CN1082074C - Print ink compound for calico-printer's soap - Google Patents
Print ink compound for calico-printer's soap Download PDFInfo
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- CN1082074C CN1082074C CN97112759A CN97112759A CN1082074C CN 1082074 C CN1082074 C CN 1082074C CN 97112759 A CN97112759 A CN 97112759A CN 97112759 A CN97112759 A CN 97112759A CN 1082074 C CN1082074 C CN 1082074C
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Abstract
The present invention relates to a print ink compound for printing soap, which is characterized in that the print ink compound for printing soap comprises requisite ingredients of nitro cellulose which is used as a printing forming agent, a methylstyrene-indene copolymer or alkyd resin which is used as a sticking agent, organic or inorganic pigment or the compound of the organic pigment and the inorganic pigment, which is used as a coloring agent, citrate which is used as a plasticizing agent and a polyethylene oxide silicone copolymer which is used as an auxiliary agent. The print ink compound for printing firstly can reduce the occurring frequency of poor printing, such as the defects, the stripping, the color spots, etc., of a printing membrane on the surface of the printing soap, and consequently, productive efficiency can be improved. Additionally, the printing soap is harmless and safe to the skin of a human body, and various diversified patterns can be formed on the washing soap freely.
Description
The present invention relates to a kind of being applicable to, more specifically, relate to a kind of with the seal ink composition of cosmetic material as moiety washing stamp soap that soap surface forms printed pattern etc. with the seal ink composition.
, had in the past,, made the soap of washing that is called the stamp soap, took this, washed the grade of soap goods with raising to increase its appearance design entertaining the washing the soap surface and wash on the face of soap interior layer and form painted printed pattern of transparent soap etc.
In the past in order to form printed pattern etc. on the soap surface etc. washing, normally adopt following method: at first, be formed in the printed matter that has printed decorative pattern etc. on the face of paper, resin film, water-soluble film etc., then, this printed matter is fixed in method on the face of washing soap surface or washing the soap interior layer; Perhaps, printed pattern is transferred to the surface of washing soap or the method for soap inner layer surface from above-mentioned printed matter; Perhaps, be to adopt method such as silk screen printing that printed pattern etc. is printed directly to the lip-deep method of soap of washing.
Yet the method for above-mentioned formation printed pattern in the past etc. has following shortcoming:
That is, by the soap of washing of the method gained that print is fixed in above-mentioned paper and resin film, because of the reason of things such as paper self can produce foreign body sensation in use, or injured skin.Again, wash soap if use by the formed stamp of water-soluble film, though then can roughly eliminate the inconvenience in the use that is caused by this foreign body sensation etc., but be fixed at it and wash the soap film or wash in the structure on the soap inner layer surface, swelling takes place because of being contained in the moisture of washing in the soap in water-soluble film self, therefore, this soap of washing has such shortcoming: its stamp part is smudgy, and image is not distinct.
Again, to wash the soap surface undue soft because of it by the formed stamp soap of method of the above-mentioned printed pattern of transfer printing etc., and transfer printing is insufficient, so impracticable.
In addition, the formed stamp soap of above-mentioned direct printing process, roughly form the printing state of printed pattern fully though can guarantee it, but, because the proterties of washing the soap raw material, when stamp and behind the stamp, staining takes place in Yin Moyi, perhaps, inequality, the defective as die takes place easily on printed film, the printing of peeling off etc. is bad.The bad occasion that forms picture on the bigger coated surface of pattern of these printings, the frequency of its generation is high.
Have again, in printing seal China ink in the past, usually the phthalic ester that contains particularly dimethyl phthalate as softening agent, diethyl phthalate, dibutyl phthalate etc., but because these compositions are harmful is as washing soap with being unfavorable.
Therefore, the object of the present invention is to provide a kind of printing that is used to wash soap with the seal China ink, described seal China ink can be eliminated aforementioned printing in the past with the shortcoming that exists in the seal China ink, can not produce die thickness inequality, defective, peel off etc. print bad, and to human body safety.
The inventor finds through painstakingly research, in that cosmetic raw material as described below during as moiety, can be achieved the above object fully, in view of the above, finished the present invention.
Promptly, stamp soap of the present invention is characterised in that with the seal ink composition, described stamp soap with the seal ink composition contain as die form agent soluble cotton, as the vinylbenzene-vinyl toluene-indene copolymer (Styrene Methyl Styrene Indene Copo1ymer) of plastering agent or Synolac, as the organic or inorganic pigment of tinting material or their composition, as the citrate of softening agent, and as the polyethylene oxide polysiloxane copolymer of auxiliary agent (below, be called the POE polysiloxane copolymer) as must composition.
According to seal ink composition of the present invention, washing the lip-deep printed layer of soap is formed by nitrocellulose membrane, this film nationality vinylbenzene-vinyl toluene-indene copolymer or Synolac and be subjected to powerful applying effect washing the soap surface, this applying effect further is reinforced because of nitrocellulosic flexibility.
Again, under its influence as the soluble cotton proterties of die material, when having the POE polysiloxane copolymer to exist, described printed layer can be made the printed layers under the homogeneous bed thickness state.That is, the POE polysiloxane copolymer has improved this seal ink composition and has washed mutual stickiness between the soap, and its effect can make the thickness homogeneous of die.Again, soluble cotton can be by organic or inorganic pigment or its hybrid pigment, and for example, Lake red C, phthalocyanine blue and phthalocyanine ash, titanium dioxide etc. are easy and stably painted, can obtain diversified printed pattern thus.
In addition, citrate, for example, citric acid acetyl triethyl, citric acid acetyl tri-n-butyl etc. can generate and are applicable to soluble cotton is implemented screen printing or padded the plastification of dye transfer flower in the presence of solvent.
Above-mentioned each formed component all can be used in cosmetic material widely.Therefore, prepared stamp is harmless with the seal ink composition.
In the relevant seal ink composition of the invention described above, each is formed component and can bring into play the ideal of its each self-applying respectively effectively and cooperate usage ratio to be: soluble cotton 20-40% (weight) (following only the expression with " % "), vinylbenzene-vinyl toluene-indene copolymer is 20-50% (weight) again, again, pigment is 10-60% (weight), and again, citrate is 5-15% (weight), again, the POE polysiloxane copolymer is 0.5-5% (weight).
When nitrocellulosic consumption less than 20% the time, then printed film easily produces and peels off; When its consumption surpasses 40%, then easily on printed film, crack again.When the consumption of vinylbenzene-vinyl toluene-indene copolymer during less than 20% (weight), the stickiness of printed film descends, and easily produces and peels off again; When its consumption surpasses 50% (weight), then easily on printed film, crack again.When the consumption of pigment less than 10% the time, it is painted insufficient; When its consumption surpasses 60%, then easily on printed film, crack, simultaneously, produce color spot.When the consumption of citrate during less than 5% (weight), then printed film becomes fragile, and becomes crack reason; When its consumption surpassed 15% (weight), then printed film was difficult to sclerosis again.When the consumption of POE polysiloxane copolymer during, easily produce color spot less than 0.5% (weight) again; And when surpassing 5% (weight), then print black composition and separate sometimes.
In addition, as the solvent of the seal ink composition of forming with respect to mentioned component, can mix and use one or two or more kinds that is selected from following composition; Ethyl acetate, butylacetate, acetone, methylethylketone, cellosolve, methyl iso-butyl ketone (MIBK), ethyl lactate, diacetone alcohol, cellosolve acetate, ethylene glycol butyl ether, Sorbitol Powder, ethylene glycol, butyleneglycol, toluene and dimethylbenzene.As single solvent,, preferably use ethylene glycol butyl ether from printing the homogeneity and the printing performance of China ink again.As mixed solvent,, preferably mix and use ethylene glycol butyl ether and butylacetate from printing the homogeneity and the printing performance of China ink again.
In addition, the cooperation ratio of this solvent and above-mentioned seal China ink moiety, preferably, more than seal ink composition use solvent 100 weight parts for 100 weight parts (below, be called for short " part "), below 500 weight parts.When the doping level of this solvent less than 100 parts, then print ink composition dissolving difficulty, viscosity increased, its printing performance variation; Again, when
The doping level of this solvent surpasses 50 parts, then prints ink composition viscosity and too reduces, and causes its print performance, simultaneously, because dissolved state is irregular, easily produces flaw in printing.
In addition, seal ink composition of the present invention also can utilize the stamp of doing in the pad dyeing printing process black with seal except being used in preferably the silk screen printing.
Embodiment
Make soap alkali by frame silk method for refining, slaking is about 50 days under the room temperature, and obtaining its composition is the soap of washing of fatty acid soaps composition 50%, granulated sugar 15%, glycerine 13% and other spices, metallic seal agent and residual water-content.With this planar rondure of washing soap arrangement becoming φ 70mm, cut along its cross section, make the soap flakes that are divided into two.
Embodiment A-1～A-5
Number the cooperation ratio of the moiety of A-1～A-5 with embodiment as shown in table 1 below, at first, mix and stir soluble cotton (RS1/4, ダ イ セ Le KCC system) and citric acid acetyl tri-n-butyl, blue No. 404 and ethylene glycol butyl ether at normal temperatures, stir with muller again, then, to this benzene mixed ethene-vinyl toluene-indene copolymer and POE polysiloxane copolymer, make the black preparation of seal respectively.
Table 1
| Form the embodiment numbering | A-1 | A-2 | A-3 | A-4 | A-5 |
| Blue No. 404 butyl cellosolves of nitrocellulose RS 1/4 styrene-methyl styrene-indene copolymer citric acid acetyl tributyl POE polysiloxane copolymer | 10 39 19 5 28 300 | 20 34 17 4 25 300 | 30 30 15 3 22 300 | 40 26 13 2 19 300 | 50 22 11 1 16 300 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 10/2 0 7/20 6/10 | 4/20 2/20 3/20 | 1/20 0/20 1/20 | 1/20 4/20 5/20 | 1/20 11/2 0 6/20 |
| Comprehensive evaluation | × | △ | ○ | △ | × |
Wherein, the numeric representation weight part of each composition in the table.
Use these to print black preparation,, on the cut surface of side soap flakes of above-mentioned incision, do the pad dyeing printing respectively by the pad dyeing printing machine.Its printing form is shown in Fig. 1, and 1 is soap flakes among the figure, and 2 and 3 is the decalcomanias on the cut surface of these soap flakes 1.Then, the CMC aqueous solution is coated on this printing cut surface in right amount, makes between the cut surface of each soap flakes that foregoing cutting forms bondingly mutually, thus, make that to wash soap integrated, become the stamp soap that has floral designs.
Use the black preparation of various seals the above-mentioned stamp soap that has floral designs to be made the stamp soap of 20 kinds of different patterns respectively.With regard to printed pattern pattern 2 and 3, by the defective of its stamp of visual assessment, peel off, and stamp after the cracking and the Yin Mose spot of seal China ink.This evaluation is made comprehensive evaluation after confirming the frequency of its generation with regard to above-mentioned each assessment item on this basis.
Again, the benchmark of this comprehensive evaluation is 0/20～1/20 to be designated as zero when very good at the occurrence frequency of each project, and the occurrence frequency of each project is 2/20～6/20 to be designated as when good, the occurrence frequency of each project be 7/20～20/20 be designated as when bad *.Again, the defective of printed film, peel off and ftracture, mainly be to betide floral designs 2, in addition, these bad degree that take place in the stamp soap of various floral designs are about equally.
Evaluation result is shown in table 1.Can see that from this result printed film is subjected to die to form the influence of the soluble cotton consumption of agent.That is, when the scope of soluble cotton consumption, can form the less good stamp of printed film defective occurrence frequency at 20%-40%; Particularly, when soluble cotton consumption during, can obtain extraordinary printing state in 30% left and right sides.
Embodiment B-1～B-6
Number the usage ratio of B-1～B-6 moiety by embodiment as shown in table 2 below, with with above-mentioned same method, make the black preparation of seal respectively,, obtain and the aforementioned same soap of washing that has floral designs by on the cut surface of soap flakes 1, printing floral designs 2 and 3 as above-mentioned method.Table 2
| Form the embodiment numbering | B-1 | B-2 | B-3 | B-4 | B-5 | B-6 |
| Blue No. 404 ethylene glycol butyl ethers of vinylbenzene-vinyl toluene-indene copolymer soluble cotton RS 1/4 citric acid acetyl fourth three ester POE polysiloxane copolymers | 10 39 19 5 27 300 | 20 34 17 4 25 300 | 30 30 15 3 22 300 | 40 26 13 2 19 300 | 50 22 11 1 16 300 | 60 17 9 1 13 300 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 11/20 4/20 7/10 | 4/20 2/20 2/20 | 0/20 1/20 1/20 | 1/20 0/20 1/20 | 2/20 5/20 2/20 | 1/20 12/20 4/20 |
| Comprehensive evaluation | × | △ | ○ | ○ | △ | × |
Crackle to the defective of stamp this moment, after peeling off, printing and the color spot under the printing state, according to estimating as aforesaid judgement criteria, its evaluation result is shown in table 2.Can see that from this result the stamp state is subjected to the influence of the vinylbenzene-vinyl toluene-indene copolymer consumption as the film plastering agent.Promptly, when the scope of vinylbenzene-vinyl toluene-indene copolymer consumption at 20%-50%, can form the less good stamp of defective occurrence frequency of printed film, particularly, vinylbenzene-vinyl toluene-indene copolymer consumption can obtain extraordinary stamp state when the scope of 25%-45%.
Embodiment C-1～C-5
Number the usage ratio of the moiety of C-1～C-5 by embodiment as shown in table 3 below, with as above-mentioned same method, make the black preparation of seal respectively,, obtain and the aforementioned same soap of washing that has floral designs by on the cut surface of soap flakes 1, stamping floral designs 2 and 3 as above-mentioned method.
Table 3
| Form the embodiment numbering | C-1 | C-2 | C-3 | C-4 | C-5 |
| Blue No. 404 ethylene glycol butyl ethers of citric acid acetyl tri-n-butyl soluble cotton RS 1/4 vinylbenzene-vinyl toluene-indene copolymer POE polysiloxane copolymer | 0 35 35 4 26 300 | 5 34 34 3 25 300 | 10 32 32 3 23 300 | 15 30 30 3 22 300 | 20 28 28 3 21 300 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 6/20 15/20 3/10 | 3/20 7/20 4/20 | 1/20 2/20 2/20 | 3/20 1/20 5/20 | 5/20 1/20 13/20 |
| Comprehensive evaluation | × | △ | ○ | △ | × |
To the defective of stamp this moment, peel off, the crackle behind the stamp and the color spot under the printing state, according to estimating as aforesaid judgement criteria, its evaluation result is shown in table 3.Can see that from this result the stamp state is subjected to the influence as the citric acid acetyl tri-n-butyl consumption of softening agent.That is, when the scope of citric acid acetyl tri-n-butyl consumption, the less good print of defective occurrence frequency of printed film can be formed, particularly,, extraordinary printing state can be obtained when citric acid acetyl tri-n-butyl consumption during in 10% left and right sides at 5%-15%.
Embodiment D-1～D-6
Number the usage ratio of the moiety of D-1～D-6 by embodiment as shown in table 4 below, with as above-mentioned same method, make the black preparation of seal respectively,, obtain and the aforementioned same soap of washing that has floral designs by on the cut surface of soap flakes 1, stamping floral designs 2 and 3 as above-mentioned method.
Table 4
| Form the embodiment numbering | D-1 | D-2 | D-3 | D-4 | D-5 | D-6 |
| Blue No. 404 ethylene glycol butyl ethers of POE polysiloxane copolymer soluble cotton RS 1/4 vinylbenzene-vinyl toluene-indene copolymer citric acid acetyl tri-n-butyl | 0 31 31 15 23 300 | 1 31 31 15 22 300 | 3 30 30 15 22 300 | 5 29 29 15 22 300 | 7 29 29 14 21 300 | 10 28 28 14 20 300 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 4/20 5/20 9/20 | 2/20 2/20 4/20 | 1/20 1/20 0/20 | 3/20 2/20 2/20 | 5/20 4/20 1/20 | 5/20 5/20 2/20 |
| Comprehensive evaluation | × | ○ | ○ | △ | × | × |
Crackle to the defective of stamp this moment, after peeling off, printing and the color spot under the printing state, according to estimating as aforesaid judgement criteria, its evaluation result is shown in table 4.Can see that from this result the printingout state is subjected to the influence as the POE polysiloxane consumption of auxiliary agent.That is, when the scope of POE polysiloxane consumption, the less good print of defective occurrence frequency of printed film can be formed, particularly,, extraordinary printing state can be obtained when POE polysiloxane consumption during at 1%-3% at 0.5%-5%.
Embodiment E-1～E-5
Number the usage ratio of the moiety of E-1～E-5 by embodiment as shown in table 5 below, with with above-mentioned same method, make the black preparation of seal respectively,, obtain and the aforementioned same soap of washing that has floral designs by on the cut surface of soap flakes 1, stamping floral designs 2 and 3 as above-mentioned method.
Table 5
| Form the embodiment numbering | E-1 | E-2 | E-3 | E-4 | E-5 |
| Blue No. 404 soluble cotton RS 1/4 vinylbenzene-vinyl toluene-indene copolymer citric acid acetyl tri-n-butyl POE polysiloxane copolymer ethylene glycol butyl ethers | 0 43 34 13 100 | 20 41 32 12 100 | 40 39 30 11 100 | 60 36 29 10 100 | 80 33 27 10 100 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 2/20 4/20 0/10 | 1/20 1/20 2/20 | 2/20 2/20 1/20 | 7/20 9/20 3/20 | 10/20 13/20 3/20 |
| Comprehensive evaluation | △ | ○ | ○ | △ | × |
Crackle to the defective of stamp this moment, after peeling off, printing and the color spot under the printing state, according to estimating as aforesaid judgement criteria, its evaluation result is shown in table 5.Can see that from this result the stamp state is subjected to the influence of pigment (the blue No. 404) consumption as tinting material.That is, when this amount of pigment 60% when following, can form the less good print of defective occurrence frequency of printed film, particularly, when the scope of this amount of pigment, can obtain extraordinary printing state at 20%-40%.
Embodiment F-1～F-5
Number the usage ratio of the moiety of F-1～F-5 by embodiment as shown in table 6 below, with as above-mentioned same method, make the black preparation of seal respectively,, obtain and the aforementioned same soap of washing that has floral designs by on the cut surface of soap flakes 1, stamping floral designs 2 and 3 as above-mentioned method.
Table 6
| Form the embodiment numbering | F-1 | F-2 | F-3 | F-4 | F-5 |
| Ethylene glycol butyl ether soluble cotton RS 1/4 vinylbenzene-vinyl toluene-indene copolymer citric acid acetyl tri-n-butyl POE polysiloxane copolymer ethylene glycol butyl ether | 50 30 30 15 3 22 | 100 30 30 15 3 22 | 300 30 30 15 3 22 | 500 30 30 15 3 22 | 700 30 30 15 3 22 |
| Defective during stamp, the color spot of crackle printed pattern when peeling off stamp | 12/20 9/20 4/20 | 7/20 6/20 3/20 | 1/20 1/20 0/20 | 2/20 1/20 5/20 | 5/20 3/20 13/20 |
| Comprehensive evaluation | × | ○ | ○ | △ | × |
Crackle to the defective of stamp this moment, after peeling off, printing and the color spot under the printing state, according to estimating as aforesaid judgement criteria, its evaluation result is shown in table 6.Can see that from this result the stamp state is subjected to the influence of solvent ethylene glycol butyl ether consumption.Promptly, when this solvent load when being the scope of 100～500 weight parts, can form the less good print of defective occurrence frequency of printed film, particularly for black preparation composition 100 weight parts of seal, when the scope of this solvent load about 300 weight parts, can obtain extraordinary printing state.
Can understand from the result of the foregoing description, can good state print washing the soap surface, in addition, each composition consumption of being mixed is limited to certain scope, can obtain very good printing state according to seal ink composition of the present invention.
The present invention is because having aforesaid structure, so can give play to following effect.
According to the seal ink composition of washing the soap surface printing that is used in of the present invention, can wash the soap surface and reducing the defective of printed film, peel off and the bad occurrence frequency of printing such as color spot. Thereby, can improve the production efficiency of the stamp soap that is printed on floral designs.
Again, the constituent in the seal ink composition of the present invention is all used as cosmetic material usually, so, even this seal ink composition is contained in to be washed in the soap, human body skin there is not any harm yet. Therefore, can obtain the very safe stamp soap that is printed on floral designs, and can be optionally this wash soap form form etc. various, sometimes need the floral designs of the black preparation of very a large amount of seals.
The simple declaration of accompanying drawing
Figure 1 shows that the orthographic plan of making the stamp state on the soap face washing.Among the figure, 1 for washing soap, and 2,3 is floral designs.
Claims (2)
1. a stamp soap is with printing ink composition, it is characterized in that, described composition comprises: the soluble cotton that forms the 20-40% (weight) of agent as printed film, vinylbenzene-vinyl toluene-indene copolymer or Synolac as the 20-50% (weight) of plastering agent, as the organic or inorganic pigment of the 10-40% (weight) of tinting material or their mixture, as the citrate of the 5-15% (weight) of softening agent and as the polyethylene oxide polysiloxane copolymer of the 0.5-5% (weight) of auxiliary agent.
2. stamp soap as claimed in claim 1 is with printing ink composition, it is characterized in that, for the described seal ink composition of 100 weight parts, with the cooperation ratio more than 100 weight parts, below 500 weight parts, use the solvent of forming by being selected from one or two or more kinds of following composition: ethyl acetate, butylacetate, acetone, methylethylketone, cellosolve, methyl iso-butyl ketone (MIBK), ethyl lactate, diacetone alcohol, cellosolve acetate, ethylene glycol butyl ether, Sorbitol Powder, ethylene glycol, butyleneglycol, toluene and dimethylbenzene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97112759A CN1082074C (en) | 1997-06-13 | 1997-06-13 | Print ink compound for calico-printer's soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97112759A CN1082074C (en) | 1997-06-13 | 1997-06-13 | Print ink compound for calico-printer's soap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1202507A CN1202507A (en) | 1998-12-23 |
| CN1082074C true CN1082074C (en) | 2002-04-03 |
Family
ID=5172462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97112759A Expired - Lifetime CN1082074C (en) | 1997-06-13 | 1997-06-13 | Print ink compound for calico-printer's soap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1082074C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300269C (en) * | 2004-09-18 | 2007-02-14 | 王尔健 | Coating oil fo alcohol soluble intaglio paper box pre-printing |
| CN103786455A (en) * | 2013-12-31 | 2014-05-14 | 丽鑫生技化妆品（上海）有限公司 | Method for forming colorful image on surface of cosmetic |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5696000A (en) * | 1979-12-28 | 1981-08-03 | Dainippon Printing Co Ltd | Production of soap with patterns |
-
1997
- 1997-06-13 CN CN97112759A patent/CN1082074C/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5696000A (en) * | 1979-12-28 | 1981-08-03 | Dainippon Printing Co Ltd | Production of soap with patterns |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1202507A (en) | 1998-12-23 |
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