl is 3.5-4.5:1.5-2.5.
Preferably, the formula of raw material by weight is as follows:
55-65 parts of graphene, 23-27 parts of graphite, 23-27 parts of organic carrier, 13-15 parts of synthetic resin, magnetic rubber 13- 15 parts, 13-15 parts of metal mixed powder, 6-8 parts of environment-friendly type thermostable conductive adhesive, 3.5-4.5 parts of corrosion-resistant agent, antistatic agent 3.5-4.5 parts, 3.5-4.5 parts of catalyst, 1.5-2.5 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
Preferably, the optimization formula of raw material by weight is as follows:
60 parts of graphene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, metal mixed powder 14 parts, 7 parts of environment-friendly type thermostable conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, the double hydroxyls of double hydroxyethyl 3 parts of the hard ester group ammonium chloride of propyl.
Preferably, the metal mixed powder be copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, The molal weight of nickel powder and silver powder ratio is 5:2:1:0.2.
Preferably, the organic carrier is methylstyrene resin, nano silica fume acetylbutyrylcellulose and addition The mixture of agent, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3: 2:0.5:0.1.
Compared with prior art, the advantageous effect of present invention is that:The present invention is raw material by graphene, and appropriate Graphite is added, the comprehensive performance for enabling to the heat generating pastes is good, and resistance is moderate, and heating power is big, suitable adding Synthetic resin, magnetic rubber and metal mixed powder, can effectively enhance the electric conductivity for going back heat generating pastes, addition it is corrosion-resistant Agent, enables to the heat generating pastes to have corrosion resistance, and the antistatic agent of addition enables to the heat generating pastes to have anti-quiet Electric energy power, and can ensure the safety that the slurry uses, the addition of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl can be right Bacterium in slurry is purged, and so as to ensure the service life of slurry, which meets the demand developed now, is suitble to It is a wide range of to promote.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 50 parts of alkene, 20 parts of graphite, 20 parts of organic carrier, 12 parts of synthetic resin, 12 parts of magnetic rubber, 12 parts of metal mixed powder, environment-friendly type 5 parts of high temperature resistant conductive adhesive, 3 parts of corrosion-resistant agent, 3 parts of antistatic agent, 3 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl 1 part of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5: 0.1。
Embodiment 2
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 55 parts of alkene, 23 parts of graphite, 23 parts of organic carrier, 13 parts of synthetic resin, 13 parts of magnetic rubber, 13 parts of metal mixed powder, environment-friendly type 6 parts of high temperature resistant conductive adhesive, 3.5 parts of corrosion-resistant agent, 3.5 parts of antistatic agent, 3.5 parts of catalyst, double hydroxyethyl bis-hydroxypropyl Hard 1.5 parts of ester group ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5: 0.1。
Embodiment 3
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 60 parts of alkene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, 14 parts of metal mixed powder, environment-friendly type 7 parts of high temperature resistant conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl 3 parts of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5: 0.1。
Embodiment 4
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 65 parts of alkene, 27 parts of graphite, 27 parts of organic carrier, 15 parts of synthetic resin, 15 parts of magnetic rubber, 15 parts of metal mixed powder, environment-friendly type 8 parts of high temperature resistant conductive adhesive, 4.5 parts of corrosion-resistant agent, 4.5 parts of antistatic agent, 4.5 parts of catalyst, double hydroxyethyl bis-hydroxypropyl Hard 2.5 parts of ester group ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5: 0.1。
Embodiment 5
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite 70 parts of alkene, 30 parts of graphite, 30 parts of organic carrier, 16 parts of synthetic resin, 16 parts of magnetic rubber, 16 parts of metal mixed powder, environment-friendly type 9 parts of high temperature resistant conductive adhesive, 5 parts of corrosion-resistant agent, 5 parts of antistatic agent, 5 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl 3 parts of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5: 0.1。
In conclusion the present invention is raw material by graphene, and graphite is properly added, enables to the comprehensive of the heat generating pastes Close functional, and resistance is moderate, and heating power is big, is adding suitable synthetic resin, magnetic rubber and metal mixed powder, The electric conductivity for going back heat generating pastes can effectively be enhanced, the corrosion-resistant agent of addition enables to the heat generating pastes to have corrosion-resistant Ability, the antistatic agent of addition enable to the heat generating pastes to have antistatic effect, and can ensure the peace that the slurry uses Quan Xing, the addition of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl, can be purged the bacterium in slurry, so as to ensure to starch The service life of material, which meets the demand developed now, suitable for large-scale promotion.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of graphene superconductive far infrared heat generating pastes, which is characterized in that the formula of its raw material by weight is as follows:Graphene 50-70 parts, 20-30 parts of graphite, 20-30 parts of organic carrier, 12-16 parts of synthetic resin, 12-16 parts of magnetic rubber, metal mixed 12-16 parts of powder, 5-9 parts of environment-friendly type thermostable conductive adhesive, 3-5 parts of corrosion-resistant agent, 3-5 parts of antistatic agent, catalyst 3-5 Part, 1-3 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
2. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that graphene, graphite, organic The weight ratio of carrier is 55-65:23-27:23-27.
3. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that synthetic resin, magnetic rubber Glue, metal mixed powder weight ratio be 13-15:13-15:13-15.
4. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that environment-friendly type thermostable is conductive Binding agent, corrosion-resistant agent, antistatic agent weight ratio be 6-8:3.5-4.5:3.5-4.5.
5. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that catalyst, double hydroxyethyl The weight ratio of the hard ester group ammonium chloride of bis-hydroxypropyl is 3.5-4.5:1.5-2.5.
6. graphene superconductive far infrared heat generating pastes according to claim 2-5, which is characterized in that its raw material is by weight Formula is as follows:
55-65 parts of graphene, 23-27 parts of graphite, 23-27 parts of organic carrier, 13-15 parts of synthetic resin, magnetic rubber 13-15 Part, 13-15 parts of metal mixed powder, 6-8 parts of environment-friendly type thermostable conductive adhesive, 3.5-4.5 parts of corrosion-resistant agent, antistatic agent 3.5-4.5 parts, 3.5-4.5 parts of catalyst, 1.5-2.5 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
7. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that its raw material is by weight most Excellent formula is as follows:
60 parts of graphene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, metal mixed powder 14 Part, the double hydroxypropyls of 7 parts of environment-friendly type thermostable conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, double hydroxyethyl 3 parts of the hard ester group ammonium chloride of base.
8. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that the metal mixed powder For the mixture of copper powder, aluminium powder, nickel powder and silver powder, and copper powder, aluminium powder, nickel powder and silver powder molal weight ratio be 5:2:1: 0.2。
9. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that the organic carrier is The mixture of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive, and methylstyrene resin, nanometer The molal weight of silica flour acetylbutyrylcellulose and additive ratio is 3:2:0.5:0.1.
CN201810068930.9A 2018-01-24 2018-01-24 A kind of graphene superconductive far infrared heat generating pastes Pending CN108260233A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109379789A (en) * 2018-09-27 2019-02-22 山东泰安亿美达能源科技有限公司 A kind of graphene electric hot plate
CN110483966A (en) * 2019-08-13 2019-11-22 牛墨石墨烯应用科技有限公司 A kind of graphene heat generating pastes and preparation method thereof
CN111303763A (en) * 2020-03-16 2020-06-19 顾广新 High-temperature-resistant high-power-density graphene heating coating and preparation method thereof
CN111818675A (en) * 2020-07-25 2020-10-23 东莞市中科智恒新材料有限公司 Far infrared electrothermal film and preparation method thereof

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CN103915134A (en) * 2014-04-17 2014-07-09 江南石墨烯研究院 Method for preparing environment-friendly graphene-based conductive carbon paste
CN105315795A (en) * 2015-12-08 2016-02-10 赵建南 Intelligent high-temperature-resistant far infrared conductive heating energy-saving material
CN105472791A (en) * 2015-12-23 2016-04-06 东莞珂洛赫慕电子材料科技有限公司 Rare earth-doped semiconductor infrared radiation thick-film electronic paste and preparation method therefor
CN105702384A (en) * 2016-03-24 2016-06-22 广州市尤特新材料有限公司 Sintered high-heating paste and preparation method thereof

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KR20110031864A (en) * 2009-09-21 2011-03-29 삼성테크윈 주식회사 Method for manufacturing graphene, graphene manufactured by the method, conductive film comprising the graphene, transparent electrode comprising the graphene, radiating or heating device comprising the graphene
CN103915134A (en) * 2014-04-17 2014-07-09 江南石墨烯研究院 Method for preparing environment-friendly graphene-based conductive carbon paste
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109379789A (en) * 2018-09-27 2019-02-22 山东泰安亿美达能源科技有限公司 A kind of graphene electric hot plate
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CN110483966A (en) * 2019-08-13 2019-11-22 牛墨石墨烯应用科技有限公司 A kind of graphene heat generating pastes and preparation method thereof
CN111303763A (en) * 2020-03-16 2020-06-19 顾广新 High-temperature-resistant high-power-density graphene heating coating and preparation method thereof
CN111818675A (en) * 2020-07-25 2020-10-23 东莞市中科智恒新材料有限公司 Far infrared electrothermal film and preparation method thereof

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