CN108203549A - A kind of high light fastness disperse dyes of blue - Google Patents

A kind of high light fastness disperse dyes of blue Download PDF

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Publication number
CN108203549A
CN108203549A CN201611165194.6A CN201611165194A CN108203549A CN 108203549 A CN108203549 A CN 108203549A CN 201611165194 A CN201611165194 A CN 201611165194A CN 108203549 A CN108203549 A CN 108203549A
Authority
CN
China
Prior art keywords
blue
high light
light fastness
disperse dyes
disperse
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611165194.6A
Other languages
Chinese (zh)
Inventor
王震
卜广玖
李柏毅
肖艳红
王海生
殷允杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Jiangnan University
Original Assignee
FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Jiangnan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd, Jiangnan University filed Critical FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Priority to CN201611165194.6A priority Critical patent/CN108203549A/en
Publication of CN108203549A publication Critical patent/CN108203549A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0034Mixtures of two or more pigments or dyes of the same type
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/008Preparations of disperse dyes or solvent dyes

Abstract

The present invention discloses method prepared by a kind of high light fastness disperse dyes of blue, belongs to technical field of textile chemical engineering.Study the sun-resistant performance of different types of disperse dyes, select the good dyestuff of sunlight fastness and carry out blending, then with ultra-violet absorber compound synergic.The sun-resistant excellent in stability of the high light fastness disperse dyes of blue of the present invention, not fugitive color.Especially suitable for automotive trim and Out-Door Sports Series top grade dyestuff, the polyester fiber good level-dyeing property after dyeing, tinctorial yield is high, has splendid sunlight fastness, and simple for process, operability is strong.

Description

A kind of high light fastness disperse dyes of blue
Technical field
The present invention relates to a kind of disperse dye composition, specially a kind of high light fastness disperse dyes of blue.
Background technology
As polyester fiber is in the special applications such as military camouflage, automobile interior trim, field sport fabric automobile textiles neck The fast development in domain, particularly automobile decoration, this requires disperse dyes must have field work or long-term high Sunlight exposure High fastness to light.Disperse dyes for outdoor textile dyeing must have the performances such as high light fastness and crock fastness. In order to enhance the light fastness of disperse dyeing polyester fabric, rationally screening is stablized with the efficiency light that disperse dyes are used cooperatively Agent and corresponding anti-ultraviolet finishing technology, this is very important.To widely used Polyester Textiles, can meet in this way The dye species asked are few, even Hensel steps what the international well-known dyestuff company such as weaving dyeization (former Ciba Specialty Chemicals) provided High light-fast disperse dyes also tend to need the cooperation of organic uv absorbers class light stabilizer, and can be only achieved special industry will It asks.At present, external dye material enterprise is proposed the Special dispersing dyestuff of some polyester fabrics and mating ultraviolet absorber, but still The requirement of outdoor high sun-resistant fabric cannot be fully met.So for high sun-resistant textile fabric, product quality, drop are improved Low production cost and the requirement for accelerating production domesticization, the development for carrying out high light-fast disperse dyes and light fastness promoting agent is very must It wants.
Invention content
It is an object of the invention to develop a kind of high light fastness disperse dyes of blue, production effect can be improved by providing one kind Rate, the high disperse dyes simultaneously with high sunlight fastness of products perfection yield.
In order to achieve the above object, the technical solution adopted by the present invention is:A kind of high light fastness disperse dyes of blue, It is characterized in that, consisting of 83 mass fraction of disperse blue is 30%~34%, 87 mass fraction of disperse blue is 10%~15%, point It is 14%~18% to dissipate 62 mass fractions of indigo plant, and 3 mass fraction of disperse blue is 38%~42%, and surplus is auxiliary agent and ultraviolet radiation absorption Agent.
Preferably, the described high light fastness disperse dyes of blue, it is characterised in that preparation process is:Indigo plant is weighed in proportion It the high light fastness disperse dyes each component of color and is uniformly mixed, 1 is pressed in dispersant, water and ultra-violet absorber:6:0.5 item Micronized is carried out to composition with crushing and grinding device under part, the slurry that grinding obtains is spray-dried, in its drying The nano silicon dioxide of addition 10% is to get to the high light fastness disperse dye composition of blue in product.
Preferably, the high light fastness disperse dyes of blue, which is characterized in that the dispersant is alkylnaphthalene sulphur Hydrochlorate formaldehyde condensation products.
Preferably, the high light fastness disperse dyes of blue, which is characterized in that the ultra-violet absorber is benzene And triazole and benzophenone class 1:1 compound UV absorption finishing agent.
The obtained high light fastness disperse dyes of blue dye polyester fiber, and light fastness is excellent, especially suitable For automotive trim and Out-Door Sports Series high-grade fabric, material tinctorial yield is high below for dyeing, good level-dyeing property, and processing step letter Single, operability is strong.The addition of nano silicon dioxide increases the reflection to exposure light, alleviates the irradiation on dyestuff.
Embodiment
By the disperse blue 87 of 30 grams of 83,10 grams of disperse blue, the wood of 3,5 grams of the disperse blue of 62,40 grams of the indigo plant of 15 grams of dispersion The mixture of quality sodium sulfonate and ultra-violet absorber (ratio 1:1) it is uniformly mixed, adds water and be ground micronized, grind Slurry afterwards is spray-dried, spray drying condition:120 DEG C of inlet temperature, outlet temperature are 60 DEG C, and in its desciccate The nano silicon dioxide of middle addition 10 grams (10%) obtains the high light fastness disperse dyes of blue.
The high light fastness disperse dye composition chromatography of blue of the present invention is complete, paints on polyester fiber, color Fastness and dyeability are excellent, and the polyester fiber after dyeing is widely used, and light fastness reaches 5 grades, 4-5 grades of fastness to rubbing, 4-5 grades of washing fastness has fairly good dyeability, is easy to wash.

Claims (4)

1. a kind of high light fastness disperse dyes of blue, which is characterized in that consisting of 83 mass fraction of disperse blue for 30%~ 34%, 87 mass fraction of disperse blue is 10%~15%, and 62 mass fraction of disperse blue is 14%~18%, disperse blue 3 mass point Number is 38%~42%, and surplus is auxiliary agent and ultra-violet absorber.
2. the high light fastness disperse dyes of blue as described in claim 1, it is characterised in that preparation process is:It weighs in proportion It the high light fastness disperse dyes each component of blue and is uniformly mixed, 1 is pressed in dispersant, water and ultra-violet absorber:6:0.5 Under the conditions of with crushing and grinding device carries out micronized to composition, obtained slurry will be ground and be spray-dried, done at it The nano silicon dioxide of addition 10% is to get to the high light fastness disperse dye composition of blue in dry product.
3. the high light fastness disperse dyes of blue as described in claim 1, which is characterized in that the dispersant is alkylnaphthalene Sulfonate and formaldehyde condensation product.
4. the high light fastness disperse dyes of blue as described in claim 1, which is characterized in that the ultra-violet absorber is Benzotriazole and benzophenone class 1:1 compound UV absorption finishing agent.
CN201611165194.6A 2016-12-20 2016-12-20 A kind of high light fastness disperse dyes of blue Pending CN108203549A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611165194.6A CN108203549A (en) 2016-12-20 2016-12-20 A kind of high light fastness disperse dyes of blue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611165194.6A CN108203549A (en) 2016-12-20 2016-12-20 A kind of high light fastness disperse dyes of blue

Publications (1)

Publication Number Publication Date
CN108203549A true CN108203549A (en) 2018-06-26

Family

ID=62602116

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611165194.6A Pending CN108203549A (en) 2016-12-20 2016-12-20 A kind of high light fastness disperse dyes of blue

Country Status (1)

Country Link
CN (1) CN108203549A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111286211A (en) * 2020-03-30 2020-06-16 金华双宏化工有限公司 Sun-proof blue acid dye and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111286211A (en) * 2020-03-30 2020-06-16 金华双宏化工有限公司 Sun-proof blue acid dye and preparation method thereof
CN111286211B (en) * 2020-03-30 2021-02-23 金华双宏化工有限公司 Sun-proof blue acid dye and preparation method thereof

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180626

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