CN108250926A - A kind of soft magnetism coating - Google Patents

A kind of soft magnetism coating Download PDF

Info

Publication number
CN108250926A
CN108250926A CN201810017888.8A CN201810017888A CN108250926A CN 108250926 A CN108250926 A CN 108250926A CN 201810017888 A CN201810017888 A CN 201810017888A CN 108250926 A CN108250926 A CN 108250926A
Authority
CN
China
Prior art keywords
soft magnetism
coating
magnetic
soft
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810017888.8A
Other languages
Chinese (zh)
Inventor
严鹏
张桂芳
杨清荣
高磊
史本慧
郑玮
姜琪
施哲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CN201810017888.8A priority Critical patent/CN108250926A/en
Publication of CN108250926A publication Critical patent/CN108250926A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23Magnetisable or magnetic paints or lacquers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K2003/023Silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0862Nickel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Hard Magnetic Materials (AREA)

Abstract

The present invention relates to a kind of soft magnetism coating, belong to magnetic powder technical field.The soft magnetism coating is by following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30~50%, carborundum powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.The soft magnetism coating that the present invention is prepared has higher magnetic flux density and relatively low coercivity, when this coating is applied to magnetic separator working face, due to having higher magnetic flux density, can strengthen the collecting ability for microfine magnetic mineral at the magnetic separation stage.

Description

A kind of soft magnetism coating
Technical field
The present invention relates to a kind of soft magnetism coating, belong to magnetic powder technical field.
Background technology
It is well known that roll-type weak magnetic separator, roll-type high intensity magnetic separator, tablet high gradient magnetic separator, strong magnetic iron removing belt etc. are forever Magnetic machine is very common in the assorting room of magnetic mineral.And it sorts face(With ore pulp contact surface)It is smooth non-magnetic Property metal or nonmetallic surface, are unfavorable for the recycling of microfine magnetic mineral.And common magnetic material in ore dressing, have high Magnetic flux density and big coercivity, but demagnetization is very difficult, and being made when magnetic coating is used for benficiation machinery surface of it can make It is difficult into ore deposit is unloaded.
Number of patent application is 2015108944843, and a kind of soft magnetism conductive coating and its preparation method and application discloses A kind of soft magnetism conductive coating, main component are 50~72 parts of low temperature curing resins, 1~10 part of soft magnetism conductive filler, 28 ~50 parts of solvents, 0.2~50 part of dispersant, 1 part of antifoaming agent and 1 part of advection agent.The patent application overcomes the soft of the prior art The problem of magnetic conducting coating amount of filler is larger is not changing coating in the performances base such as metal surface adhesive force, corrosion resistance Electric conductivity is improved on plinth;In the case of identical filler additive amount, realize that conductivity increases the effect of an order of magnitude.But It is the magnetic flux density and coercivity that soft magnetism conductive coating in the patent application does not involve the need for improving the coating The characteristics of small.
Invention content
For the above-mentioned prior art there are the problem of and deficiency, the present invention a kind of soft magnetism coating is provided.The present invention is prepared into The soft magnetism coating arrived has higher saturation flux density and relatively low coercivity.The invention is realized by the following technical scheme.
A kind of soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30~50%, carbon SiClx powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.
The soft magnet powder is iron-nickel alloy, one or any two kinds of mixed-powders in ferro-silicium, and powder size is 0.074mm~0.018mm.
The iron-nickel alloy is Fe50wt% and Ni50wt%.
The ferro-silicium is Fe94wt% and Si6wt%.
The beneficial effects of the invention are as follows:The soft magnetism coating that the present invention is prepared has higher magnetic flux density and relatively low Coercivity when this coating is applied to magnetic separator working face, due to having higher magnetic flux density, can be strengthened at the magnetic separation stage For the collecting ability of microfine magnetic mineral;When unloading the ore deposit stage due to smaller coercivity, magnetic mineral is not interfered with Unload ore deposit;So coating is conducive to improve the rate of recovery and grade of magnetic mineral.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 25%, polyurethane 45%, carborundum powder 15%, diformazan Benzene 15%, four kinds of component summations are 100%.Wherein soft magnet powder is iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), iron Ni alloy powder and carborundum powder granularity are 0.045mm~0.018mm.
Above-mentioned soft magnetism coating saturation flux density is 1.3T, coercivity 0.75Oe.
Tablet high gradient magnetic separator, roll-type is strong(It is weak)It dries in the air after rinsing well in the sorting face of magnetic separator or belt-type iron remover It is dry, the soft magnetism coating that the present embodiment is prepared uniformly is applied to a surface.
The potassium feldspar sample ore in Guangdong somewhere is carried out using tablet high gradient magnetic separator except iron tests, sorting granularity is -200 Mesh accounts for 80%, contains Fe2O3For 3.02wt%, after removing iron using ordinary flat high gradient magnetic separator, sample contains Fe2O3For 0.88wt%, except iron rate is 70.86%;Under the same conditions, only with the soft magnetism coating in embodiment 1 to tablet high-gradient magnetic separation The sorting belt of machine is carried out after being brushed except iron tests, and obtained sample contains Fe2O3For 0.53wt%, except iron rate is 82.45%.
Embodiment 2
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20%, polyurethane 50%, carborundum powder 10%, diformazan Benzene 20%, four kinds of component summations are 100%.Wherein soft magnet powder is ferro-silicium(Ferro-silicium is Fe94wt% and Si6wt%), ferrosilicon Alloy powder and carborundum powder granularity are 0.074mm~0.045mm.
Above-mentioned soft magnetism coating saturation flux density is 1.5T, coercivity 3.9Oe.
Embodiment 3
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 35%, polyurethane 40%, carborundum powder 10%, diformazan Benzene 15%, four kinds of component summations are 100%.It is 1 that wherein soft magnet powder, which is mass ratio,:1 ferro-silicium(Ferro-silicium is Fe94wt% And Si6wt%)And iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), soft magnetic powder and carborundum powder granularity are 0.074mm~0.045mm.
Above-mentioned soft magnetism coating saturation flux density is 1.38T, coercivity 1.1Oe.
Embodiment 4
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20%, polyurethane 30%, carborundum powder 20%, diformazan Benzene 30%, four kinds of component summations are 100%.It is 1 that wherein soft magnet powder, which is mass ratio,:1 ferro-silicium(Ferro-silicium is Fe94wt% And Si6wt%)And iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), soft magnetic powder and carborundum powder granularity are 0.074mm~0.045mm.
The specific embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party Formula within the knowledge of a person skilled in the art, can also be made under the premise of present inventive concept is not departed from Go out various change.

Claims (4)

1. a kind of soft magnetism coating, it is characterised in that:By following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30 ~50%, carborundum powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.
2. soft magnetism coating according to claim 1, it is characterised in that:The soft magnet powder is iron-nickel alloy, in ferro-silicium One or any two kinds of mixed-powders, powder size are 0.074mm~0.018mm.
3. soft magnetism coating according to claim 2, it is characterised in that:The iron-nickel alloy is Fe50wt% and Ni50wt%.
4. soft magnetism coating according to claim 2, it is characterised in that:The ferro-silicium is Fe94wt% and Si6wt%.
CN201810017888.8A 2018-01-09 2018-01-09 A kind of soft magnetism coating Pending CN108250926A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810017888.8A CN108250926A (en) 2018-01-09 2018-01-09 A kind of soft magnetism coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810017888.8A CN108250926A (en) 2018-01-09 2018-01-09 A kind of soft magnetism coating

Publications (1)

Publication Number Publication Date
CN108250926A true CN108250926A (en) 2018-07-06

Family

ID=62725056

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810017888.8A Pending CN108250926A (en) 2018-01-09 2018-01-09 A kind of soft magnetism coating

Country Status (1)

Country Link
CN (1) CN108250926A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551446A (en) * 2019-09-21 2019-12-10 盐城增材科技有限公司 Magnetic flame-retardant waterborne polyurethane coating and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0967567A1 (en) * 1998-06-23 1999-12-29 Agfa-Gevaert N.V. A chip card comprising an imaged image-receiving layer
CN104231708A (en) * 2013-06-20 2014-12-24 广州新莱福磁电有限公司 Soft magnetic coating used multipolar static magnetic field, and preparation method of soft magnetic coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0967567A1 (en) * 1998-06-23 1999-12-29 Agfa-Gevaert N.V. A chip card comprising an imaged image-receiving layer
CN104231708A (en) * 2013-06-20 2014-12-24 广州新莱福磁电有限公司 Soft magnetic coating used multipolar static magnetic field, and preparation method of soft magnetic coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551446A (en) * 2019-09-21 2019-12-10 盐城增材科技有限公司 Magnetic flame-retardant waterborne polyurethane coating and application thereof

Similar Documents

Publication Publication Date Title
CN103003900B (en) Permanent magnet and the method manufacturing permanent magnet
CN108831655B (en) Method for improving coercive force of neodymium iron boron sintered permanent magnet
CN108565109B (en) Preparation method of soft magnetic composite material
CN108987025B (en) High-permeability low-loss soft magnetic composite material and preparation method thereof
CN106783131A (en) A kind of preparation method of sintered NdFeB thin slice magnet
Darcy et al. Challenges in recycling end-of-life rare earth magnets
CN109887698B (en) Composite magnetic powder core and preparation method thereof
CN111653407B (en) Gradient-distributed neodymium-iron-boron magnet and preparation method thereof
CN106920669B (en) Preparation method of R-Fe-B sintered magnet
CN108597713B (en) Preparation method of magnetic material
CN108250926A (en) A kind of soft magnetism coating
CN110853910A (en) Preparation method of high-permeability low-loss soft magnetic composite material and magnetic ring thereof
CN108962582A (en) A kind of neodymium iron boron magnetic body coercivity method for improving
CN102453882A (en) Magnetic circuit for sputtering apparatus
US3887395A (en) Cobalt-rare earth magnets comprising sintered products bonded with cobalt-rare earth bonding agents
JPH0244606A (en) Composite material for magnetic and electron shield and permanent magnet
CN108987020B (en) Method for reducing surface magnetic difference of two surfaces of sintered neodymium iron boron magnet cutting black sheet
Itoh et al. Recycle of rare earth sintered magnet powder scraps as electromagnetic wave absorbers in gigahertz range
CN110853861B (en) Magnetic separation sheet for wireless charging receiving end and preparation method thereof
CN111068992A (en) Powder coating method, finished product powder and finished product magnetic powder core preparation method
US2154399A (en) Demagnetization
CN112908603A (en) Iron-based amorphous magnetic powder core and preparation method thereof
Menad et al. Recovery of permanent magnets type NdFeB from WEEE
CN108565108B (en) Iron-silicon-titanium magnetic powder core and preparation method and application thereof
KR101235764B1 (en) METHOD FOR SEPARATION OF POWDERED FeNi METAL FROM FERRO NICKEL SLAG/RECYCLE AND APPARATUS THEREOF

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180706

RJ01 Rejection of invention patent application after publication