CN102719816A - Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method - Google Patents

Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method Download PDF

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Publication number
CN102719816A
CN102719816A CN2012102071905A CN201210207190A CN102719816A CN 102719816 A CN102719816 A CN 102719816A CN 2012102071905 A CN2012102071905 A CN 2012102071905A CN 201210207190 A CN201210207190 A CN 201210207190A CN 102719816 A CN102719816 A CN 102719816A
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China
Prior art keywords
water
preparation
washing
raw materials
ethylene glycol
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Pending
Application number
CN2012102071905A
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Chinese (zh)
Inventor
潘德顺
耿斌
戴亿锋
孟兆文
张铁峰
陶乃琦
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Dalian Sandaaoke Chemistry Co Ltd
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Dalian Sandaaoke Chemistry Co Ltd
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Publication date
Application filed by Dalian Sandaaoke Chemistry Co Ltd filed Critical Dalian Sandaaoke Chemistry Co Ltd
Priority to CN2012102071905A priority Critical patent/CN102719816A/en
Publication of CN102719816A publication Critical patent/CN102719816A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a water-washing-free spraying comprehensive treating agent before spray coating of an electronic scale bed plate and a preparation method. The comprehensive treating agent is prepared from the raw materials in percentage by weight: 10-22% of phosphoric acid, 1-1.5% of zinc oxide, 1-2% of tartaric acid, 0.5-1.5% of phytic acid, 10-30% of SP-16, 1-4% of QYL-10F, 1-3% of isopropanol, 0.6-1.6% of ethylene glycol monobutyl ether, 0.6-1.2% of defoaming agent and the balance of water. The preparation method comprises the steps of: adding calculated and weighed water to a reaction kettle, starting a stirrer and controlling the rotation speed at 80 rpm, then sequentially and slowly adding calculated and weighed phosphoric acid, zinc oxide, SP-16, tartaric acid, phytic acid, QYL-10F, isopropanol, ethylene glycol monobutyl ether and defoaming agent to the reaction kettle, stirring for 10-20 min after each raw material is added, continuing stirring until the solution is transparent light-green liquid after all raw materials are added, discharging and packaging.

Description

Exempt from washing spray comprehensive treatment agent and preparation method before the electronic platform scale seat board spray-coating
Technical field
The present invention relates to agent of a kind of metal spraying Coating Pretreatment and preparation method, especially a kind ofly exempt from degreasing washing, but fast filming, guarantee to exempt from washing spray comprehensive treatment agent and preparation method before the electronic platform scale seat board spray-coating of coating quality.
Background technology
Metal works all should carry out the phosphatization conversion processing to its surface before spray-coating, make it generate the phosphate conversion film.Its effect is to make the coating protecting layer on surface with metallic matrix good combining arranged on the one hand; In the time of can or being corroded the medium eating thrown in the local damage of topcoating protective layer on the other hand; Protecting metallic matrix; Exempt from the direct corrosion of medium, prevent the metallic corrosion expansion under the topcoating protective layer metallic matrix.For this reason as the phosphatization conversion film of spray-coating bottom, require that rete is fine and close, quality is even, crystal grain is tiny, thickness is moderate.According to bibliographical information, spray-coating can improve 12 times than the solidity to corrosion of direct spray-coating after the process conversion processing film forming of metallic surface.At present; The treatment process of the professional plant of electronic platform scale before to electronic platform scale seat board spray-coating is: artificial mechanism polishing → manual wipping surface → dress is suspended on the automation line → enters into the electrostatic powder coating coating process; Promptly the seat board surface of steel plate is carried out the artificial mechanism polishing; Dress is suspended on the chain of spray-coating automation line then, directly electrostatic powder coating application.The unavoidable secondary oxidation that produces in electronic platform scale seat board surface after polishing is handled, add polishing after residual dust be difficult to Ex-all, so can not guarantee the technological effect of spray-coating, to such an extent as to all there is serious obscission in electronic platform scale seat board surface sprayed coating.Because existing phosphating process all needs degreasing, after washing and phosphatization after washing etc. eliminate rust, descale; Otherwise the accumulation of remained on surface liquid will be difficult to guarantee the surface quality of Workpiece painting application; The construction of automation lines such as washing is complicated, cost is high, long in time limit and increase; For this reason, the professional plant of existing electronic platform scale still continues to use the production technique that tradition falls behind.
Summary of the invention
The present invention is in order to solve the above-mentioned technical problem of existing in prior technology, to provide a kind of and exempt from degreasing, washing, but fast filming, guarantees to exempt from washing spray comprehensive treatment agent and preparation method before the electronic platform scale seat board spray-coating of coating quality.
Technical solution of the present invention is: exempt from washing spray comprehensive treatment agent before a kind of electronic platform scale seat board spray-coating, it is characterized in that raw materials used and mass percent following:
Phosphatase 11 0 ~ 22%
Zinc oxide 1 ~ 1.5%
Tartrate 1 ~ 2%
Phytic acid 0.5 ~ 1.5%
Comprehensive bonderizing auxiliary agent 10 ~ 30%
Soak degreasing special surfactant 1 ~ 4%
Virahol 1 ~ 3%
Ethylene glycol monobutyl ether 0.6 ~ 1.6%
Skimmer 0.6 ~ 1.2%
Water surplus.
Exempt to wash the preparation method of spray comprehensive treatment agent before a kind of above-mentioned electronic platform scale seat board spray-coating; It is characterized in that carrying out as follows: the water that will calculate weighing joins in the reaction kettle; Start whisking appliance, the control rotating speed is 80 rev/mins, and phosphoric acid, zinc oxide, comprehensive bonderizing auxiliary agent, tartrate, phytic acid, soak degreasing special surfactant, Virahol, ethylene glycol monobutyl ether, the skimmer that will calculate weighing then successively join in the reaction kettle slowly; Whenever add a kind of raw material; Need to stir 10 ~ 20min, all raw materials add continued and are stirred to solution and are till the transparent light green liquid blowing packing.
The present invention can (accomplish cleaning and degreasing, rust cleaning, remove welding oxide debris and stores, and can change into phosphatization conversion film up to standard in the short relatively time simultaneously in 1.5 ~ 2.5min).Especially the workpiece surface after the phosphatization conversion processing need not can directly get into the drying tunnel oven dry through washing, and the workpiece surface after the oven dry does not have the accumulation of debris, has guaranteed the surface quality of Workpiece painting application.
Embodiment
Embodiment 1:
Raw materials used and mass percent is following:
Phosphatase 11 0%
Zinc oxide 1.5%
Tartrate 1%
Phytic acid 1.5%
Comprehensive bonderizing auxiliary agent 10%
Soak degreasing special surfactant 4%
Virahol 1%
Ethylene glycol monobutyl ether 1.6%
Skimmer 0.6%
Water surplus.
The preparation method carries out as follows: the water that will calculate weighing joins in the reaction kettle; Start whisking appliance; The control rotating speed is 80 rev/mins; Phosphoric acid, zinc oxide, comprehensive bonderizing auxiliary agent, tartrate, phytic acid, soak degreasing special surfactant, Virahol, ethylene glycol monobutyl ether, the skimmer that will calculate weighing then successively join in the reaction kettle slowly, whenever add a kind of raw material, need to stir 10 ~ 20min; All raw materials add continued and are stirred to solution and are till the transparent light green liquid blowing packing.
Raw materials usedly be the raw materials used commercially available prod that is, wherein the soak degreasing special surfactant is the product that Yang Long Science and Technology Ltd. is opened by the Shenzhen, and product type is QYL-10F; Comprehensive bonderizing auxiliary agent is the product of Dalian Sandaaoke Chemistry Co., Ltd., and product type is SP-16.
Embodiment 2:
Raw materials used and mass percent is following:
Phosphoric acid 22%
Zinc oxide 1%
Tartrate 2%
Phytic acid 0.5%
Comprehensive bonderizing auxiliary agent 30%
Soak degreasing special surfactant 1%
Virahol 3%
Ethylene glycol monobutyl ether 0.6%
Skimmer 1.2%
Water surplus.
Preparing method and raw material sources are with embodiment 1.
Embodiment 3:
Raw materials used and mass percent is following:
Phosphatase 11 6%
Zinc oxide 1.25%
Tartrate 1.5%
Phytic acid 1.0%
Comprehensive bonderizing auxiliary agent 20%
Soak degreasing special surfactant 2.5%
Virahol 2%
Ethylene glycol monobutyl ether 1.0%
Skimmer 0.8%
Water surplus.
Preparing method and raw material sources are with embodiment 1.
The embodiment of the invention 1,2 or 3 waters are by concentration 5 ~ 10% preparation working fluids; Total acidity 28 ~ 36Pt; Acid ratio 12 ~ 16 is applied to following automatic production line: dress is hung and to be accomplished the long compressed ir spray gun of the comprehensive pre-treatment → 2m of disposable high pressure spraying in the long glass spray chamber of workpiece → 4m and blow off water and blow off debris → 18m length and heat in the drying tunnel oven dry → 26m long air and cool off → change over to the electrostatic powder coating coating process.The processing parameter of the comprehensive pre-treatment of high pressure spraying is: spray pressure MPa0.2 ~ 0.3, spray time 1.5 ~ 2.5min, 30 ℃ of spray temperature.The present invention has reached degreasing, and-remove the technology purpose of floating rust-changing into-passivation, following road electrostatic powder coating application rete reaches the technical requirements of GB1771-86, GB1720-86, GB1732-86 and GB6807-86 technological standard each item index fully.

Claims (2)

1. exempt from washing spray comprehensive treatment agent before the electronic platform scale seat board spray-coating, it is characterized in that raw materials used and mass percent following:
Phosphatase 11 0 ~ 22%
Zinc oxide 1 ~ 1.5%
Tartrate 1 ~ 2%
Phytic acid 0.5 ~ 1.5%
Comprehensive bonderizing auxiliary agent 10 ~ 30%
Soak degreasing special surfactant 1 ~ 4%
Virahol 1 ~ 3%
Ethylene glycol monobutyl ether 0.6 ~ 1.6%
Skimmer 0.6 ~ 1.2%
Water surplus.
2. exempt to wash the preparation method who sprays comprehensive treatment agent before the electronic platform scale seat board spray-coating according to claim 1 for one kind; It is characterized in that carrying out as follows: the water that will calculate weighing joins in the reaction kettle; Start whisking appliance, the control rotating speed is 80 rev/mins, and phosphoric acid, zinc oxide, comprehensive bonderizing auxiliary agent, tartrate, phytic acid, soak degreasing special surfactant, Virahol, ethylene glycol monobutyl ether, the skimmer that will calculate weighing then successively join in the reaction kettle slowly; Whenever add a kind of raw material; Need to stir 10 ~ 20min, all raw materials add continued and are stirred to solution and are till the transparent light green liquid blowing packing.
CN2012102071905A 2012-06-21 2012-06-21 Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method Pending CN102719816A (en)

Priority Applications (1)

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CN2012102071905A CN102719816A (en) 2012-06-21 2012-06-21 Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method

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Application Number Priority Date Filing Date Title
CN2012102071905A CN102719816A (en) 2012-06-21 2012-06-21 Water-washing-free spraying comprehensive treating agent before spray coating of electronic scale bed plate and preparation method

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CN102719816A true CN102719816A (en) 2012-10-10

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978632A (en) * 2012-12-06 2013-03-20 三达奥克化学股份有限公司 Guided missile empennage aluminum alloy work piece degreasing and film-removing comprehensive treating agent and preparation method
CN104195579A (en) * 2014-07-01 2014-12-10 国家电网公司 Surface-tolerant rust treatment fluid
CN107435146A (en) * 2017-07-20 2017-12-05 漳州艾思洁日化科技有限公司 A kind of New process for spray-coating powder of hardware

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101705485A (en) * 2009-11-16 2010-05-12 大连三达奥克化学股份有限公司 Wiping type metal transformation treating agent and preparation method thereof
CN102443793A (en) * 2011-12-30 2012-05-09 大连三达奥克化学股份有限公司 Ejection conversion film treating agent used before steel workpiece surface painting and production method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101705485A (en) * 2009-11-16 2010-05-12 大连三达奥克化学股份有限公司 Wiping type metal transformation treating agent and preparation method thereof
CN102443793A (en) * 2011-12-30 2012-05-09 大连三达奥克化学股份有限公司 Ejection conversion film treating agent used before steel workpiece surface painting and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张鸿等: "高耐蚀常温磷化液的研制", 《电镀与涂饰》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978632A (en) * 2012-12-06 2013-03-20 三达奥克化学股份有限公司 Guided missile empennage aluminum alloy work piece degreasing and film-removing comprehensive treating agent and preparation method
CN104195579A (en) * 2014-07-01 2014-12-10 国家电网公司 Surface-tolerant rust treatment fluid
CN107435146A (en) * 2017-07-20 2017-12-05 漳州艾思洁日化科技有限公司 A kind of New process for spray-coating powder of hardware

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Application publication date: 20121010