CN108250489A - A kind of plastics cyan colorant composition and dyeing particles - Google Patents
A kind of plastics cyan colorant composition and dyeing particles Download PDFInfo
- Publication number
- CN108250489A CN108250489A CN201810054674.8A CN201810054674A CN108250489A CN 108250489 A CN108250489 A CN 108250489A CN 201810054674 A CN201810054674 A CN 201810054674A CN 108250489 A CN108250489 A CN 108250489A
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- China
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- parts
- plastics
- cyan colorant
- colorant composition
- particles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention discloses a kind of plastics cyan colorant composition and dyeing particles.A kind of plastics cyan colorant composition includes 220 230 parts of titanium dioxides, 0.025 0.035 parts of toner black smokes, 0.15 0.25 parts of red powder, 1.3 1.4 parts of blue powder, 12 15 parts of phthalocyanine colors, 18 21 parts of EBS, 48 52 parts of magnesium stearates；It dyes particles and includes 98.9 99.9 parts of ABS, 1.0 1.1 parts of plastics cyan colorant compositions as described above.The defects of plastics cyan colorant composition provided by the present invention and dyeing particles will not generate stain, gas trace in the production process of coloured plastics grain, coloring agent composition provided by the invention can carry out plastics good uniform dyeing simultaneously, its durable weatherability is very good, it is very suitable for long-term exposed plastic product, the cyan of preparation can reduce the injury to eyesight；In addition, dyeing particles extension tensile property provided by the invention is good, embrittlement is not susceptible to, small to the abrasion of machinery equipment in preparation process, energy conservation and environmental protection.
Description
Technical field
The invention belongs to plastic colorant fields, and in particular to a kind of plastics cyan colorant composition and dyeing plastic cement
Grain.
Background technology
Mainly it there are thermoplasticity and thermosetting plastic according to the molecular structure point of synthetic resin：To what, thermoplastic plastic refers to
Heating is the plastic cement for plasticity repeatedly, and dyes particles and be primarily referred to as using toner or Masterbatch as dyeing pigment and auxiliary agent group
The particles of conjunction mainly have the common raw material such as ABS/PP/475/PE/, due to plastic product will and color coordination, take out grain raw material be
Pigment is mixed into raw material, each plastics material is colored, so forming product colour stable and uniform.Dye plastic cement
Grain be primarily referred to as using toner or Masterbatch as dyeing pigment and the particles of auxiliary combination, extensive use in automobile (such as instrument board,
Tool hatch door, wheel cover, reflective mirror case etc.), refrigerator, big strength tools (such as hair drier, blender, food processor,
Grass trimmer etc.), telephone case, typewriter keyboard, recreational vehicle such as golf cart and jet-propelled sledge vehicle etc..
In the prior art, the technological process that is made for dyeing particles is generally divided into following steps：
1st, raw material stoving；
2nd, stain dilution is stood and mixing color, modification agent combine；
3rd, pre- colour mixture-stir evenly toner and raw material in blender is done pre-dispersed；
4th, heating melting stirring in gun barrel；
5th, it squeezes bracing wire, cross water cooling, blowing draining；
6th, pelletizing, sieving, heating stirring drying.
Wherein, the allotment ratio of stain accounts for success or failure key in alloying process, is also easy to produce dispersion and is not easy, stain, gasAfterwards
The upper multiple spot geat of section molding application is easily rupturable, brittle failure, and illiquidity causes molding uneven not full, and material coke, stirring are not
Easily, the bad phenomenons such as screw rod is worn, power consumption, and production capacity is bad.
Invention content
Based on problem of the existing technology, the object of the present invention is to provide a kind of function admirable, coloring it is good and not
It influences the plastics cyan colorant composition of plastic shaping and dyes particles and preparation method.
The present invention is achieved by the following technical solution：
A kind of plastics include following parts by weight of component with cyan colorant composition：
220-230 parts of titanium dioxides, 0.025-0.035 parts of toner black smokes, 0.15-0.25 parts of red powder, 1.3-1.4 parts of blues
Powder, 12-15 part phthalocyanine color, 18-21 parts of EBS, 48-52 parts of magnesium stearates；EBS, that is, the ethylene bis stearamide.
It is further preferred that above-mentioned plastics include following parts by weight of component with cyan colorant composition：
228 parts of titanium dioxides, 0.03 part of toner black smoke, 0.2 part of red powder, 1.35 parts of blue powder, 14 parts of phthalocyanine colors, 20 parts
EBS, 50 parts of magnesium stearates.
Further, above-mentioned plastics titanium dioxide described in cyan colorant composition is rutile-type.
The present invention also provides a kind of dyeing particles to include following parts by weight of component：98.9-99.9 ABS, 1.0-1.1 parts of part
Plastics cyan colorant composition as described above.
ABS, that is, the acrylonitrile-butadiene-styrene copolymer is by three kinds of acrylonitrile, butadiene and styrene chemistry
Monomer synthetic copolymer, component content：Acrylonitrile 15-20%, butadiene 15-25%, styrol copolymer 60-65%.
It is further preferred that above-mentioned dyeing particles include following parts by weight of component：98.96555 part ABS, 1.03445 parts
Plastics cyan colorant composition as described above.
Plastics provided by the present invention cyan colorant composition and dyeing particles coloured plastics grain production
The defects of stain, gas trace will not be generated in journey, while coloring agent composition provided by the invention can be good to plastics progress equal
Even dyeing, durable weatherability is very good, is very suitable for long-term exposed plastic product, and the cyan of preparation can be reduced pair
The injury of eyesight；In addition, dyeing particles extension tensile property provided by the invention is good, embrittlement is not susceptible to, was being prepared
, energy conservation and environmental protection small to the abrasion of machinery equipment in journey, specifically the reduction of the inventive formulation proportion of goods damageds is horizontal as follows：Polystyrene matter
It measures mass rate of material loss of the proportion of goods damageds not higher than 0.09%, ABS and is not higher than 0.08%；Using the processing procedure power consumption expense of this formula by existing
1,680,000/the year for having technology is reduced to for 1,370,000/year.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.The embodiment is only the preferred implementation of the present invention
Example, is not intended to restrict the invention, for those skilled in the art, the present invention can have various changes and change
Change.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention
Protection domain within.It is the A5878 of Di Gaosha, red powder that ABS used, which is BASF ABS GP35, toner black smoke, in embodiment
Be ARIMOTO 8320, blue powder be the 5824 of CIBY.
Embodiment 1
By 2.28kg rutile type titanium whites, 0.3g toners black smoke, 2g red powder, 13.5g blues powder, 0.14kg phthalocyanine face
Material, 0.2kg EBS, 0.5kg magnesium stearates add in blender after mixing, then 98.96555kg ABS are added in blender
It stirs evenly, the heating melting stirring in gun barrel, through squeezing bracing wire, crossing water cooling, blowing draining；Pelletizing, sieving, heating stirring drying
Obtain product.
Embodiment 2
By 2.3kg rutile type titanium whites, 0.28g toners black smoke, 1.8g red powder, 13g blues powder, 0.15kg phthalocyanine face
Material, 0.18kg EBS, 0.5kg magnesium stearates add in blender after mixing, then 99.8kg ABS are added in blender and are stirred
It is even, the heating melting stirring in gun barrel, through squeezing bracing wire, crossing water cooling, blowing draining；Pelletizing, sieving, heating stirring are dried
Product.
Embodiment 3
By 2.2kg rutile type titanium whites, 0.35g toners black smoke, 2.2g red powder, 14g blues powder, 0.13kg phthalocyanine face
Material, 0.2kg EBS, 0.51kg magnesium stearates add in blender after mixing, then 98.9kg ABS are added in blender and are stirred
It is even, the heating melting stirring in gun barrel, through squeezing bracing wire, crossing water cooling, blowing draining；Pelletizing, sieving, heating stirring are dried
Product.
Embodiment 1 to embodiment 3 prepares products obtained therefrom physical property measurement result：It rushes powerful under 19.1MPa, molten condition
Mobility MI not less than 33.2, mean specific gravity 1.05.
Claims (5)
1. a kind of plastics cyan colorant composition, which is characterized in that including following parts by weight of component：
220-230 parts of titanium dioxides, 0.025-0.035 parts of toner black smokes, 0.15-0.25 parts of red powder, 1.3-1.4 part blue powder,
12-15 parts of phthalocyanine colors, 18-21 parts of EBS, 48-52 parts of magnesium stearates.
2. plastics according to claim 1 cyan colorant composition, which is characterized in that including following parts by weight group
Point：
228 parts of titanium dioxides, 0.03 part of toner black smoke, 0.2 part of red powder, 1.35 parts of blue powder, 14 parts of phthalocyanine colors, 20 parts of EBS,
50 parts of magnesium stearates.
3. plastics according to claim 1 or 2 cyan colorant composition, which is characterized in that
The titanium dioxide is rutile-type.
4. a kind of dyeing particles, which is characterized in that including following parts by weight of component：
98.9-99.9 parts of ABS, 1.0-1.1 parts of plastics as described in any one in claims 1 to 3 cyan colorant group
Close object.
5. dyeing particles according to claim 3, which is characterized in that including following parts by weight of component：
98.96555 parts of ABS, 1.03445 parts of plastics as described in any one in claims 1 to 3 are combined with cyan colorant
Object.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810054674.8A CN108250489A (en) | 2018-01-19 | 2018-01-19 | A kind of plastics cyan colorant composition and dyeing particles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810054674.8A CN108250489A (en) | 2018-01-19 | 2018-01-19 | A kind of plastics cyan colorant composition and dyeing particles |
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| Publication Number | Publication Date |
|---|---|
| CN108250489A true CN108250489A (en) | 2018-07-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810054674.8A Pending CN108250489A (en) | 2018-01-19 | 2018-01-19 | A kind of plastics cyan colorant composition and dyeing particles |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690492A (en) * | 2012-05-16 | 2012-09-26 | 洛阳市河之阳高分子材料有限公司 | Heat-resistant weather-resistant blue grey color masterbatch for ABS (acrylonitrile butadiene styrene) and preparation process of blue grey color masterbatch |
| CN103160038A (en) * | 2013-02-04 | 2013-06-19 | 南华大学 | Moire fringe antibiosis color master batch used for polystyrene category rigid plastic toy and preparation method |
| CN108559175A (en) * | 2018-03-27 | 2018-09-21 | 广东聚石化学股份有限公司 | It is a kind of to exempt from spray coating polypropylene material and preparation method thereof with marble black and white texture |
-
2018
- 2018-01-19 CN CN201810054674.8A patent/CN108250489A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690492A (en) * | 2012-05-16 | 2012-09-26 | 洛阳市河之阳高分子材料有限公司 | Heat-resistant weather-resistant blue grey color masterbatch for ABS (acrylonitrile butadiene styrene) and preparation process of blue grey color masterbatch |
| CN103160038A (en) * | 2013-02-04 | 2013-06-19 | 南华大学 | Moire fringe antibiosis color master batch used for polystyrene category rigid plastic toy and preparation method |
| CN108559175A (en) * | 2018-03-27 | 2018-09-21 | 广东聚石化学股份有限公司 | It is a kind of to exempt from spray coating polypropylene material and preparation method thereof with marble black and white texture |
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Application publication date: 20180706 |