CN108220867A - A kind of manufacturing method of biotransformation film metal plate - Google Patents
A kind of manufacturing method of biotransformation film metal plate Download PDFInfo
- Publication number
- CN108220867A CN108220867A CN201711413071.4A CN201711413071A CN108220867A CN 108220867 A CN108220867 A CN 108220867A CN 201711413071 A CN201711413071 A CN 201711413071A CN 108220867 A CN108220867 A CN 108220867A
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- China
- Prior art keywords
- film
- biotransformation
- manufacturing
- metallic plate
- bioconversion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The invention discloses a kind of manufacturing method of biotransformation film metal plate of biotechnology, which is as follows:S1:The surface of metallic plate is polished using grinding agent;S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning;S4:It is rinsed with deionized water after the completion of alkali cleaning, metal sheet surface is dried repeatedly using hair-dryer;S5:Bioconversion film is sprayed into metal surface using the plasma jet that plasma gun generates and forms coating;S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, biotransformation film metal plate finished product is made, the present invention is combined into bioconversion film layer with water-base resin, has the advantages that binding force is strong, anti-flammability is high, electric conductivity is strong.
Description
Technical field
The invention discloses a kind of manufacturing methods of biotransformation film metal plate, specially biotechnology.
Background technology
At present, metallic plate needs to clean the surface of metallic plate before spray painting.The cleaning process of metallic plate is will be former
Metal sheet surface carries out oil removing, derusting, and the process of cleaning is to immerse metallic plate in the cleansing mediums such as hydrochloric acid or sulfuric acid, purpose
It is to remove the grease for being adhered to metallic plate stromal surface, dirt, after metal sheet surface is cleaned, needs to spray in time
Paint, otherwise metallic plate can be polluted again, not only cause economic loss, and subsequent procedure of processing can also be caused to become complicated.For
This, we have proposed a kind of manufacturing methods of biotransformation film metal plate to come into operation, to solve the above problems.
Invention content
The purpose of the present invention is to provide a kind of manufacturing method of biotransformation film metal plate, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides following technical solution:A kind of manufacturing method of biotransformation film metal plate,
The manufacturing method is as follows:
S1:The surface of metallic plate is polished using grinding agent, to remove the greasy dirt of metal surface and oxide skin;
S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80~90 DEG C, alkali cleaning
Time is 10~20min;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up
Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached
Metal surface is sprayed under molten condition and forms coating;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made
Metal board finished product.
Preferably, in the step S1, grinding agent passes through resistance furnace high temperature for quartz sand, petroleum coke, sawdust and salt
It smelts.
Preferably, in the step S3, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate,
Wherein sodium hydroxide:Sodium bicarbonate:Sodium phosphate=0.8:1.5:1.1.
Preferably, in the step S5, bioconversion film is by hyaluronic acid, collagen, chitosan, alginate, aqueous
Resin, amino acid, lactic acid and organic acid composition.
Preferably, the water-base resin is polyester resin, phenolic resin, acrylic resin, organic siliconresin and poly- ammonia
One kind in ester resin.
Preferably, in the step S5, during plasma gun sprays, bioconversion film liquid coated weight and film
Layer thickness control is advisable in metal sheet surface complete wetting, uniform fold, without holiday, without hydrops.
Preferably, in the step S6, the temperature in baking oven is 100~150 DEG C, and drying time is 8~12min.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention can improve the anticorrosive energy of metal sheet surface
Power and antioxygenic property, in the case of humidity≤70%, metallic plate can store not corrosion in 12 years in storehouse, extend corrosion week
Phase reduces because of the various expenses needed for maintenance, bioconversion film layer is combined into water-base resin, strong, fire-retardant with binding force
Property it is high, electric conductivity is strong the advantages of.
Description of the drawings
Fig. 1 is manufacturing flow chart of the present invention.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work
Embodiment shall fall within the protection scope of the present invention.
Embodiment one
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground
Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 3min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80 DEG C, the alkali cleaning time
For 10min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate
Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up
Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached
Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 20
Part, 15 parts of collagen, 8 parts of chitosan, 12 parts of alginate, 30 parts of polyester resin, 5 parts of amino acid 1,5 parts of lactic acid and organic acid 7
Part composition, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate table
Face complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made
Metal board finished product, the temperature in baking oven are 100 DEG C, drying time 8min.
Embodiment two
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground
Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 90 DEG C, the alkali cleaning time
For 20min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate
Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up
Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached
Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 22
Part, 16 parts of collagen, 9 parts of chitosan, 10 parts of alginate, 45 parts of phenolic resin, 0 part of amino acid 1,7 parts of lactic acid and organic acid
10 parts of compositions, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate
Surface complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made
Metal board finished product, the temperature in baking oven are 150 DEG C, drying time 12min.
Embodiment three
A kind of manufacturing method of biotransformation film metal plate, the manufacturing method are as follows:
S1:The surface of metallic plate using grinding agent is polished, to remove the greasy dirt of metal surface and oxide skin, is ground
Grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting;
S2:Metallic plate is placed in acetone soln, and 4min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 85 DEG C, the alkali cleaning time
For 15min, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Bicarbonate
Sodium:Sodium phosphate=0.8:1.5:1.1;
S4:It is rinsed repeatedly with deionized water after the completion of alkali cleaning, wine is used after the alkaline solution of metal sheet surface is cleaned up
Essence goes metal sheet surface water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, is being melted or is being approached
Metal surface is sprayed under molten condition and forms coating, bioconversion film is made of the component of following parts by weight:Hyaluronic acid 25
Part, 15 parts of collagen, 10 parts of chitosan, 8 parts of alginate, 40 parts of organic siliconresin, 7 parts of amino acid, 8 parts of lactic acid and organic acid
15 parts of compositions, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are in metallic plate
Surface complete wetting, uniform fold are advisable without holiday, without hydrops;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film is made
Metal board finished product, the temperature in baking oven are 140 DEG C, drying time 10min.
In summary described in embodiment, highly preferred embodiment of the present invention is embodiment three, and the present invention can improve metallic plate
The resistance to corrosion and antioxygenic property on surface, in the case of humidity≤70%, metallic plate can store 12 years not in storehouse
Corrosion extends the corrosion period, reduces because of the various expenses needed for maintenance, bioconversion film layer is combined into water-base resin, has
There is the advantages of binding force is strong, anti-flammability is high, electric conductivity is strong.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of manufacturing method of biotransformation film metal plate, it is characterised in that:The manufacturing method is as follows:
S1:The surface of metallic plate is polished using grinding agent, to remove the greasy dirt of metal surface and oxide skin;
S2:Metallic plate is placed in acetone soln, and 3~5min is cleaned under ultrasonic wave;
S3:Then metallic plate is placed in alkaline solution and carries out alkali cleaning, wherein the temperature of alkali cleaning is 80~90 DEG C, the alkali cleaning time
For 10~20min;
S4:It is rinsed with deionized water after the completion of alkali cleaning, is gone after the alkaline solution of metal sheet surface is cleaned up with alcohol repeatedly
Metal sheet surface is water stain, and metal sheet surface is dried using hair-dryer;
S5:Bioconversion film is heated and accelerated by the plasma jet generated using plasma gun, in melting or close melting
Metal surface is sprayed under state and forms coating;
S6:Metallic plate is placed in an oven, makes the biological film baking and curing of metal sheet surface, bioconversion film metal is made
Board finished product.
2. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S1
In, grinding agent is formed for quartz sand, petroleum coke, sawdust and salt by resistance furnace pyrolytic semlting.
3. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S3
In, alkaline solution is the mixed solution of sodium hydroxide, sodium bicarbonate and sodium phosphate, wherein sodium hydroxide:Sodium bicarbonate:Phosphoric acid
Sodium=0.8:1.5:1.1.
4. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S5
In, bioconversion film is by hyaluronic acid, collagen, chitosan, alginate, water-base resin, amino acid, lactic acid and organic acid
Composition.
5. a kind of manufacturing method of biotransformation film metal plate according to claim 4, it is characterised in that:The aqueous tree
Fat is one kind in polyester resin, phenolic resin, acrylic resin, organic siliconresin and polyurethane resin.
6. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S5
In, during plasma gun sprays, bioconversion film liquid coated weight and thicknesses of layers control are complete in metal sheet surface
Full wetting, uniform fold are advisable without holiday, without hydrops.
7. a kind of manufacturing method of biotransformation film metal plate according to claim 1, it is characterised in that:The step S6
In, the temperature in baking oven is 100~150 DEG C, and drying time is 8~12min.
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CN201711413071.4A CN108220867A (en) | 2017-12-24 | 2017-12-24 | A kind of manufacturing method of biotransformation film metal plate |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102277584A (en) * | 2011-08-22 | 2011-12-14 | 络力螯(昆山)生物科技研发中心有限公司 | Manufacturing method of biotransformation film metal plate |
CN102277568A (en) * | 2011-08-22 | 2011-12-14 | 络力螯(昆山)生物科技研发中心有限公司 | Bioconversion film treating agent |
CN106913906A (en) * | 2015-12-24 | 2017-07-04 | 中国科学院上海硅酸盐研究所 | A kind of antioxidation biology coating and preparation method thereof |
-
2017
- 2017-12-24 CN CN201711413071.4A patent/CN108220867A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102277584A (en) * | 2011-08-22 | 2011-12-14 | 络力螯(昆山)生物科技研发中心有限公司 | Manufacturing method of biotransformation film metal plate |
CN102277568A (en) * | 2011-08-22 | 2011-12-14 | 络力螯(昆山)生物科技研发中心有限公司 | Bioconversion film treating agent |
CN106913906A (en) * | 2015-12-24 | 2017-07-04 | 中国科学院上海硅酸盐研究所 | A kind of antioxidation biology coating and preparation method thereof |
Non-Patent Citations (2)
Title |
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王海娟等: "生物化学转化膜新型防腐蚀技术——先进表面工程技术在金属防腐蚀的应用", 《首届国际(西安)涂料、涂装、表面工程高层论坛论文集(第二分册 涂装前处理)》 * |
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