CN108219361A - The method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product - Google Patents
The method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Abstract
The invention discloses the method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product, step is as follows：A. the raw material for manufacturing mineral fibre synthesizing environment-friendly resin-oatmeal is weighed.B. imitative porcelain recycling product is subjected to HIGH TEMPERATURE PURGE, crushing, grinding.C. it reacts.D. it mediates.E. it dries.F. it grinds.G. it detects.H. the raw material for manufacturing bamboo fibre minerals synthesis particle is weighed.I. it mediates.J. it dries.K. it crushes.L. the mineral fibre synthesizing environment-friendly resin-oatmeal that accounting is 80% and the bamboo fibre minerals synthesis particle that accounting is 20% are weighed, then puts into stainless steel blender after stirring evenly to pack and complete.This method for production is by a relatively simple rationally, using imitative porcelain recycling product, solves waste product waste problems, reduction enterprise's production cost very well, and the density of material made by this method is high, structure is strong.
Description
Technical field
The present invention relates to the methods for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product.
Background technology
Existing ceramic imitation product, such as imitative porcelain eats butterfly, service plate waste product and while manufacturing tableware generates leftover pieces because can not degrade,
Also it does not recycle well.So as to cause the generation of a large amount of defective works, environment can not only be caused certain bad
It influences, while also increases the production cost of enterprise, while the burning of biological plants fibre object such as stalk, paddy etc. also can be to environment
Cause larger pollution.
Invention content
For overcome the deficiencies in the prior art, present invention offer is using imitative porcelain recycling product, solution waste product waste material is asked very well
Topic, reduce enterprise's production cost, increase the intensity of product, heat resistance, improve material molecular weight, enhancing product density with biology
Plant the method that fibre object makes advanced composite material (ACM) with imitative porcelain recycling product.
The technical solution adopted by the present invention to solve the technical problems is：
The method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product, step are as follows：A. following percentage is pressed
The raw material of mineral fibre synthesizing environment-friendly resin-oatmeal is manufactured than weighing：Imitative porcelain recycling product 20%, formaldehyde：20%th, melamine:
10%th, biological plants fibre object：10%th, citric acid is received：10%th, amino film plastics particle 5%, wood fibre：5%th, bamboo fibre:5%th, titanium white
Powder：2.1%th, natural environmental-protective minerals 5%, nano silicon dioxide 3%, zinc stearate：0.193%th, curing agent：0.083%th, dibutyl ester：
0.08%th, brightening agent：0.25%th, pigment is eaten：0.004%th, brightener：0.3%th, toughener：0.02%th, plasticizer：0.5%th, it is release
Agent：1.2%th, anti-caking agent：1.38%th, antioxidant：0.2%th, fire retardant：0.15%th, insulation agent：0.4%th, sterilization agent：0.12%th, stabilizer
0.02%.B. imitative porcelain recycling product is subjected to HIGH TEMPERATURE PURGE, steam heating is carried out to material, powdering then is crushed to it,
Then impurity is filtered, then carries out high-temperature stirring grinding, formed powder stone shape material, filter again, life is added in after filtering
Object carries out steam heating after planting fibre object, becomes biological plants fiber powder.C. it reacts：By biological plants fiber powder, formaldehyde,
In melamine input reaction kettle, by stirring, being steam heated to 90 DEG C so that material in reactor is sufficiently mixed, in the process
PH value and drop white effect are detected, and adds in stabilizer to adjust the acid-base value of mixture and reaction time, reaches predetermined standard time
Reaction is completed and obtains melamino-formaldehyde reacting resin.D. it mediates：By melamino-formaldehyde reacting resin, wood fibre, hard
Resin acid zinc, curing agent, brightening agent, dibutyl ester, mould release, citric acid are received, amino film plastics particle, bamboo fibre, nanometer titanium dioxide
Silicon adds in kneader, is mutually sheared, mediated by agitating paddle in kneader, carries out steam heating by control pressurer system, protects
It holds and mediates built-in temperature between 65 to 70 degrees Celsius, material is made to stir dehydration in constant temperature, while improve molecular weight, when sharing
45 to 60 minutes.E. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value 0.5MPa,
75-95 DEG C of set temperature, layer thickness are 8cm or so, thickness control are carried out using inductive probe, above or below lid thickness meeting
Automatic alarm is able to ensure the uniform of the bed of material, dry duration 2.5-3 hours, moisture 1.5-2.2%, mobility 195-
205cm obtains particle after 65 seconds forming and hardening time.F. it grinds：By particulate material input jacket type stainless steel cooling milling apparatus
In, add in edible pigment, plasticizer, natural environmental-protective minerals, brightener, toughener, anti-caking agent, antioxidant, fire retardant, heat-insulated
Agent, sterilization agent, titanium dioxide.Grinding 15 to 20 hours, milling apparatus use temperature control system, ensure grinding temperature constant temperature
Between 65 to 70 degrees Celsius.G. it detects：A series of detections such as sampling observation color, mobility, density, brightness and intensity after grinding
Project after reaching examination criteria, is sieved with the full-automatic rotary strainer of 50 to 80 mesh and obtains mineral fibre synthesizing environment-friendly resin
Powder.H. the raw material for manufacturing bamboo fibre minerals synthesis particle is weighed by following percentage：Melamino-formaldehyde reacting resin：81%、
Bamboo fibre：8%th, natural environmental-protective minerals 7%, zinc stearate：0.2%th, curing agent：0.5%th, dibutyl ester：0.1%th, brightening agent：0.3%、
Citric acid is received：0.25%th, plasticizer：0.85%th, mould release：1.5%th, titanium dioxide 0.3%.I. it mediates：Melamino-formaldehyde is reacted
Resin, bamboo fibre, natural environmental-protective minerals, zinc stearate, curing agent, dibutyl ester, brightening agent, citric acid are received, plasticizer, release
Agent, titanium dioxide add in kneader, are mutually sheared, mediated by agitating paddle in kneader, steam is carried out by control pressurer system
Heating will mediate between built-in temperature is maintained at 65 to 70 degrees Celsius, and material be made to stir dehydration in constant temperature, while improve molecule
Amount, 45 to 60 minutes used times.J. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value
0.5MPa, 90 to 130 DEG C of set temperature, layer thickness are 7cm or so, carry out thickness control using inductive probe, are more than or low
In lid thickness meeting automatic alarm, it is able to ensure the uniform of the bed of material, dry duration 4.5-5 hours, moisture 0.5-1%, mobility
120-135cm.K. it crushes：By the unified crushing of dried particulate material, bamboo fibre mineral are obtained after carrying out dusting cover with Double-layer screen
Matter synthesis particle.L. the mineral fibre synthesizing environment-friendly resin-oatmeal that accounting is 80% and the bamboo fibre minerals that accounting is 20% are weighed
Then synthesis particle puts into stainless steel blender after stirring evenly to pack and complete.
The beneficial effects of the invention are as follows：This method for production is by a relatively simple rationally, and production process safety and environmental protection not only solves
Determined existing ceramic imitation product and problem can not be degraded and be recycled to product leftover pieces, by this method can also improve the product feature of environmental protection,
Can be by Ceramic-imitated tableware recycling, after forming Novel environment-friendlymaterial material, while increase the intensity of product, brightness, heat resistance, raising
Material molecular weight.
Specific embodiment
The method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product, step are as follows：
A. the raw material for manufacturing mineral fibre synthesizing environment-friendly resin-oatmeal is weighed by following percentage：Imitative porcelain recycling product 20%, first
Aldehyde：20%th, melamine:10%th, biological plants fibre object：10%th, citric acid is received：10%th, amino film plastics particle 5%, wood fibre：
5%th, bamboo fibre:5%th, titanium dioxide：2.1%th, natural environmental-protective minerals 5%, nano silicon dioxide 3%, zinc stearate：0.193%th, cure
Agent：0.083%th, dibutyl ester：0.08%th, brightening agent：0.25%th, pigment is eaten：0.004%th, brightener：0.3%th, toughener：0.02%、
Plasticizer：0.5%th, mould release：1.2%th, anti-caking agent：1.38%th, antioxidant：0.2%th, fire retardant：0.15%th, insulation agent：0.4%th, disappear
Microbial inoculum：0.12%th, stabilizer 0.02%.
B. imitative porcelain recycling product is subjected to HIGH TEMPERATURE PURGE, steam heating is carried out to material, powder is then crushed into it
Then impurity is filtered by shape, then carry out high-temperature stirring grinding, is formed powder stone shape material, is filtered, added in after filtering again
Steam heating is carried out after biological plants fibre object, becomes biological plants fiber powder.
C. it reacts：Biological plants fiber powder, formaldehyde, melamine are put into reaction kettle, by stirring, being steam heated to
90 DEG C so that material in reactor is sufficiently mixed, and detects pH value and drop white effect in the process, and adds in stabilizer to adjust mixing
The acid-base value of object and reaction time reach predetermined standard time reaction and complete and obtain melamino-formaldehyde reacting resin.
D. it mediates：By melamino-formaldehyde reacting resin, wood fibre, zinc stearate, curing agent, brightening agent, dibutyl ester,
Mould release, citric acid are received, amino film plastics particle, bamboo fibre, nano silicon dioxide add in kneader, by being stirred in kneader
Paddle is mutually sheared, is mediated, by control pressurer system carry out steam heating, keep mediate built-in temperature 65 to 70 degrees Celsius it
Between, material is made to stir dehydration in constant temperature, while improve molecular weight, 45 to 60 minutes when sharing.
E. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value 0.5MPa, set
75-95 DEG C of temperature, layer thickness are 8cm or so, and thickness control is carried out using inductive probe, can be automatic above or below lid thickness
Alarm is able to ensure the uniform of the bed of material, dries duration 2.5-3 hours, moisture 1.5-2.2%, mobility 195-205cm, into
Particle is obtained after 65 seconds type hardening times.
F. it grinds：By in particulate material input jacket type stainless steel cooling milling apparatus, edible pigment, plasticizer, day are added in
So environmental protection minerals, brightener, toughener, anti-caking agent, antioxidant, fire retardant, insulation agent, sterilization agent, titanium dioxide.Grinding 15 to
20 hours, milling apparatus used temperature control system, ensured grinding temperature constant temperature between 65 to 70 degrees Celsius.
G. it detects：A series of detection projects such as sampling observation color, mobility, density, brightness and intensity, reach after grinding
After examination criteria, it is sieved with the full-automatic rotary strainer of 50 to 80 mesh and obtains mineral fibre synthesizing environment-friendly resin-oatmeal.
H. the raw material for manufacturing bamboo fibre minerals synthesis particle is weighed by following percentage：Melamino-formaldehyde reaction tree
Fat：81%th, bamboo fibre：8%th, natural environmental-protective minerals 7%, zinc stearate：0.2%th, curing agent：0.5%th, dibutyl ester：0.1%th, it brightens
Agent：0.3%th, citric acid is received：0.25%th, plasticizer：0.85%th, mould release：1.5%th, titanium dioxide 0.3%.
I. it mediates：By melamino-formaldehyde reacting resin, bamboo fibre, natural environmental-protective minerals, zinc stearate, curing agent,
Dibutyl ester, brightening agent, citric acid are received, plasticizer, mould release, titanium dioxide add in kneader, mutual by agitating paddle in kneader
Shearing is mediated, and steam heating is carried out by control pressurer system, will be mediated between built-in temperature is maintained at 65 to 70 degrees Celsius,
Material is made to stir dehydration in constant temperature, while improves molecular weight, 45 to 60 minutes used times.
J. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value 0.5MPa, set
90 to 130 DEG C of temperature, layer thickness are 7cm or so, and thickness control is carried out using inductive probe, can be certainly above or below lid thickness
Dynamic alarm is able to ensure the uniform of the bed of material, dry duration 4.5-5 hours, moisture 0.5-1%, mobility 120-135cm.
K. it crushes：By the unified crushing of dried particulate material, bamboo fibre minerals are obtained after carrying out dusting cover with Double-layer screen
Synthesis particle.
L. it weighs the mineral fibre synthesizing environment-friendly resin-oatmeal that accounting is 80% and the bamboo fibre minerals that accounting is 20% is closed
Into particle, then put into stainless steel blender after stirring evenly to pack and complete.This method for production is by a relatively simple rationally, raw
Process safety environmental protection is produced, not only solves the problems, such as that existing ceramic imitation product and product leftover pieces can not be degraded and be recycled, passes through we
Method can also improve the product feature of environmental protection, after forming Novel environment-friendlymaterial material, while Ceramic-imitated tableware recycling can be increased product
Intensity, heat resistance, improves material molecular weight at brightness.
Claims (1)
1. the method for making advanced composite material (ACM) with imitative porcelain recycling product with biological plants fibre object, which is characterized in that step is as follows：
A. the raw material for manufacturing mineral fibre synthesizing environment-friendly resin-oatmeal is weighed by following percentage：Imitative porcelain recycling product 20%, first
Aldehyde：20%th, melamine:10%th, biological plants fibre object：10%th, citric acid is received：10%th, amino film plastics particle 5%, wood fibre：
5%th, bamboo fibre:5%th, titanium dioxide：2.1%th, natural environmental-protective minerals 5%, nano silicon dioxide 3%, zinc stearate：0.193%th, cure
Agent：0.083%th, dibutyl ester：0.08%th, brightening agent：0.25%th, pigment is eaten：0.004%th, brightener：0.3%th, toughener：0.02%、
Plasticizer：0.5%th, mould release：1.2%th, anti-caking agent：1.38%th, antioxidant：0.2%th, fire retardant：0.15%th, insulation agent：0.4%th, disappear
Microbial inoculum：0.12%th, stabilizer 0.02%.
B. imitative porcelain recycling product is subjected to HIGH TEMPERATURE PURGE, steam heating is carried out to material, powdering is then crushed to it, so
Impurity is filtered afterwards, then carries out high-temperature stirring grinding, powder stone shape material is formed, filters again, biology is added in after filtering
Steam heating is carried out after planting fibre object, becomes biological plants fiber powder.
C. it reacts：Biological plants fiber powder, formaldehyde, melamine are put into reaction kettle, by stirring, being steam heated to 90
DEG C so that material in reactor is sufficiently mixed, and detects pH value and drop white effect in the process, and add in stabilizer to adjust mixture
Acid-base value and the reaction time, reach predetermined standard time reaction and complete and obtain melamino-formaldehyde reacting resin.
D. it mediates：By melamino-formaldehyde reacting resin, wood fibre, zinc stearate, curing agent, brightening agent, dibutyl ester, release
Agent, citric acid are received, amino film plastics particle, bamboo fibre, nano silicon dioxide add in kneader, pass through agitating paddle phase in kneader
Mutually shearing, kneading carry out steam heating by control pressurer system, keep mediating built-in temperature between 65 to 70 degrees Celsius,
Material is made to stir dehydration in constant temperature, while improves molecular weight, 45 to 60 minutes when sharing.
E. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value 0.5MPa, set temperature
75-95 DEG C, layer thickness is 8cm or so, carries out thickness control using inductive probe, can be reported automatically above or below lid thickness
It is alert, it is able to ensure the uniform of the bed of material, dry duration 2.5-3 hours, moisture 1.5-2.2%, mobility 195-205cm, molding
Particle is obtained after 65 seconds hardening times.
F. it grinds：By in particulate material input jacket type stainless steel cooling milling apparatus, edible pigment, plasticizer, native annulus are added in
Protect minerals, brightener, toughener, anti-caking agent, antioxidant, fire retardant, insulation agent, sterilization agent, titanium dioxide.Grinding 15 to 20 is small
When, milling apparatus uses temperature control system, ensures grinding temperature constant temperature between 65 to 70 degrees Celsius.
G. it detects：A series of detection projects such as sampling observation color, mobility, density, brightness and intensity, reach detection after grinding
After standard, it is sieved with the full-automatic rotary strainer of 50 to 80 mesh and obtains mineral fibre synthesizing environment-friendly resin-oatmeal.
H. the raw material for manufacturing bamboo fibre minerals synthesis particle is weighed by following percentage：Melamino-formaldehyde reacting resin：
81%th, bamboo fibre：8%th, natural environmental-protective minerals 7%, zinc stearate：0.2%th, curing agent：0.5%th, dibutyl ester：0.1%th, brightening agent：
0.3%th, citric acid is received：0.25%th, plasticizer：0.85%th, mould release：1.5%th, titanium dioxide 0.3%.I. it mediates：By melamino-formaldehyde
Reacting resin, bamboo fibre, natural environmental-protective minerals, zinc stearate, curing agent, dibutyl ester, brightening agent, citric acid are received, plasticizer,
Mould release, titanium dioxide add in kneader, are mutually sheared, mediated by agitating paddle in kneader, carried out by control pressurer system
Steam heats, and will mediate between built-in temperature is maintained at 65 to 70 degrees Celsius, material is made to stir dehydration in constant temperature, is improved simultaneously
Molecular weight, 45 to 60 minutes used times.
J. it dries：Kneaded material is transported in fully automatic network band drier, vapour pressure force value 0.5MPa, set temperature
90 to 130 DEG C, layer thickness is 7cm or so, carries out thickness control using inductive probe, can be reported automatically above or below lid thickness
It is alert, it is able to ensure the uniform of the bed of material, dry duration 4.5-5 hours, moisture 0.5-1%, mobility 120-135cm.
K. it crushes：By the unified crushing of dried particulate material, the synthesis of bamboo fibre minerals is obtained after carrying out dusting cover with Double-layer screen
Particle.
L. the mineral fibre synthesizing environment-friendly resin-oatmeal that accounting is 80% and the bamboo fibre minerals that accounting is 20% synthesis are weighed
Then grain puts into stainless steel blender after stirring evenly to pack and complete.
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| CN201710832814.5A CN108219361A (en) | 2017-09-15 | 2017-09-15 | The method for making advanced composite material (ACM) with biological plants fibre object and imitative porcelain recycling product |
| CN201810574095.6A CN108841194A (en) | 2017-09-15 | 2018-06-05 | Utilize the composite material and preparation method of biomass fiber and the preparation of imitative porcelain salvage material |
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| CN114705034A (en) * | 2022-04-14 | 2022-07-05 | 安徽道源食品有限公司 | Automatic drying control management system |
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| CN109679362A (en) * | 2018-11-29 | 2019-04-26 | 蔡春歆 | A kind of production method of porcelain imitation material and preparation method thereof and imitative porcelain hand basin |
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| TWI223657B (en) * | 2000-10-18 | 2004-11-11 | Chang Chun Plastics Co Ltd | Amino resin composition for the cleaning of the mold |
| CN101113230B (en) * | 2007-08-08 | 2010-08-18 | 华南理工大学 | Method for preparing unsaturated polyester cross-linking waste mold plastic |
| CN102558761A (en) * | 2010-12-31 | 2012-07-11 | 陈天云 | Amino environment-friendly plastic and production method thereof |
| CN102382419A (en) * | 2011-08-18 | 2012-03-21 | 东阳市雅尔密胺餐具厂 | Method for manufacturing bamboo fiber melamine product |
| CN105566845A (en) * | 2016-02-17 | 2016-05-11 | 德清县联诚氨基塑料制品有限公司 | Bi-color stripe melamine powder |
| CN105936738B (en) * | 2016-05-25 | 2018-10-02 | 山东国正化工有限公司 | A kind of preparation method of the anti-aging melamine molding compound of high temperature resistant |
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