CN108193022A - Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively - Google Patents

Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively Download PDF

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Publication number
CN108193022A
CN108193022A CN201810225533.8A CN201810225533A CN108193022A CN 108193022 A CN108193022 A CN 108193022A CN 201810225533 A CN201810225533 A CN 201810225533A CN 108193022 A CN108193022 A CN 108193022A
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China
Prior art keywords
brick
air brick
air
block
porous core
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CN201810225533.8A
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Chinese (zh)
Inventor
张小旭
陈瑞峰
赵晓东
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Luoyang Xuanshi High Temperature Materials Co Ltd
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Luoyang Xuanshi High Temperature Materials Co Ltd
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Priority to CN201810225533.8A priority Critical patent/CN108193022A/en
Publication of CN108193022A publication Critical patent/CN108193022A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively,Provide a kind of ventilative brick structure and production method,It is remarkably improved bottom-blown air brick comprehensive life,Build two blocks of air bricks in ladle by laying bricks or stones,First block of air brick is conventional monolithic devices air brick,Second block of air brick is by ventilating seat brick,Porous core and perfusion castable three parts composition,The height that castable is perfused is 30mm 100mm,It is 40% 80% that castable and the uncombined area in brick cup bellmouth side, which is perfused,,Faying face is not evenly distributed in strip,Castable is perfused, the gap that thickness is 1mm 2mm is set by the method for brushing paraffin when making with ventilative wicking surface,First block of air brick is first used during use,Self-flowing material is blocked after first block of air brick reaches the service life with corundum to block,Then second block of air brick is blown open with oxygen rifle to begin to use.

Description

Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively
Technical field
The present invention relates to the BOTTOM ARGON BLOWING air bricks of refinement outside-furnace field, particularly fire resisting material field.
Background technology
External refining is to ensure the critical process of its grade of steel product quality and raising, and in furnace outer refining process, BOTTOM ARGON BLOWING is saturating Gas brick is its Core Feature element, and the meaning of air brick is by conveying argon gas into packet so as to reach the mesh of liquid steel refining 's.
Air brick is formed from it at present is divided into split type and two kinds of monoblock type in structure, two kinds of air bricks respectively have good and bad spy Point, but the more or monoblock type air brick at domestic smelting iron and steel scene.Monoblock type air brick refers in cast brick cup In the process, air brick core is preset in brick cup mold, becomes an entirety (direct prefabrication type), also have porous core and After ventilating seat brick is made respectively, the two is fitted together (packaging) by chamotte, when use is built by laying bricks or stones at packet bottom, generally For when porous core is consumed to safe altitude, the integral air brick complete mission, need offline replacement.Whole brick has peace Entirely, reliably, the advantages of installation is built by laying bricks or stones the characteristics of simple, split air brick is that porous core can be online after being consumed to safe altitude Heat changes porous core, therefore its comprehensive life is high compared with integral air brick, but its security risk is higher, this is that many steel mills are unwilling to adopt One of the main reason for split type air brick.
With the development of air brick technology, pass through brick, the optimization design of air supply channel and the refinery practice of breathing freely It continuously improves, such as the addition of pro-molten refining slag, the adding technology of refined alloy etc., general middle-size and small-size ladle only needs one piece to breathe freely Brick can meet refining requirement, if using split type air brick, security risk is higher, needs stringent field management and installation Build working specification by laying bricks or stones, if using monoblock type air brick the air brick service life may influence entire ladle lining.
It is practical at present smelt scene there is also a ladle build two blocks of monolithic devices air bricks by laying bricks or stones and only with one piece of Argon, completely Under the premise of foot refining requirement, one piece of air brick Argon is first opened, another piece of not Argon every several times (such as 5 times), is closed current Air brick is opened another piece of air brick Argon, is so recycled, and this technique can extend the bottom-blown air brick longevity to a certain extent Life, but problem appear to is that the air brick of Argon is not immersed in molten steel for a long time and forms natural wastage, and can be easy to lead Cause cleans the technology accidents such as obstructed when oozing steel, the fracture of brick core, opening.
About the design of air brick flow, adjusted at present generally by the quantity and specification of porous core air supply channel, Such as slot-type ventilating brick, the quantity of slit can be arranged to 24, can also be arranged to 48, but the flow of the latter is necessarily than preceding Person is big.
About air brick material, color differentiation can be Chrome-free and containing two class of chromium after burning, after the high temperature of air brick containing chromium is burnt For color according to chromium content in different degrees of red, Chrome-free air brick is in raw material color, generally white.
Invention content
In order to solve above-mentioned contradiction existing for current middle-size and small-size air brick of steel ladle, with insufficient, the present invention is using monolithic devices saturating Under the premise of gas brick, devise air brick in a kind of ladle first builds form by laying bricks or stones, while provide a kind of structure of air brick, Make it that can achieve the purpose that extend the air brick service life when in use.
The technical solution adopted in the present invention is:
1, by adjusting the slit of porous core, designing a kind of higher air brick of flow enables it to ensure one block of air brick Meet ladle refining requirement, when Ladle Bottom is built by laying bricks or stones, build two blocks of air bricks by laying bricks or stones, during onsite application, first using first block of air brick, Until it reaches terminal life, first piece of air brick corundum for using terminal life is blocked self-flowing material blocks, then Make its start-up operation by second piece of porous core is boiled with oxygen rifle, first block of air brick is conventional monolithic devices air brick, second piece The porous core of air brick is not directly exposed to brick cup surface, but has the distance of 30mm-100mm away from brick cup upper surface and be embedded in seat Monolithic devices air brick inside brick.
The characteristics of the technical program is only with one piece of Argon, air brick when building two blocks of higher air bricks of flow but work by laying bricks or stones Flow can be easier to, reliably adjust at present, therefore can meet general ladle flow demand, such as 180T refining ladles, when first piece When air brick is using all service life, blocks self-flowing material with corundum and block, ensure safety;Secondly, it is the characteristics of second block of air brick Porous core is not contacted with molten steel before porous core is not directly exposed to brick cup surface, that is, second piece of air brick Argon, is ensured Self performance, when first block of air brick was used to the service life, the class brick cup material of the pre-buried 30mm-100mm thickness of second block of air brick Also basic loss finishes material, is easy to be blown with oxygen rifle at this time and logical carries out Argon work.
The production method of second block of air brick is:
1.1 direct prefabrication type integral air bricks:
1.1.1 porous core is placed on inside brick cup mold, porous core is lower 30mm-100mm than brick cup at this time, needs saturating Gaseous core microcephaly fixes an easily demoulding taper die, and taper die concentric reducer diameter difference is 5mm-10mm, major part outwardly, Highly not less than brick cup upper surface, taper die must be completely covered by porous core air supply channel after being contacted with porous core, saturating Gaseous core microcephaly's brushing a layer thickness is the paraffin of 1mm-2mm, and makes its solidification, then installs taper die, sets conical die Start prefabricated brick cup after tool, next step disposition is carried out after maintenance, form removal tool, drying;
1.1.2 sundries in the bellmouth of air brick is cleaned out, is in porous core microcephaly's external coating a layer thickness The paraffin of 1mm-2mm simultaneously makes its solidification, then Zi ventilative wicking surface to brick cup surface discontinuities formula painter on bellmouth side Industry machine oil, brushing surface are the 40%-80% of bellmouth lateral area, are evenly distributed in strip, can also be with thickness no more than 0.2mm's Paper slip, plastic foil, which are pasted onto on the side of bellmouth, replaces painter's industry machine oil.
1.1.3 finally perfusion and the distinguishing castable of brick cup material color, the differentiation of color can pass through in bellmouth The addition of chromium oxide adjusts, and completes the production after drying, it is desirable that refractoriness >=1700 DEG C of castable, 110 DEG C of bakings are perfused It is roasting for 24 hours under the conditions of compressive resistance and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h be arrange in pairs or groups therewith it is resistance under brick cup corresponding conditions The 70%-90% of Compressive Strength, 1600 DEG C burn after Linear change rate be 0.02%-0.35%.
In scheme 1.1.1 the limitation of taper die concentric reducer diameter difference and major part outwardly and smear paraffin requirement be in order to It can realize making and ensure performance;1.1.2 industrial machine oil is equally smeared in or is replaced with other materials, it is therefore an objective to painting machine The position of oil, perfusion castable do not generate combination with brick cup, and other positions for not smearing machine oil generate combination, when the air brick is opened When beginning to use with oxygen rifle it is boiled when convenient for boiled;1.1.3 the difference of middle perfusion castable and brick cup material property may be such that the During one piece of air brick use, the loss that castable is perfused can be more very fast than brick cup material and cannot be depleted completely, substantially A pit is formed, it is boiled convenient for oxygen rifle capturing position, equally, perfusion castable and brick cup material are distinguished by chromium oxide Color is also this purpose.
1.2 packaging integral air bricks:
Porous core is assembled with brick cup by chamotte, at this time self-assembling formation depth be 30mm-100mm bellmouth, bore to With described in 1.1 on the contrary, then being made according to the method for 1.1.2,1.1.3.
2, two blocks of air bricks are that range of flow under air conditions is in normal temperature state, pressure 0.3MPa, medium 30Nm3/h-65Nm3/ h, and specifically being set according to ladle size, when being on active service in ladle, the pressure of argon bottom-blowing need to be In the range of 0.8MPa-2.2MPa by hand valve flexibly, facilitate adjustment.
The purpose of requirement that this programme is carried is as far as possible in ton by adjusting air brick flow and adjustment argon bottom-blowing pressure Implement the present invention on the larger ladle in position to expand application range.
The beneficial effects of the invention are as follows:
1, the feasible adjusted design of air brick flow can ensure that the present invention is implemented as far as possible in larger ladle, mostly new at present The characteristics of ladle processed is that diameter is smaller and highly higher compared with more early ladle, and this ladle design feature is more suitable for the present invention's Using;
2, on the one hand the design of second piece of air brick structure and material feature ensures ventilative core performance before use not by ring Border is influenced or little effect is easily found accurately porous core position again simultaneously and blown open with oxygen rifle;
3, can extend that bottom blowing comprehensive life reaches original through the above scheme 1.5-1.7 times;
4, the raising nature in bottom-blown air brick service life leads to the raising of efficiency, reduces whole ladle lining The advantageous effects such as the energy consumption waste, avoided air brick generation of changing the day off.
Description of the drawings:
Fig. 1:First piece of air brick sectional view;
Fig. 2:Second piece of air brick sectional view of direct prefabrication type;
Fig. 3:Packaging second piece of air brick sectional view;
Fig. 4:Air brick sectional view before castable is constructed is perfused;
Fig. 5:Industrial machine oil schematic diagram is smeared after the expansion of bellmouth side;
Fig. 6:Sectional view after first block of air brick is used to service life closure;
Fig. 7:Second piece of air brick section shape appearance figure after first block of air brick was used to the service life.
In figure 1.:Ventilating seat brick;②:Porous core;③:Castable is perfused;④:Smear industrial machine oil portion in bellmouth side Position;⑤:Bellmouth side keeps cleaning position;⑥:The position of porous core surface smear paraffin;⑦:Block self-flowing material;⑧:Fire Mud;⑨:Bellmouth;⑩:Bellmouth height is 30mm-100mm.
Specific embodiment
1, in 180 tons of refining ladle examples:
1.1 make first block of air brick, and using direct prefabrication type air brick, porous core is 2. narrow using pink fused alumina spinel Seam, slot number are 54, flow 65Nm3/ h, ventilating seat brick is 1. using corundum spinel, 1. 110 DEG C of ventilating seat brick Compressive resistance under the conditions of baking for 24 hours is 65MPa, and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h is 185MPa, 1600 DEG C of burnings Linear change rate is 0.41% afterwards.
1.2 make second block of air brick, and using direct prefabrication type air brick, porous core is 2. narrow using pink fused alumina spinel Seam, slot number are 54, flow 65Nm3/ h, ventilating seat brick is 1. using corundum spinel, 1. 110 DEG C of ventilating seat brick Compressive resistance under the conditions of baking for 24 hours is 65MPa, and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h is 185MPa, 1600 DEG C of burnings Linear change rate is 0.41% afterwards, 10. bellmouth height takes 38mm.
3. 1.3 prepare perfusion castable, material selection pink fused alumina spinel, chromic oxide content 3%, 110 DEG C of bakings Compressive resistance under the conditions of for 24 hours is 58MPa, and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h is 160MPa, 1600 DEG C burn after line Change rate is 0.22%.
1.4 second blocks of air bricks are made in after Fig. 4 states, first the stone in porous core 2. one layer of 1mm thickness of external coating Wax, in bellmouth, 9. industrial machine oil is brushed in side after solidification, and 25mm every wide applies 8 altogether, then 3. pours into perfusion castable It in bellmouth, smashes or jolt ramming, making can be completed after solidification, without baking, when ventilative brick masonry is in ladle with ladle one With baking.
1.5 by above-mentioned two pieces of ventilative brick masonries in packet, first with first block of air brick, molten steel is needed to seethe feelings according to refining Condition adjusts argon flow amount.
1.6 according to certain steel mill's actual conditions, and first block of air brick averagely can be used 38 times, after first block of air brick to service life First piece of brick cup of air brick 1. steel of hole surface, slag are cleaned up with oxygen rifle.
1.7 second piece of air brick position pattern of observation, depressed area are porous core 2. place position, shown in Fig. 7, use oxygen The boiled second block of air brick of rifle.
1.8 by ladle vertically-arranged, then 7. blocks first block of air brick with blocking self-flowing material, blocks self-flowing material and seat 7. may be selected 1. girth seam self-flowing material can meet needs to brick, and first after closure block air brick is in shown in Fig. 6.
Ladle normal use after 1.9 closure, selects second piece of air brick argon bottom-blowing.
2, in 100T refining ladle examples:
2.1 make first block of air brick, and using packaging type air brick, 2. porous core uses pink fused alumina spinel slit Formula air brick, slot number are 36, flow 30Nm3/ h, ventilating seat brick use corundum spinel, ventilating seat brick 1. 110 Compressive resistance under the conditions of DEG C baking for 24 hours is 65MPa, and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h is 145MPa, 1600 DEG C Linear change rate is 0.38% after burning.
2. and ventilating seat brick 2.2 make second block of air brick, using packaging integral air brick, make porous core respectively 1. porous core is 2. using pink fused alumina spinel slot-type ventilating brick, slot number is 36, flow 30Nm3/ h, seat of breathing freely Brick is 1. using corundum spinel, and compressive resistance of the ventilating seat brick 1. under the conditions of 110 DEG C of bakings for 24 hours is 65MPa, 1600 DEG C of heat preservations Compressive resistance under the conditions of 3h is 145MPa, 1600 DEG C burn after Linear change rate be 0.38%, bellmouth highly takes 45mm, Ran Houtong Chamotte is crossed 8. to assemble, and the air brick after assembling is spare after 150 DEG C dry.
3. 2.3 prepare perfusion castable, material selection pink fused alumina spinel, chromic oxide content 4%, 110 DEG C of bakings Compressive resistance under the conditions of for 24 hours is 55MPa, and the compressive resistance under the conditions of 1600 DEG C of heat preservation 3h is 120MPa, 1600 DEG C burn after line Change rate is 0.21%.
2.4 first in the paraffin of the porous core of second block of air brick 2. one layer of 1mm thickness of external coating, in taper after solidification 9. industrial machine oil is brushed in side in hole, and 20mm every wide applies 8 altogether, then 3. pours into bellmouth perfusion castable, smashes or shake It is real, making can be completed after solidification, without baking, toasted together with ladle when ventilative brick masonry is in ladle.
2.5 by above-mentioned two pieces of ventilative brick masonries in packet, first with first block of air brick, molten steel is needed to seethe feelings according to refining Condition adjusts argon flow amount.
2.6 according to certain steel mill's actual conditions, and first block of air brick averagely can be used 40 times, after first block of air brick to service life First piece of brick cup of air brick 1. steel of hole surface, slag are cleaned up with oxygen rifle.
2.7 second piece of air brick position pattern of observation, depressed area be porous core 2. where position, with oxygen rifle boiled the Two blocks of air bricks.
2.8 by ladle vertically-arranged, then 7. blocks first block of air brick with blocking self-flowing material, blocks self-flowing material and seat 7. may be selected 1. girth seam self-flowing material can meet needs to brick.
Ladle normal use after 2.9 closure, selects second piece of air brick argon bottom-blowing.
3, three blocks of air bricks in ladle can be theoretically installed, bottom blowing is can further improve according to technical solution of the present invention Air brick comprehensive life:
First piece, second block of air brick carried out according to above-mentioned example, second block of air brick can be according to class after using to the service life As method block after begin to use third block air brick.
The position at packet bottom needs to install pocket block, air brick, and three pieces are installed in ladle bottom according to current actual conditions What air brick can be achieved on.

Claims (2)

1. Argon to be to extend the method for bottom blowing monolithic devices air brick comprehensive life successively, it is characterized in that:By adjusting porous core Slit, designing a kind of higher air brick of flow makes it ensure that one block of air brick disclosure satisfy that ladle refining requirement, in Ladle Bottom When building by laying bricks or stones, two blocks of air bricks are built by laying bricks or stones, during onsite application, first using first block of air brick, until it reaches terminal life, will use First block of air brick to terminal life blocks self-flowing material with corundum and blocks, and is then made with oxygen rifle by second piece of porous core is boiled It is started to work, and first block of air brick is conventional monolithic devices air brick, and the porous core of second block of air brick is not directly exposed to Brick cup surface, but the monolithic devices air brick for having the distance of 30mm-100mm away from brick cup upper surface and being embedded in inside brick cup, second Block air brick can be fabricated to direct prefabrication type and two kinds packaging, and production method is as follows:
1.1 direct prefabrication types:
1.1.1 porous core is placed on inside brick cup mold, porous core is lower 30mm-100mm than brick cup at this time, needs in porous core Microcephaly fixes an easily demoulding taper die, and taper die concentric reducer diameter difference is 5mm-10mm, and outwardly, height is or not major part Less than brick cup upper surface, taper die must be completely covered by porous core air supply channel after being contacted with porous core, small in porous core Head brushing a layer thickness is the paraffin of 1mm-2mm, and makes its solidification, then installs taper die, is opened after setting taper die Begin prefabricated brick cup, and next step disposition is carried out after maintenance, form removal tool, drying;
1.1.2 sundries in the bellmouth of air brick is cleaned out, is 1mm-2mm in porous core microcephaly's external coating a layer thickness Paraffin and make its solidification, then on bellmouth side Zi ventilative wicking surface to brick cup surface discontinuities formula brushing industry machine oil, Brushing surface is the 40%-80% of bellmouth lateral area, is evenly distributed in strip, can also use paper slip of the thickness no more than 0.2mm, modeling Material film, which is pasted onto on the side of bellmouth, replaces painter's industry machine oil;
1.1.3 finally perfusion and the distinguishing castable of brick cup material color, the differentiation of color can pass through oxidation in bellmouth The addition of chromium adjusts, and completes the production after drying, it is desirable that refractoriness >=1700 DEG C of castable is perfused, 110 DEG C of bakings are for 24 hours Under the conditions of compressive resistance and 1600 DEG C heat preservation 3h under the conditions of compressive resistance be therewith arrange in pairs or groups brick cup corresponding conditions under resistance to pressure The 70%-90% of degree, 1600 DEG C burn after Linear change rate be 0.02%-0.35%;
It is 1.2 packaging:
Porous core is assembled with brick cup by chamotte, at this time self-assembling formation depth be 30mm-100mm bellmouth, then according to 1.1.2, the method for 1.1.3 makes.
2. according to the method described in claim 1, the pressure value of argon bottom-blowing and its adjustment when air brick own traffic and work It is crucial, it is characterized in that:Range of flow of two blocks of air bricks in the case where normal temperature state, pressure 0.3MPa, medium are air conditions For 30Nm3/h-65Nm3/ h, and specifically being set according to ladle size, when being on active service in ladle, the pressure of argon bottom-blowing need to be In the range of 0.8MPa-2.2MPa by hand valve flexibly, facilitate adjustment.
CN201810225533.8A 2018-03-19 2018-03-19 Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively Pending CN108193022A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810225533.8A CN108193022A (en) 2018-03-19 2018-03-19 Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810225533.8A CN108193022A (en) 2018-03-19 2018-03-19 Argon is to extend the method for bottom blowing monolithic devices air brick comprehensive life successively

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CN108193022A true CN108193022A (en) 2018-06-22

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993969A (en) * 2009-08-21 2011-03-30 宝山钢铁股份有限公司 Converter bottom blowing air brick and using method thereof
CN203437635U (en) * 2013-08-19 2014-02-19 浙江自立股份有限公司 Standby ventilation brick in steel ladle
CN203992353U (en) * 2014-06-23 2014-12-10 山东银山耐火材料有限公司 Novel ladle porous core mounting structure
CN205874478U (en) * 2016-05-31 2017-01-11 中钢集团洛阳耐火材料研究院有限公司 High heat conduction air brick

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993969A (en) * 2009-08-21 2011-03-30 宝山钢铁股份有限公司 Converter bottom blowing air brick and using method thereof
CN203437635U (en) * 2013-08-19 2014-02-19 浙江自立股份有限公司 Standby ventilation brick in steel ladle
CN203992353U (en) * 2014-06-23 2014-12-10 山东银山耐火材料有限公司 Novel ladle porous core mounting structure
CN205874478U (en) * 2016-05-31 2017-01-11 中钢集团洛阳耐火材料研究院有限公司 High heat conduction air brick

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Application publication date: 20180622