CN108218348A - A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof - Google Patents

A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof Download PDF

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Publication number
CN108218348A
CN108218348A CN201810105281.5A CN201810105281A CN108218348A CN 108218348 A CN108218348 A CN 108218348A CN 201810105281 A CN201810105281 A CN 201810105281A CN 108218348 A CN108218348 A CN 108218348A
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CN
China
Prior art keywords
water
alkali
concrete
pervious concrete
preparation
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Pending
Application number
CN201810105281.5A
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Chinese (zh)
Inventor
张磊
韩玉
王雪平
荣辉
杨久俊
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Tianjin Chengjian University
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Tianjin Chengjian University
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Application filed by Tianjin Chengjian University filed Critical Tianjin Chengjian University
Priority to CN201810105281.5A priority Critical patent/CN108218348A/en
Publication of CN108218348A publication Critical patent/CN108218348A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof, including:1) 4~12% high-calcium fly ass, 6~18% miberal powders, 0~3% silicon ash, 4~8% cement, 5~15% water, 60~80% single particle size aggregates, 1~3% alkali-activator, 0~2% polycarboxylate water-reducer are taken by mass percentage;2) single particle size aggregate and 20% 30% water are added in blender and stirred 30 seconds;Then cement, miberal powder, high-calcium fly ass, silicon ash and remaining 60% 70% water are sequentially added, continues stirring 90 seconds;Alkali-activator and polycarboxylate water-reducer are eventually adding, is further continued for stirring 2 minutes, celluar concrete is formed;3) celluar concrete is fitted into two times in mold, using artificial plus mechanical concrete vibrating mode molding;4) continue band mold after being molded to conserve, until form removal after 24 hours;5) it uses after form removal and is conserved, and once concrete surface is kept to moisten every 8 hours shower waters under normal temperature condition;Maintenance to 28 day age obtains pervious concrete finished product of the present invention.

Description

A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof
Technical field
The present invention relates to the preparation methods of a kind of concrete and its product, and in particular to a kind of room temperature maintenance alkali-activated carbonatite gelling The preparation method of material pervious concrete and its product belongs to field of material technology.
Background technology
For China cities and towns, currently and from now on the development of a period of time, government will propose the mesh for building sponge city Mark, it is so-called to build " sponge city ", exactly city is built up can absorb water when rainy, water storage, infiltration, water purification, drying season The water " release " stored when needing is out used.Thus, for the construction material built used in " sponge city ", also need Show this function of saving-discharge water, such as ground surface material.It develops with excellent infiltration, resistance to compression, wear-resisting, anti-skidding Performance and environmental protection, beauty, comfortable easy care simultaneously can sound-absorbing noise abatement etc. by be industry research and development target, have and save-discharge water work( The road construction material of energy, will make town pavement also can effectively alleviate city while as the landscape road surface of " can breathe " Tropical island effect makes urban pavement no longer generate heat.
Permeable concrete is sponge urban pavement material more satisfactory at present.Common cement pervious concrete pavement Brick has higher intensity, wearability and durability, is typically matched by raw material such as cement, sand, stone, water according to certain Than pouring or compression moulding and being obtained through maintenance to regulation age.
The present inventor is intended to the pervious concrete for being substituted traditional cement using alkali-activated carbonatite cementitious material and being prepared high intensity And road surface tile product, be resource using waste coal ash, slag etc., given full play in terms of environmental protection take on while, system The standby product for providing higher-strength, wearability and durability.
Invention content
It is an object of the present invention to provide a kind of alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof, including step:
1) each material is taken by mass percentage:4~12% high-calcium fly ass, 6~18% miberal powders, 0~3% silicon ash, 4~ 8% cement, 5~15% water, 60~80% single particle size aggregates, 1~3% alkali-activator, 0~2% polycarboxylate water-reducer;
2) water of single particle size aggregate and total Water 20%-30% is added in blender, stirred 30 seconds;Then successively The water of cement, miberal powder, high-calcium fly ass, silicon ash and remaining 60%-70% are added in, continues stirring 90 seconds;Alkali is eventually adding to swash Agent and polycarboxylate water-reducer are sent out, is further continued for stirring 2 minutes, celluar concrete is formed;
3) celluar concrete for obtaining step 2) is encased in two times in mold, using artificial plus mechanical concrete vibrating mode into Type;
4) continue band mold after being molded to conserve, until form removal after 24 hours;
5) it uses after form removal and is conserved, and once concrete surface is kept to moisten every 8 hours shower waters under normal temperature condition;It supports Shield to 28 day age obtains pervious concrete finished product of the present invention.
The alkali-activator is the water glass solution of 1.2 moduluses, and suitable modulus of water glass is allocated using granular NaOH.
The single aggregate size is preferred:4.75-9.5 millimeter;
The single aggregate is preferred:Stone in nature.
The advantages and features of the present invention:
1. alkali-activated carbonatite porous concrete product has many advantages, such as the porosity of higher-strength, high coefficient of permeability and stabilization.
2. with higher wearability and durability.
3. making full use of flyash, slag the like waste, waste is made to be converted into resource.
Specific embodiment
For a better understanding of the present invention, with reference to embodiment, the present invention will be further described, but embodiment is not right The present invention is construed as limiting.
The material that embodiment and comparative example use is as follows:
The Portland cement of the PO42.5 grades in Tianjin development cement plant, the production of Tianjin Bo Di chemical inc Sodium silicate solution, modulus 3.3, Baume degrees 40, the content of Na2O is 22.8-23.5%.This experiment uses modulus For 1.2 waterglass, the waterglass of this modulus is prepared with sodium hydroxide.Single particle size aggregate be stone, grain size 4.75- 9.5mm。
Embodiment:
Take by mass percentage 4.8% high-calcium fly ass, 7.2% miberal powder, 0.3% silicon ash, 5.3% portland cement, 71.56% stone, 9.4% water, 1.26% waterglass, 0.18% polycarboxylate water-reducer.
First the water of stone and total Water 20%-30% is added in blender, is stirred 30 seconds;Then water is sequentially added Mud, miberal powder, high-calcium fly ass, silicon ash and remaining 60%-70% water, continue 1 point of stirring 30 seconds;Be eventually adding waterglass and Polycarboxylate water-reducer is further continued for stirring 2 minutes, and celluar concrete is formed;The alkali-activated carbonatite cementitious material that this is stirred is permeable mixed Solidifying soil is encased in two times in three gang moulds of 100 × 100 × 100mm, using manually plus machinery vibrates molding.
Continue band mold after molding to conserve to 24 hours, form removal;Since this pervious concrete is alkali-activated carbonatite, using water curing It easily generates alkali to be precipitated, so keeping concrete table using maintenance under normal temperature condition after form removal and every water of 8 hours sprays Face moistens;Maintenance to 28 day age obtains pervious concrete finished product of the present invention.
Comparative example
The preparation method is the same as that of Example 1, and difference part is that raw material are only cement, stone, polycarboxylate water-reducer, water.
Test result compares:
The pervious concrete prepared to embodiment and comparative example carries out performance detection, and testing result is as shown in the table:

Claims (3)

1. a kind of alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof, it is characterised in that including step:
1) each material is taken by mass percentage:4~12% high-calcium fly ass, 6~18% miberal powders, 0~3% silicon ash, 4~8% water Mud, 5~15% water, 60~80% single particle size aggregates, 1~3% alkali-activator, 0~2% polycarboxylate water-reducer;
2) water of single particle size aggregate and total Water 20%-30% is added in blender, stirred 30 seconds;Then it sequentially adds Cement, miberal powder, high-calcium fly ass, silicon ash and remaining 60%-70% water, continue stirring 90 seconds;It is eventually adding alkali-activator And polycarboxylate water-reducer, stirring 2 minutes is further continued for, celluar concrete is formed;
3) celluar concrete for obtaining step 2) is encased in two times in mold, using artificial plus mechanical concrete vibrating mode molding;
4) continue band mold after being molded to conserve, until form removal after 24 hours;
5) it uses after form removal and is conserved, and once concrete surface is kept to moisten every 8 hours shower waters under normal temperature condition;Maintenance is extremely 28 day age obtained pervious concrete finished product of the present invention;
The alkali-activator is the water glass solution of 1.2 moduluses, and suitable modulus of water glass is allocated using granular NaOH.
2. a kind of alkali-activated carbonatite cementitious material pervious concrete as described in claim 1 and preparation method thereof, it is characterised in that single One aggregate size is 4.75-9.5 millimeters.
3. a kind of alkali-activated carbonatite cementitious material pervious concrete as described in claim 1 and preparation method thereof, it is characterised in that single One aggregate is the stone in nature.
CN201810105281.5A 2018-02-02 2018-02-02 A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof Pending CN108218348A (en)

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Application Number Priority Date Filing Date Title
CN201810105281.5A CN108218348A (en) 2018-02-02 2018-02-02 A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof

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CN201810105281.5A CN108218348A (en) 2018-02-02 2018-02-02 A kind of room temperature maintenance alkali-activated carbonatite cementitious material pervious concrete and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807763A (en) * 2020-06-10 2020-10-23 成都宏基建材股份有限公司 Preparation method of alkali-activated pervious concrete
CN112895073A (en) * 2021-01-23 2021-06-04 河海大学 Method for preparing hydrological physical model permeable medium layer by adopting concrete material to replace soil
CN113173744A (en) * 2021-04-12 2021-07-27 武汉大学 Method for preparing geopolymer-based non-pressed water permeable brick through natural curing at normal temperature
CN114436621A (en) * 2022-03-04 2022-05-06 西北农林科技大学 Alkali-activated composite recycled powder recycled aggregate pervious concrete and preparation method thereof

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CN103819125A (en) * 2013-12-03 2014-05-28 福建建工建材科技开发有限公司 High-strength permeable brick additive and preparation method thereof
CN105174995A (en) * 2015-09-14 2015-12-23 马鞍山科诺墙体材料制造有限公司 Static-pressure high-strength wear-resisting concrete anti-blocking and water-permeable brick and preparation method thereof
CN105565723A (en) * 2016-01-27 2016-05-11 昆明市宜鑫荣商品混凝土有限公司 Pervious concrete formula and construction method
CN105819886A (en) * 2016-05-13 2016-08-03 长沙理工大学 Preparation and maintenance method of pervious concrete
CN106278364A (en) * 2016-08-30 2017-01-04 廊坊荣盛混凝土有限公司 A kind of permeable concrete and preparation method thereof
CN106747114A (en) * 2017-01-17 2017-05-31 河南理工大学 A kind of novel pavement porous concrete product and preparation method thereof
CN106904903A (en) * 2017-01-17 2017-06-30 河南理工大学 A kind of gradient type porous concrete product and preparation method thereof
CN107382358A (en) * 2017-07-24 2017-11-24 重庆大学 It is a kind of suitable for permeable alkali-slag concrete of Supporting Load Pavement and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819125A (en) * 2013-12-03 2014-05-28 福建建工建材科技开发有限公司 High-strength permeable brick additive and preparation method thereof
CN105174995A (en) * 2015-09-14 2015-12-23 马鞍山科诺墙体材料制造有限公司 Static-pressure high-strength wear-resisting concrete anti-blocking and water-permeable brick and preparation method thereof
CN105565723A (en) * 2016-01-27 2016-05-11 昆明市宜鑫荣商品混凝土有限公司 Pervious concrete formula and construction method
CN105819886A (en) * 2016-05-13 2016-08-03 长沙理工大学 Preparation and maintenance method of pervious concrete
CN106278364A (en) * 2016-08-30 2017-01-04 廊坊荣盛混凝土有限公司 A kind of permeable concrete and preparation method thereof
CN106747114A (en) * 2017-01-17 2017-05-31 河南理工大学 A kind of novel pavement porous concrete product and preparation method thereof
CN106904903A (en) * 2017-01-17 2017-06-30 河南理工大学 A kind of gradient type porous concrete product and preparation method thereof
CN107382358A (en) * 2017-07-24 2017-11-24 重庆大学 It is a kind of suitable for permeable alkali-slag concrete of Supporting Load Pavement and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807763A (en) * 2020-06-10 2020-10-23 成都宏基建材股份有限公司 Preparation method of alkali-activated pervious concrete
CN112895073A (en) * 2021-01-23 2021-06-04 河海大学 Method for preparing hydrological physical model permeable medium layer by adopting concrete material to replace soil
CN112895073B (en) * 2021-01-23 2021-11-09 河海大学 Method for preparing hydrological physical model permeable medium layer by adopting concrete material to replace soil
CN113173744A (en) * 2021-04-12 2021-07-27 武汉大学 Method for preparing geopolymer-based non-pressed water permeable brick through natural curing at normal temperature
CN114436621A (en) * 2022-03-04 2022-05-06 西北农林科技大学 Alkali-activated composite recycled powder recycled aggregate pervious concrete and preparation method thereof

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Application publication date: 20180629