CN108250926A - A kind of soft magnetism coating - Google Patents
A kind of soft magnetism coating Download PDFInfo
- Publication number
- CN108250926A CN108250926A CN201810017888.8A CN201810017888A CN108250926A CN 108250926 A CN108250926 A CN 108250926A CN 201810017888 A CN201810017888 A CN 201810017888A CN 108250926 A CN108250926 A CN 108250926A
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- China
- Prior art keywords
- soft magnetism
- coating
- magnetic
- soft
- powder
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- 239000011248 coating agent Substances 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 230000005389 magnetism Effects 0.000 title claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 28
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 10
- 229920002635 polyurethane Polymers 0.000 claims abstract description 7
- 239000004814 polyurethane Substances 0.000 claims abstract description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 10
- 239000011812 mixed powder Substances 0.000 claims description 2
- 230000004907 flux Effects 0.000 abstract description 10
- 239000006148 magnetic separator Substances 0.000 abstract description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 6
- 239000011707 mineral Substances 0.000 abstract description 6
- 239000006247 magnetic powder Substances 0.000 abstract description 4
- 238000007885 magnetic separation Methods 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005347 demagnetization Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006246 high-intensity magnetic separator Substances 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/23—Magnetisable or magnetic paints or lacquers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/023—Silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Hard Magnetic Materials (AREA)
Abstract
The present invention relates to a kind of soft magnetism coating, belong to magnetic powder technical field.The soft magnetism coating is by following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30~50%, carborundum powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.The soft magnetism coating that the present invention is prepared has higher magnetic flux density and relatively low coercivity, when this coating is applied to magnetic separator working face, due to having higher magnetic flux density, can strengthen the collecting ability for microfine magnetic mineral at the magnetic separation stage.
Description
Technical field
The present invention relates to a kind of soft magnetism coating, belong to magnetic powder technical field.
Background technology
It is well known that roll-type weak magnetic separator, roll-type high intensity magnetic separator, tablet high gradient magnetic separator, strong magnetic iron removing belt etc. are forever
Magnetic machine is very common in the assorting room of magnetic mineral.And it sorts face(With ore pulp contact surface)It is smooth non-magnetic
Property metal or nonmetallic surface, are unfavorable for the recycling of microfine magnetic mineral.And common magnetic material in ore dressing, have high
Magnetic flux density and big coercivity, but demagnetization is very difficult, and being made when magnetic coating is used for benficiation machinery surface of it can make
It is difficult into ore deposit is unloaded.
Number of patent application is 2015108944843, and a kind of soft magnetism conductive coating and its preparation method and application discloses
A kind of soft magnetism conductive coating, main component are 50~72 parts of low temperature curing resins, 1~10 part of soft magnetism conductive filler, 28
~50 parts of solvents, 0.2~50 part of dispersant, 1 part of antifoaming agent and 1 part of advection agent.The patent application overcomes the soft of the prior art
The problem of magnetic conducting coating amount of filler is larger is not changing coating in the performances base such as metal surface adhesive force, corrosion resistance
Electric conductivity is improved on plinth;In the case of identical filler additive amount, realize that conductivity increases the effect of an order of magnitude.But
It is the magnetic flux density and coercivity that soft magnetism conductive coating in the patent application does not involve the need for improving the coating
The characteristics of small.
Invention content
For the above-mentioned prior art there are the problem of and deficiency, the present invention a kind of soft magnetism coating is provided.The present invention is prepared into
The soft magnetism coating arrived has higher saturation flux density and relatively low coercivity.The invention is realized by the following technical scheme.
A kind of soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30~50%, carbon
SiClx powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.
The soft magnet powder is iron-nickel alloy, one or any two kinds of mixed-powders in ferro-silicium, and powder size is
0.074mm~0.018mm.
The iron-nickel alloy is Fe50wt% and Ni50wt%.
The ferro-silicium is Fe94wt% and Si6wt%.
The beneficial effects of the invention are as follows:The soft magnetism coating that the present invention is prepared has higher magnetic flux density and relatively low
Coercivity when this coating is applied to magnetic separator working face, due to having higher magnetic flux density, can be strengthened at the magnetic separation stage
For the collecting ability of microfine magnetic mineral;When unloading the ore deposit stage due to smaller coercivity, magnetic mineral is not interfered with
Unload ore deposit;So coating is conducive to improve the rate of recovery and grade of magnetic mineral.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 25%, polyurethane 45%, carborundum powder 15%, diformazan
Benzene 15%, four kinds of component summations are 100%.Wherein soft magnet powder is iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), iron
Ni alloy powder and carborundum powder granularity are 0.045mm~0.018mm.
Above-mentioned soft magnetism coating saturation flux density is 1.3T, coercivity 0.75Oe.
Tablet high gradient magnetic separator, roll-type is strong(It is weak)It dries in the air after rinsing well in the sorting face of magnetic separator or belt-type iron remover
It is dry, the soft magnetism coating that the present embodiment is prepared uniformly is applied to a surface.
The potassium feldspar sample ore in Guangdong somewhere is carried out using tablet high gradient magnetic separator except iron tests, sorting granularity is -200
Mesh accounts for 80%, contains Fe2O3For 3.02wt%, after removing iron using ordinary flat high gradient magnetic separator, sample contains Fe2O3For
0.88wt%, except iron rate is 70.86%;Under the same conditions, only with the soft magnetism coating in embodiment 1 to tablet high-gradient magnetic separation
The sorting belt of machine is carried out after being brushed except iron tests, and obtained sample contains Fe2O3For 0.53wt%, except iron rate is 82.45%.
Embodiment 2
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20%, polyurethane 50%, carborundum powder 10%, diformazan
Benzene 20%, four kinds of component summations are 100%.Wherein soft magnet powder is ferro-silicium(Ferro-silicium is Fe94wt% and Si6wt%), ferrosilicon
Alloy powder and carborundum powder granularity are 0.074mm~0.045mm.
Above-mentioned soft magnetism coating saturation flux density is 1.5T, coercivity 3.9Oe.
Embodiment 3
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 35%, polyurethane 40%, carborundum powder 10%, diformazan
Benzene 15%, four kinds of component summations are 100%.It is 1 that wherein soft magnet powder, which is mass ratio,:1 ferro-silicium(Ferro-silicium is Fe94wt%
And Si6wt%)And iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), soft magnetic powder and carborundum powder granularity are
0.074mm~0.045mm.
Above-mentioned soft magnetism coating saturation flux density is 1.38T, coercivity 1.1Oe.
Embodiment 4
The soft magnetism coating, by following mass percent into being grouped as:Soft magnet powder 20%, polyurethane 30%, carborundum powder 20%, diformazan
Benzene 30%, four kinds of component summations are 100%.It is 1 that wherein soft magnet powder, which is mass ratio,:1 ferro-silicium(Ferro-silicium is Fe94wt%
And Si6wt%)And iron-nickel alloy(Iron-nickel alloy is Fe50wt% and Ni50wt%), soft magnetic powder and carborundum powder granularity are
0.074mm~0.045mm.
The specific embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula within the knowledge of a person skilled in the art, can also be made under the premise of present inventive concept is not departed from
Go out various change.
Claims (4)
1. a kind of soft magnetism coating, it is characterised in that:By following mass percent into being grouped as:Soft magnet powder 20~35%, polyurethane 30
~50%, carborundum powder 10~20%, dimethylbenzene 15~30%, four kinds of component summations are 100%.
2. soft magnetism coating according to claim 1, it is characterised in that:The soft magnet powder is iron-nickel alloy, in ferro-silicium
One or any two kinds of mixed-powders, powder size are 0.074mm~0.018mm.
3. soft magnetism coating according to claim 2, it is characterised in that:The iron-nickel alloy is Fe50wt% and Ni50wt%.
4. soft magnetism coating according to claim 2, it is characterised in that:The ferro-silicium is Fe94wt% and Si6wt%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810017888.8A CN108250926A (en) | 2018-01-09 | 2018-01-09 | A kind of soft magnetism coating |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810017888.8A CN108250926A (en) | 2018-01-09 | 2018-01-09 | A kind of soft magnetism coating |
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Publication Number | Publication Date |
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CN108250926A true CN108250926A (en) | 2018-07-06 |
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ID=62725056
Family Applications (1)
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CN201810017888.8A Pending CN108250926A (en) | 2018-01-09 | 2018-01-09 | A kind of soft magnetism coating |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110551446A (en) * | 2019-09-21 | 2019-12-10 | 盐城增材科技有限公司 | Magnetic flame-retardant waterborne polyurethane coating and application thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0967567A1 (en) * | 1998-06-23 | 1999-12-29 | Agfa-Gevaert N.V. | A chip card comprising an imaged image-receiving layer |
CN104231708A (en) * | 2013-06-20 | 2014-12-24 | 广州新莱福磁电有限公司 | Soft magnetic coating used multipolar static magnetic field, and preparation method of soft magnetic coating |
-
2018
- 2018-01-09 CN CN201810017888.8A patent/CN108250926A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0967567A1 (en) * | 1998-06-23 | 1999-12-29 | Agfa-Gevaert N.V. | A chip card comprising an imaged image-receiving layer |
CN104231708A (en) * | 2013-06-20 | 2014-12-24 | 广州新莱福磁电有限公司 | Soft magnetic coating used multipolar static magnetic field, and preparation method of soft magnetic coating |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110551446A (en) * | 2019-09-21 | 2019-12-10 | 盐城增材科技有限公司 | Magnetic flame-retardant waterborne polyurethane coating and application thereof |
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Application publication date: 20180706 |
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