CN108252178A - A kind of technique for being used to prepare afforestation pavement seepage material - Google Patents

A kind of technique for being used to prepare afforestation pavement seepage material Download PDF

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Publication number
CN108252178A
CN108252178A CN201711444325.9A CN201711444325A CN108252178A CN 108252178 A CN108252178 A CN 108252178A CN 201711444325 A CN201711444325 A CN 201711444325A CN 108252178 A CN108252178 A CN 108252178A
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parts
solid waste
slag
water
aggregate
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CN108252178B (en
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杜耀中
冀涛
丁湘强
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Henan University of Science and Technology
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Henan University of Science and Technology
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • E01C11/226Coherent pavings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1051Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Road Paving Structures (AREA)

Abstract

A kind of technique for being used to prepare afforestation pavement seepage material, seepage material includes rubber layer, pervious bed, screed and base layer, base layer is uniformly mixed rear compression moulding by cement, solid waste coarse aggregate, solid waste fine aggregate, pervious bed is kneaded after after-pouring vulcanizes on pervious bed by natural rubber, butadiene-styrene rubber, white carbon, silicon carbide, water-absorbing resin, vulcanizing agent, activating agent and ecological additive and is formed by cement, solid waste coarse aggregate, reinforcing fiber compression moulding after mixing, rubber layer;Coarse aggregate is to form the coarse inflated slag in internal aperture by the water quenching of high temperature sludge elder generation to crush, and fine aggregate is to form the tiny closely knit slag in internal aperture by high temperature sludge elder generation natural cooling, regrinds into fine powder and is fired into compact grain;Slightly, fine aggregate is put into progress surface hydrophobicity modification in modification liquid;The present invention makes seepage material using solid waste, the pervious bed on the road surfaces such as pavement, park is can be widely applied to, conducive to ground water circulation.

Description

A kind of technique for being used to prepare afforestation pavement seepage material
Technical field
The present invention relates to afforestation field, specifically a kind of work for being used to prepare afforestation pavement seepage material Skill.
Background technology
City dweller occupies residence mainly by waterproof with granite, marble, glazed tile, cement and pitch etc. at present Material be laid with city square, commercial street, pavement, community activity, the ground in parking lot etc. surround, hardened ground pair The harm of urban environment is very big, and when raining, hardened ground prevents rainwater and directly infiltrates through ground, and completely ponding makes one Trip become very inconvenient;And when not raining, hardened ground is again extremely dry, easily accumulates dust, dust is caused to fly everywhere The situation raised, ground and air carry out heat, moisture exchanges relatively difficult, adjust urban surface temperature, the ability of humidity And then it being lower, the radiant heat of the sun can also largely be reflected, retain and be discharged in ground, substantially increase the tropical island effect in city, Greatly reduce The Surroundings in Cities comfort level.
The dank material of some water-permeable bricks of building materials field, porous pavement etc. mainly uses bulky grain bone currently on the market Frame and cement composition are formed using artificial treatment sand and high polymer binder, the problem is that cement water-permeable brick permeability rate Not high or compression strength is insufficient, this two aspects performance difficulty is taken into account, while the exploitation of raw material causes the destruction to environment;According to system The discharge capacity of the solid waste such as meter, slag, ferrochrome slag, gangue is very big, and about 180Kg can all be discharged by often producing 1 ton of crude steel Slag, the discharge capacity of ferrochrome slag is being increased every year with the speed more than 400,000 tons, if not comprehensively utilized, these solid wastes Object will deposit river, filling water channel, appropriation of land, polluted source and air, cause environmental hazard;In view of these solid waste Inside is porous structure, but has certain intensity, therefore can be used for solid waste to manufacture seepy material, can both be reduced The discharge of solid waste, and resource can be utilized, achieve the purpose that two-win.
Invention content
The purpose of the present invention is to solve the deficiency of above-mentioned technical problem, it is green that the present invention proposes that one kind is used to prepare gardens The technique for changing pavement seepage material, including being located at the base layer on upper strata, positioned at the pervious bed of lower floor and by the base layer, described Pervious bed bonds the screed of getting up, and base layer and pervious bed are made of cement, solid waste aggregate, reinforcing fiber, can be simultaneous Care for water penetration and crushing resistance.
Present invention deficiency to solve above-mentioned technical problem and the technical solution adopted is that:One kind is used to prepare afforestation The technique of pavement seepage material, the seepage material include the pervious bed positioned at upper strata and the base layer positioned at lower floor, prepare Technique includes the following steps:
(1)In parts by weight, 45 ~ 55 parts of binding agent, 120 ~ 180 parts of solid waste coarse aggregate, solid waste fine aggregate are taken 100 ~ 120 parts, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, 1 ~ 2min is stirred, is put into solid Waste coarse aggregate continues 1 ~ 2min of stirring, adds solid waste fine aggregate, after stirring evenly, injects in mold and is pressed into Type is placed on vibratory compaction on bumper, and it is spare to demould obtained base layer;
(2)In parts by weight, 40 ~ 45 parts of binding agent, 80 ~ 100 parts of solid waste coarse aggregate, 10 ~ 20 parts of water-absorbing resin are taken, it is fine 80 ~ 120 parts of dimension, 5 ~ 8 parts of additive, 8 ~ 10 parts of water add in water and additive in cement, stir 1 ~ 2min, be put into fiber after 1 ~ 2min of continuous stirring is placed into after solid waste coarse aggregate stirs evenly, is injected compression moulding in mold, be placed on bumper It is spare that pervious bed is made in vibratory compaction after demoulding;
(3)In step(1)One layer of mortar is smeared in the upper surface of base layer obtained, by step(2)Pervious bed obtained is placed on mortar On, cohesive body is made, and cover straw mat, watering maintenance 1 ~ 3 day is spare;
(4)In parts by weight, 15 ~ 20 parts of natural rubber, 20 ~ 25 parts of butadiene-styrene rubber, 25 ~ 30 parts of white carbon, silicon carbide 5 ~ 10 are taken Part, 5 ~ 8 parts of water-absorbing resin, 15 ~ 20 parts of vulcanizing agent, 0.5 ~ 1 part of activating agent, ecological 3 ~ 5 parts of additive, and above-mentioned raw materials are put into It is kneaded in kneading machine, melting temperature is 110 ~ 115 DEG C, and mixing time is 15 ~ 20min, spare after mixing;
(5)By step(3)In cohesive body sander by 1 ~ 2mm of surface rubbing, and one layer of step is poured on surface(4)In mix Slurry after refining pours thickness as 3 ~ 5mm, green body is made, green body then is put into hot-air channel and is vulcanized, curing temperature It is 150 ~ 170 DEG C, greening seepage material in road surface is can be prepared by after cooling.
Further, the preparation method of the solid waste coarse aggregate includes the following steps:
(1)The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture;
(2)The inflated slag of slag, ferrochrome slag, gangue is taken, is put into the particle that 5 ~ 10mm is crushed in crusher, and particle is added Heat is spare to 120 ~ 200 DEG C;
(3)Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~ 10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste coarse aggregate is made.
Further, the preparation method of the solid waste fine aggregate includes the following steps:
(1)The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture Slag;
(2)The closely knit slag of slag, ferrochrome slag, gangue is taken, grinding in ball mill is put into after crushing and, into fine powder, adds fine powder The kaolin of total weight 10 ~ 15% and the water of fine powder total weight 3 ~ 5% are granulated and grain size are controlled to be done for 0.1 ~ 6mm after mixing It is put into after dry in high temperature furnace after being sintered 1 ~ 2h at 1300 ~ 1350 DEG C and cools to 120 ~ 200 DEG C with the furnace, it is 0.08 ~ 5mm that grain size, which is made, Particle, it is spare;
(3)Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~ 10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste fine aggregate is made.
Further, the screed is foaming screed, in parts by weight, including 60 ~ 65 parts of cement, flyash 10 ~ 15 parts, 5 ~ 10 parts of zeolite powder, 3 ~ 5 parts of charcoal, 15 ~ 20 parts of sand, 20 ~ 30 parts of sodium chloride.
The preparation method of the further foaming screed includes the following steps:In parts by weight, cement 60 ~ 65 is taken Part, 10 ~ 15 parts of flyash, 5 ~ 10 parts of zeolite powder, 3 ~ 5 parts of charcoal, 15 ~ 20 parts of sand, 20 ~ 30 parts of sodium chloride add in 40 ~ 50 The water of part, stirs evenly in agitated kettle, takes 0.05 ~ 0.1 part of foaming agent, 0.05 ~ 0.08 part of foam stabilizer, after adding in 3 ~ 5 parts of water It after high-speed stirred forms foam, pours into the mortar in agitated kettle, after stirring evenly, you can foaming mortar is made.
Further, the binding agent presses 2 ~ 4 by cement and flyash:What 1 mass ratio mixed, the cement For aluminate cement, the additive is antifreezing agent.
Further, the fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre Any one of dimension, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several combination.
Further, which is characterized in that the fiber has also carried out modification, the modifying agent include resin, Polyether-ketone and nano silicon carbide granulate.
Further, the modification processing method of the fiber is as follows:In parts by weight, first take 15 ~ 20 parts of resins 80 ~ It is dry at a temperature of 100 DEG C, then dried resin is dissolved in solvent, resin solution is obtained, while again into resin solution 3 ~ 4% nano silicon carbide granulate of polyether-ketone solution and total resin weight of total resin weight 20 ~ 22% is added in, is obtained after mixing Then fiber is put into modifying agent and is modified processing, you can obtains modified fibre by modifying agent.
The beneficial effects of the invention are as follows:
The present invention is to provide a kind of technique for being used to prepare afforestation pavement seepage material, the matrix including being located at lower floor Layer bonds the screed to get up and the wear-resisting rubber on base layer positioned at the pervious bed on upper strata and by base layer, pervious bed Glue-line, base layer are made of cement, solid waste coarse aggregate, solid waste fine aggregate, and pervious bed is by cement, solid waste Object coarse aggregate, reinforcing fiber composition, rubber layer is by natural rubber, butadiene-styrene rubber, white carbon, silicon carbide, water-absorbing resin, vulcanizing agent It is formed with activating agent;Solid waste coarse aggregate is to be first passed through water quenching by the slag, ferrochrome slag, gangue come out from high temperature and formed The characteristics of coarse inflated slag in internal aperture, then be broken into the particle of 5 ~ 10mm, Water Quenching Slag is that internal holes are mostly to be interconnected Through-hole, and aperture is larger by the use of the slag type as coarse aggregate, can improve the permeability of ponding, solid waste fine aggregate be from Slag, ferrochrome slag, the gangue of high temperature out first pass through natural cooling and form the tiny closely knit slag in internal aperture, regrind into fine powder The compact grain formed is fired, first, aperture is tiny inside air-cooled slag, another on the one hand with some strength as fine aggregate The porous structure of aspect can also coordinate the permeability for improving ponding with coarse aggregate;Coarse aggregate and fine aggregate are also put into modification liquid Surface hydrophobicity modification is carried out, one layer of dense film is formed in aggregate surface and pore surface, interfacial transition zone can be optimized, Blocking and outside moisture and ion exchange channels, avoid aggregate water absorbing properties from being lower, while hydrophobic treatment can flow through aggregate And the moisture of aggregate internal void is not absorbed by aggregate, is permeated down;From the foregoing, it will be observed that due to the thick bone of solid waste in base layer The presence of material and solid waste fine aggregate not only makes base layer have certain intensity, while also has certain water penetration, Only containing the larger coarse aggregate of internal holes diameter in pervious bed, after modification, can make moisture along internal holes slowly down Infiltration flows through the dirt bed that base layer enters lower section;It is also added into carrying out the modified fiber of enhancing in pervious bed, by using tree The mobility encapsulated nanoparticles and fiber of lipoprotein solution realize nano particle, fiber is mixed with the uniform of resin, raising fiber Activeness and quietness effect in pervious bed, avoid making pervious bed due to the generation built on the sand of configuration aspects it is larger the defects of, cause Pavement crack even caves in;One layer of abrasive rubber layer has also been poured on the surface of pervious bed, it, can be with wherein added with water-absorbing resin Play the role of absorbing in the water on road surface, prevent surface gathered water, cause inconvenient walking, rubber layer has certain elasticity, makes road Face walking is more comfortable, while can also protect the pervious bed of lower section;In conclusion the present invention utilizes slag, ferrochrome slag, gangue Etc. solid waste make seepage material, turn waste into wealth, cheap compared with resin type seepy material, water penetration is good, can It is widely used in the pervious bed on the road surfaces such as pavement, park and residential quarters, conducive to ground water circulation.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated.
Embodiment 1
A kind of technique for being used to prepare afforestation pavement seepage material, the seepage material include the pervious bed positioned at upper strata With the base layer positioned at lower floor, preparation process includes the following steps:
(1)In parts by weight, 45 parts of binding agent, 120 parts of solid waste coarse aggregate, 100 parts of solid waste fine aggregate, outer is taken Add 10 parts of agent, 15 parts of water, water and additive are added in cement, stir 1 ~ 2min, be put into solid waste coarse aggregate and continue to stir 1 ~ 2min is mixed, adds solid waste fine aggregate, after stirring evenly, compression moulding in mold is injected, is placed on bumper and shakes It is dynamic closely knit, it is spare to demould obtained base layer;
(2)In parts by weight, 40 parts of binding agent, 80 parts of solid waste coarse aggregate, 10 parts of water-absorbing resin are taken, it is 80 parts of fiber, outer Add 5 parts of agent, 8 parts of water, water and additive are added in cement, stir 1 ~ 2min, be put into fiber and continue 1 ~ 2min of stirring, place into After solid waste coarse aggregate stirs evenly, compression moulding in mold is injected, is placed on vibratory compaction on bumper, be made after demoulding Pervious bed is spare;
(3)In step(1)One layer of mortar is smeared in the upper surface of base layer obtained, by step(2)Pervious bed obtained is placed on mortar On, cohesive body is made, and cover straw mat, watering maintenance 1 ~ 3 day is spare;
(4)In parts by weight, 15 parts of natural rubber, 20 parts of butadiene-styrene rubber, 25 parts of white carbon, 5 parts of silicon carbide, water-absorbing resin 5 are taken Part, 15 parts of vulcanizing agent, 0.5 part of activating agent, ecological 3 parts of additive, and above-mentioned raw materials are put into kneading machine and are kneaded, it is kneaded Temperature is 110 DEG C, mixing time 15min, spare after mixing;
(5)By step(3)In cohesive body sander by surface rubbing 1mm, and one layer of step is poured on surface(4)Middle mixing Slurry afterwards pours thickness as 3mm, green body is made, green body then is put into hot-air channel and is vulcanized, curing temperature is 150 DEG C, greening seepage material in road surface is can be prepared by after cooling.
Further, the preparation method of the solid waste coarse aggregate includes the following steps:
(1)The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture;
(2)The inflated slag of slag, ferrochrome slag, gangue is taken, is put into the particle that 5 ~ 10mm is crushed in crusher, and particle is added Heat is spare to 120 DEG C;
(3)Take 5 parts of silicone oil, 20 parts of polyacrylate emulsions, 0.5 part of surfactant, 5 parts of organic solvents and 89 in parts by weight again Part water is deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste coarse aggregate is made.
Further, the preparation method of the solid waste fine aggregate includes the following steps:
(1)The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture Slag;
(2)The closely knit slag of slag, ferrochrome slag, gangue is taken, grinding in ball mill is put into after crushing and, into fine powder, adds fine powder The kaolin of total weight 10% and the water of fine powder total weight 3% are granulated and control grain size as 0.1 ~ 6mm, after mixing after dry The furnace cooling after 1300 DEG C of sintering 1h is put into high temperature furnace, the particle that grain size is 0.08 ~ 5mm is made, it is spare;
(3)Take 5 parts of silicone oil, 20 parts of polyacrylate emulsions, 0.5 part of surfactant, 5 parts of organic solvents and 89 in parts by weight again Part water is deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity modification in modification liquid, is dried in the air after being disposed It is dry to can be prepared by solid waste fine aggregate.
Further, the screed for foaming screed, in parts by weight, including 60 parts of cement, 10 parts of flyash, 5 parts of zeolite powder, 3 parts of charcoal, 15 parts of sand, 20 parts of sodium chloride.
The preparation method of the further foaming screed includes the following steps:In parts by weight, 60 parts of cement, powder are taken 10 parts of coal ash, 5 parts of zeolite powder, 3 parts of charcoal, 15 parts of sand, 20 parts of sodium chloride add in 40 parts of water, are stirred in agitated kettle Uniformly, it takes 0.05 part of foaming agent, 0.05 part of foam stabilizer, adds in after high-speed stirred after 3 parts of water forms foam, pour into agitated kettle In mortar, after stirring evenly, you can foaming mortar is made.
Further, the binding agent presses 2 by cement and flyash:What 1 mass ratio mixed, the cement is Aluminate cement, the additive are antifreezing agent.
Further, the fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre Any one of dimension, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several combination.
Further, which is characterized in that the fiber has also carried out modification, the modifying agent include resin, Polyether-ketone and nano silicon carbide granulate.
Further, the modification processing method of the fiber is as follows:In parts by weight, 15 parts of resins are first taken in 80 DEG C of temperature The lower drying of degree, then dried resin is dissolved in solvent, resin solution is obtained, while add in resin into resin solution again 3% nano silicon carbide granulate of polyether-ketone solution and total resin weight of total weight 20%, obtains modifying agent after mixing, then will Fiber, which is put into modifying agent, is modified processing, you can obtains modified fibre.
Embodiment 2
A kind of technique for being used to prepare afforestation pavement seepage material, the seepage material include the pervious bed positioned at upper strata With the base layer positioned at lower floor, preparation process includes the following steps:
(1)In parts by weight, 50 parts of binding agent, 150 parts of solid waste coarse aggregate, 110 parts of solid waste fine aggregate, outer is taken Add 15 parts of agent, 20 parts of water, water and additive are added in cement, stir 1 ~ 2min, be put into solid waste coarse aggregate and continue to stir 1 ~ 2min is mixed, adds solid waste fine aggregate, after stirring evenly, compression moulding in mold is injected, is placed on bumper and shakes It is dynamic closely knit, it is spare to demould obtained base layer;
(2)In parts by weight, 42 parts of binding agent, 90 parts of solid waste coarse aggregate, 15 parts of water-absorbing resin are taken, it is 100 parts of fiber, outer Add 7 parts of agent, 9 parts of water, water and additive are added in cement, stir 1 ~ 2min, be put into fiber and continue 1 ~ 2min of stirring, place into After solid waste coarse aggregate stirs evenly, compression moulding in mold is injected, is placed on vibratory compaction on bumper, be made after demoulding Pervious bed is spare;
(3)In step(1)One layer of mortar is smeared in the upper surface of base layer obtained, by step(2)Pervious bed obtained is placed on mortar On, cohesive body is made, and cover straw mat, watering maintenance 1 ~ 3 day is spare;
(4)In parts by weight, 18 parts of natural rubber, 23 parts of butadiene-styrene rubber, 28 parts of white carbon, 8 parts of silicon carbide, water-absorbing resin 7 are taken Part, 18 parts of vulcanizing agent, 0.8 part of activating agent, ecological 4 parts of additive, wherein the ecological additive is by humic acid, charcoal By 4:1:What 0.5 mass ratio mixed, and above-mentioned raw materials are put into kneading machine and are kneaded, melting temperature is 112 DEG C, Mixing time is 18min, spare after mixing;Humic acid is the remains of animals and plants remains, mainly plant, by microorganism Decomposition and conversion and a series of geochemical processes a kind of organic substance for causing and accumulating, charcoal is raw Object organic material is in anoxic or anoxybiotic environment, the solid product that is generated after high temperature pyrolysis, can not only be used for the high-quality energy, Soil conditioner can also be used as reducing agent, fertilizer slow release carrier and carbon dioxide sequestration agent etc., be widely used to carbon sequestration and subtract Row, water source purifying, heavy metal adsorption and soil improvement etc. can carry out vegetative coverage, therefore in pervious bed on pervious bed A certain amount of humic acid and charcoal are added, the fertilizer conservation performance and nutrient-supply capacity of greening pavement seepage material can be improved, is increased Available nutrient may assist in the vegetation healthy growth planted on pervious bed, be really achieved the work for adjusting ecology, beautifying the environment With;
(5)By step(3)In cohesive body sander by surface rubbing 1.5mm, and one layer of step is poured on surface(4)In mix Slurry after refining pours thickness as 4mm, green body is made, green body then is put into hot-air channel and is vulcanized, curing temperature is 160 DEG C, greening seepage material in road surface is can be prepared by after cooling.
Further, the preparation method of the solid waste coarse aggregate includes the following steps:
(1)The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture;
(2)The inflated slag of slag, ferrochrome slag, gangue is taken, is put into the particle that 5 ~ 10mm is crushed in crusher, and particle is added Heat is spare to 160 DEG C;
(3)Take 8 parts of silicone oil, 25 parts of polyacrylate emulsions, 0.8 part of surfactant, 8 parts of organic solvents and 95 in parts by weight again Part water is deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste coarse aggregate is made.
Further, the preparation method of the solid waste fine aggregate includes the following steps:
(1)The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture Slag;
(2)The closely knit slag of slag, ferrochrome slag, gangue is taken, grinding in ball mill is put into after crushing and, into fine powder, adds fine powder The kaolin of total weight 12% and the water of fine powder total weight 4% are granulated and control grain size as 0.1 ~ 6mm, after mixing after dry It is put into high temperature furnace after being sintered 1.5h at 1320 DEG C and cools to 160 DEG C with the furnace, the particle that grain size is 0.08 ~ 5mm is made, it is spare;
(3)Take 8 parts of silicone oil, 25 parts of polyacrylate emulsions, 0.8 part of surfactant, 8 parts of organic solvents and 95 in parts by weight again Part water is deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste fine aggregate is made.
Further, the screed for foaming screed, in parts by weight, including 62 parts of cement, 13 parts of flyash, 8 parts of zeolite powder, 4 parts of charcoal, 18 parts of sand, 25 parts of sodium chloride.
Further, the preparation method of the foaming screed includes the following steps:In parts by weight, take 62 parts of cement, 13 parts of flyash, 8 parts of zeolite powder, 4 parts of charcoal, 18 parts of sand, 25 parts of sodium chloride add in 45 parts of water, are stirred in agitated kettle It mixes uniformly, takes 0.08 part of foaming agent, 0.07 part of foam stabilizer, add in after high-speed stirred after 4 parts of water forms foam, pour into agitated kettle Mortar in, after stirring evenly, you can be made foaming mortar.
Further, the binding agent presses 3 by cement and flyash:What 1 mass ratio mixed, the cement is Aluminate cement, the additive are antifreezing agent.
Further, the fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre Any one of dimension, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several combination.
Further, which is characterized in that the fiber has also carried out modification, the modifying agent include resin, Polyether-ketone and nano silicon carbide granulate.
Further, the modification processing method of the fiber is as follows:In parts by weight, 18 parts of resins are first taken in 90 DEG C of temperature The lower drying of degree, then dried resin is dissolved in solvent, resin solution is obtained, while add in resin into resin solution again 3.5% nano silicon carbide granulate of polyether-ketone solution and total resin weight of total weight 21%, obtains modifying agent, then after mixing Fiber is put into modifying agent and is modified processing, you can obtains modified fibre.
Embodiment 3
A kind of technique for being used to prepare afforestation pavement seepage material, the seepage material include the pervious bed positioned at upper strata With the base layer positioned at lower floor, preparation process includes the following steps:
(1)In parts by weight, 55 parts of binding agent, 180 parts of solid waste coarse aggregate, 120 parts of solid waste fine aggregate, outer is taken Add 20 parts of agent, 25 parts of water, water and additive are added in cement, stir 1 ~ 2min, be put into solid waste coarse aggregate and continue to stir 1 ~ 2min is mixed, adds solid waste fine aggregate, after stirring evenly, compression moulding in mold is injected, is placed on bumper and shakes It is dynamic closely knit, it is spare to demould obtained base layer;
(2)In parts by weight, 45 parts of binding agent, 100 parts of solid waste coarse aggregate, 20 parts of water-absorbing resin are taken, 120 parts of fiber, 8 parts of additive, 10 parts of water add in water and additive in cement, stir 1 ~ 2min, are put into fiber and continue 1 ~ 2min of stirring, then It is put into after solid waste coarse aggregate stirs evenly, injects compression moulding in mold, vibratory compaction on bumper is placed on, after demoulding It is spare that pervious bed is made;
(3)In step(1)One layer of mortar is smeared in the upper surface of base layer obtained, by step(2)Pervious bed obtained is placed on mortar On, cohesive body is made, and cover straw mat, watering maintenance 1 ~ 3 day is spare;
(4)In parts by weight, 20 parts of natural rubber, 25 parts of butadiene-styrene rubber, 30 parts of white carbon, 10 parts of silicon carbide, water-absorbing resin 8 are taken Part, 20 parts of vulcanizing agent, 1 part of activating agent, ecological 5 parts of additive, and above-mentioned raw materials are put into kneading machine and are kneaded, it is kneaded temperature It is 115 DEG C to spend, mixing time 20min, spare after mixing;
(5)By step(3)In cohesive body sander by surface rubbing 2mm, and one layer of step is poured on surface(4)Middle mixing Slurry afterwards pours thickness as 5mm, green body is made, green body then is put into hot-air channel and is vulcanized, curing temperature is 170 DEG C, greening seepage material in road surface is can be prepared by after cooling.
Further, the preparation method of the solid waste coarse aggregate includes the following steps:
(1)The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture;
(2)The inflated slag of slag, ferrochrome slag, gangue is taken, is put into the particle that 5 ~ 10mm is crushed in crusher, and particle is added Heat is spare to 200 DEG C;
(3)Take in parts by weight again 10 parts of silicone oil, 30 parts of polyacrylate emulsions, 1 part of surfactant, 10 parts of organic solvents and 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste coarse aggregate is made.
Further, the preparation method of the solid waste fine aggregate includes the following steps:
(1)The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture Slag;
(2)The closely knit slag of slag, ferrochrome slag, gangue is taken, grinding in ball mill is put into after crushing and, into fine powder, adds fine powder The kaolin of total weight 15% and the water of fine powder total weight 5% are granulated and control grain size as 0.1 ~ 6mm, after mixing after dry It is put into high temperature furnace after being sintered 2h at 1350 DEG C and cools to 200 DEG C with the furnace, the particle that grain size is 0.08 ~ 5mm is made, it is spare;
(3)Take in parts by weight again 10 parts of silicone oil, 30 parts of polyacrylate emulsions, 1 part of surfactant, 10 parts of organic solvents and 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste fine aggregate is made.
Further, the screed for foaming screed, in parts by weight, including 65 parts of cement, 15 parts of flyash, 10 parts of zeolite powder, 5 parts of charcoal, 20 parts of sand, 30 parts of sodium chloride.
Further, the preparation method of the foaming screed includes the following steps:In parts by weight, take 65 parts of cement, 15 parts of flyash, 10 parts of zeolite powder, 5 parts of charcoal, 20 parts of sand, 30 parts of sodium chloride add in 50 parts of water, are stirred in agitated kettle It mixes uniformly, takes 0.1 part of foaming agent, 0.08 part of foam stabilizer, add in after high-speed stirred after 5 parts of water forms foam, pour into agitated kettle Mortar in, after stirring evenly, you can be made foaming mortar.
Further, the binding agent presses 4 by cement and flyash:What 1 mass ratio mixed, the cement is Aluminate cement, the additive are antifreezing agent.
Further, the fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre Any one of dimension, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several combination.
Further, which is characterized in that the fiber has also carried out modification, the modifying agent include resin, Polyether-ketone and nano silicon carbide granulate.
Further, the modification processing method of the fiber is as follows:In parts by weight, 20 parts of resins are first taken at 100 DEG C At a temperature of it is dry, then dried resin is dissolved in solvent, obtains resin solution, while add in tree into resin solution again 4% nano silicon carbide granulate of polyether-ketone solution and total resin weight of fat total weight 22%, obtains modifying agent, then after mixing Fiber is put into modifying agent and is modified processing, you can obtains modified fibre.
The existing water-permeable brick sample 1 prepared by general aggregate, the water-permeable brick sample prepared by sand are bought on the market 2, it is compared with the embodiment of the present invention 1, it is as a result as follows:
From the foregoing, it will be observed that afforestation pavement seepage material prepared by present invention process, due to the thick bone of solid waste in base layer The presence of material and solid waste fine aggregate, and coarse aggregate and fine aggregate are also put into modification liquid and carry out at surface hydrophobicity modification Reason forms one layer of dense film in aggregate surface and pore surface, can optimize interfacial transition zone, block with outside moisture and from Sub- interchange channel avoids aggregate water absorbing properties from being lower, while hydrophobic treatment can flow through the water of aggregate and aggregate internal void Divide and do not absorbed by aggregate, permeated down, therefore not only make base layer that there is certain intensity, while also there is centainly permeable Property only containing the larger coarse aggregate of internal holes diameter in pervious bed, after modification, can make moisture slowly past along internal holes Lower infiltration flows through the dirt bed that base layer enters lower section;One layer of abrasive rubber layer is also poured on the surface of pervious bed, wherein adding Added with water-absorbing resin, it can play the role of absorbing in the water on road surface, prevent surface gathered water, cause inconvenient walking, rubber layer tool There is certain elasticity, make road surface walking more comfortable, while the pervious bed of lower section can also be protected;It is saturating with being prepared by general aggregate Water brick sample 1, the water-permeable brick sample 2 prepared by sand are compared, and have higher intensity and preferable water penetration, and present invention profit Seepage material is made with solid waste such as slag, ferrochrome slag, gangues, is turned waste into wealth, cheap, water penetration is good, can It is widely used in the pervious bed on the road surfaces such as pavement, park and residential quarters, conducive to ground water circulation.
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent most wide range of point.

Claims (9)

1. a kind of technique for being used to prepare afforestation pavement seepage material, which is characterized in that the seepage material includes position Pervious bed in upper strata and the base layer positioned at lower floor, preparation process include the following steps:
(1)In parts by weight, 45 ~ 55 parts of binding agent, 120 ~ 180 parts of solid waste coarse aggregate, solid waste fine aggregate are taken 100 ~ 120 parts, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, 1 ~ 2min is stirred, is put into solid Waste coarse aggregate continues 1 ~ 2min of stirring, adds solid waste fine aggregate, after stirring evenly, injects in mold and is pressed into Type is placed on vibratory compaction on bumper, and it is spare to demould obtained base layer;
(2)In parts by weight, 40 ~ 45 parts of binding agent, 80 ~ 100 parts of solid waste coarse aggregate, 10 ~ 20 parts of water-absorbing resin are taken, it is fine 80 ~ 120 parts of dimension, 5 ~ 8 parts of additive, 8 ~ 10 parts of water add in water and additive in cement, stir 1 ~ 2min, be put into fiber after 1 ~ 2min of continuous stirring is placed into after solid waste coarse aggregate stirs evenly, is injected compression moulding in mold, be placed on bumper It is spare that pervious bed is made in vibratory compaction after demoulding;
(3)In step(1)One layer of mortar is smeared in the upper surface of base layer obtained, by step(2)Pervious bed obtained is placed on mortar On, cohesive body is made, and cover straw mat, watering maintenance 1 ~ 3 day is spare;
(4)In parts by weight, 15 ~ 20 parts of natural rubber, 20 ~ 25 parts of butadiene-styrene rubber, 25 ~ 30 parts of white carbon, silicon carbide 5 ~ 10 are taken Part, 5 ~ 8 parts of water-absorbing resin, 15 ~ 20 parts of vulcanizing agent, 0.5 ~ 1 part of activating agent, ecological 3 ~ 5 parts of additive, and above-mentioned raw materials are put into It is kneaded in kneading machine, melting temperature is 110 ~ 115 DEG C, and mixing time is 15 ~ 20min, spare after mixing;
(5)By step(3)In cohesive body sander by 1 ~ 2mm of surface rubbing, and one layer of step is poured on surface(4)In mix Slurry after refining pours thickness as 3 ~ 5mm, green body is made, green body then is put into hot-air channel and is vulcanized, curing temperature It is 150 ~ 170 DEG C, greening seepage material in road surface is can be prepared by after cooling.
2. a kind of technique for being used to prepare afforestation pavement seepage material as described in claim 1, which is characterized in that described The preparation method of solid waste coarse aggregate include the following steps:
(1)The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture;
(2)The inflated slag of slag, ferrochrome slag, gangue is taken, is put into the particle that 5 ~ 10mm is crushed in crusher, and particle is added Heat is spare to 120 ~ 200 DEG C;
(3)Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~ 10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste coarse aggregate is made.
3. a kind of technique for being used to prepare afforestation pavement seepage material as described in claim 1, which is characterized in that described The preparation method of solid waste fine aggregate include the following steps:
(1)The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture Slag;
(2)The closely knit slag of slag, ferrochrome slag, gangue is taken, grinding in ball mill is put into after crushing and, into fine powder, adds fine powder The kaolin of total weight 10 ~ 15% and the water of fine powder total weight 3 ~ 5% are granulated and grain size are controlled to be done for 0.1 ~ 6mm after mixing It is put into after dry in high temperature furnace after being sintered 1 ~ 2h at 1300 ~ 1350 DEG C and cools to 120 ~ 200 DEG C with the furnace, it is 0.08 ~ 5mm that grain size, which is made, Particle, it is spare;
(3)Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~ 10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid;
(4)Particle after heating is put into modification liquid, be sufficiently stirred and is cooled down after being centrifuged with cold air rapidly, makes modification Liquid is in aggregate and the surface solidification overlay film of hole, you can completes surface hydrophobicity modification, solid waste fine aggregate is made.
4. a kind of technique for being used to prepare afforestation pavement seepage material as described in claim 1, which is characterized in that described Screed be foaming screed, in parts by weight, including 60 ~ 65 parts of cement, 10 ~ 15 parts of flyash, 5 ~ 10 parts of zeolite powder, raw 3 ~ 5 parts of object charcoal, 15 ~ 20 parts of sand, 20 ~ 30 parts of sodium chloride.
5. a kind of technique for being used to prepare afforestation pavement seepage material as claimed in claim 4, which is characterized in that described The preparation method of foaming screed includes the following steps:In parts by weight, 60 ~ 65 parts of cement, 10 ~ 15 parts of flyash, zeolite are taken 5 ~ 10 parts of powder, 3 ~ 5 parts of charcoal, 15 ~ 20 parts of sand, 20 ~ 30 parts of sodium chloride add in 40 ~ 50 parts of water, are stirred in agitated kettle Uniformly, it takes 0.05 ~ 0.1 part of foaming agent, 0.05 ~ 0.08 part of foam stabilizer, adds in after high-speed stirred after 3 ~ 5 parts of water forms foam, Enter in the mortar in agitated kettle, after stirring evenly, you can foaming mortar is made.
6. a kind of technique for being used to prepare afforestation pavement seepage material as described in claim 1, which is characterized in that described Binding agent press 2 ~ 4 by cement and flyash:What 1 mass ratio mixed, the cement is aluminate cement, described additional Agent is antifreezing agent.
7. a kind of technique for being used to prepare afforestation pavement seepage material as described in claim 1, which is characterized in that described Fiber for degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre, polyvinyl chloride fibre, polyphenyl Any one of vinyl fiber, Fypro, polyester fiber or arbitrary several combination.
8. a kind of technique for being used to prepare afforestation pavement seepage material as claimed in claim 7, which is characterized in that described Fiber also carried out modification, the modifying agent includes resin, polyether-ketone and nano silicon carbide granulate.
9. a kind of technique for being used to prepare afforestation pavement seepage material as claimed in claim 8, which is characterized in that described Fiber modification processing method it is as follows:In parts by weight, first take 15 ~ 20 parts of resins dry at a temperature of 80 ~ 100 DEG C, then will Dried resin is dissolved in solvent, obtains resin solution, while add in total resin weight 20 ~ 22% into resin solution again 3 ~ 4% nano silicon carbide granulate of polyether-ketone solution and total resin weight, obtain modifying agent after mixing, then put fiber Enter and processing is modified in modifying agent, you can obtain modified fibre.
CN201711444325.9A 2017-12-27 2017-12-27 Process for preparing landscaping pavement water seepage material Expired - Fee Related CN108252178B (en)

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CN116903337B (en) * 2023-09-13 2023-11-14 高密市东泰建材有限公司 Special polymer permeable mortar for paving garden permeable pavement bricks

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