CN108260233A - A kind of graphene superconductive far infrared heat generating pastes - Google Patents
A kind of graphene superconductive far infrared heat generating pastes Download PDFInfo
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- CN108260233A CN108260233A CN201810068930.9A CN201810068930A CN108260233A CN 108260233 A CN108260233 A CN 108260233A CN 201810068930 A CN201810068930 A CN 201810068930A CN 108260233 A CN108260233 A CN 108260233A
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- graphene
- heat generating
- powder
- far infrared
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 36
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 24
- 239000010439 graphite Substances 0.000 claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- 239000011812 mixed powder Substances 0.000 claims abstract description 21
- 238000005260 corrosion Methods 0.000 claims abstract description 18
- 230000007797 corrosion Effects 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 16
- 239000002216 antistatic agent Substances 0.000 claims abstract description 16
- 125000004185 ester group Chemical group 0.000 claims abstract description 16
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 16
- 239000000057 synthetic resin Substances 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 15
- -1 hydroxyethyl bis-hydroxypropyl Chemical group 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 13
- 230000001070 adhesive effect Effects 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims description 18
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 14
- 239000004411 aluminium Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 13
- 229910021487 silica fume Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 10
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000002002 slurry Substances 0.000 abstract description 8
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 150000001336 alkenes Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Conductive Materials (AREA)
Abstract
The invention discloses a kind of graphene superconductive far infrared heat generating pastes, the formula of raw material by weight is as follows:50 70 parts of graphene, 20 30 parts of graphite, 20 30 parts of organic carrier, 12 16 parts of synthetic resin, 12 16 parts of magnetic rubber, 12 16 parts of metal mixed powder, 59 parts of environment-friendly type thermostable conductive adhesive, 35 parts of corrosion-resistant agent, 35 parts of antistatic agent, 35 parts of catalyst, 13 parts of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl.The present invention is raw material by graphene, and is properly added graphite, and the comprehensive performance for enabling to the heat generating pastes is good, and resistance is moderate, and heating power is big, can effectively enhance the electric conductivity for going back heat generating pastes, so as to ensure the service life of slurry.
Description
Technical field
The present invention relates to technical field of graphene more particularly to a kind of graphene superconductive far infrared heat generating pastes.
Background technology
The manufacture and application of graphene are a new industries, which has excellent mechanics, electricity, calorifics
Can, there will be important application in terms of energy storage, conduction, heat conduction, mechanics enhancing.Our company is mainly in high quality thin graphene
Mass produce technology of preparing exploitation and the conduction based on high quality thin graphene, heat conduction, the powder of stored energy application, slurry
The series of products such as material, coating, ink.Major customer concentrates on the energy storage enterprises such as lithium electricity, super capacitor, conductive, antistatic polymerization
Object composite material is developed and processing enterprise, and the photoelectric devices heat conduction and heat radiation such as mobile phone, computer electronic device and LED, laser should
With enterprises such as enterprise, polymers anti-corrosive paint enterprise, catalyst carrier materials.Meanwhile high quality thin graphene powder product
Also it is at home and abroad used widely in the scientific research market of institution of higher education, scientific research institutions.
At present, graphene industry is also in one, and product development has just started, but show huge with application and marketing
Big potentiality, it is contemplated that after several years, rapid growth trend will occur in whole market.The extensive market demand and potentiality, indicate graphite
Alkene associated materials will be an industry with considerably long life cycle.Currently with graphene generate slurry, longevity
Life is insufficient.For this purpose, we have proposed a kind of graphene superconductive far infrared heat generating pastes.
Invention content
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, to solve mentioned above in the background art ask
Topic.
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
50-70 parts of alkene, 20-30 parts of graphite, 20-30 parts of organic carrier, 12-16 parts of synthetic resin, 12-16 parts of magnetic rubber, metal mix
Close 12-16 parts of powder, 5-9 parts of environment-friendly type thermostable conductive adhesive, 3-5 parts of corrosion-resistant agent, 3-5 parts of antistatic agent, catalyst 3-5
Part, 1-3 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
Preferably, graphene, graphite, organic carrier weight ratio be 55-65:23-27:23-27.
Preferably, synthetic resin, magnetic rubber, metal mixed powder weight ratio be 13-15:13-15:13-15.
Preferably, environment-friendly type thermostable conductive adhesive, corrosion-resistant agent, antistatic agent weight ratio be 6-8:3.5-4.5:
3.5-4.5。
Preferably, the weight ratio of the hard ester group ammonium chloride of catalyst, double hydroxyethyl bis-hydroxypropyl is 3.5-4.5:1.5-2.5.
Preferably, the formula of raw material by weight is as follows:
55-65 parts of graphene, 23-27 parts of graphite, 23-27 parts of organic carrier, 13-15 parts of synthetic resin, magnetic rubber 13-
15 parts, 13-15 parts of metal mixed powder, 6-8 parts of environment-friendly type thermostable conductive adhesive, 3.5-4.5 parts of corrosion-resistant agent, antistatic agent
3.5-4.5 parts, 3.5-4.5 parts of catalyst, 1.5-2.5 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
Preferably, the optimization formula of raw material by weight is as follows:
60 parts of graphene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, metal mixed powder
14 parts, 7 parts of environment-friendly type thermostable conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, the double hydroxyls of double hydroxyethyl
3 parts of the hard ester group ammonium chloride of propyl.
Preferably, the metal mixed powder be copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder,
The molal weight of nickel powder and silver powder ratio is 5:2:1:0.2.
Preferably, the organic carrier is methylstyrene resin, nano silica fume acetylbutyrylcellulose and addition
The mixture of agent, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:
2:0.5:0.1.
Compared with prior art, the advantageous effect of present invention is that:The present invention is raw material by graphene, and appropriate
Graphite is added, the comprehensive performance for enabling to the heat generating pastes is good, and resistance is moderate, and heating power is big, suitable adding
Synthetic resin, magnetic rubber and metal mixed powder, can effectively enhance the electric conductivity for going back heat generating pastes, addition it is corrosion-resistant
Agent, enables to the heat generating pastes to have corrosion resistance, and the antistatic agent of addition enables to the heat generating pastes to have anti-quiet
Electric energy power, and can ensure the safety that the slurry uses, the addition of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl can be right
Bacterium in slurry is purged, and so as to ensure the service life of slurry, which meets the demand developed now, is suitble to
It is a wide range of to promote.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
50 parts of alkene, 20 parts of graphite, 20 parts of organic carrier, 12 parts of synthetic resin, 12 parts of magnetic rubber, 12 parts of metal mixed powder, environment-friendly type
5 parts of high temperature resistant conductive adhesive, 3 parts of corrosion-resistant agent, 3 parts of antistatic agent, 3 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl
1 part of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and
The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive
Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5:
0.1。
Embodiment 2
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
55 parts of alkene, 23 parts of graphite, 23 parts of organic carrier, 13 parts of synthetic resin, 13 parts of magnetic rubber, 13 parts of metal mixed powder, environment-friendly type
6 parts of high temperature resistant conductive adhesive, 3.5 parts of corrosion-resistant agent, 3.5 parts of antistatic agent, 3.5 parts of catalyst, double hydroxyethyl bis-hydroxypropyl
Hard 1.5 parts of ester group ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and
The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive
Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5:
0.1。
Embodiment 3
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
60 parts of alkene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, 14 parts of metal mixed powder, environment-friendly type
7 parts of high temperature resistant conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl
3 parts of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and
The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive
Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5:
0.1。
Embodiment 4
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
65 parts of alkene, 27 parts of graphite, 27 parts of organic carrier, 15 parts of synthetic resin, 15 parts of magnetic rubber, 15 parts of metal mixed powder, environment-friendly type
8 parts of high temperature resistant conductive adhesive, 4.5 parts of corrosion-resistant agent, 4.5 parts of antistatic agent, 4.5 parts of catalyst, double hydroxyethyl bis-hydroxypropyl
Hard 2.5 parts of ester group ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and
The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive
Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5:
0.1。
Embodiment 5
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes, and the formula of raw material by weight is as follows:Graphite
70 parts of alkene, 30 parts of graphite, 30 parts of organic carrier, 16 parts of synthetic resin, 16 parts of magnetic rubber, 16 parts of metal mixed powder, environment-friendly type
9 parts of high temperature resistant conductive adhesive, 5 parts of corrosion-resistant agent, 5 parts of antistatic agent, 5 parts of catalyst, the hard ester group of double hydroxyethyl bis-hydroxypropyl
3 parts of ammonium chloride.
The metal mixed powder is copper powder, aluminium powder, nickel powder and silver powder mixture, and copper powder, aluminium powder, nickel powder and
The molal weight ratio of silver powder is 5:2:1:0.2.
The organic carrier is the mixing of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive
Object, and the molal weight ratio of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive is 3:2:0.5:
0.1。
In conclusion the present invention is raw material by graphene, and graphite is properly added, enables to the comprehensive of the heat generating pastes
Close functional, and resistance is moderate, and heating power is big, is adding suitable synthetic resin, magnetic rubber and metal mixed powder,
The electric conductivity for going back heat generating pastes can effectively be enhanced, the corrosion-resistant agent of addition enables to the heat generating pastes to have corrosion-resistant
Ability, the antistatic agent of addition enable to the heat generating pastes to have antistatic effect, and can ensure the peace that the slurry uses
Quan Xing, the addition of the hard ester group ammonium chloride of double hydroxyethyl bis-hydroxypropyl, can be purged the bacterium in slurry, so as to ensure to starch
The service life of material, which meets the demand developed now, suitable for large-scale promotion.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of graphene superconductive far infrared heat generating pastes, which is characterized in that the formula of its raw material by weight is as follows:Graphene
50-70 parts, 20-30 parts of graphite, 20-30 parts of organic carrier, 12-16 parts of synthetic resin, 12-16 parts of magnetic rubber, metal mixed
12-16 parts of powder, 5-9 parts of environment-friendly type thermostable conductive adhesive, 3-5 parts of corrosion-resistant agent, 3-5 parts of antistatic agent, catalyst 3-5
Part, 1-3 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
2. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that graphene, graphite, organic
The weight ratio of carrier is 55-65:23-27:23-27.
3. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that synthetic resin, magnetic rubber
Glue, metal mixed powder weight ratio be 13-15:13-15:13-15.
4. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that environment-friendly type thermostable is conductive
Binding agent, corrosion-resistant agent, antistatic agent weight ratio be 6-8:3.5-4.5:3.5-4.5.
5. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that catalyst, double hydroxyethyl
The weight ratio of the hard ester group ammonium chloride of bis-hydroxypropyl is 3.5-4.5:1.5-2.5.
6. graphene superconductive far infrared heat generating pastes according to claim 2-5, which is characterized in that its raw material is by weight
Formula is as follows:
55-65 parts of graphene, 23-27 parts of graphite, 23-27 parts of organic carrier, 13-15 parts of synthetic resin, magnetic rubber 13-15
Part, 13-15 parts of metal mixed powder, 6-8 parts of environment-friendly type thermostable conductive adhesive, 3.5-4.5 parts of corrosion-resistant agent, antistatic agent
3.5-4.5 parts, 3.5-4.5 parts of catalyst, 1.5-2.5 parts of double hydroxyethyl bis-hydroxypropyl hard ester group ammonium chloride.
7. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that its raw material is by weight most
Excellent formula is as follows:
60 parts of graphene, 25 parts of graphite, 25 parts of organic carrier, 14 parts of synthetic resin, 14 parts of magnetic rubber, metal mixed powder 14
Part, the double hydroxypropyls of 7 parts of environment-friendly type thermostable conductive adhesive, 4 parts of corrosion-resistant agent, 4 parts of antistatic agent, 4 parts of catalyst, double hydroxyethyl
3 parts of the hard ester group ammonium chloride of base.
8. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that the metal mixed powder
For the mixture of copper powder, aluminium powder, nickel powder and silver powder, and copper powder, aluminium powder, nickel powder and silver powder molal weight ratio be 5:2:1:
0.2。
9. graphene superconductive far infrared heat generating pastes according to claim 1, which is characterized in that the organic carrier is
The mixture of methylstyrene resin, nano silica fume acetylbutyrylcellulose and additive, and methylstyrene resin, nanometer
The molal weight of silica flour acetylbutyrylcellulose and additive ratio is 3:2:0.5:0.1.
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CN201810068930.9A CN108260233A (en) | 2018-01-24 | 2018-01-24 | A kind of graphene superconductive far infrared heat generating pastes |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109379789A (en) * | 2018-09-27 | 2019-02-22 | 山东泰安亿美达能源科技有限公司 | A kind of graphene electric hot plate |
CN110483966A (en) * | 2019-08-13 | 2019-11-22 | 牛墨石墨烯应用科技有限公司 | A kind of graphene heat generating pastes and preparation method thereof |
CN111303763A (en) * | 2020-03-16 | 2020-06-19 | 顾广新 | High-temperature-resistant high-power-density graphene heating coating and preparation method thereof |
CN111818675A (en) * | 2020-07-25 | 2020-10-23 | 东莞市中科智恒新材料有限公司 | Far infrared electrothermal film and preparation method thereof |
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CN109379789A (en) * | 2018-09-27 | 2019-02-22 | 山东泰安亿美达能源科技有限公司 | A kind of graphene electric hot plate |
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CN111303763A (en) * | 2020-03-16 | 2020-06-19 | 顾广新 | High-temperature-resistant high-power-density graphene heating coating and preparation method thereof |
CN111818675A (en) * | 2020-07-25 | 2020-10-23 | 东莞市中科智恒新材料有限公司 | Far infrared electrothermal film and preparation method thereof |
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