CN108206073A - Fire-resisting cable is pressed in a kind of novel flame-retardant A classes - Google Patents

Fire-resisting cable is pressed in a kind of novel flame-retardant A classes Download PDF

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Publication number
CN108206073A
CN108206073A CN201711458306.1A CN201711458306A CN108206073A CN 108206073 A CN108206073 A CN 108206073A CN 201711458306 A CN201711458306 A CN 201711458306A CN 108206073 A CN108206073 A CN 108206073A
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China
Prior art keywords
layer
parts
retardant
flame
cable
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Inventor
何正寅
陆容
李金连
田忠
冯国五
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Yangzhou Shuguang Cable Co Ltd
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Yangzhou Shuguang Cable Co Ltd
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Priority to CN201711458306.1A priority Critical patent/CN108206073A/en
Publication of CN108206073A publication Critical patent/CN108206073A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • H01B9/022Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of longitudinal lapped tape-conductors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • H01B13/227Pretreatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • H01B13/24Sheathing; Armouring; Screening; Applying other protective layers by extrusion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0208Cables with several layers of insulating material
    • H01B7/0216Two layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0291Disposition of insulation comprising two or more layers of insulation having different electrical properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/185Sheaths comprising internal cavities or channels
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/1875Multi-layer sheaths
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/22Metal wires or tapes, e.g. made of steel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/282Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
    • H01B7/2825Preventing penetration of fluid, e.g. water or humidity, into conductor or cable using a water impermeable sheath
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/292Protection against damage caused by extremes of temperature or by flame using material resistant to heat
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/006Constructional features relating to the conductors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses press fire-resisting cable in a kind of novel flame-retardant A classes, including conductor, the periphery of the conductor sets gradually wrapped mica tape flame retardant coating, organosilane crosslinked polyethylene insulation layer, the conductor at least two, the at least two twisted conductors with organosilane crosslinked polyethylene insulation layer form core wire, set gradually polyester belt lapping layer and copper strips internal shield Component units core respectively every group of core wire periphery;At least two unit cores are twisted into cable core with filled layer, wrapped alkali-free glass fibre band belting layer, the total shielded layer of copper strips are set gradually outside the cable core, extrudes Ceramic silicon rubber liner layer, galvanized steel strip armor and flame retardant sheath layer, and between mutually fit closely.The configuration of the present invention is simple, novel in design, stable structure, fire protecting performance is good, has excellent heat-resisting, ageing-resistant, fire-retardant, insulation performance and electric property, has good social benefit, economic benefit and extensive market prospects.

Description

Fire-resisting cable is pressed in a kind of novel flame-retardant A classes
Technical field
The present invention relates to a kind of cable, fire-resisting cable is pressed in specially a kind of novel flame-retardant A classes, belongs to flame retardant cable technology Field.
Background technology
The voltage class overwhelming majority of fireproof power cable product concentrates on 1kV and hereinafter, and some super-huge height at present If layer building, the large-scale key project of country etc. use 0.6-1kV low voltage distribution cables, cable dosage and laying as usual Installation workload, more usual building increase into decades of times, and cable laying space increases into several times, not only consumptive material, but also energy consumption;And Cable laying is excessive, excessive in building, and adverse effect can be also brought to safe handling.Therefore, as these both need mesohigh Power transmission and distribution require the occasion of flame-retardant that must just use medium voltage fire again.Existing middle pressure fire-resisting cable is in cable Combination flame retardant coating is set outside core, due to the use of refractory material and unreasonable structure, cause current-carrying capacity of cable relatively low, cable occurs Fever phenomenon;The outside diameter of cable is larger simultaneously makes troubles to laying installation, also increases product cost.
Therefore, it proposes to press fire-resisting cable in a kind of novel flame-retardant A classes regarding to the issue above.
Invention content
The purpose of the present invention is that solve the above-mentioned problems and provides in a kind of novel flame-retardant A classes and press fire-resisting cable.
The present invention is achieved through the following technical solutions above-mentioned purpose, and fire-resisting cable is pressed in a kind of novel flame-retardant A classes, including Conductor, the periphery of the conductor set gradually wrapped mica tape flame retardant coating, organosilane crosslinked polyethylene insulation layer, and the conductor is at least Two, at least two twisted conductors with organosilane crosslinked polyethylene insulation layer form core wires, every group of core wire periphery respectively according to Secondary setting polyester belt lapping layer and copper strips internal shield Component units core;At least two unit cores and filled layer twisted synthesizing cable Core, the cable core set gradually wrapped alkali-free glass fibre band belting layer, the total shielded layer of copper strips, extrude in Ceramic silicon rubber outside Lining, galvanized steel strip armor and flame retardant sheath layer, and between mutually fit closely;
The flame-proof cable sheath pipe, is made of the raw material of following parts by weight:
75-85 parts of ethylene -- octene copolymer,
0.6-0.8 parts of silane coupling agent,
1.5-1.8 parts of stearic acid,
3-5 parts of electrolytic zinc acid leaching slag,
30-40 parts of talcum powder,
3-4 parts of vulcanizing agent,
8-10 parts of carbon black,
4-6 parts of graphite,
2-5 parts of Arabic gum.
Preferably, the copper strips internal shield and the total shielded layer of copper strips are made using copper strips longitudinal wrap embossing technique Shielded layer.
Preferably, the filled layer is using one kind in asbestos cord, glass cord, mineral and carbonate containing the crystallization water Or multiple material mixes.
Preferably, the wrapped alkali-free glass fibre band belting layer, the total shielded layer of copper strips, extrude Ceramic silicon rubber liner The thickness of layer, galvanized steel strip armor and flame retardant sheath layer is equal.
Preferably, the conductor is oxygen-free copper bar.
Preferably, the preparation method of the flame-proof cable sheath pipe, comprises the steps of:
Step 1::In order with parts by weight mixed ethylene -- octene copolymer, silane coupling agent, stearic acid, electrolysis zincic acid Then phase analysis, talcum powder and vulcanizing agent will mix all raw materials stirring terminated, be kneaded;
Step 2:Step 1 is kneaded to the raw material of end, sequentially adds carbon black, graphite and Arabic gum in sequence, is melted After melting blending, sizing material is obtained;
Step 3:By the sizing material obtained by step 2 by double thread extruding machine, sizing material is transported to sizing head, machine by extruding machine Modeling product is extruded into plastics by head;
Step 4:By the plastics obtained by step 3 by blanching unit, secondary drawing-die processing is carried out, then through overmolding, fixed After diameter, traction and cutting, protecting pipe is obtained.
Preferably, the rotating speed that raw material stirs in the step 1 is 600r/min, time 20-30min.
Preferably, melting temperature is 170-190 DEG C in the step 2, and the blending time is 10-25min.
The beneficial effects of the invention are as follows:The configuration of the present invention is simple, novel in design, stable structure, fire protecting performance is good, and Even if fire encounters water and nor affect on its operation when occurring, there is excellent heat-resisting, ageing-resistant, fire-retardant, insulation performance and electrical Performance improves the shield effectiveness and bending property of cable, can effectively reduce electromagnetic interference between cable pair, has good society Meeting benefit, economic benefit and extensive market prospects, are worth of widely use.Protecting pipe provided by the invention not only have both intensity and The characteristics of toughness, and the excellent result in terms of flame retardant property.
Description of the drawings
Fig. 1 is overall structure diagram of the present invention.
In figure:1st, core wire, 11, conductor, 12, wrapped mica tape flame retardant coating, 13, crosslinked polyetylene insulated layer, 2, unit wires Core, 21, polyester belt lapping layer, 22, copper strips internal shield, 3, filled layer, 4, wrapped alkali-free glass fibre band belting layer, 5, copper strips Total shielded layer, 6, liner layer, 7, galvanized steel strip armor, 8, flame retardant sheath layer.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment shall fall within the protection scope of the present invention.
Refering to Figure 1, fire-resisting cable is pressed in a kind of novel flame-retardant A classes, and including conductor 11, the periphery of the conductor 11 Set gradually wrapped mica tape flame retardant coating 12, organosilane crosslinked polyethylene insulation layer 13, the conductor 11 at least two, at least two The twisted conductor 1 with organosilane crosslinked polyethylene insulation layer 13 forms core wire 1, is set gradually respectively every group of 1 periphery of core wire poly- Ester band 22 Component units core 2 of lapping layer 21 and copper strips internal shield;At least two unit cores 2 and 3 twisted synthesizing cable of filled layer Core, the cable core set gradually wrapped alkali-free glass fibre band belting layer 4, the total shielded layer 5 of copper strips, extrude Ceramic silicon rubber outside Liner layer 6, galvanized steel strip armor 7 and flame retardant sheath layer 8, and between mutually fit closely.
As a kind of technical optimization scheme of the present invention, the copper strips internal shield 22 and the total shielded layer 5 of copper strips are adopted The shielded layer being made with copper strips longitudinal wrap embossing technique.
As a kind of technical optimization scheme of the present invention, the filled layer 3 uses asbestos cord, glass cord, containing crystallization One or more of the mineral and carbonate of water material mixes.
As a kind of technical optimization scheme of the present invention, the wrapped alkali-free glass fibre band belting layer 4, copper strips always shield Layer 5, to extrude Ceramic silicon rubber liner layer 6, galvanized steel strip armor 7 equal with the thickness of flame retardant sheath layer 8.
As a kind of technical optimization scheme of the present invention, the conductor 11 is oxygen-free copper bar.
Embodiment 1
The flame resistance protecting pipe of the present invention, is made of the raw material of following parts by weight:
75 parts of ethylene -- octene copolymer, 0.6 part of silane coupling agent, 1.5 parts of stearic acid, 3 parts of electrolytic zinc acid leaching slag, talcum 30 parts of powder, 3 parts of vulcanizing agent, 8 parts of carbon black, 4 parts of graphite, 2 parts of Arabic gum.
The raw material of above-mentioned parts by weight is carried out to the making of protecting pipe in accordance with the following steps:
Step 1:The raw material of following parts by weight is mixed in order:75 parts of ethylene -- octene copolymer, silane coupling agent 0.6 Then part, 1.5 parts of stearic acid, 3 parts of electrolytic zinc acid leaching slag, 30 parts of talcum powder, 3 parts of vulcanizing agent will mix all raw materials terminated 20min is stirred with the rotating speed of 600r/min, is kneaded;
Step 2:Step 1 is kneaded to the raw material of end, sequentially adds the raw material of following parts by weight in sequence:Carbon black 8 Part, 4 parts of graphite, 2 parts of Arabic gum melts at a temperature of 170 DEG C, after 10min is blended, obtains the stronger sizing material of stability;
Step 3:By the sizing material obtained by step 2 by double thread extruding machine, sizing material is transported to sizing head, machine by extruding machine Modeling product is extruded into plastics by head;
Step 4:By the plastics obtained by step 3 by blanching unit, secondary drawing-die processing is carried out, then through overmolding, fixed After diameter, traction and cutting, protecting pipe is obtained, the protecting pipe is then subjected to strength character and flame retardant property is tested, as a result such as table 1 It is shown.
Embodiment 2
A kind of flame resistance protecting pipe is made of the raw material of following parts by weight:
80 parts of ethylene -- octene copolymer, 0.7 part of silane coupling agent, 1.6 parts of stearic acid, 4 parts of electrolytic zinc acid leaching slag, talcum 35 parts of powder, 3.5 parts of vulcanizing agent, 9 parts of carbon black, 5 parts of graphite, 4 parts of Arabic gum.
The raw material of above-mentioned parts by weight is carried out to the making of protecting pipe in accordance with the following steps:
Step 1:The raw material of following parts by weight is mixed in order:80 parts of ethylene -- octene copolymer, silane coupling agent 0.7 Then part, 1.6 parts of stearic acid, 4 parts of electrolytic zinc acid leaching slag, 35 parts of talcum powder, 3.5 parts of vulcanizing agent will mix all originals terminated Material stirs 25min with the rotating speed of 600r/min, is kneaded;
Step 2:Step 1 is kneaded to the raw material of end, sequentially adds the raw material of following parts by weight in sequence:Carbon black 9 Part, 5 parts of graphite melts at a temperature of 180 DEG C, after 18min is blended, obtains the stronger sizing material of stability;
Step 3:By the sizing material obtained by step 2 by double thread extruding machine, sizing material is transported to sizing head, machine by extruding machine Modeling product is extruded into plastics by head;
Step 4:By the plastics obtained by step 3 by blanching unit, secondary drawing-die processing is carried out, then through overmolding, fixed After diameter, traction and cutting, protecting pipe is obtained, the protecting pipe is then subjected to strength character and flame retardant property is tested, as a result such as table 1 It is shown.
Embodiment 3
A kind of flame resistance protecting pipe is made of the raw material of following parts by weight:
85 parts of ethylene -- octene copolymer, 0.8 part of silane coupling agent, 1.8 parts of stearic acid, 5 parts of electrolytic zinc acid leaching slag, talcum 40 parts of powder, 4 parts of vulcanizing agent, 10 parts of carbon black, 6 parts of graphite, 5 parts of Arabic gum.
The invention also includes the production method of above-mentioned flame resistance protecting pipe, step is as follows:
Step 1:The raw material of following parts by weight is mixed in order:85 parts of ethylene -- octene copolymer, silane coupling agent 0.8 Then part, 1.8 parts of stearic acid, 5 parts of electrolytic zinc acid leaching slag, 40 parts of talcum powder, 4 parts of vulcanizing agent will mix all raw materials terminated 30min is stirred with the rotating speed of 600r/min, is kneaded;
Step 2:Step 1 is kneaded to the raw material of end, sequentially adds the raw material of following parts by weight in sequence:Carbon black 10 Part, 6 parts of graphite, 5 parts of Arabic gum melts at a temperature of 190 DEG C, after 25min is blended, obtains the stronger sizing material of stability;
Step 3:By the sizing material obtained by step 2 by double thread extruding machine, sizing material is transported to sizing head, machine by extruding machine Modeling product is extruded into plastics by head;
Step 4:By the plastics obtained by step 3 by blanching unit, secondary drawing-die processing is carried out, then through overmolding, fixed After diameter, traction and cutting, the protecting pipe is then subjected to strength character and flame retardant property is tested, the results are shown in Table 1.
" electrolytic zinc acid leaching slag " refers to the electrolytic zinc acid leaching slag that zinc hydrometallurgy is discharged, contains in this electrolytic zinc acid leaching slag There are a large amount of inorganic ions, zinc silicate, copper, lead, silicon, iron, calcium, magnesium.This electrolytic zinc acid leaching slag belongs at present be easy to cause ring The waste product of border pollution, the present invention in protecting pipe raw material composition by adding a certain proportion of electrolytic zinc acid leaching slag, to enhance shield The intensity of casing.
Arabic gum derives from a wealth of sources, cheap, and generation preferably resistance can be cooperateed in the material combination of protecting pipe Fuel efficiency fruit.
Due to using above-mentioned preparation method, the raw material of cable sheath tube is by reaction, mutually collaboration, the shield so as to make Casing has high intensity and high flame retardant.So that the cable sheath tube tensile strength of the present invention is in more than 28MPa, elongation at break More than 770%, for oxygen index (OI) more than 37, flame retardant property reaches A grades, and it is strong to have both significant significant intensity high flame resistance Feature;Meanwhile the waste electrolytic zinc acid leaching slag to damage to environment has been recycled, reduce environmental pollution, reduce Production cost has significant economic benefit and environmental benefit.
Strength character and flame retardant property test
Testing standard:According to the drawing of the protecting pipe obtained by the standard testing embodiment of the present invention 1-3 of GB/T1040.1-2006 Stretch intensity and elongation at break;According to the oxygen of the protecting pipe obtained by the standard testing embodiment of the present invention 1-3 of GB/T2406-1993 Index;According to the flame retardant rating of the protecting pipe obtained by the standard testing embodiment of the present invention 1-3 of GB12666.5;Its result such as table 1 It is shown.
1 strength character of table and flame retardant property test result:
Embodiment 1 Embodiment 2 Embodiment 3
Tensile strength (MPa) 28 29 36
Elongation at break (%) 770 800 860
Oxygen index (OI) 37 37 39
Flame retardant rating A A A
As it can be seen from table 1 the product of above-described embodiment, the characteristics of significant intensity high flame resistance is strong is had both.
In the use of the present invention, the conducting wire that conductor material is formed for oxygen-free copper bar drawing, conducting wire process, which uses, presses structure, Make its surfacing, mica tape flame retardant coating can closely be attached to conductive surface, be conducive to electric fields uniform distribution, reduce cost; Setting flame retardant coating outside cable conductor, effect are when fire occurs, and insulating layer and flame retardant sheath layer are by fiery situation about having burnt Under, the mica tape on conductor generates insoluble white stiff shell silica after meeting fire, has good insulating properties Can, and with certain mechanical strength and water-fast, to ensure ignition of cable when keeps the safe operation of certain time;Wrapped mica During band, priority control mica tape broadband, wrapping angle and tension ensure that Mica tape is smooth, close;Using irradiation crosslinkable silane Join polyethylene layer, improve the heat-resisting, ageing-resistant, fire-retardant of product, insulation performance and electric property;By designing fire-retardant fill out It fills outside layer, cable core and wrapped alkali-free glass fibre is set with belting layer, Ceramic silicon rubber liner layer and halogen-free flameproof oversheath Structure makes the flame retardant property of product reach A classes, while has excellent fire resistance;Using the pair twist unit of different pitches, drop Cross-talk between low line pair;Unit shielded layer (separated-shielding) improves the shielding effect of cable using copper strips longitudinal wrap embossing technique Fruit and bending property can effectively reduce electromagnetic interference between cable pair;Cable core always shielding effectively reduces cable and ambient enviroment is produced Raw electromagnetic interference or ambient enviroment generate interference to cable;Using steel-tape armouring, product mechanical performance is improved, is enhanced simultaneously The gear fire flame retardant property of product.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.Any reference numeral in claim should not be considered as to the involved claim of limitation.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (8)

1. fire-resisting cable is pressed in a kind of novel flame-retardant A classes, including conductor (11), it is characterised in that:The periphery of the conductor (11) Set gradually wrapped mica tape flame retardant coating (12), organosilane crosslinked polyethylene insulation layer (13), the conductor (1) at least two, until Few two twisted conductors (11) with organosilane crosslinked polyethylene insulation layer (13) form core wire (1), every group of core wire (1) periphery Polyester belt lapping layer (21) and copper strips internal shield (22) Component units core (2) are set gradually respectively;At least two unit wires Core (2) is twisted into cable core with filled layer (3), and wrapped alkali-free glass fibre band belting layer (4), copper strips are set gradually outside the cable core Total shielded layer (5) extrudes Ceramic silicon rubber liner layer (6), galvanized steel strip armor (7) and flame retardant sheath layer (8), and between Mutually fit closely;
The flame-proof cable sheath pipe, is made of the raw material of following parts by weight:
75-85 parts of ethylene -- octene copolymer,
0.6-0.8 parts of silane coupling agent,
1.5-1.8 parts of stearic acid,
3-5 parts of electrolytic zinc acid leaching slag,
30-40 parts of talcum powder,
3-4 parts of vulcanizing agent,
8-10 parts of carbon black,
4-6 parts of graphite,
2-5 parts of Arabic gum.
2. press fire-resisting cable in novel flame-retardant A classes according to claim 1, it is characterised in that:The copper strips internal shield (22) and the total shielded layer of copper strips (5) is the shielded layer being made using copper strips longitudinal wrap embossing technique.
3. press fire-resisting cable in novel flame-retardant A classes according to claim 1, it is characterised in that:The filled layer (3) uses In asbestos cord, glass cord, mineral and carbonate containing the crystallization water or multiple material mixes.
4. press fire-resisting cable in novel flame-retardant A classes according to claim 1, it is characterised in that:The wrapped alkali-free glass Fiber band belting layer (4), the total shielded layer of copper strips (5), extrude Ceramic silicon rubber liner layer (6), galvanized steel strip armor (7) and The thickness of flame retardant sheath layer (8) is equal.
5. press fire-resisting cable in novel flame-retardant A classes according to claim 1, it is characterised in that:The conductor (11) is nothing Oxygen copper bar.
6. press fire-resisting cable in novel flame-retardant A classes according to claim 1, it is characterised in that:The flame-proof cable sheath The preparation method of pipe, comprises the steps of:
Step 1::In order with parts by weight mixed ethylene -- octene copolymer, silane coupling agent, stearic acid, electrolytic zinc acid leaching slag, Then talcum powder and vulcanizing agent will mix all raw materials stirring terminated, be kneaded;
Step 2:Step 1 is kneaded to the raw material of end, sequentially adds carbon black, graphite and Arabic gum in sequence, melting is altogether After mixed, sizing material is obtained;
Step 3:By the sizing material obtained by step 2 by double thread extruding machine, sizing material is transported to sizing head by extruding machine, and head will Modeling product is extruded into plastics;
Step 4:By the plastics obtained by step 3 by blanching unit, carry out secondary drawing-die processing, then through overmolding, sizing, lead After drawing and cutting, protecting pipe is obtained.
7. press fire-resisting cable in novel flame-retardant A classes according to claim 5, it is characterised in that:Raw material stirs in the step 1 The rotating speed mixed is 600r/min, time 20-30min.
8. the production method of flame-proof cable sheath pipe according to claim 5, it is characterised in that:It is melted in the step 2 Temperature is 170-190 DEG C, and the blending time is 10-25min.
CN201711458306.1A 2017-12-28 2017-12-28 Fire-resisting cable is pressed in a kind of novel flame-retardant A classes Pending CN108206073A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111627609A (en) * 2020-06-05 2020-09-04 苏州首控光伏电力开发有限公司 A anticorrosive temperature-resistant type high-voltage cable for electric power
CN112679818A (en) * 2020-11-24 2021-04-20 浙江亘古电缆股份有限公司 Environment-friendly cable based on recovered plant ash and electrolytic zinc acid leaching residues
CN113410002A (en) * 2021-06-29 2021-09-17 友光电线电缆有限公司 Preparation process of cable with flame-retardant and heat-insulation functions
CN114188080A (en) * 2021-11-17 2022-03-15 江苏通鼎光电科技有限公司 Temperature-resistant fireproof rail transit axle counting cable and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237867A (en) * 2014-04-21 2016-01-13 赵月 Cable sheath tube preparation method
CN205028678U (en) * 2015-09-28 2016-02-10 四川新蓉电缆有限责任公司 Medium voltage fireproof cable

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237867A (en) * 2014-04-21 2016-01-13 赵月 Cable sheath tube preparation method
CN205028678U (en) * 2015-09-28 2016-02-10 四川新蓉电缆有限责任公司 Medium voltage fireproof cable

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111627609A (en) * 2020-06-05 2020-09-04 苏州首控光伏电力开发有限公司 A anticorrosive temperature-resistant type high-voltage cable for electric power
CN112679818A (en) * 2020-11-24 2021-04-20 浙江亘古电缆股份有限公司 Environment-friendly cable based on recovered plant ash and electrolytic zinc acid leaching residues
CN113410002A (en) * 2021-06-29 2021-09-17 友光电线电缆有限公司 Preparation process of cable with flame-retardant and heat-insulation functions
CN113410002B (en) * 2021-06-29 2022-05-06 友光电线电缆有限公司 Preparation process of cable with flame-retardant and heat-insulation functions
CN114188080A (en) * 2021-11-17 2022-03-15 江苏通鼎光电科技有限公司 Temperature-resistant fireproof rail transit axle counting cable and manufacturing method thereof
CN114188080B (en) * 2021-11-17 2024-01-09 江苏通鼎光电科技有限公司 Temperature-resistant fireproof type track traffic axle counting cable and manufacturing method thereof

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Application publication date: 20180626