CN108249617B - A kind of trade effluent recovery and treatment method - Google Patents

A kind of trade effluent recovery and treatment method Download PDF

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Publication number
CN108249617B
CN108249617B CN201810033268.3A CN201810033268A CN108249617B CN 108249617 B CN108249617 B CN 108249617B CN 201810033268 A CN201810033268 A CN 201810033268A CN 108249617 B CN108249617 B CN 108249617B
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mud
fluoride
calcirm
treatment method
trade effluent
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CN201810033268.3A
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CN108249617A (en
Inventor
陈立波
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Negative-ion cooking fume purifier
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Negative-Ion Cooking Fume Purifier
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/12Halogens or halogen-containing compounds
    • C02F2101/14Fluorine or fluorine-containing compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of trade effluent recovery and treatment methods, comprising the following steps: (1) industrial wastewater is after flocculation basin and sedimentation basin, by waste water lifting to reaction tank;Quick lime is added in waste water into reaction tank, is stirred to react 2-6h, the filtrate A of containing sulfate radicals is obtained after filtering;(2) white lime is added into filtrate A, is stirred to react 0.5-4h, calcirm-fluoride wet slag and tail washings are obtained after filtering, tail washings may be recovered utilization.

Description

A kind of trade effluent recovery and treatment method
Technical field
The invention belongs to technical field of industrial sewage treatment, more particularly, to a kind of trade effluent recovery and treatment method.
Background technique
With the rapid development of economy, the total emission volumn of fluorine-containing industrial wastewater is growing, fluoride pollution is caused to get worse. Therefore, people start the processing method of positive research fluoride waste, recycle, that is, drop after fluorine-containing waste water is handled The low pollution to environment, and realize the recycling to resource.But the processing method treatment effect of traditional fluoride waste compared with Difference, treated, and often there is fluorine ion and sulfate ion residual in waste water, and pollution is equally easily caused after discharge.If lengthening pair The processing time of fluoride waste increases processing step, then working efficiency is low, and processing cost is high.
Summary of the invention
The present invention for overcome the deficiencies in the prior art, provides a kind of trade effluent recovery processing side that work efficiency is high Method.
To achieve the goals above, the invention adopts the following technical scheme: a kind of trade effluent recovery and treatment method, including Following steps:
(1) industrial wastewater is after flocculation basin and sedimentation basin, by waste water lifting to reaction tank;Add in waste water into reaction tank Add quick lime, be stirred to react 2-6h, the filtrate A of containing sulfate radicals is obtained after filtering;
(2) white lime is added into filtrate A, is stirred to react 0.5-4h, calcirm-fluoride wet slag and tail washings, tail washings is obtained after filtering It may be recovered utilization.
Further, the residue being obtained by filtration in the step (1) is calcirm-fluoride wet slag, takes fluoride waste, is given up to fluorine-containing The calcirm-fluoride is added in water, after being stirred to react 3-5h, calcirm-fluoride and liquor B is obtained by filtration.
Further, calcium sulfate is added in backward liquor B, after being stirred to react 1-3h, gypsum and sulfuric acid are obtained after filtering Solution.
Further, the input amount of the quick lime is 50-80kg/L.
Further, the input amount of the white lime is 40-70kg/L.
Further, the input amount of the calcirm-fluoride is 45-85kg/L
Further, mud-scraping apparatus is equipped in the sedimentation basin;Solid matter in sedimentation basin is drowned into precipitating bottom of pond portion, Convenient for reprocessing process in turn to sewage convenient for subsequent except a large amount of solid pollutant in decontaminated water;It is arranged in sedimentation basin and scrapes Mud device can scrape the mud for sinking to precipitating bottom of pond portion to the center of sedimentation basin, by the spoil disposal pipeline for being set to precipitating bottom of pond portion By the mud discharge in sedimentation basin, then it is uniformly processed, avoids mud and accumulate in sedimentation basin, cause in sedimentation basin A large amount of microorganism is bred, avoids aggravating water pollution.
Further, the mud-scraping apparatus includes rotating member, the supporting element being connected with the rotating member and is arranged at intervals at Multiple on the supporting element scrape mud component;The mud component of scraping includes cleaning shoe and scrapes mud part, and the mud part of scraping connects by one Relay part is detachably connected with the cleaning shoe;Rotating member and supporting element are set, rotate to drive supporting element by rotating member It rotates with, scrapes mud component effectively for mud scraped clean to drive;Mud component will be scraped to be arranged to scrape mud part and cleaning shoe, Cleaning shoe can realize and fix to scraping mud part, can also obstruct the mud swept and cross and scrape mud part and fall into again to original position, set simultaneously Setting cleaning shoe can also effectively limit flow direction of the mud when being swept, and accumulate mud mutually and towards in sedimentation basin It is flowed at the heart;And setting scrapes mud part and can scrape the mud of bottom, the mud that will precipitate bottom of pond portion removes;It is Wear-resistant plastic that this, which scrapes mud part, Material, wearability is good, not easy to wear, therefore long service life, strong to the mud scraping abilities of precipitating bottom of pond portion;And connection is set Component can be installed convenient for that will scrape mud part to cleaning shoe, scrape mud part convenient for replacing after long-term use, scrape mud part in connecting component Upper convenient for disassembly and assembly, installation effectiveness is high;Connecting component can also float up and down, therefore have convex block etc. meeting precipitating bottom of pond portion It, can be effectively to movement, so that ensuring equipment is stable in the case where stuck;Arcwall face will be set on cleaning shoe, therefore scraped The mud risen can be moved upwards along arcwall face and mud can be fallen to again after movement along the arcwall face The side that cleaning shoe pushes, and arcwall face setting can shovel the mud of bottom, and original mud of scraping is changed as shovel mud, is scraped Mud effect is strong;Convex ribs, which are arranged, can reinforce the intensity of cleaning shoe, and the service life that mud is pulled is scraped in extension, and the setting of convex ribs can also reduce Adhesive capacity of the mud on cleaning shoe, convenient for sending mud to the center of sedimentation basin.
In conclusion the present invention is by the difference of calcium chloride and calcium sulfate solubility product, the fluorine ion in precipitation and separation waste water, Guarantee that fluorine ion is separated with sulfate ion, and calcirm-fluoride can be obtained;It, can be with sulfate radical by the addition of quick lime/white lime Reaction obtains gypsum, continues to use in investment sewage treatment, resource utilization is high.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is cross-sectional view of the invention.
Fig. 3 scrapes mud modular construction schematic diagram for of the invention.
Fig. 4 is the enlarged drawing of A in Fig. 3.
Fig. 5 is the enlarged drawing of B in Fig. 3.
Specific embodiment
In order to make those skilled in the art better understand the present invention program, below in conjunction in the embodiment of the present invention Attached drawing, the technical scheme in the embodiment of the invention is clearly and completely described.
Embodiment 1
A kind of trade effluent recovery and treatment method, comprising the following steps: (1) industrial wastewater after flocculation basin and sedimentation basin, By waste water lifting to reaction tank;It during reaction in flocculation basin needs that flocculant is added into flocculation basin, specifically, described Flocculant is aluminium polychloride;Mud-scraping apparatus 2 is equipped in the sedimentation basin, by the mud-scraping apparatus to the sludge for being deposited on bottom of pond It is struck off;Quick lime is added in waste water into reaction tank, the input amount of quick lime is specially 50kg/L;2h is stirred to react, The filtrate A and residue of containing sulfate radicals: calcirm-fluoride wet slag are obtained after filtering;(2) white lime, the throwing of white lime are added into filtrate A Entering amount is specially 40kg/L;It is stirred to react 0.5h, calcirm-fluoride wet slag and tail washings are obtained after filtering, tail washings may be recovered utilization; Fluoride waste is taken later, the calcirm-fluoride being obtained by filtration in above-mentioned steps is added into fluoride waste, and the input amount of calcirm-fluoride is specific For 45kg/L, after being stirred to react 3h, calcirm-fluoride and liquor B is obtained by filtration;Backward liquor B in calcium sulfate is added, calcium sulfate Input amount is specially 45kg/L, and after being stirred to react 1h, gypsum and sulfuric acid solution are obtained after filtering.
As shown in Figs. 1-5, the sedimentation basin 1 is a conical tank, and the sedimentation basin 1 is poured by cement;It is heavy at this A spoil disposal pipeline is connected at the center of the bottom in shallow lake pond 1, the mud that mud-scraping apparatus 2 is swept enters in spoil disposal pipeline, then It is excluded via spoil disposal pipeline, specific spoil disposal pipeline spoil disposal is the prior art, therefore details are not described herein;The mud-scraping apparatus 2 Including motor 20, rotating member 21, supporting element 22 and scrape mud component 3, the rotating member 21 be one perpendicular to horizontal plane metal Bar, the upper end of the rotating member 21 are connected with the motor 20, drive the rotating member 21 to rotate by motor 20;Described Supporting element 22 is that end is fixed on the metallic rod on the rotating member 21, the bottom bevel of the supporting element 22 and the sedimentation basin 1 In parallel, the mud component 3 of scraping is located on rotating member 21, and scrape mud component 3 be it is multiple, two adjacent scrape between mud component 3 Spacing distance is identical;The mud component 3 of scraping includes the cleaning shoe 31 being connected with supporting element 22 and scrapes mud part 32, and described scrapes Mud plate 31 is a metal plate, and the mud part 32 of scraping is a Wear-resistant plastic flitch, scrapes mud part 32 and passes through a connecting component 4 and cleaning shoe 31 are detachably connected.
Specifically, the connecting component 4 includes multiple elastic components 41 and connector 42, the elastic component 41 is bullet Spring, the connector 42 are the thicker metal strip of thickness;Multiple placed cavities 311 are arranged at intervals on the cleaning shoe 31, The placed cavity 311 is a cylindrical chamber, and the spacing distance of two adjacent placed cavities 311 is identical, 41 quantity of elastic component with The quantity of placed cavity 311 is identical, and each elastic component 41 is corresponding to be put into a placed cavity 311, and elastic component 41 Upper end is fixedly connected with the bottom of placed cavity 311, and the outer and described connector of placed cavity 311 is stretched out in the lower end of elastic component 41 42 are connected;It is specifically connected as, multiple connecting cavities 425 is equipped on the connector 42, in 41 end of elastic component On be connected with a regulating part 43;Setting regulating part is penetrated to connecting cavity, so that regulating part is screwed into cavity wall is connect Together, the lower part of elastic component is realized and is fixed;Likewise, adjusting by rotation, the hardness of elastic component can control, convenient for according to need It adjusts elastic component and generates downward pressure size to connector, and then the controllable pressure scraped between mud part and precipitating bottom of pond portion Power, improve scrape mud part scrape mud efficiency.
The regulating part 43 includes adjustment portion 431 and spiro union portion 432, adjusts socket part 431 and spiro union portion 432 to be integrally formed, institute The adjustment portion 431 stated is hexagonal metal block, and the middle of the adjustment portion 431 is equipped with the through-hole passed through for 41 end of elastic component 436, the spiro union portion 432 is the metal column that an inner hollow forms cavity 435, and the outer wall of spiro union portion 432 is equipped with outer Screw thread;Therefore 41 end of elastic component is passed into from the through-hole 436 to cavity 435, then on elastic component 41 A sheet metal is welded, which forms the anticreep protuberance 44 on 41 end of elastic component, the anticreep protuberance 44 Upper surface and the lower end surface of adjustment portion 431 are in contact, and disengage in regulating part 44 to limit elastic component 41;It is set by this Mode is set, regulating part 44 can the rotation of relative resilient part 41;Therefore in connection, the regulating part 44 is screwed into the connection In chamber 425, it is detachably connected between elastic component 41 and connector 42 to realize;Setting adjustment portion can be convenient for needing to adjust When, the equipment such as spanner, which could be sandwiched in adjustment portion, rotates entire regulating part, is easy to use;Likewise, adjustment portion can also limit entirely Regulating part enters in connecting cavity, additionally it is possible to reinforce the thickness of regulating part upper end, the intensity of enhancement device entirety;Spiro union portion is set It can be screwed into placed cavity, mutually be limited by the external screw thread of spiro union portion and the internal screw thread of connecting cavity, effectively control bullet Property part compression intensity;And adjustment portion and spiro union portion setting are integrally formed, it can effectively reinforce the integral strength of regulating part, mention The service life of top adjustment part.
Further, it is respectively equipped with a recess portion 310 on 31 left and right sides of cleaning shoe, on each recess portion 310 It is fixed with a fixing piece 33 by screw, the lower end surface of the fixing piece 33 extends outward to form fixed part 331, the fixation Portion 331 and fixing piece 33 are integrally formed;Fixing piece, which is arranged, to protect the lower end of elastic component, to match with placed cavity It closes, elastic component is integrally wrapped;Likewise, fixing piece can also limit connector, it is further to ensure connector not Can occur left and right offset, the setting of the fixing piece can also connector easy to disassemble, during installation, elastic component lower part is exposed outside, It can easily be installed together with connector, then again install fixing piece, and the mounting means is simple, equally be also convenient for Replace connector;Setting fixed part is penetrated to the first groove, can effectively limit connector range movable up and down, and may be used also It further ensures that mud cannot be introduced between two fixing piece of elastic component, reinforces the protection to elastic component.
It is equipped with one first groove 421 on the connector 42, is fixed in recess portion 310 it on 33 top of fixing piece Afterwards, the fixed part 331 is penetrated to the first groove 421, the wider width of first groove 421, therefore is being connected When upper and lower displacement occurs for part 42, fixed part 331 can be moved up and down relative to the first groove 421;Pass through setting for fixing piece 33 It sets;The second groove 422 is further respectively had in the left and right sidewall of the connector 33, it is recessed which is set to first The lower section of slot 421, and one first extension 423 is also vertically installed on the bottom of the second groove 422;Described scrapes on mud part 32 Equipped with anti-delinking part 321, which is to penetrate to second groove 422, the anti-delinking part 321 lower end towards Under extend to form the second extension 323, second extension 323 and the first extension 423 are in contact;In order to preferably solid Mud part 32 is scraped described in fixed, is equipped with a bolt respectively in the left and right end portions for scraping mud part 32, which is connected with connector 42; The second groove is arranged can be when mud part be scraped in installation, and anti-delinking part is penetrated from the end of the second groove to the second groove, to ensure The stable connection between mud part and fixing piece is scraped, to scrape mud part will not fall from downwards;Likewise, the set-up mode also ensures Scrape mud part can not opposite joints left and right offset occurs, ensure and scrape the efficiency of mud;First extension is set and the second extension can Reinforce scraping the stability between mud part and connector.
Further, the cleaning shoe 31 is equipped with an arcwall face 301, which is the side of cleaning shoe 31, Multiple convex ribs 302 are provided on the arcwall face 301, which is that bending is set;In order to preferably use, Positioned at 301 side of arcwall face fixing piece 33 to lower end be equipped with a rubber block, which can effectively prevent from becoming silted up Mud enters in the first groove 421 and the second groove 422 of connector 42.
Embodiment 2
A kind of trade effluent recovery and treatment method, comprising the following steps: (1) industrial wastewater after flocculation basin and sedimentation basin, By waste water lifting to reaction tank;It during reaction in flocculation basin needs that flocculant is added into flocculation basin, specifically, described Flocculant is aluminium polychloride;Mud-scraping apparatus 2 is equipped in the sedimentation basin, by the mud-scraping apparatus to the sludge for being deposited on bottom of pond It is struck off;Quick lime is added in waste water into reaction tank, the input amount of quick lime is specially 80kg/L;6h is stirred to react, The filtrate A and residue of containing sulfate radicals: calcirm-fluoride wet slag are obtained after filtering;(2) white lime, the throwing of white lime are added into filtrate A Entering amount is specially 70kg/L;It is stirred to react 4h, calcirm-fluoride wet slag and tail washings are obtained after filtering, tail washings may be recovered utilization;It After take fluoride waste, the calcirm-fluoride that is obtained by filtration in above-mentioned steps is added into fluoride waste, the input amount of calcirm-fluoride is specially After being stirred to react 5h, calcirm-fluoride and liquor B is obtained by filtration in 85kg/L;Backward liquor B in calcium sulfate, the throwing of calcium sulfate is added Entering amount is specially 85kg/L, and after being stirred to react 1-3h, gypsum and sulfuric acid solution are obtained after filtering.
Mud-scraping apparatus in the present embodiment is in the same manner as in Example 1, and so it will not be repeated.
Embodiment 3
A kind of trade effluent recovery and treatment method, comprising the following steps: (1) industrial wastewater after flocculation basin and sedimentation basin, By waste water lifting to reaction tank;It during reaction in flocculation basin needs that flocculant is added into flocculation basin, specifically, described Flocculant is aluminium polychloride;Mud-scraping apparatus 2 is equipped in the sedimentation basin, by the mud-scraping apparatus to the sludge for being deposited on bottom of pond It is struck off;Quick lime is added in waste water into reaction tank, the input amount of quick lime is specially 70kg/L;4h is stirred to react, The filtrate A and residue of containing sulfate radicals: calcirm-fluoride wet slag are obtained after filtering;(2) white lime, the throwing of white lime are added into filtrate A Entering amount is specially 50kg/L;It is stirred to react 2h, calcirm-fluoride wet slag and tail washings are obtained after filtering, tail washings may be recovered utilization;It After take fluoride waste, the calcirm-fluoride that is obtained by filtration in above-mentioned steps is added into fluoride waste, the input amount of calcirm-fluoride is specially After being stirred to react 3h, calcirm-fluoride and liquor B is obtained by filtration in 65kg/L;Backward liquor B in calcium sulfate, the throwing of calcium sulfate is added Entering amount is specially 60kg/L, and after being stirred to react 2h, gypsum and sulfuric acid solution are obtained after filtering.
Mud-scraping apparatus in the present embodiment is in the same manner as in Example 1, and so it will not be repeated.
Obviously, described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment should fall within the scope of the present invention.

Claims (6)

1. a kind of trade effluent recovery and treatment method, it is characterised in that: the following steps are included:
Industrial wastewater is after flocculation basin and sedimentation basin, by waste water lifting to reaction tank;Raw stone is added in waste water into reaction tank Ash is stirred to react 2-6h, and the filtrate A of containing sulfate radicals is obtained after filtering;
White lime is added into filtrate A, is stirred to react 0.5-4h, calcirm-fluoride wet slag and tail washings is obtained after filtering, tail washings is returned It receives and utilizes;
Mud-scraping apparatus (2) are equipped in the sedimentation basin, the mud-scraping apparatus (2) includes rotating member (21) and the rotating member (21) connected supporting element (22) and be arranged at intervals on the supporting element (22) multiple scrape mud component (3);It is described to scrape mud portion Part (3) includes cleaning shoe (31) and scrapes mud part (32), and described scrape mud part (32) pass through a connecting component (4) and the cleaning shoe (31) it is detachably connected;
The connecting component (4) includes the elastic component (41) being connected with the cleaning shoe (31) and is connected with the elastic component (41) Connector (42), the mud part (32) of scraping is detachably connected with the connector (42);
The cleaning shoe (31) is equipped with an arcwall face (301), which is the side of cleaning shoe (31), described Arcwall face (301) on be provided with multiple convex ribs (302), the convex ribs (302) be bending setting.
2. a kind of trade effluent recovery and treatment method according to claim 1, it is characterised in that: the residue being obtained by filtration is Calcirm-fluoride wet slag, takes fluoride waste, and the calcirm-fluoride is added into fluoride waste, and after being stirred to react 3-5h, calcirm-fluoride is obtained by filtration And liquor B.
3. a kind of trade effluent recovery and treatment method according to claim 2, it is characterised in that: backward liquor B in plus Enter calcium sulfate, after being stirred to react 1-3h, gypsum and sulfuric acid solution are obtained after filtering.
4. a kind of trade effluent recovery and treatment method according to claim 1, it is characterised in that: the investment of the quick lime Amount is 50-80kg/L.
5. a kind of trade effluent recovery and treatment method according to claim 1, it is characterised in that: the investment of the white lime Amount is 40-70kg/L.
6. a kind of trade effluent recovery and treatment method according to claim 2, it is characterised in that: the investment of the calcirm-fluoride Amount is 45-85kg/L.
CN201810033268.3A 2018-01-14 2018-01-14 A kind of trade effluent recovery and treatment method Active CN108249617B (en)

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CN108249617B true CN108249617B (en) 2019-04-12

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110776142A (en) * 2019-11-12 2020-02-11 张家港宏昌钢板有限公司 Physicochemical coagulation defluorination and precipitation integrated wastewater treatment method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104370389A (en) * 2014-11-14 2015-02-25 无锡伊佩克科技有限公司 Process for removing fluorine in pickling waste liquid in steel and iron industry
CN105617730A (en) * 2014-11-20 2016-06-01 徐静 Regulating-type central transmission mud scraper
CN106927550A (en) * 2017-03-07 2017-07-07 广东省资源综合利用研究所 A kind of recovery method of fluorine-containing industrial wastewater

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104370389A (en) * 2014-11-14 2015-02-25 无锡伊佩克科技有限公司 Process for removing fluorine in pickling waste liquid in steel and iron industry
CN105617730A (en) * 2014-11-20 2016-06-01 徐静 Regulating-type central transmission mud scraper
CN106927550A (en) * 2017-03-07 2017-07-07 广东省资源综合利用研究所 A kind of recovery method of fluorine-containing industrial wastewater

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