CN108251172A - A kind of efficient emission-reducing state IV diesel quality elevators - Google Patents
A kind of efficient emission-reducing state IV diesel quality elevators Download PDFInfo
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- CN108251172A CN108251172A CN201810039963.0A CN201810039963A CN108251172A CN 108251172 A CN108251172 A CN 108251172A CN 201810039963 A CN201810039963 A CN 201810039963A CN 108251172 A CN108251172 A CN 108251172A
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
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- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
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- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/12—Use of additives to fuels or fires for particular purposes for improving the cetane number
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
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- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
- C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
- C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
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- C10L1/14—Organic compounds
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Abstract
The present invention relates to a kind of fuel oil additives, particularly a kind of quality-improving agent for state's IV diesel oil, include the compound of following parts by weight:38 parts of isooctyl ester nitrate, 5 10 parts of lubricant, 12 18 parts of polyisobutene succinimide, 10 15 parts of polyetheramine, 8 12 parts of plastic of poly vinyl acetate, 10 25 parts of dimethyl carbonate, 5 10 parts of polymethoxy dimethyl ether, 5 10 parts of dispersant, 16 24 parts of solvent naphtha.Compared with prior art, product of the present invention is in neutrality, and any acid and alkali corrosion will not be caused to diesel engine;Product can effectively improve fuel efficiency;The greasy property that frictional dissipation in cylinder improves diesel oil can be reduced, promotes fuel economy;And PM10, PM2.5, CO, HC and NO can be reduced simultaneouslyxDischarge and reduction fuel consumption, increasing service life of engine have important actual application value.
Description
Technical field
The present invention relates to a kind of fuel oil additives, particularly a kind of quality-improving agent for state's IV diesel oil.
Background technology
At present, frequent haze weather has become the main atmosphere pollution problem that China faces.The generation of haze with it is motor-driven
The nitrogen oxides of vehicle discharge(NOx), fine particle(PM2.5)Wait pollutants directly related, the wherein NO of emission of diesel enginexIt is close
The 70% of vehicle mass exhaust total quantity, particulate matter are even more more than 90%.The consumption of diesel oil just increases year by year, and a large amount of diesel consumption causes
The discharge of vehicle nuisance is further exacerbated by.Therefore diesel emission abatement is the most important thing that haze is administered.Do not change vehicle with
Engine structure under conditions of also not increasing equipment, can change the physical property of fuel using diesel fuel additives, fuel is made fully to fire
It burns, so as to fulfill energy saving and purification discharge.Therefore, the diesel fuel additives for developing efficient emission-reducing is the emphasis studied from now on, is solved
One of Main way of haze weather.
Diesel fuel additives both domestic and external is broadly divided into three classes:First, energy saving additive, main purpose is to improve
The power of engine reduces oil consumption;Second is that environment protection additive, main purpose is the discharge of purifying engine, reduces pollution;
Third, comprehensive additive, content not only energy saving but also that harmful substance in engine exhaust can be reduced.Due in conventional diesel engine
Burning be difficult to take into account PM2.5 and NOxDischarge improves diesel quality performance, while it is gentle to reduce PM2.5 by quality-improving agent
State pollutant emission simultaneously saves the method that fuel oil is worth exploration.Due to particulate matter and NO in diesel engine combustionxGeneration
It mutually restricts, is only possible to obtain comprehensive efficient emission-reducing effect using composite additive.At present, applied to state's IV bavins
Oil can reduce HC, CO, PM2.5 and NO simultaneouslyxAdditive have not been reported.
Invention content
The present invention seeks to fill a hole in the market, a kind of diesel oil addition of high-performance high-quality for state's IV diesel oil is provided
Agent.
Technical solution disclosed by the invention is:This quality-improving agent for state's IV diesel oil includes following parts by weight
Compound:
3-8 parts of isooctyl ester nitrate
5-10 parts of lubricant
12-18 parts of polyisobutene succinimide
10-15 parts of polyetheramine
8-12 parts of plastic of poly vinyl acetate
10-25 parts of dimethyl carbonate
5-10 parts of polymethoxy dimethyl ether
5-10 parts of dispersant
16-24 parts of solvent naphtha.
The wherein described lubricant is one or more of monooctyl ester, the own ester of acetoacetate, aphthenic acids, hexyl oleate;Point
Powder is one or more of vinyl alcohol butyl ether, triethylene tetramine, triethylamine, vinyl alcohol butyl ether and Span-80;Solvent naphtha is
120#, 200# solvent naphtha one or two therein.
The preparation method of this quality-improving agent for state's IV diesel oil, have main steps that by the component of aforementioned weight according to
Heating is reacted 20 minutes under the conditions of 40 DEG C in secondary addition reaction kettle.
The application method of this quality-improving agent for state's IV diesel oil is by the aforementioned diesel quality elevator prepared
According to diesel quality elevator:State IV diesel oil=1:The volumetric ratio acceding state IV diesel oil of 1000-2000, stirs evenly.
Compared with prior art, product of the present invention is in neutrality, and any acid and alkali corrosion will not be caused to diesel engine.Product
Fuel efficiency can be effectively improved, while reduces the greasy property that frictional dissipation in cylinder improves diesel oil, promotes fuel economy;From
And reach while reduce PM10, PM2.5, CO, HC and NOxDischarge and reduction fuel consumption, increasing service life of engine, have
Important actual application value.
Specifically, the present invention has following features:
1st, this product contains series polymeric body organic matter, without the harmful components such as metal and phosphorus, chlorine, contains dispersant, product tool
There are good " intersolubility " and " anti-corrosive properties ".
2nd, the addition of isooctyl ester nitrate can improve the Cetane number of diesel oil, improve the combustibility of diesel oil, improve diesel oil hair
Fire shortens ignition time, reduces burning point, improves locomotive thermal condition dynamic property.
3rd, polyisobutene succinimide has the surfactant of amphiprotic group, passes through hydrophilic radical and lipophilic group
Collective effect promotes fuel spray finer and smoother, unit interval oil spout particle flux is made to attenuate, so that its total specific surface area increase, makes
Micro-droplet of oil accelerated expansion under high temperature action gasifies, and make combustion gas mixing uniform, so as to accelerate its evaporation rate, ignition temperature
It reduces, so that increased flame speeds, make flame propagation velocity orderly, burning is more abundant, and fuel thermal efficiency improves, and reduces combustion
Oilconsumption.
4th, the addition of polyetheramine, dimethyl carbonate makes fuel oil adequately all burn, and reduces the generation of carbon particle, improves
Burning velocity makes thermal discharge reach cycle thermal discharge.It is mainly shown as enhancing power, reduces oil consumption, reduces exhaust emission row
High-volume.
5th, the addition of plastic of poly vinyl acetate makes cold vehicle easily start, reduces noise, extending the service life of engine;
Due to the addition of polymethoxy dimethyl ether, diesel oil oxygen content can be improved, increases the Cetane number of diesel oil, improves that engine is cold to be opened
Dynamic property achievees the purpose that combustion-supporting reduction smoke intensity.
6th, the addition of polyisobutene succinimide can be removed effectively and inhibit engine fuel system and combustion chamber deposit
Substance(Such as carbon distribution, colloid), the service life of engine fuel oil system parts is improved, prevents fuel feed pump plunger, oil burner
Phenomena such as sintering, occurs.
Specific embodiment
Embodiment 1
Isooctyl ester nitrate 5g
Lubricant 5g
Polyisobutene succinimide 12g
Polyetheramine 10g
Plastic of poly vinyl acetate 10g
Dimethyl carbonate 25g
Polymethoxy dimethyl ether 8g
Dispersant 5g
120# solvent naphthas 18g
Said components are sequentially added by weight and heat reaction 20 minutes in reaction kettle under the conditions of 40 DEG C.
Embodiment 2
Isooctyl ester nitrate 3g
Lubricant 8g
Polyisobutene succinimide 12g
Polyetheramine 12g
Plastic of poly vinyl acetate 10g
Dimethyl carbonate 18g
Polymethoxy dimethyl ether 5g
Dispersant 5g
200# solvent naphthas 20g
Said components are sequentially added by weight and heat reaction 20 minutes in reaction kettle under the conditions of 40 DEG C.
Embodiment 3
Isooctyl ester nitrate 7g
Lubricant 10g
Polyisobutene succinimide 12g
Polyetheramine 15g
Plastic of poly vinyl acetate 10g
Dimethyl carbonate 10g
Polymethoxy dimethyl ether 10g
Dispersant 7g
120# solvent naphthas 12g
200# solvent naphthas 12g
Said components are sequentially added by weight and heat reaction 20 minutes in reaction kettle under the conditions of 40 DEG C.
By the 50L states IV 0# diesel oil for not adding in any additive labeled as sample A, above-mentioned three kinds will be separately added into specifically
Diesel quality elevator 150ml prepared by embodiment is added to 50L states IV 0# diesel oil, and sample is respectively labeled as after stirring evenly
Product B, C, D, by 4 samples according to GB17691-2005《Automobile-used compression-ignited, gaseous fuel spark-ignition engine and automobile exhaust are dirty
Contaminate object emission limit and measuring method(Chinese III, IV, V stage)》Carry out platform experiment, experimental result such as following table:
From upper table test result can be seen that add in the present invention diesel quality elevator after, major pollutants index PM and
PM2.5 declines more than 10%, CO, HC, NOxAlso it significantly decreases, therefore the present invention can reduce PM and CO, HC, NO simultaneouslyxPollution
Object discharges, and has important actual application value.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (4)
1. a kind of quality-improving agent for state's IV diesel oil includes the compound of following parts by weight:
3-8 parts of isooctyl ester nitrate
5-10 parts of lubricant
12-18 parts of polyisobutene succinimide
10-15 parts of polyetheramine
8-12 parts of plastic of poly vinyl acetate
10-25 parts of dimethyl carbonate
5-10 parts of polymethoxy dimethyl ether
5-10 parts of dispersant
16-24 parts of solvent naphtha.
2. a kind of quality-improving agent for state's IV diesel oil according to claim 1, it is characterised in that:The lubricant
For one or more of monooctyl ester, the own ester of acetoacetate, aphthenic acids, hexyl oleate;Dispersant is vinyl alcohol butyl ether, triethylene four
One or more of amine, triethylamine, vinyl alcohol butyl ether and Span-80;Solvent naphtha is 120#, 200# solvent naphtha one kind therein
Or two kinds.
3. a kind of preparation method of quality-improving agent for state's IV diesel oil described in claims 1 or 2, including by aforementioned weight
Part component sequentially add in reaction kettle under the conditions of 40 DEG C heating reaction 20 minutes the step of.
4. a kind of application method of quality-improving agent for state's IV diesel oil described in claims 1 or 2, is the bavin that will be prepared
Oil quality elevator is according to diesel quality elevator:State IV diesel oil=1:The volumetric ratio acceding state IV diesel oil of 1000-2000, stirring
Uniformly.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108998121A (en) * | 2018-07-31 | 2018-12-14 | 泰安汉能能源科技有限公司 | Diesel oil synchronous working liquid |
CN111286377A (en) * | 2020-02-19 | 2020-06-16 | 四川天舟通用航空科技有限公司 | Diesel oil environment-friendly additive and clean diesel oil |
CN111909739A (en) * | 2020-07-31 | 2020-11-10 | 王金龙 | Diesel energy-saving cleaning synergist and preparation method thereof |
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CN101709233A (en) * | 2009-10-28 | 2010-05-19 | 上海应用技术学院 | Diesel fuel pour-point depressant dispersant and preparation method thereof |
CN103805297A (en) * | 2012-11-15 | 2014-05-21 | 亚申科技研发中心(上海)有限公司 | Smokeless diesel oil and preparation method thereof |
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