CN108252161B - Scratch-resistant color foil wallpaper and preparation method thereof - Google Patents
Scratch-resistant color foil wallpaper and preparation method thereof Download PDFInfo
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- CN108252161B CN108252161B CN201711241362.XA CN201711241362A CN108252161B CN 108252161 B CN108252161 B CN 108252161B CN 201711241362 A CN201711241362 A CN 201711241362A CN 108252161 B CN108252161 B CN 108252161B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
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- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention relates to the technical field of interior decoration materials, in particular to scratch-resistant color foil wallpaper and a preparation method thereof. The color foil wallpaper comprises a wallpaper base material, a fluorescent layer compounded on the surface of the base material, a color foil layer compounded on the surface of the fluorescent layer, a decoration layer compounded on the surface of the color foil layer, and a scratch-resistant layer compounded on the surface of the decoration layer, wherein the fluorescent layer is made of resin, fluorescent powder, an auxiliary agent and functional additives, the decoration layer is made of granular materials, and the scratch-resistant layer is made of scratch-resistant materials. The color foil wallpaper is attractive and gorgeous, has a better stereoscopic vision effect, high economic value and good scratch resistance, is not easy to separate, does not fade and is durable.
Description
Technical Field
The invention relates to the technical field of interior decoration materials, in particular to scratch-resistant color foil wallpaper and a preparation method thereof.
Background
The color foil wallpaper is also called color wallpaper and handmade color wallpaper, is a special high-grade and luxurious handmade wallpaper, and is one kind of building decoration material. 99.99 percent of metal (gold, silver, copper, platinum and the like) is beaten into one in ten-thousandth thin sheets through a dozen of special processes, then manually pasted on the surface of base paper, and finally made into the color foil wallpaper through processing treatments such as various printing and the like.
The colored foil wall paper gets into market and has reached 10 years old, the most wearability of the more popular colored foil wall paper in the market at present, scratch resistance is relatively poor, the wall paper just constantly drops after the wall is gone up, especially through not having friction and the scraping of sharp object bump, and the colour also becomes dull and stereotyped gradually, cause use cost to be high, consequently, need to develop one kind and be difficult for dropping, be difficult for losing colour, durable's colored foil wall paper, present colored foil wall paper single structure in addition, lack the variety, same product appears in multiple occasion, cause visual fatigue easily.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide the gorgeous color foil wallpaper which is good in three-dimensional effect, attractive and attractive, has good scratch resistance, is not easy to separate and fade, and is durable in use.
The invention also aims to provide a preparation method of the scratch-resistant color foil wallpaper, the preparation method is simple in process and strong in operability, and the prepared color foil wallpaper is durable and is not easy to fall off.
The purpose of the invention is realized by the following technical scheme: the scratch-resistant colored foil wallpaper comprises a wallpaper base material, a fluorescent layer compounded on the surface of the base material, a colored foil layer compounded on the surface of the fluorescent layer, a decoration layer compounded on the surface of the colored foil layer, and a scratch-resistant layer compounded on the surface of the decoration layer, wherein the fluorescent layer is prepared from resin, fluorescent powder, an auxiliary agent and a functional additive, the decoration layer is prepared from a granular material, the scratch-resistant layer is prepared from a scratch-resistant material, and the scratch-resistant material comprises the following raw materials in parts by weight:
in addition, the invention designs the spot-decoration layer made of granular materials, so that the stereoscopic vision effect of the color foil wallpaper is better, and the economic value of the wallpaper is favorably improved.
Further, the alkoxysilane is one or a mixture of two or more of methyltrimethoxysilane, methyltriethoxysilane, octyltriethoxysilane, isobutyltriethoxysilane, vinyltriethoxysilane, tetraethoxysilane and tetra-n-butoxysilane.
The alkoxy silane can be hydrolyzed to produce network-shaped nano SiO 2 Network-like nano SiO 2 The hydrogen bond between the sol and the resin has larger function and the interface action strength is high, thereby ensuring the scratch resistance of the scratch-resistant coatingCan be obviously improved, and is directly added with granular nano SiO 2 Compared with the prior art, the film is more compact and has higher hardness.
Further, the scratch-resistant paint comprises the following raw materials in parts by weight:
further, the organic solvent is at least one of butyl acetate, propyl acetate and cyclohexanone.
Further, the acrylic ester polyol resin has a structural formula as follows:
wherein R is 1 、R 3 is-H or alkyl; r 2 Is an alkyl group; r 4 is-C y H 2y -; x is any structure or group; m, n and y are natural numbers.
The invention obtains SiO by hydrolyzing the acrylic ester polyol resin with the structure and alkoxy silane 2 Better combination, large hydrogen bond effect and large interface effect strength, thereby obviously improving the scratch resistance of the scratch resistant paint.
Further, the isocyanate is one or a mixture of more than two of diphenylmethane diisocyanate, toluene diisocyanate, 1,6-hexamethylene diisocyanate, naphthalene diisocyanate, isophorone diisocyanate and trans-cyclohexane diisocyanate.
Further, the catalyst is at least one of dibutyltin dilaurate and octylstannous.
Further, the functional additive is one or a mixture of more of an antistatic agent, a flame retardant, a mildew preventive, an antibacterial agent and an anion agent.
Further, the particle size of the granular material is l0-100 μm.
Further, the granular material is one or a mixture of more of gold flash chips, metal particles, sand particles, plastic particles and rubber particles. The Jin Shanpian is one or a mixture of more than one of PET, PVC, OPP and aluminum.
Furthermore, the thickness of the scratch-resistant layer is 10-100 μm.
A preparation method of scratch-resistant color foil wallpaper is characterized by comprising the following steps: the method comprises the following steps:
(1) Selecting a substrate layer and drying;
(2) Adding fluorescent powder, functional additives and auxiliaries into resin, dispersing uniformly, and forming a fluorescent layer on the substrate layer through printing, brushing or drawing processes;
(3) Gluing the surface of the fluorescent layer, and then attaching the color foil paper to the fluorescent layer to form a color foil layer;
(4) Arranging the granular material on the color foil layer by means of glue to form a decoration layer;
(5) And coating a scratch-resistant coating on the surface of the decoration layer to form a scratch-resistant layer, and finally obtaining the scratch-resistant color foil wallpaper.
The preparation method of the color foil paper has simple process and easy operation, and the prepared color foil wallpaper has beautiful appearance, high economic value and good consistency.
Further, the substrate layer can be selected from substrates commonly used for wallpaper and wall cloth, such as wood pulp paper, non-woven fabric, plain woven fabric, paper cloth composite, composite cloth and the like.
Further, in the step (2), the resin comprises one of polyvinyl chloride, acrylate, polyurethane, epoxy resin and polyolefin.
Further, the attaching mode of the color foil paper and the fluorescent layer in the step (3) is any one of the following modes:
(1) According to the design requirement, coating a pattern on the fluorescent layer by using glue, attaching the color foil on the glue, and removing the part of the color foil which is not attached to the color foil after the color foil is tightly attached to the glue to form the color foil layer with the pattern.
(2) And coating glue on the fluorescent layer, cutting the color foil into designed patterns according to the design requirement, and then attaching the color foil to the glue to form the color foil layer with the patterns.
Further, the manner of forming the dotted layer by the granular material through glue in the step (4) is any one of the following manners:
(1) According to the design requirement, glue is selectively coated on the color foil layer, granular materials are arranged on the color foil layer and the glue in a sprinkling mode, after the color foil layer and the glue are tightly adhered, the granular materials which are not adhered are removed, and the decoration layer is formed.
(2) And (3) sticking the granular material with glue to the color foil layer according to the design requirement to form the decoration layer.
Further, the preparation method of the scratch-resistant paint comprises the following steps:
(a) Uniformly mixing alkoxy silane, water and ethanol, adding acetic acid, and stirring and dispersing at 40-60 ℃ for 6-10 hours to obtain silicon dioxide sol;
(b) Dissolving acrylic ester polyol resin into a mixed solution of KOH and water, then adding the silica sol in the step (a), and stirring at the temperature of 90-110 ℃ to evaporate ethanol, thereby obtaining the silicon modified acrylic ester polyol resin.
(c) Mixing the silicon modified acrylic ester polyol resin in the step (b), isocyanate and an organic solvent, adding a catalyst, and heating for reaction for a certain time to obtain the scratch-resistant paint.
The invention adopts a sol-gel method and a polycondensation reaction to prepare a scratch-resistant coating: the network-shaped nano SiO can be produced by hydrolyzing alkoxy silane 2 Then using network-like nano SiO 2 The silicon modified acrylic ester polyol resin is obtained by removing the modified acrylic ester polyol, and then the silicon modified acrylic ester polyol resin is reacted with isocyanate to obtain the scratch-resistant paint, so that the obtained scratch-resistant paint has better film forming property, higher hardness and better scratch resistance.
The invention has the beneficial effects that: according to the invention, by designing the fluorescent layer, the fluorescent layer is matched with the metal effect of the color foil, patterns and patterns on the wallpaper can be seen even in the absence of illumination, and the wallpaper is more beautiful and gorgeous; according to the invention, the scratch-resistant layer is coated on the surface of the color foil layer, so that the color foil is not easy to separate, does not fade and is durable; according to the invention, silicon modified acrylic ester polyol resin is obtained by modifying acrylic ester polyol with silicon dioxide sol prepared by a sol-gel method, and then the silicon modified acrylic ester polyol resin is reacted with isocyanate to obtain the scratch-resistant paint, so that the scratch-resistant paint has better film forming property and better scratch resistance; the method for preparing the color foil wallpaper has the advantages of simple process and strong operability, and the prepared color foil wallpaper is durable and is not easy to fall off.
Detailed Description
The present invention will be further described with reference to the following examples for facilitating understanding of those skilled in the art, and the description of the embodiments is not intended to limit the present invention.
Example 1
The scratch-resistant colored foil wallpaper comprises a wallpaper base material, a fluorescent layer compounded on the surface of the base material, a colored foil layer compounded on the surface of the fluorescent layer, a decoration layer compounded on the surface of the colored foil layer, and a scratch-resistant layer compounded on the surface of the decoration layer. The fluorescent layer is made of resin, fluorescent powder, an additive and a functional additive, the decoration layer is made of a granular material, the scratch-resistant layer is made of a scratch-resistant coating, and the scratch-resistant coating comprises the following raw materials in parts by weight:
further, the organic solvent is butyl acetate.
Further, the alkoxy silane is octyl triethoxysilane and tetra-n-butoxy silane in a mass ratio of 1:3, and mixing to obtain a mixture.
Further, the acrylic ester polyol resin has a structural formula as follows:
wherein R is 1 、R 2 、R 3 Is an alkyl group; r 4 is-C y H 2y -; x is a polystyrene group; m, n and y are natural numbers.
Further, the isocyanate is diphenylmethane diisocyanate and toluene diisocyanate in a mass ratio of 1:3, and mixing to obtain a mixture.
Further, the catalyst is dibutyltin dilaurate.
Further, the functional additive is a mixture of an antistatic agent, a flame retardant, a mildew preventive, an antibacterial agent and a negative ion agent in a mass ratio of 1.
Further, the granular material is gold flash tablets, and the particle size of the granular material is 100 microns.
Further, the thickness of the scratch-resistant layer is 100 μm.
A preparation method of scratch-resistant color foil wallpaper is characterized by comprising the following steps: the method comprises the following steps:
(1) Selecting a substrate layer and drying;
(2) Adding fluorescent powder, functional additives and auxiliaries into resin, uniformly dispersing, and forming a fluorescent layer on the substrate layer through a drawing process;
(3) Gluing the surface of the fluorescent layer, and then attaching the color foil paper to the fluorescent layer to form a color foil layer;
(4) Coating glue on the surface of the color foil layer, and then arranging the granular materials on the color foil layer to form a dotted layer;
(5) And coating a scratch-resistant coating on the surface of the decoration layer to form a scratch-resistant layer, and finally obtaining the scratch-resistant color foil wallpaper.
Further, in the step (3), the attaching mode of the color foil paper and the fluorescent layer is according to the design requirement, the color pattern is coated on the fluorescent layer by glue, the color foil is attached to the glue, and after the color foil is tightly attached, the part of the color foil which is not attached is removed, so that the color foil layer with the pattern is formed.
Further, in the step (4), the granular material is stained with glue by a mode of forming the decoration layer by means of the glue, and the granular material is stuck to the color foil layer according to the design requirement to form the decoration layer.
Further, the preparation method of the scratch-resistant paint comprises the following steps:
(a) Uniformly mixing alkoxy silane, water and ethanol, adding acetic acid, and stirring and dispersing at 40 ℃ for 10 hours to obtain silicon dioxide sol;
(b) Dissolving acrylic ester polyol resin into a mixed solution of KOH and water, then adding the silica sol in the step (a), and stirring at 90 ℃ to evaporate ethanol to obtain the silicon modified acrylic ester polyol resin.
(c) Mixing the silicon modified acrylic ester polyol resin in the step (b), isocyanate and an organic solvent, adding a catalyst, and reacting for 20 minutes at 90 ℃ to obtain the scratch-resistant paint.
Example 2
Example 2 differs from example 1 in that the scratch-resistant layer has a thickness of 10 μm
Example 3
Example 3 differs from example 1 in that,
the scratch-resistant paint comprises the following raw materials in parts by weight:
example 4
Example 4 differs from example 1 in that,
the scratch-resistant paint comprises the following raw materials in parts by weight:
further, the alkoxy silane is methyl triethoxysilane and tetraethoxysilane according to a mass ratio of 1:3, and mixing to obtain a mixture.
Example 5
Example 5 differs from example 1 in that,
the scratch-resistant paint comprises the following raw materials in parts by weight:
example 6
Example 6 differs from example 1 in that the scratch resistant coating was prepared by a method comprising the steps of:
(a) Uniformly mixing alkoxy silane, water and ethanol, adding acetic acid, and stirring and dispersing at 40 ℃ for 10 hours to obtain silicon dioxide sol;
(b) Dissolving acrylic ester polyol resin into a mixed solution of KOH and water, then adding the silica sol in the step (a), and stirring at 90 ℃ to evaporate ethanol to obtain the silicon modified acrylic ester polyol resin.
(c) Mixing the silicon modified acrylic ester polyol resin in the step (b), isocyanate and an organic solvent, adding a catalyst, and reacting for 50 minutes at 70 ℃ to obtain the scratch-resistant paint.
Example 7
Example 7 differs from example 1 in that the scratch resistant coating was prepared by a process comprising the steps of:
(a) Uniformly mixing alkoxy silane, water and ethanol, adding acetic acid, and stirring and dispersing at 60 ℃ for 6 hours to obtain silicon dioxide sol;
(b) Dissolving acrylic ester polyol resin into a mixed solution of KOH and water, then adding the silica sol in the step (a), and stirring at 90 ℃ to evaporate ethanol to obtain the silicon modified acrylic ester polyol resin.
(c) Mixing the silicon modified acrylic ester polyol resin, isocyanate and an organic solvent, adding a catalyst, and reacting at 70 ℃ for 50 minutes to obtain the scratch-resistant coating.
Comparative example 1:
the scratch-resistant colored foil wallpaper comprises a wallpaper base material, a fluorescent layer compounded on the surface of the base material, a colored foil layer compounded on the surface of the fluorescent layer, a decoration layer compounded on the surface of the colored foil layer, and a scratch-resistant layer compounded on the surface of the decoration layer. The fluorescent layer is made of resin, fluorescent powder, an additive and a functional additive, the decoration layer is made of a granular material, the scratch-resistant layer is made of a scratch-resistant coating, and the scratch-resistant coating is composed of the following raw materials in parts by weight:
further, the organic solvent is cyclohexanone.
Further, the acrylic ester polyol resin has a structural formula as follows:
wherein R is 1 、R 2 、R 3 Is an alkyl group; r 4 is-C y H 2y -; x is a polystyrene group; m, n and y are natural numbers.
Further, the isocyanate is diphenylmethane diisocyanate and toluene diisocyanate in a mass ratio of 1:3, and mixing to obtain a mixture.
Further, the catalyst is dibutyltin dilaurate.
Furthermore, the functional additive is a mixture of an antistatic agent, a flame retardant, a mildew preventive, an antibacterial agent and an anion agent.
Further, the granular material is gold flash tablets, and the particle size of the granular material is 100 microns.
Further, the thickness of the scratch resistant layer is 100 μm.
A preparation method of scratch-resistant color foil wallpaper is characterized by comprising the following steps: the method comprises the following steps:
(1) Selecting a substrate layer and drying;
(2) Adding fluorescent powder, functional additives and auxiliaries into resin, uniformly dispersing, and forming a fluorescent layer on the substrate layer through a drawing process;
(3) Gluing the surface of the fluorescent layer, and then attaching the color foil paper to the fluorescent layer to form a color foil layer;
(4) Arranging the granular material on the color foil layer by means of glue to form a decoration layer;
(5) And coating a scratch-resistant coating on the surface of the decoration layer to form a scratch-resistant layer, and finally obtaining the scratch-resistant color foil wallpaper.
Further, the preparation method of the scratch-resistant paint comprises the following steps:
(A) Dissolving the acrylic ester polyol resin into a mixed solution of KOH and water, then adding nano silicon dioxide powder, and stirring at the temperature of 90 ℃ to obtain the silicon dioxide composite acrylic ester polyol resin.
(B) Mixing the silicon dioxide composite acrylic ester polyol resin, isocyanate and an organic solvent, adding a catalyst, and reacting for 20 minutes at 90 ℃ to obtain the scratch-resistant coating.
Comparative example 2
Comparative example 2 differs from comparative example 1 in that the scratch resistant layer has a thickness of 10 μm.
Scratch resistance, washability test, adhesion test, and test data for the scratch-resistant color foil wallpapers prepared in examples 1-7 and comparative examples 1-2 are shown in table 1. Wherein the scratch resistance of the scratch-resistant wallpaper is tested according to GB/T6739-1996 by testing the hardness comparison of scratch-resistant paint; the washability test of the scratch-resistant wallpaper is tested according to the QB/T4043-2010 standard; the adhesion test of scratch-resistant wallpaper was carried out in accordance with GB/T9286-1998.
Table 1:
as can be seen from the above table, examples 1, 3 and 4 of the present invention are superior in scratch resistance and washability to comparative example 1, and example 2 is superior in scratch resistance and washability to comparative example 2. The color foil wallpaper provided by the invention has excellent comprehensive performance.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments, such as the selection of the type and components of the alkoxysilane, ethanol, acetic acid, acrylate polyol resin, isocyanate, catalyst, and various parameters of the stirring time, reaction time, temperature, etc., of the various steps in the scratch resistant coating preparation method will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present application. Thus, the present application is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles disclosed herein.
Claims (9)
1. The scratch-resistant colored foil wallpaper is characterized by comprising a wallpaper base material, a fluorescent layer compounded on the surface of the base material, a colored foil layer compounded on the surface of the fluorescent layer, a decoration layer compounded on the surface of the colored foil layer, and a scratch-resistant layer compounded on the surface of the decoration layer, wherein the fluorescent layer is made of resin, fluorescent powder, an auxiliary agent and a functional additive, the decoration layer is made of a granular material, the scratch-resistant layer is made of a scratch-resistant material, and the scratch-resistant material comprises the following raw materials in parts by weight:
3-20 parts of alkoxy silane;
80-150 parts of ethanol;
20-80 parts of acetic acid;
100 parts of acrylate polyol resin;
50-200 parts of isocyanate;
0.1-2 parts of a catalyst;
80-150 parts of water;
5-20 parts of KOH;
20-100 parts of an organic solvent;
the structural formula of the acrylic ester polyol resin is as follows:
wherein R is 1 、R 3 is-H or alkyl; r 2 Is an alkyl group; r 4 is-C y H 2y -; x is any structure or group; m, n and y are natural numbers.
2. The scratch-resistant color foil wallpaper according to claim 1, wherein: the alkoxy silane is one or a mixture of more than two of methyl trimethoxy silane, methyl triethoxy silane, octyl triethoxy silane, isobutyl triethoxy silane, vinyl triethoxy silane, tetraethoxy silane and tetra-n-butoxy silane.
3. The scratch-resistant color foil wallpaper according to claim 1, wherein: the isocyanate is one or a mixture of more than two of diphenylmethane diisocyanate, toluene diisocyanate, 1,6-hexamethylene diisocyanate, naphthalene diisocyanate, isophorone diisocyanate and trans cyclohexane diisocyanate.
4. The scratch-resistant color foil wallpaper according to claim 1, wherein: the catalyst is at least one of dibutyltin dilaurate and octylstannous.
5. The scratch-resistant color foil wallpaper according to claim 1, wherein: the functional additive is one or a mixture of more of an antistatic agent, a flame retardant, a mildew preventive, an antibacterial agent and an anion agent.
6. The scratch-resistant color foil wallpaper according to claim 1, wherein: the granular material is one or a mixture of more of gold flash sheets, metal particles, sand particles, plastic particles and rubber particles, and the particle size of the granular material is l0-100 mu m.
7. The scratch-resistant color foil wallpaper according to claim 1, wherein: the thickness of the scratch-resistant layer is 10-100 mu m.
8. The method for preparing the scratch-resistant color foil wallpaper according to any one of claims 1-7, wherein the method comprises the following steps: the method comprises the following steps:
(1) Selecting a substrate layer and drying;
(2) Adding fluorescent powder, functional additives and auxiliaries into resin, uniformly dispersing, and forming a fluorescent layer on the substrate layer through printing, brushing or drawing processes;
(3) Gluing the surface of the fluorescent layer, and then attaching the color foil paper to the fluorescent layer to form a color foil layer;
(4) Arranging the granular material on the color foil layer by means of glue to form a decoration layer;
(5) And coating a scratch-resistant coating on the surface of the decoration layer to form a scratch-resistant layer, and finally obtaining the scratch-resistant color foil wallpaper.
9. The method for preparing the scratch-resistant color foil wallpaper according to claim 8, wherein the method comprises the following steps: the preparation method of the scratch-resistant paint comprises the following steps:
(a) Uniformly mixing alkoxy silane, water and ethanol, adding acetic acid, and stirring and dispersing at 40-60 ℃ for 6-10 hours to obtain silicon dioxide sol;
(b) Dissolving acrylic ester polyol resin into a mixed solution of KOH and water, then adding the silica sol obtained in the step (a), and stirring at the temperature of 90-110 ℃ to evaporate ethanol, thereby obtaining silicon modified acrylic ester polyol resin;
(c) Mixing the silicon modified acrylic ester polyol resin in the step (b), isocyanate and an organic solvent, adding a catalyst, and heating for reaction for a certain time to obtain the scratch-resistant paint.
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| CN201711241362.XA CN108252161B (en) | 2017-11-30 | 2017-11-30 | Scratch-resistant color foil wallpaper and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07117183A (en) * | 1993-08-30 | 1995-05-09 | Toppan Printing Co Ltd | Composite decorative sheet and manufacture thereof |
| CN102559031A (en) * | 2011-12-30 | 2012-07-11 | 江苏创基新材料有限公司 | Organosilicon-modified aqueous polyurethane-acrylate composite coating agent and preparation method thereof |
| CN203499177U (en) * | 2013-05-08 | 2014-03-26 | 广东玉兰装饰材料有限公司 | Multilayer metal colored foil wallpaper |
| CN107254808A (en) * | 2017-07-07 | 2017-10-17 | 广东玉兰集团股份有限公司 | A kind of wallpaper skin covering of the surface and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6592700B2 (en) * | 2001-08-27 | 2003-07-15 | San Fang Chemical Industry Co., Ltd. | Method of producing retro-reflective sheet with high abrasion resistance |
-
2017
- 2017-11-30 CN CN201711241362.XA patent/CN108252161B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07117183A (en) * | 1993-08-30 | 1995-05-09 | Toppan Printing Co Ltd | Composite decorative sheet and manufacture thereof |
| CN102559031A (en) * | 2011-12-30 | 2012-07-11 | 江苏创基新材料有限公司 | Organosilicon-modified aqueous polyurethane-acrylate composite coating agent and preparation method thereof |
| CN203499177U (en) * | 2013-05-08 | 2014-03-26 | 广东玉兰装饰材料有限公司 | Multilayer metal colored foil wallpaper |
| CN107254808A (en) * | 2017-07-07 | 2017-10-17 | 广东玉兰集团股份有限公司 | A kind of wallpaper skin covering of the surface and preparation method thereof |
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