CN108219721A - Sealant for equipment installation of hydraulic and hydroelectric engineering - Google Patents

Sealant for equipment installation of hydraulic and hydroelectric engineering Download PDF

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Publication number
CN108219721A
CN108219721A CN201611149871.5A CN201611149871A CN108219721A CN 108219721 A CN108219721 A CN 108219721A CN 201611149871 A CN201611149871 A CN 201611149871A CN 108219721 A CN108219721 A CN 108219721A
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parts
powder
oil
mesh
nano
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梁荣强
谢小坚
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Zhongshan Degaoxing Intellectual Property Center LP
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Zhongshan Degaoxing Intellectual Property Center LP
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/02Condensation polymers of aldehydes or ketones only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

The invention relates to a sealant for equipment installation of hydraulic and hydroelectric engineering, which consists of the following components: ketone-aldehyde resin, bisphenol A epoxy resin, PVC resin powder, MBS resin, modified polypropylene, polyglycerol, rose essential oil, grapeseed oil, tung oil, triethylene oleate, arbutin, polyhexamethylene biguanide hydrochloride, vanillin, nano silver-loaded zirconium phosphate antibacterial agent, nano zirconium oxide powder, nano titanium oxide, ammonium tungstate, lithopone, aluminum borate whisker, ammonium sulfate, zirconium oxychloride powder, hexabromocyclododecane, trichloroethyl phosphate, guanylurea phosphate, diethyl ethylphosphonate, diethylene glycol, sodium alkylsulfonate, coconut oil acid, glycerol monostearate, hydroxymethyl cellulose and castor oil. The product of the invention has good pressure flow viscosity, shore hardness, shear strength, elongation at break and tensile strength, high pressure tightness and excellent performance, and improves the product performance.

Description

A kind of hydraulic and hydroelectric engineering equipment installation fluid sealant
Technical field
The present invention relates to a kind of hydraulic and hydroelectric engineering equipment installation fluid sealants, belong to WR and hydropower construction technical field.
Background technology
In hydraulic and hydroelectric engineering installation, it is often necessary to use different equipment, during these equipment are installed and used, having must Suitable fluid sealant is used, to conform better to requirement.The use of general fluid sealant, most performance can not meet It is required that so that using effect is bad, it is necessary to improve using effect using suitable mode.
Invention content
The purpose of the present invention is to provide a kind of hydraulic and hydroelectric engineering equipment installation fluid sealant, so that water is better achieved The use function of sharp hydroelectric project equipment installation fluid sealant improves product performance.
To achieve these goals, technical scheme is as follows.
A kind of hydraulic and hydroelectric engineering equipment installation fluid sealant, is made of the component of following mass fraction:Ketone resin 26 ~30 parts, 24~28 parts of bisphenol A type epoxy resin, 24~28 parts of PVC resin powder, 22~26 parts of MBS resins, modified polypropene 24 ~28 parts, 24~28 parts of polyglycereol, 22~26 parts of rose ethereal oil, 24~28 parts of grape seed oil, 24~28 parts of tung oil, oleic acid three Sweet 22~26 parts of ester, 22~26 parts of albutin, 22~26 parts of hexamethylene, vanillic aldehyde 24~28 part, nanometer 22~26 parts of silver-zirconium phosphate antimicrobial, 20~24 parts of nano zirconium oxide powder, 24~28 parts of nano-titanium oxide, ammonium tungstate 22~ 26 parts, 20~24 parts of lithopone, 22~26 parts of aluminium borate whisker, 20~24 parts of ammonium sulfate, 20~24 parts of basic zirconium chloride powder, six 20~24 parts of bromine cyclododecane, 18~22 parts of trichloroethyl phosphate, 14~18 parts of guanylurea phosphate, diethyl ethylphosphate 12 ~16 parts, 12~16 parts of diethylene glycol (DEG), 12~16 parts of sodium alkyl sulfonate, 12~16 parts of cocinic acid, glyceryl monostearate 12~ 16 parts, 12~16 parts of hydroxymethyl cellulose, 100~200 parts of castor oil.
Further, above-mentioned hydraulic and hydroelectric engineering equipment installation fluid sealant, is made of the component of following mass fraction:Ketone It is 26 parts of urea formaldehyde, 24 parts of bisphenol A type epoxy resin, 24 parts of PVC resin powder, 22 parts of MBS resins, 24 parts of modified polypropene, poly- sweet 24 parts of oil, 22 parts of rose ethereal oil, 24 parts of grape seed oil, 24 parts of tung oil, 22 parts of oleic acid triglyceride, 22 parts of albutin, poly- six Asia 22 parts of methyl biguanide hydrochloride, 20 parts of nano zirconium oxide powder, is received 22 parts of 24 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 24 parts of titanium oxide of rice, 22 parts of ammonium tungstate, 20 parts of lithopone, 22 parts of aluminium borate whisker, 20 parts of ammonium sulfate, basic zirconium chloride powder 20 It is part, 20 parts of hexabromocyclododecane, 18 parts of trichloroethyl phosphate, 14 parts of guanylurea phosphate, 12 parts of diethyl ethylphosphate, two sweet 12 parts of alcohol, 12 parts of sodium alkyl sulfonate, 12 parts of cocinic acid, 12 parts of glyceryl monostearate, 12 parts of hydroxymethyl cellulose, castor oil 100 parts.
Further, above-mentioned hydraulic and hydroelectric engineering equipment installation fluid sealant, is made of the component of following mass fraction:Ketone It is 28 parts of urea formaldehyde, 26 parts of bisphenol A type epoxy resin, 26 parts of PVC resin powder, 24 parts of MBS resins, 26 parts of modified polypropene, poly- sweet 26 parts of oil, 24 parts of rose ethereal oil, 26 parts of grape seed oil, 26 parts of tung oil, 24 parts of oleic acid triglyceride, 24 parts of albutin, poly- six Asia 24 parts of methyl biguanide hydrochloride, 22 parts of nano zirconium oxide powder, is received 24 parts of 26 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 26 parts of titanium oxide of rice, 24 parts of ammonium tungstate, 22 parts of lithopone, 24 parts of aluminium borate whisker, 22 parts of ammonium sulfate, basic zirconium chloride powder 22 It is part, 22 parts of hexabromocyclododecane, 20 parts of trichloroethyl phosphate, 16 parts of guanylurea phosphate, 14 parts of diethyl ethylphosphate, two sweet 14 parts of alcohol, 14 parts of sodium alkyl sulfonate, 14 parts of cocinic acid, 14 parts of glyceryl monostearate, 14 parts of hydroxymethyl cellulose, castor oil 150 parts.
Further, above-mentioned hydraulic and hydroelectric engineering equipment installation fluid sealant, is made of the component of following mass fraction:Ketone It is 30 parts of urea formaldehyde, 28 parts of bisphenol A type epoxy resin, 28 parts of PVC resin powder, 26 parts of MBS resins, 28 parts of modified polypropene, poly- sweet 28 parts of oil, 26 parts of rose ethereal oil, 28 parts of grape seed oil, 28 parts of tung oil, 26 parts of oleic acid triglyceride, 26 parts of albutin, poly- six Asia 26 parts of methyl biguanide hydrochloride, 24 parts of nano zirconium oxide powder, is received 26 parts of 28 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 28 parts of titanium oxide of rice, 26 parts of ammonium tungstate, 24 parts of lithopone, 26 parts of aluminium borate whisker, 24 parts of ammonium sulfate, basic zirconium chloride powder 24 It is part, 24 parts of hexabromocyclododecane, 22 parts of trichloroethyl phosphate, 18 parts of guanylurea phosphate, 16 parts of diethyl ethylphosphate, two sweet 16 parts of alcohol, 16 parts of sodium alkyl sulfonate, 16 parts of cocinic acid, 16 parts of glyceryl monostearate, 16 parts of hydroxymethyl cellulose, castor oil 200 parts.
Further, the nano zirconium oxide powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3~12: 4~8: 1.
Further, the basic zirconium chloride powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30 ~50 mesh, 50~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3~9: 2~8: 1.
Further, the viscosity of the grape seed oil is 120~160mpa.s at 25 DEG C.
Further, the nano-titanium oxide is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 20~ 50 mesh, 50~70 mesh, 70~90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 2~8: 3~9: 1.
Further, the viscosity of the tung oil is 80~120mpa.s at 25 DEG C.
Further, above-mentioned hydraulic and hydroelectric engineering equipment installation is as follows with fluid sealant preparation method step:
(1) it is the ketone resin of the mass fraction, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modification is poly- Propylene, polyglycereol, rose ethereal oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, Vanillic aldehyde, nanometer silver-zirconium phosphate antimicrobial, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminum borate crystal whisker Must, ammonium sulfate be added in the castor oil of above-mentioned mass fraction, from room temperature with 2~5 DEG C of the speed of heating up per hour, while stirring 60~90 DEG C are warming up to, is stirred evenly, is then let cool by cooling down per hour to room temperature in a manner of 4~10 DEG C, obtains mixture A;
(2) basic zirconium chloride powder, hexabromocyclododecane, trichloroethyl phosphate, the amidine phosphate of the mass fraction are added in Base urea, diethyl ethylphosphate, from room temperature with 5~8 DEG C of the speed of heating up per hour, warming while stirring to 80~90 DEG C, and 1~3h is kept at 80~90 DEG C, cooled to room temperature obtains mixture B;
(3) diethylene glycol (DEG), sodium alkyl sulfonate, cocinic acid, glyceryl monostearate, the methylol of the mass fraction are added in Cellulose, from room temperature with 8~10 DEG C of the speed of heating up per hour, warming while stirring to 70~90 DEG C, under stirring in 70~90 DEG C of 1~3h of holding, cooled to room temperature obtain mixture C;
(4) remaining ingredient of above-mentioned mass fraction is added in mixture C, is the true of -0.06~-0.1Mpa in vacuum degree Under empty condition, from room temperature with 1~3 DEG C of the speed of heating up per hour, warming while stirring is stirred evenly to 50~70 DEG C, is cooled down To room temperature, this product is obtained.
The advantageous effect of the invention is:Hydraulic and hydroelectric engineering equipment installation fluid sealant in the present invention, by with the following group It is grouped as:Ketone resin, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modified polypropene, polyglycereol, rose anthosin Oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, vanillic aldehyde, nanometer basic zirconium phosphate carry silver Antiseptic, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminium borate whisker, ammonium sulfate, oxychloride zirconium powder End, hexabromocyclododecane, trichloroethyl phosphate, guanylurea phosphate, diethyl ethylphosphate, diethylene glycol (DEG), sodium alkyl sulfonate, coconut palm Seed oil acid, glyceryl monostearate, hydroxymethyl cellulose.Process of preparing of the present invention is simple, and prepared product has good Press flow viscosity well, shore hardness, shear strength, elongation at break, tensile strength, pressure-resistant stopping property is high, has excellent performance, and fits It closes and is used in multiple fields, improve properties of product, processing is easy to use.
Specific embodiment
The specific embodiment of the present invention is described with reference to embodiment, to be better understood from the present invention.
Embodiment 1
Hydraulic and hydroelectric engineering equipment installation fluid sealant in the present embodiment, is made of the component of following mass fraction:Ketone It is 26 parts of urea formaldehyde, 24 parts of bisphenol A type epoxy resin, 24 parts of PVC resin powder, 22 parts of MBS resins, 24 parts of modified polypropene, poly- sweet 24 parts of oil, 22 parts of rose ethereal oil, 24 parts of grape seed oil, 24 parts of tung oil, 22 parts of oleic acid triglyceride, 22 parts of albutin, poly- six Asia 22 parts of methyl biguanide hydrochloride, 20 parts of nano zirconium oxide powder, is received 22 parts of 24 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 24 parts of titanium oxide of rice, 22 parts of ammonium tungstate, 20 parts of lithopone, 22 parts of aluminium borate whisker, 20 parts of ammonium sulfate, basic zirconium chloride powder 20 It is part, 20 parts of hexabromocyclododecane, 18 parts of trichloroethyl phosphate, 14 parts of guanylurea phosphate, 12 parts of diethyl ethylphosphate, two sweet 12 parts of alcohol, 12 parts of sodium alkyl sulfonate, 12 parts of cocinic acid, 12 parts of glyceryl monostearate, 12 parts of hydroxymethyl cellulose, castor oil 100 parts.
The nano zirconium oxide powder is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3: 4: 1.
The basic zirconium chloride powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50 ~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3: 2: 1.
The viscosity of the grape seed oil is 120mpa.s at 25 DEG C.
The nano-titanium oxide is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 20~50 mesh, 50~ 70 mesh, 70~90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 2: 3: 1.
The viscosity of the tung oil is 80mpa.s at 25 DEG C.
Above-mentioned hydraulic and hydroelectric engineering equipment installation is as follows with fluid sealant preparation method step:
(1) it is the ketone resin of the mass fraction, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modification is poly- Propylene, polyglycereol, rose ethereal oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, Vanillic aldehyde, nanometer silver-zirconium phosphate antimicrobial, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminum borate crystal whisker Must, ammonium sulfate be added in the castor oil of above-mentioned mass fraction, from room temperature with 2 DEG C of the speed of heating up per hour, rise while stirring Temperature is stirred evenly to 60 DEG C, is then let cool by cooling down per hour to room temperature in a manner of 4 DEG C, is obtained mixture A;
(2) basic zirconium chloride powder, hexabromocyclododecane, trichloroethyl phosphate, the amidine phosphate of the mass fraction are added in Base urea, diethyl ethylphosphate, from room temperature with 5 DEG C of the speed of heating up per hour, warming while stirring is to 80 DEG C, and in 80 DEG C of guarantors 3h is held, cooled to room temperature obtains mixture B;
(3) diethylene glycol (DEG), sodium alkyl sulfonate, cocinic acid, glyceryl monostearate, the methylol of the mass fraction are added in Cellulose, from room temperature with 8 DEG C of the speed of heating up per hour, warming while stirring is to 70 DEG C, in 70 DEG C of holdings under stirring 3h, cooled to room temperature obtain mixture C;
(4) remaining ingredient of above-mentioned mass fraction is added in mixture C, in the vacuum condition that vacuum degree is -0.06Mpa Under, from room temperature with 1 DEG C of the speed of heating up per hour, warming while stirring is stirred evenly, is cooled to room temperature to 50 DEG C, obtains this Product.
Embodiment 2
Hydraulic and hydroelectric engineering equipment installation fluid sealant in the present embodiment, is made of the component of following mass fraction:Ketone It is 28 parts of urea formaldehyde, 26 parts of bisphenol A type epoxy resin, 26 parts of PVC resin powder, 24 parts of MBS resins, 26 parts of modified polypropene, poly- sweet 26 parts of oil, 24 parts of rose ethereal oil, 26 parts of grape seed oil, 26 parts of tung oil, 24 parts of oleic acid triglyceride, 24 parts of albutin, poly- six Asia 24 parts of methyl biguanide hydrochloride, 22 parts of nano zirconium oxide powder, is received 24 parts of 26 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 26 parts of titanium oxide of rice, 24 parts of ammonium tungstate, 22 parts of lithopone, 24 parts of aluminium borate whisker, 22 parts of ammonium sulfate, basic zirconium chloride powder 22 It is part, 22 parts of hexabromocyclododecane, 20 parts of trichloroethyl phosphate, 16 parts of guanylurea phosphate, 14 parts of diethyl ethylphosphate, two sweet 14 parts of alcohol, 14 parts of sodium alkyl sulfonate, 14 parts of cocinic acid, 14 parts of glyceryl monostearate, 14 parts of hydroxymethyl cellulose, castor oil 150 parts.
The nano zirconium oxide powder is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 8: 6: 1.
The basic zirconium chloride powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50 ~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 6: 5: 1.
The viscosity of the grape seed oil is 140mpa.s at 25 DEG C.
The nano-titanium oxide is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 20~50 mesh, 50~ 70 mesh, 70~90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 5: 6: 1.
The viscosity of the tung oil is 100mpa.s at 25 DEG C.
Above-mentioned hydraulic and hydroelectric engineering equipment installation is as follows with fluid sealant preparation method step:
(1) it is the ketone resin of the mass fraction, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modification is poly- Propylene, polyglycereol, rose ethereal oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, Vanillic aldehyde, nanometer silver-zirconium phosphate antimicrobial, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminum borate crystal whisker Must, ammonium sulfate be added in the castor oil of above-mentioned mass fraction, from room temperature with 3 DEG C of the speed of heating up per hour, rise while stirring Temperature is stirred evenly to 75 DEG C, is then let cool by cooling down per hour to room temperature in a manner of 7 DEG C, is obtained mixture A;
(2) basic zirconium chloride powder, hexabromocyclododecane, trichloroethyl phosphate, the amidine phosphate of the mass fraction are added in Base urea, diethyl ethylphosphate, from room temperature with 6 DEG C of the speed of heating up per hour, warming while stirring is to 85 DEG C, and in 85 DEG C of guarantors 2h is held, cooled to room temperature obtains mixture B;
(3) diethylene glycol (DEG), sodium alkyl sulfonate, cocinic acid, glyceryl monostearate, the methylol of the mass fraction are added in Cellulose, from room temperature with 9 DEG C of the speed of heating up per hour, warming while stirring is to 80 DEG C, in 80 DEG C of holdings under stirring 2h, cooled to room temperature obtain mixture C;
(4) remaining ingredient of above-mentioned mass fraction is added in mixture C, in the vacuum condition that vacuum degree is -0.08Mpa Under, from room temperature with 2 DEG C of the speed of heating up per hour, warming while stirring is stirred evenly, is cooled to room temperature to 60 DEG C, obtains this Product.
Embodiment 3
Hydraulic and hydroelectric engineering equipment installation fluid sealant in the present embodiment, is made of the component of following mass fraction:Ketone It is 30 parts of urea formaldehyde, 28 parts of bisphenol A type epoxy resin, 28 parts of PVC resin powder, 26 parts of MBS resins, 28 parts of modified polypropene, poly- sweet 28 parts of oil, 26 parts of rose ethereal oil, 28 parts of grape seed oil, 28 parts of tung oil, 26 parts of oleic acid triglyceride, 26 parts of albutin, poly- six Asia 26 parts of methyl biguanide hydrochloride, 24 parts of nano zirconium oxide powder, is received 26 parts of 28 part, nanometer silver-zirconium phosphate antimicrobial of vanillic aldehyde 28 parts of titanium oxide of rice, 26 parts of ammonium tungstate, 24 parts of lithopone, 26 parts of aluminium borate whisker, 24 parts of ammonium sulfate, basic zirconium chloride powder 24 It is part, 24 parts of hexabromocyclododecane, 22 parts of trichloroethyl phosphate, 18 parts of guanylurea phosphate, 16 parts of diethyl ethylphosphate, two sweet 16 parts of alcohol, 16 parts of sodium alkyl sulfonate, 16 parts of cocinic acid, 16 parts of glyceryl monostearate, 16 parts of hydroxymethyl cellulose, castor oil 200 parts.
The nano zirconium oxide powder is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 12: 8: 1.
The basic zirconium chloride powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50 ~80 mesh, 80~100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 9: 8: 1.
The viscosity of the grape seed oil is 160mpa.s at 25 DEG C.
The nano-titanium oxide is made of the powder of three kinds of grain size mesh numbers, grain size mesh number be respectively 20~50 mesh, 50~ 70 mesh, 70~90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 8: 9: 1.
The viscosity of the tung oil is 120mpa.s at 25 DEG C.
Above-mentioned hydraulic and hydroelectric engineering equipment installation is as follows with fluid sealant preparation method step:
(1) it is the ketone resin of the mass fraction, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modification is poly- Propylene, polyglycereol, rose ethereal oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, Vanillic aldehyde, nanometer silver-zirconium phosphate antimicrobial, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminum borate crystal whisker Must, ammonium sulfate be added in the castor oil of above-mentioned mass fraction, from room temperature with 5 DEG C of the speed of heating up per hour, rise while stirring Temperature is stirred evenly to 90 DEG C, is then let cool by cooling down per hour to room temperature in a manner of 10 DEG C, is obtained mixture A;
(2) basic zirconium chloride powder, hexabromocyclododecane, trichloroethyl phosphate, the amidine phosphate of the mass fraction are added in Base urea, diethyl ethylphosphate, from room temperature with 8 DEG C of the speed of heating up per hour, warming while stirring is to 90 DEG C, and in 90 DEG C of guarantors 1h is held, cooled to room temperature obtains mixture B;
(3) diethylene glycol (DEG), sodium alkyl sulfonate, cocinic acid, glyceryl monostearate, the methylol of the mass fraction are added in Cellulose, from room temperature with 10 DEG C of the speed of heating up per hour, warming while stirring is to 90 DEG C, in 90 DEG C of holdings under stirring 1~3h, cooled to room temperature obtain mixture C;
(4) remaining ingredient of above-mentioned mass fraction is added in mixture C, in the vacuum condition that vacuum degree is -0.1Mpa Under, from room temperature with 3 DEG C of the speed of heating up per hour, warming while stirring is stirred evenly, is cooled to room temperature to 70 DEG C, obtains this Product.
Embodiment 1, embodiment 2 and embodiment 3 and certain commercial product are tested for the property as a control group, as a result such as Under:
Embodiment 1 Embodiment 2 Embodiment 3 Control group
Press flow viscosity/s 70 80 72 50
Density/kgm-3 1.4×103 1.1×103 1.2×103 1.1×103
Solid content/% 94 95 96 82
Surface drying time/min 5 6 5 10
Shore hardness A types/HA 38 35 40 25
Shear strength/MPa 2.5 2.4 2.7 1.8
Elongation at break/% 450 430 440 300
Tensile strength/MPa 2.4 2.9 2.8 1.5
Pressure-resistant stopping property/bar 0.4 0.5 0.4 0.1
From the result in upper table can be seen that fluid sealant provided by the invention with good press flow viscosity, shore hardness, Shear strength, elongation at break, tensile strength, pressure-resistant stopping property is high, has excellent performance.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (10)

1. a kind of hydraulic and hydroelectric engineering equipment installation fluid sealant, it is characterised in that:It is made of the component of following mass fraction:Ketone 26~30 parts of urea formaldehyde, 24~28 parts of PVC resin powder, 22~26 parts of MBS resins, is modified 24~28 parts of bisphenol A type epoxy resin 24~28 parts of polypropylene, 24~28 parts of polyglycereol, 22~26 parts of rose ethereal oil, 24~28 parts of grape seed oil, tung oil 24~28 Part, 22~26 parts of oleic acid triglyceride, 22~26 parts of albutin, 22~26 parts of hexamethylene, vanillic aldehyde 24~ 28 22~26 parts of part, nanometer silver-zirconium phosphate antimicrobials, 20~24 parts of nano zirconium oxide powder, 24~28 parts of nano-titanium oxide, 22~26 parts of ammonium tungstate, 20~24 parts of lithopone, 22~26 parts of aluminium borate whisker, 20~24 parts of ammonium sulfate, basic zirconium chloride powder 20~24 parts, 20~24 parts of hexabromocyclododecane, 18~22 parts of trichloroethyl phosphate, 14~18 parts of guanylurea phosphate, ethyl 12~16 parts of diethyl phosphonate, 12~16 parts of diethylene glycol (DEG), 12~16 parts of sodium alkyl sulfonate, 12~16 parts of cocinic acid, glycerine list 12~16 parts of stearate, 12~16 parts of hydroxymethyl cellulose, 100~200 parts of castor oil.
2. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The water conservancy and hydropower Engineering equipment installation is made of with fluid sealant the component of following mass fraction:26 parts of ketone resin, bisphenol A type epoxy resin 24 Part, 24 parts of PVC resin powder, 22 parts of MBS resins, 24 parts of modified polypropene, 24 parts of polyglycereol, 22 parts of rose ethereal oil, grape pip 24 parts of oil, 24 parts of tung oil, 22 parts of oleic acid triglyceride, 22 parts of albutin, 22 parts of hexamethylene, vanillic aldehyde 24 Part, 22 parts of nanometer silver-zirconium phosphate antimicrobial, 20 parts of nano zirconium oxide powder, 24 parts of nano-titanium oxide, 22 parts of ammonium tungstate, zinc barium White 20 parts, 22 parts of aluminium borate whisker, 20 parts of ammonium sulfate, 20 parts of basic zirconium chloride powder, 20 parts of hexabromocyclododecane, trichloroethyl phosphorus 18 parts of acid esters, 14 parts of guanylurea phosphate, 12 parts of diethyl ethylphosphate, 12 parts of diethylene glycol (DEG), 12 parts of sodium alkyl sulfonate, cocinic acid 12 parts, 12 parts of glyceryl monostearate, 12 parts of hydroxymethyl cellulose, 100 parts of castor oil.
3. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The water conservancy and hydropower Engineering equipment installation is made of with fluid sealant the component of following mass fraction:28 parts of ketone resin, bisphenol A type epoxy resin 26 Part, 26 parts of PVC resin powder, 24 parts of MBS resins, 26 parts of modified polypropene, 26 parts of polyglycereol, 24 parts of rose ethereal oil, grape pip 26 parts of oil, 26 parts of tung oil, 24 parts of oleic acid triglyceride, 24 parts of albutin, 24 parts of hexamethylene, vanillic aldehyde 26 Part, 24 parts of nanometer silver-zirconium phosphate antimicrobial, 22 parts of nano zirconium oxide powder, 26 parts of nano-titanium oxide, 24 parts of ammonium tungstate, zinc barium White 22 parts, 24 parts of aluminium borate whisker, 22 parts of ammonium sulfate, 22 parts of basic zirconium chloride powder, 22 parts of hexabromocyclododecane, trichloroethyl phosphorus 20 parts of acid esters, 16 parts of guanylurea phosphate, 14 parts of diethyl ethylphosphate, 14 parts of diethylene glycol (DEG), 14 parts of sodium alkyl sulfonate, cocinic acid 14 parts, 14 parts of glyceryl monostearate, 14 parts of hydroxymethyl cellulose, 150 parts of castor oil.
4. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The water conservancy and hydropower Engineering equipment installation is made of with fluid sealant the component of following mass fraction:30 parts of ketone resin, bisphenol A type epoxy resin 28 Part, 28 parts of PVC resin powder, 26 parts of MBS resins, 28 parts of modified polypropene, 28 parts of polyglycereol, 26 parts of rose ethereal oil, grape pip 28 parts of oil, 28 parts of tung oil, 26 parts of oleic acid triglyceride, 26 parts of albutin, 26 parts of hexamethylene, vanillic aldehyde 28 Part, 26 parts of nanometer silver-zirconium phosphate antimicrobial, 24 parts of nano zirconium oxide powder, 28 parts of nano-titanium oxide, 26 parts of ammonium tungstate, zinc barium White 24 parts, 26 parts of aluminium borate whisker, 24 parts of ammonium sulfate, 24 parts of basic zirconium chloride powder, 24 parts of hexabromocyclododecane, trichloroethyl phosphorus 22 parts of acid esters, 18 parts of guanylurea phosphate, 16 parts of diethyl ethylphosphate, 16 parts of diethylene glycol (DEG), 16 parts of sodium alkyl sulfonate, cocinic acid 16 parts, 16 parts of glyceryl monostearate, 16 parts of hydroxymethyl cellulose, 200 parts of castor oil.
5. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:It is described nano oxidized Zirconium powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, on The mixing quality ratio for stating three kinds of powders is 3~12: 4~8: 1.
6. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The basic zirconium chloride Powder is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, above-mentioned The mixing quality ratio of three kinds of powders is 3~9: 2~8: 1.
7. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The grape seed oil Viscosity 25 DEG C be 120~160mpa.s.
8. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:It is described nano oxidized Titanium is made of the powder of three kinds of grain size mesh numbers, and grain size mesh number is respectively 20~50 mesh, 50~70 mesh, 70~90 mesh, and above-mentioned three The mixing quality ratio of kind powder is 2~8: 3~9: 1.
9. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The tung oil glues Degree is 80~120mpa.s at 25 DEG C.
10. hydraulic and hydroelectric engineering equipment installation fluid sealant according to claim 1, it is characterised in that:The water conservancy water The installation of electrical engineering equipment is as follows with fluid sealant preparation method step:
(1) by the ketone resin of the mass fraction, bisphenol A type epoxy resin, PVC resin powder, MBS resins, modified polypropene, Polyglycereol, rose ethereal oil, grape seed oil, tung oil, oleic acid triglyceride, albutin, hexamethylene, chinese cymbidium Element, nanometer silver-zirconium phosphate antimicrobial, nano zirconium oxide powder, nano-titanium oxide, ammonium tungstate, lithopone, aluminium borate whisker, sulphur Sour ammonium is added in the castor oil of above-mentioned mass fraction, from room temperature with 2~5 DEG C of the speed of heating up per hour, warming while stirring It to 60~90 DEG C, stirs evenly, is then let cool by cooling down per hour to room temperature in a manner of 4~10 DEG C, obtain mixture A;
(2) add in the basic zirconium chloride powder of the mass fraction, hexabromocyclododecane, trichloroethyl phosphate, guanylurea phosphate, Diethyl ethylphosphate, from room temperature with 5~8 DEG C of the speed of heating up per hour, warming while stirring to 80~90 DEG C, and 80~ 90 DEG C of 1~3h of holding, cooled to room temperature obtain mixture B;
(3) diethylene glycol (DEG), sodium alkyl sulfonate, cocinic acid, glyceryl monostearate, the hydroxylmethyl cellulose of the mass fraction are added in Element, from room temperature with 8~10 DEG C of the speed of heating up per hour, warming while stirring to 70~90 DEG C, under stirring in 70~ 90 DEG C of 1~3h of holding, cooled to room temperature obtain mixture C;
(4) remaining ingredient of above-mentioned mass fraction is added in mixture C, in the vacuum item that vacuum degree is -0.06~-0.1Mpa Under part, from room temperature with 1~3 DEG C of the speed of heating up per hour, warming while stirring stirs evenly to 50~70 DEG C, is cooled to room Temperature obtains this product.
CN201611149871.5A 2016-12-13 2016-12-13 Sealant for equipment installation of hydraulic and hydroelectric engineering Pending CN108219721A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611149871.5A CN108219721A (en) 2016-12-13 2016-12-13 Sealant for equipment installation of hydraulic and hydroelectric engineering

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611149871.5A CN108219721A (en) 2016-12-13 2016-12-13 Sealant for equipment installation of hydraulic and hydroelectric engineering

Publications (1)

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CN108219721A true CN108219721A (en) 2018-06-29

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Country Status (1)

Country Link
CN (1) CN108219721A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237845A (en) * 2015-10-28 2016-01-13 无锡贺邦金属制品有限公司 High-pressure-resistant sealing material and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237845A (en) * 2015-10-28 2016-01-13 无锡贺邦金属制品有限公司 High-pressure-resistant sealing material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴世敏等: "《简明精细化工大辞典》", 30 June 1999, 辽宁科学技术出版社 *

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