CN108220867A - A kind of manufacturing method of biotransformation film metal plate - Google Patents

A kind of manufacturing method of biotransformation film metal plate Download PDF

Info

Publication number
CN108220867A
CN108220867A CN201711413071.4A CN201711413071A CN108220867A CN 108220867 A CN108220867 A CN 108220867A CN 201711413071 A CN201711413071 A CN 201711413071A CN 108220867 A CN108220867 A CN 108220867A
Authority
CN
China
Prior art keywords
film
biotransformation
manufacturing
metallic plate
bioconversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711413071.4A
Other languages
Chinese (zh)
Inventor
梁荣强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Ruan Shang Home Development Co Ltd
Original Assignee
Zhongshan Ruan Shang Home Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongshan Ruan Shang Home Development Co Ltd filed Critical Zhongshan Ruan Shang Home Development Co Ltd
Priority to CN201711413071.4A priority Critical patent/CN108220867A/en
Publication of CN108220867A publication Critical patent/CN108220867A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

The invention discloses a kind of manufacturing method of biotransformation film metal plate of biotechnology, which is as follows:S1:The surface of metallic plate is polished using grinding agent;S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning;S4:It is rinsed with deionized water after the completion of alkali cleaning, metal sheet surface is dried repeatedly using hair-dryer;S5:Bioconversion film is sprayed into metal surface using the plasma jet that plasma gun generates and forms coating;S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, biotransformation film metal plate finished product is made, the present invention is combined into bioconversion film layer with water-base resin, has the advantages that binding force is strong, anti-flammability is high, electric conductivity is strong.

Description

A kind of manufacturing method of biotransformation film metal plate
Technical field
The invention discloses a kind of manufacturing methods of biotransformation film metal plate, specially biotechnology.
Background technology
At present, metallic plate needs to clean the surface of metallic plate before spray painting.The cleaning process of metallic plate is will be former Metal sheet surface carries out oil removing, derusting, and the process of cleaning is to immerse metallic plate in the cleansing mediums such as hydrochloric acid or sulfuric acid, purpose It is to remove the grease for being adhered to metallic plate stromal surface, dirt, after metal sheet surface is cleaned, needs to spray in time Paint, otherwise metallic plate can be polluted again, not only cause economic loss, and subsequent procedure of processing can also be caused to become complicated.For This, we have proposed a kind of manufacturing methods of biotransformation film metal plate to come into operation, to solve the above problems.
Invention content
The purpose of the present invention is to provide a kind of manufacturing method of biotransformation film metal plate, to solve above-mentioned background technology The problem of middle proposition.
To achieve the above object, the present invention provides following technical solution:A kind of manufacturing method of biotransformation film metal plate, The manufacturing method is as follows:
S1:The surface of metallic plate is polished using grinding agent, to remove the greasy dirt of metal surface and oxide skin;
S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80~90 DEG C, alkali cleaning Time is 10~20min;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached Metal surface is sprayed under molten condition and forms coating;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made Metal board finished product.
Preferably, in the step S1, grinding agent passes through resistance furnace high temperature for quartz sand, petroleum coke, sawdust and salt It smelts.
Preferably, in the step S3, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, Wherein sodium hydroxide:Sodium bicarbonate:Sodium phosphate=0.8:1.5:1.1.
Preferably, in the step S5, bioconversion film is by hyaluronic acid, collagen, chitosan, alginate, aqueous Resin, amino acid, lactic acid and organic acid composition.
Preferably, the water-base resin is polyester resin, phenolic resin, acrylic resin, organic siliconresin and poly- ammonia One kind in ester resin.
Preferably, in the step S5, during plasma gun sprays, bioconversion film liquid coated weight and film Layer thickness control is advisable in metal sheet surface complete wetting, uniform fold, without holiday, without hydrops.
Preferably, in the step S6, the temperature in baking oven is 100~150 DEG C, and drying time is 8~12min.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention can improve the anticorrosive energy of metal sheet surface Power and antioxygenic property, in the case of humidity≤70%, metallic plate can store not corrosion in 12 years in storehouse, extend corrosion week Phase reduces because of the various expenses needed for maintenance, bioconversion film layer is combined into water-base resin, strong, fire-retardant with binding force Property it is high, electric conductivity is strong the advantages of.
Description of the drawings
Fig. 1 is manufacturing flow chart of the present invention.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment shall fall within the protection scope of the present invention.
Embodiment one
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 3min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80 DEG C, the alkali cleaning time For 10min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 20 Part, 15 parts of collagen, 8 parts of chitosan, 12 parts of alginate, 30 parts of polyester resin, 5 parts of amino acid 1,5 parts of lactic acid and organic acid 7 Part composition, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate table Face complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made Metal board finished product, the temperature in baking oven are 100 DEG C, drying time 8min.
Embodiment two
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 90 DEG C, the alkali cleaning time For 20min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 22 Part, 16 parts of collagen, 9 parts of chitosan, 10 parts of alginate, 45 parts of phenolic resin, 0 part of amino acid 1,7 parts of lactic acid and organic acid 10 parts of compositions, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate Surface complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made Metal board finished product, the temperature in baking oven are 150 DEG C, drying time 12min.
Embodiment three
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 4min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 85 DEG C, the alkali cleaning time For 15min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 25 Part, 15 parts of collagen, 10 parts of chitosan, 8 parts of alginate, 40 parts of organic siliconresin, 7 parts of amino acid, 8 parts of lactic acid and organic acid 15 parts of compositions, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate Surface complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made Metal board finished product, the temperature in baking oven are 140 DEG C, drying time 10min.
In summary described in embodiment, highly preferred embodiment of the present invention is embodiment three, and the present invention can improve metallic plate The resistance to corrosion and antioxygenic property on surface, in the case of humidity≤70%, metallic plate can store 12 years not in storehouse Corrosion extends the corrosion period, reduces because of the various expenses needed for maintenance, bioconversion film layer is combined into water-base resin, has There is the advantages of binding force is strong, anti-flammability is high, electric conductivity is strong.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of manufacturing method of biotransformation film metal plate, it is characterised in that:The manufacturing method is as follows:
S1:The surface of metallic plate is polished using grinding agent, to remove the greasy dirt of metal surface and oxide skin;
S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80~90 DEG C, the alkali cleaning time For 10~20min;
S4:It is rinsed with deionized water after the completion of alkali cleaning, is gone after the alkaline solution of metal sheet surface is cleaned up with alcohol repeatedly Metal sheet surface is water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, in melting or close melting Metal surface is sprayed under state and forms coating;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film metal is made Board finished product.
2. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S1 In, grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting.
3. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S3 In, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Sodium bicarbonate:Phosphoric acid Sodium=0.8:1.5:1.1.
4. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S5 In, bioconversion film is by hyaluronic acid, collagen, chitosan, alginate, water-base resin, amino acid, lactic acid and organic acid Composition.
5. a kind of manufacturing method of biotransformation film metal plate according to claim 4, it is characterised in that:The aqueous tree Fat is one kind in polyester resin, phenolic resin, acrylic resin, organic siliconresin and polyurethane resin.
6. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S5 In, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are complete in metal sheet surface Full wetting, uniform fold are advisable without holiday, without hydrops.
7. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S6 In, the temperature in baking oven is 100~150 DEG C, and drying time is 8~12min.
CN201711413071.4A 2017-12-24 2017-12-24 A kind of manufacturing method of biotransformation film metal plate Pending CN108220867A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711413071.4A CN108220867A (en) 2017-12-24 2017-12-24 A kind of manufacturing method of biotransformation film metal plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711413071.4A CN108220867A (en) 2017-12-24 2017-12-24 A kind of manufacturing method of biotransformation film metal plate

Publications (1)

Publication Number Publication Date
CN108220867A true CN108220867A (en) 2018-06-29

Family

ID=62648536

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711413071.4A Pending CN108220867A (en) 2017-12-24 2017-12-24 A kind of manufacturing method of biotransformation film metal plate

Country Status (1)

Country Link
CN (1) CN108220867A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277584A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Manufacturing method of biotransformation film metal plate
CN102277568A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Bioconversion film treating agent
CN106913906A (en) * 2015-12-24 2017-07-04 中国科学院上海硅酸盐研究所 A kind of antioxidation biology coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277584A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Manufacturing method of biotransformation film metal plate
CN102277568A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Bioconversion film treating agent
CN106913906A (en) * 2015-12-24 2017-07-04 中国科学院上海硅酸盐研究所 A kind of antioxidation biology coating and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王海娟等: "生物化学转化膜新型防腐蚀技术——先进表面工程技术在金属防腐蚀的应用", 《首届国际(西安)涂料、涂装、表面工程高层论坛论文集(第二分册 涂装前处理)》 *
赵树东: "钢材预处理及防护技术探讨", 《现代涂料与涂装》 *

Similar Documents

Publication Publication Date Title
CN105817839B (en) A kind of technological process of production of zinc steel guard rail
CN107511312A (en) A kind of fluorocarbon-sprayed method of aluminium alloy extrusions
CN105088218B (en) A kind of metal surface coating process
CN105149195A (en) Paint construction technology of novel steel structure
CN110787979A (en) Steel structure corrosion prevention process
CN102560486A (en) Surface treatment and coating technology for magnesium alloy surface to resist neutral salt spray test
CN105140013B (en) The lacquer spraying technique of oil-filled transformer corrugated tank
CN107791156A (en) A kind of Shot Blasting method for steel plate derusting rust-proofing
CN105442018A (en) Conductive oxidation process for automobile aluminum alloy parts
CN102051624A (en) Anticorrosion treatment method for surface of aluminum or aluminum alloy product
CN104028430A (en) Clean metal powder spraying process
CN104289396B (en) A kind of method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment
CN105951024A (en) Preparation method for composite coating on surface of protective guard
CN111074186A (en) Fingerprint-resistant treatment method for surface of metal plate
CN108220867A (en) A kind of manufacturing method of biotransformation film metal plate
CN105214924A (en) A kind of application techniques of crop dryer surface
CN102019267B (en) Metal surface protective treatment method and system
CN109880406A (en) Coating and preparation method thereof and kitchen electric equipment
CN104651866A (en) Oil removing method for metal component
CN102719816A (en) Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method
CN106011837A (en) Environment-friendly type metal surface treatment technology
CN107552356A (en) Process for surface preparation before the spray painting of the chemical pump pump housing
CN104984948B (en) One kind applies primer part reworking method
CN107552365A (en) A kind of oil tank of transformer spraying polyurethane paint and spraying coating process
CN111155051A (en) Stainless steel, stainless steel surface treatment process and application of stainless steel surface treatment process in preparation of water tank

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180629

RJ01 Rejection of invention patent application after publication