CN108217575A - A kind of sensor and preparation method thereof - Google Patents

A kind of sensor and preparation method thereof Download PDF

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Publication number
CN108217575A
CN108217575A CN201711305897.9A CN201711305897A CN108217575A CN 108217575 A CN108217575 A CN 108217575A CN 201711305897 A CN201711305897 A CN 201711305897A CN 108217575 A CN108217575 A CN 108217575A
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CN
China
Prior art keywords
electrode
sensor
lower electrode
projection
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711305897.9A
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Chinese (zh)
Inventor
周国富
沈振鹏
周蕤
李君�
尼克·德·罗伊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
South China Normal University
Shenzhen Guohua Optoelectronics Co Ltd
Academy of Shenzhen Guohua Optoelectronics
Original Assignee
South China Normal University
Shenzhen Guohua Optoelectronics Co Ltd
Academy of Shenzhen Guohua Optoelectronics
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by South China Normal University, Shenzhen Guohua Optoelectronics Co Ltd, Academy of Shenzhen Guohua Optoelectronics filed Critical South China Normal University
Priority to CN201711305897.9A priority Critical patent/CN108217575A/en
Publication of CN108217575A publication Critical patent/CN108217575A/en
Priority to PCT/CN2018/109628 priority patent/WO2019114390A1/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B3/00Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
    • B81B3/0018Structures acting upon the moving or flexible element for transforming energy into mechanical movement or vice versa, i.e. actuators, sensors, generators
    • B81B3/0021Transducers for transforming electrical into mechanical energy or vice versa
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/0009Structural features, others than packages, for protecting a device against environmental influences
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00134Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems comprising flexible or deformable structures
    • B81C1/00142Bridges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00841Cleaning during or after manufacture
    • B81C1/00849Cleaning during or after manufacture during manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2201/00Specific applications of microelectromechanical systems
    • B81B2201/02Sensors
    • B81B2201/0221Variable capacitors

Abstract

The invention discloses a kind of sensor, including substrate, at least one lower electrode, at least one middle electrode and at least one top electrode;Lower electrode is set to surface, middle electrode, top electrode are set to the top of descended electrode and lower electrode, middle electrode, top electrode are respectively arranged in the Different Plane being mutually parallel in space, the projecting of the lower electrode of sensor, the projection of middle electrode and the projection of top electrode intersect at projection crosspoint to form at least one microbridge, sensor further includes the sensing material contacted with middle electrode, and sensing material is set in projection crosspoint;The invention also discloses a kind of preparation methods of sensor.Sensor of the invention is type polar distance variable capacitance formula sensor, and at least one differential microbridge, realizes highly sensitive sensing measurement, nonlinear error reduction.In addition, a kind of preparation method of sensor of the present invention, for making the sensor, preparation method is simple.

Description

A kind of sensor and preparation method thereof
Technical field
The present invention relates to sensor field, especially a kind of sensor and preparation method thereof.
Background technology
Today's society Automation of Manufacturing Process constantly expands to every field, and the single sensor of function cannot meet The growing measurement demand of people, can not meet the needs of automatical measure and control system.When marching toward industry 4.0 with the mankind In generation, sensor miniaturization, intelligence and standardization are trends of the times, reduce sensor bulk and weight, improve sensitivity, are resisted Interference with it is multi-functional into for people's lives in social production to an urgent demand of sensor.Due to condenser type in numerous sensors Sensor structure is simple, cheap, high sensitivity, zero magnetic hysteresis, vacuum compatibility, overload capacity is strong, dynamic response characteristic it is good with To high temperature, radiation, the strong mal-conditions such as shake adaptable, the advantages that realizing non-cpntact measurement, so as to be used widely.
But condenser type Multifunction Sensor majority belongs to dielectric constant variable type, and one layer of sensing material is coated on substrate Realize sensing, sensitivity is poor, while will appear in measurement process since tested gas or other impurities are attached on substrate Lead to measurement noise caused by change in dielectric constant, accuracy is low.
Invention content
In order to solve the above-mentioned technical problem, the object of the present invention is to provide a kind of sensor and preparation method thereof, for carrying The sensitivity of high sensor and accuracy.
The technical solution adopted in the present invention is:A kind of sensor, including substrate, the sensor further includes at least one Lower electrode, at least one middle electrode and at least one top electrode;The lower electrode is set to surface, the middle electrode, on Electrode is set to the top of the lower electrode and the lower electrode, middle electrode, top electrode are respectively arranged in space and are mutually parallel Different Plane on, the projecting of the lower electrode of the sensor, the projection of middle electrode and the projection of top electrode intersect at projection For crosspoint to form at least one microbridge, the sensor further includes the sensing material contacted with middle electrode, the sensing material It is set in projection crosspoint.
Further, the orthographic projection phase of the orthographic projection of the lower electrode of the sensor, the orthographic projection of middle electrode and top electrode Meet at projection crosspoint.
Further, orthographic projection, the orthographic projection of middle electrode and the orthographic projection of top electrode of the lower electrode of the sensor are hung down Directly intersect at projection crosspoint.
Further, the lower electrode, middle electrode, top electrode material be nano silver material.
Further, the thickness of the sensing material is 2-3 μm.
Further, the sensing material includes acetylbutyrylcellulose, Nanometer Copper functional composite material or paraffinic base work( It can composite material.
Further, the substrate is pet substrate.
Further, the thickness of the middle electrode is 2 μm, and width is 80 μm, length 2mm.
Further, the thickness of the top electrode is 2 μm, and width is 65 μm, and length is 1888 μm.
Another technical solution of the present invention is:A kind of preparation method of sensor, applied to the sensor, Include the following steps:
S1, cleaning simultaneously dry up substrate, heat the substrate;
S2, it is heated after carrying out oxygen plasma treatment to the surface of the substrate;
S3, on the substrate, Nano silver solution using inkjet printing technology printed to heat after obtaining lower electrode;
S4, it photoresist and propylene glycol methyl ether acetate is carried out to mixed preparing obtains preparing solution, along the lower electrode, It is heated after using inkjet printing technology, the preparation solution is printed upon above the lower electrode;
S5, the edge direction vertical with the lower electrode, using inkjet printing technology by the Nano silver solution in the light It is printed to be heated after obtaining middle electrode in photoresist;
S6, sensing material is printed upon on the overlapping region of the middle electrode and the photoresist using inkjet printing technology After heated;
S7, along the lower electrode, the preparation solution is printed upon on the sensing material using inkjet printing technology After heated;
S8, will to obtain top electrode on the Nano silver solution substrate that is printed upon that treated using inkjet printing technology laggard Row heating;
S9, photoresist is removed using developer solution.
The beneficial effects of the invention are as follows:
A kind of sensor of the present invention including substrate, at least one lower electrode, at least one middle electrode and at least one powers on Pole;Lower electrode is set to surface, and middle electrode, top electrode are set to the top of descended electrode and lower electrode, middle electrode, power on Pole is respectively arranged in the Different Plane being mutually parallel in space, the projecting of the lower electrode of sensor, the projection of middle electrode and The projection of top electrode intersects at projection crosspoint to form at least one microbridge, and sensor further includes the sensing contacted with middle electrode Material, sensing material are set in projection crosspoint.Sensor of the invention is type polar distance variable capacitance formula sensor, and is had At least one differential microbridge realizes highly sensitive sensing measurement, nonlinear error reduction.
In addition, the present invention also provides a kind of preparation method of sensor, for making the sensor, preparation method letter It is single.
Description of the drawings
The specific embodiment of the present invention is described further below in conjunction with the accompanying drawings:
Fig. 1 is an a kind of specific embodiment schematic diagram of sensor of the present invention;
Fig. 2 is an a kind of specific embodiment sectional view of the microbridge of sensor of the present invention;
Fig. 3 is an a kind of specific embodiment stereoscopic schematic diagram of the microbridge of sensor of the present invention;
Wherein, 1-PET substrates;Electrode under 2-;Electrode in 3-;4- top electrodes;5- sensing materials;A- microbridges.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the application can phase Mutually combination.
A kind of sensor, including substrate, at least one lower electrode, at least one middle electrode and at least one top electrode;Under Electrode is set to surface, and middle electrode, top electrode are set to the top of lower electrode and lower electrode, middle electrode, top electrode difference It is set in the Different Plane being mutually parallel in space, the projecting of the lower electrode of sensor, the projection of middle electrode and top electrode Projection intersect at projection crosspoint to form at least one microbridge, sensor further includes the sensing material contacted with middle electrode, Sensing material is set in projection crosspoint.
Sensor of the invention is using type polar distance variable difference structure, wherein descend electrode and power on extremely fixed electrode, Sensing material and the contact of middle electrode, sensing material occur swollen because being measured (i.e. measurand, such as humidity, temperature) change Electrode bends during swollen or polycondensation drives, and changes its pole span with upper and lower electrode so as to cause capacitance variations, realizes sensing inspection It surveys, therefore, middle electrode is movable electrode;And since at least one differential microbridge, multiple differential microbridges are carried out at the same time biography Sense detects, then microbridge parallel-connection structure of the invention has unrivaled relative to existing monopole type polar distance variable capacitance formula sensor Sensitivity, nonlinearity erron reduce.
As being further improved for technical solution, the orthographic projection of the lower electrode of sensor, the orthographic projection of middle electrode and power on The orthographic projection of pole intersects at projection crosspoint, i.e. top electrode, middle electrode is spatially parallel with lower electrode and in orthographic projection direction On intersection point, the intersection point be form sensor micro-bridge structure, for sensing detection.Further, with reference to figure 1, Fig. 2 and figure 3, Fig. 1 be an a kind of specific embodiment schematic diagram of sensor of the present invention;Fig. 2 is an a kind of tool of the microbridge of sensor of the present invention Body embodiment sectional view;Fig. 3 is an a kind of specific embodiment stereoscopic schematic diagram of the microbridge of sensor of the present invention;Wherein, substrate It is surface size for 2mm*2mm, thickness is 100 μm of pet substrate 1;In Fig. 1, outer rim is pet substrate 1, and horizontal line represents sensing The middle electrode 3 of device, vertical line are the lower electrode 2 and top electrode 4 overlapped, and horizontal line and vertical line in Fig. 1 are crossed to form projection crosspoint, That is microbridge A, Fig. 1 include in the lower electrodes 2 of eight row, ten rows 3 and eight row top electrode 4 of electrode and formed 80 microbridge A (edge Except intersection point);Fig. 2 and Fig. 3 illustrates that the schematic construction of microbridge A in Fig. 1, and sensing material 5 is arranged on the top of middle electrode 3, In fact, sensing material 5 can also be arranged on the lower section of middle electrode 3, if sensing material 5 be arranged in projection crosspoint and with Middle electrode 3 contacts.In fact, left and right sides of the middle electrode 3 across pet substrate 1, top electrode 4 and lower electrode 2 are across PE substrates 1 upper and lower sides.In addition, in the present embodiment, the orthographic projection of the lower electrode 2 of sensor, the orthographic projection of middle electrode 3 and top electrode 4 Orthographic projection is vertically intersected on projection crosspoint.Lower electrode 2, middle electrode 3, top electrode 4 material be nano silver material.Lower electrode 2 Thickness for 200nm, width is 65 μm, and length is 1880 μm;The thickness of middle electrode 3 is 2 μm, and width is 80 μm, and length is 2mm;The thickness of top electrode 4 is 2 μm, and width is 65 μm, and length is 1888 μm.The thickness of sensing material 5 is 2-3 μm.Further Acetylbutyrylcellulose, Nanometer Copper functional composite material or paraffin base functional composite material may be used in ground, sensing material 5.
With reference to figure 1, different sensing materials can be printed in different microbridge A, realize the measurement of multiple physical quantitys.It can be with Producing micron-sized micro-bridge structure as shown in Figure 2 as much as possible in pet substrate, this is the least unit of sensing, The quantity of microbridge A is more in unit area, and compared to other type polar distance variable sensors, the sensitivity of sensor is higher.Secondly, middle electricity The lead of pole can be drawn from the left or right side of substrate, and the lead of upper and lower electrode can draw from substrate the upper side and lower side respectively Go out, be conducive to subsequent sensor test using vertical parallel.
A kind of preparation method of sensor, applied to the sensor, includes the following steps:
S1, cleaning simultaneously dry up substrate, heat the substrate.
Successively with acetone, isopropanol and deionized water continuous dipping substrate 10 minutes, and dried up with nitrogen.
140 degrees Celsius are heated to the substrate hot plate again, continues 30 minutes.
S2, it is heated after carrying out oxygen plasma treatment to the surface of substrate.
To treated, substrate surface carries out power as 50W, and frequency is the oxygen plasma treatment of 13.56MHz, continues 35 Second, this is the wetability in order to enhance substrate surface, improves the hydrophily of substrate, and the solution for preventing from subsequently adding in is in substrate surface It flows everywhere, solution is allowed to be adhered to substrate surface, be conducive to precisely make electrode structure.Treated substrate puts into oven with 120 degrees Celsius are toasted 5 minutes, this is to cause to print to prevent marking ink from stretching in substrate while maintaining substrate wetability Line it is too wide.
S3, on substrate, Nano silver solution is printed to heat after obtaining lower electrode using inkjet printing technology.
It it is 40 μm using inkjet printing setting ink-jet point spacing, the printing number of plies is 2 layers, by the nano silver that solid content is 20% Lower electrode is used as on slurry (i.e. Nano silver solution) is printed upon that treated substrate.
It puts oven into gained sample to toast 30 minutes with 140 degrees Celsius, lower electrode is allowed to cure.
S4, by photoresist and propylene glycol methyl ether acetate using mass ratio as 1:9 progress mixed preparings obtain preparing solution, edge Electrode down, will be prepared after solution is printed upon above lower electrode and heated using inkjet printing technology.
Since photoresist directly cannot directly be sprayed with inkjet printing, for convenience using inkjet printing technology to sensor It is processed, by photoresist and propylene glycol methyl ether acetate using mass ratio as 1:9 carry out being sufficiently mixed preparation injection Inkjet Cartridge, profit It is 20 μm with inkjet printing setting ink-jet point spacing, nozzle temperature is 55 degree, and excitation speed and frequency are respectively 9m/s and 7kHz, It is 2 layers to print the number of plies, will prepare solution and gained sample is printed along lower electrode path, formed lower electrode and middle electrode it Between interval, in subsequent step the photoresist of sensor remove after so as to form the gap of capacitance structure, such as Fig. 2 and Fig. 3 It is shown.It is put into 115 degrees Celsius of hot plate to gained sample to heat 10 minutes, cures photoresist.
S5, the edge direction vertical with lower electrode, are beaten Nano silver solution using inkjet printing technology on a photoresist Print is heated after obtaining middle electrode.
By above-mentioned nanometer silver paste using 20 μm of inkjet printing setting ink-jet point spacing, printed along the direction vertical with lower electrode Electrode in 6 layers of conduct often prints in one layer and will heat sample 30 minutes with 115 degrees Celsius of hot plate after electrode, this is The nanometer silver paste of the top is flowed down along photoresist wall in order to prevent, can cause the micro-bridge structure of middle electrode excessively fragile in this way.
S6, added after using inkjet printing technology, sensing material is printed upon on the overlapping region of middle electrode and photoresist Heat.
Sensing material is for example measured using inkjet printing humidity acetylbutyrylcellulose be printed upon the middle electrode with The overlapping region of photoresist is (in addition, sensing material can also change to send out by sensing material in middle base part because being measured Electrode bending during raw expansion or polycondensation drive, changes its pole span with upper/lower electrode so as to cause capacitance variations), and according to sensing Device is placed on hot plate and is heated 30 minutes with 110 degree by material character.Sensing material can also be the expanded by heating for thermometric Nanometer Copper/paraffin base functional composite material and other functional materials.
S7, along lower electrode, will be prepared after solution is printed upon on sensing material and heated using inkjet printing technology.
By photoresist and propylene glycol methyl ether acetate using mass ratio as 1:9 carry out being sufficiently mixed preparation, utilize inkjet printing It is 20 μm to set ink-jet point spacing, and nozzle temperature is 55 degree, and it is respectively 9m/s and 7kHz to encourage speed and frequency, and the printing number of plies is 2 layers, solution will be prepared, gained sample is printed along lower electrode path, the gap in formation between electrode and top electrode.
It is put into 115 degrees Celsius of hot plate to gained sample to heat 10 minutes, cures photoresist.
S8, added after obtaining top electrode on the Nano silver solution substrate that is printed upon that treated using inkjet printing technology Heat.
It it is 40 μm using inkjet printing setting ink-jet point spacing, the printing number of plies is 2 layers, by the nano silver that solid content is 20% As top electrode on slurry is printed upon that treated substrate.Oven is put into gained sample to toast 30 minutes with 140 degrees Celsius.
S9, photoresist is removed using developer solution.
Completely cut off electrode using photoresist, photoresist is removed again after being heating and curing.
The photoresist in gained sample is removed using developer solution, the making of the difference structure of sensor is completed, that is, is formed such as Include the capacitive sensor structure of top electrode, lower electrode and middle electrode shown in Fig. 2.
It is that the preferable of the present invention is implemented to be illustrated, but the invention is not limited to the implementation above Example, those skilled in the art can also make various equivalent variations under the premise of without prejudice to spirit of the invention or replace It changes, these equivalent deformations or replacement are all contained in the application claim limited range.

Claims (10)

1. a kind of sensor, including substrate, which is characterized in that the sensor further includes at least one lower electrode, at least one Middle electrode and at least one top electrode;The lower electrode is set to surface, the middle electrode, top electrode be set to it is described under The top of the electrode and lower electrode, middle electrode, top electrode are respectively arranged in the Different Plane being mutually parallel in space, institute It states the projecting of the lower electrode of sensor, the projection of middle electrode and the projection of top electrode and intersects at projection crosspoint to form at least one A microbridge, the sensor further include the sensing material contacted with middle electrode, and the sensing material is set in projection crosspoint.
2. sensor according to claim 1, which is characterized in that the orthographic projection of the lower electrode of the sensor, middle electrode Orthographic projection and the orthographic projection of top electrode intersect at projection crosspoint.
3. sensor according to claim 1, which is characterized in that the orthographic projection of the lower electrode of the sensor, middle electrode Orthographic projection and the orthographic projection of top electrode be vertically intersected on projection crosspoint.
4. sensor according to claim 1, which is characterized in that the lower electrode, middle electrode, top electrode material to receive Rice ag material.
5. sensor according to claim 1, which is characterized in that the thickness of the sensing material is 2-3 μm.
6. sensor according to claim 1, which is characterized in that the sensing material includes acetylbutyrylcellulose, receives Rice copper functional composite material or paraffin base functional composite material.
7. sensor according to any one of claims 1 to 6, which is characterized in that the substrate is pet substrate.
8. sensor according to any one of claims 1 to 6, which is characterized in that the thickness of the middle electrode is 2 μm, wide It is 80 μm to spend, length 2mm.
9. sensor according to any one of claims 1 to 6, which is characterized in that the thickness of the top electrode is 2 μm, wide It is 65 μm to spend, and length is 1888 μm.
10. a kind of preparation method of sensor, applied to claim 1 to 9 any one of them sensor, which is characterized in that Include the following steps:
S1, cleaning simultaneously dry up substrate, heat the substrate;
S2, it is heated after carrying out oxygen plasma treatment to the surface of the substrate;
S3, on the substrate, Nano silver solution using inkjet printing technology printed to heat after obtaining lower electrode;
S4, photoresist and propylene glycol methyl ether acetate progress mixed preparing are obtained preparing solution, along the lower electrode, is utilized Inkjet printing technology heats after the preparation solution is printed upon above the lower electrode;
S5, the edge direction vertical with the lower electrode, using inkjet printing technology by the Nano silver solution in the photoresist On printed to be heated after obtaining middle electrode;
S6, using inkjet printing technology by sensing material be printed upon the middle electrode with it is laggard on the overlapping region of the photoresist Row heating;
S7, along the lower electrode, the preparation solution is printed upon using inkjet printing technology laggard on the sensing material Row heating;
S8, added after obtaining top electrode on the Nano silver solution substrate that is printed upon that treated using inkjet printing technology Heat;
S9, photoresist is removed using developer solution.
CN201711305897.9A 2017-12-11 2017-12-11 A kind of sensor and preparation method thereof Pending CN108217575A (en)

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PCT/CN2018/109628 WO2019114390A1 (en) 2017-12-11 2018-10-10 Sensor, and manufacturing method thereof

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