CN108191349A - A kind of filler for being suitable for discarded underground people's air defense hole processing and preparation method thereof - Google Patents

A kind of filler for being suitable for discarded underground people's air defense hole processing and preparation method thereof Download PDF

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Publication number
CN108191349A
CN108191349A CN201810185296.7A CN201810185296A CN108191349A CN 108191349 A CN108191349 A CN 108191349A CN 201810185296 A CN201810185296 A CN 201810185296A CN 108191349 A CN108191349 A CN 108191349A
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CN
China
Prior art keywords
parts
air defense
filler
cement
underground people
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Pending
Application number
CN201810185296.7A
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Chinese (zh)
Inventor
温小栋
冯蕾
张振亚
王赛赛
马永政
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Ningbo University of Technology
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Ningbo University of Technology
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Priority to CN201810185296.7A priority Critical patent/CN108191349A/en
Publication of CN108191349A publication Critical patent/CN108191349A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of fillers of discarded underground people's air defense hole processing and preparation method thereof, and feature is made of following raw material and its weight number:40 60 parts of cement, 15 35 parts of solid waste, 0.5 2 parts of hydrophober, 0.1 0.3 parts of plasticiser, 0.05 0.5 parts of 21.5 36.5 parts of water and foaming agent, also disclose the preparation method of the filler, this method includes cement based sizing Concrete Mixing Station and prepares and transport, it is prepared by engineering site foam, cement based sizing is mixed with the scene of foam, advantage is to improve strength of filling mass, improve filling effect, effectively interference of the control to surrounding buildings, reduce construction environment pollution, maximally utilize solid waste, reduce filling cost, with very extensive application value.

Description

A kind of filler for being suitable for discarded underground people's air defense hole processing and preparation method thereof
Technical field
The invention belongs to underground engineering technical fields, are suitable for filling for discarded underground people's air defense hole processing more particularly, to a kind of Filling chock material and preparation method thereof.
Background technology
In sandstone industry, steel industry, a large amount of solid waste --- the mountain flour of mechanism sandstone production discharge and combustion The sintering desulfuration lime-ash of coal burning boiler discharge is all outdoor stockpiling mostly, not only occupied ground, but also can cause environmental pollution.This The processing and utilization of a little solid waste are the practical problems that must currently solve.
The end of the sixties, the beginning of the seventies, for the call of response " deep-cut hole, extensively store up grain, prepare against war and natural disasters ", China cities and towns start Build the mass movement in bomb shelter.The construction of these underground people's air defense holes is random very big, and quality is not also high, in addition older aging, greatly Approached is scrapped or has been scrapped more.At the same time, with the continuous propulsion of Development of China's Urbanization, it is difficult to avoid ground some buildings, Rail traffic main line and urban road pass through these discarded underground people's air defense holes, are controlled if not discarding underground people's air defense hole to these Reason, easily causes the serious consequences such as surface collapse.
Currently to the processing in discarded underground people's air defense hole, optionally use and beat digging up and filling in or using envelope storehouse method for strengthening or top Method for strengthening or placement method are supportted by bomb shelter packing, wherein the most extensive with placement method.Traditional filler is with sand, mixed Based on solidifying soil, mortar and cement base injection slurry.104099943 A of patent CN disclose " diaphram wall and discarded underground people's air defense Engineering intersects processing method ", wherein people's air defense both ends is taken to block the deeper people's air defense hole of buried depth, intermediate perfusion mortar blocks After hole backfill is closely knit, then the periphery soil body is further reinforced with high-pressure rotary jet grouting pile.103275460 A of patent CN disclose a kind of " people Anti- plugging material, subway people's air defense reserving hole plugging structure and method for blocking ", wherein people's air defense plugging material are used by asphalt mixtures modified by epoxy resin Fat, curing agent and building block filler hybrid modulation and cure, and subway people's air defense reserving hole plugging structure is reserved by being plugged in The high intensity plugging material at hole both ends and intermediate fire prevention calking are formed.However, underground people's air defense hole is mostly in main city zone traffic In the side ground of thoroughfare or residential building, it is necessary first to especially pay attention to disturbing influence of the filling construction to surrounding enviroment;Secondly, ground Narrow space in lower people's air defense hole, construction channel set up difficulty, and need to consider that obturation is subjected to underground water for a long time in military service process Immersion or drying and watering cycle.Thus, the above-mentioned published patent is not paid attention to filler and is filled out not fully for underground people's air defense hole feature Fill rate and durability.
Invention content
The technical problems to be solved by the invention be to provide a kind of good fluidity, pack effectiveness are high, durability is good, it is sharp useless and Neighboring buildings are disturbed with small filler for being suitable for discarded underground people's air defense hole processing and preparation method thereof.
Technical solution is used by the present invention solves above-mentioned technical problem:One kind is suitable for discarded underground people's air defense hole and handles Filler, be made of following raw material and its parts by weight:40-60 parts of cement, 15-35 parts of solid waste, hydrophober 0.05-0.5 parts of 0.6-2 parts, 0.1-0.3 parts of plasticiser, 21.5-59 parts of water and foaming agent.
The cement is not less than 42.5 grades of common portland cement for strength grade;The hydrophober is white powder Last shape calcium stearate;The plasticiser be solid content be 40% and water-reducing rate be more than 25% poly carboxylic acid series water reducer;It is described Foaming agent be commercially available composite foamable agent.
The solid waste for sintering desulfuration lime-ash either tufa stone original state mountain flour or by sintering desulfuration lime-ash and Tufa stone original state mountain flour is by the mixture that mass ratioes is waited to mix, the sintering desulfuration lime-ash and the tufa stone original state Mountain flour is the powder that 200 mesh percent of pass are more than 95%.
The sintering desulfuration lime-ash that the sintering desulfuration lime-ash is given off by steel industry;The tufa stone original state stone The tufa stone original state mountain flour that powder is discharged by mechanism sandstone industry,
The preparation method of the filler for being suitable for discarded underground people's air defense hole processing, includes the following steps:
(1)Cement based sizing prepares and transport:In parts by weight by 40-60 parts of cement, 15-35 parts of solid waste, hydrophober 20-35 parts of 0.5-2 parts, 0.1-0.3 parts of plasticiser and water mix in Concrete Mixing Station, and cement is made in stirring 3-5min After based sizing, transported using mortar stirring tank vehicle to discarded underground people's air defense hole engineering site, it is spare;
(2)It is prepared by engineering site foam:In discarded underground people's air defense hole, engineering site uses foaming machine compressed air, and will compression Air and frothing solution mixing, it is spare to be made foam, and wherein frothing solution composition is in parts by weight by 1.5 parts of water and foaming agent 0.05-0.5 parts are uniformly mixed formation;
(3)Cement based sizing is mixed with the scene of foam:It will(1)In step gained cement based sizing with(2)It is formed in step Foam uniformly mix, formed filler.
Compared with prior art, the advantage of the invention is that:
1st, strength of filling mass is improved, improves filling effect, improves durability, and effectively control the interference to surrounding buildings, 750 ~ 850kg/m of its dry density3, 28d intensity >=3MPa, water absorption rate≤20%, 28d coefficient of softing >=0.75, resisting erosion of sulfate Performance >=KS90, drying shrinkage value≤0.75mm/m;
2. reducing construction personnel in underground and the operation intensity of small space, security risk is reduced;
3. avoiding the mix of engineering site foam concrete siccative, dust emission in engineering is reduced;
4. tufa stone mountain flour that mechanism sandstone discharges, steel industry flue gas sintering desulfuration lime-ash are introduced into filler, it is Recycling for solid waste provides path, reduces the pollution of environment;And these solid waste have lateral reactivity, Activity activator method has thermal activation, chemical activation etc., and the present invention utilizes underground people's air defense hole enclosure space, the packing material prepared The characteristics of good heat preservation performance, carries out thermal activation, so as to not using hydrated cementitious accumulation heat in packing material to solid waste It needs in the case of additionally adding active stimulator, the heat thermal activation solid that hydrated cementitious is released when realizing engineering site filling gives up Gurry promotes solid waste activity;Meanwhile the expansion sources provided using desulfurization ash, under without using swelling agent, compensation is filled The contraction of body is filled out, raising connects top rate.
In conclusion a kind of filler for being suitable for discarded underground people's air defense hole processing of the present invention and preparation method thereof, knot Discarded underground people's air defense hole engineering characteristic is closed, the filler suitable for discarded underground people's air defense hole processing is had developed, reduces cement and use Amount largely dissolves solid waste, reduces filling cost, improves strength of filling mass, improves filling effect, promotes the resistance to of obturation Long property, effectively interference of the control to surrounding buildings, has very extensive application value.
Specific embodiment
The present invention is described in further detail with reference to embodiments.
In example below, common portland cement derives from Ningbo Shun Jiang Cement Co., Ltds;Tufa stone original state mountain flour It is built from Xiangshan along building stones Co., Ltd;Sintering desulfuration lime-ash derives from Ningbo Iron and Steel Co;Calcium stearate derives from Shanghai Bei Te Chemical Co., Ltd.s;Plasticiser derives from Ningbo Run Xin concrete admixtures Co., Ltd;Blowing agent source is in river The HTW-1 type composite foamable agents that building materials development corporation, Ltd. of Nanhua Thailand provides.
Embodiment 1
The present embodiment provides a kind of filler of discarded underground people's air defense hole processing and its weight fraction is:40 parts of cement is consolidated 35 parts of body waste, 0.6 part of hydrophober, 0.1 part of plasticiser, 21.5 parts of water, 0.05 part of foaming agent.
Above-mentioned cement is 42.5 Portland cements of P.O;
Gains of the sintering desulfuration lime-ash that above-mentioned solid waste is discharged by steel industry after ball mill grinding, 200 mesh Percent of pass is more than 95%;
Above-mentioned hydrophober living is commercially available calcium stearate, is white powder;
Above-mentioned plasticiser is poly carboxylic acid series water reducer, and solid content 40%, water-reducing rate is more than 25%;
Above-mentioned foaming agent is commercially available composite foamable agent.
The preparation method of discarded underground people's air defense hole filler described in the present embodiment, its step are as follows:
(1)Cement based sizing prepares and transport:By the cement of above-mentioned parts by weight, solid waste, hydrophober, plasticiser and water It mixed in Concrete Mixing Station, stir 3-5min, after cement based sizing is made, transported using mortar stirring tank vehicle to useless Underground people's air defense hole engineering site is abandoned, it is spare;
(2)It is prepared by engineering site foam:In discarded underground people's air defense hole, engineering site uses foaming machine(Such as HT-60 types, Henan China Safe new material Science and Technology Co., Ltd.)Compressed air, and compressed air is mixed with frothing solution, it is spare to be made foam, Middle frothing solution composition is to be uniformly mixed and form frothing solution 0.05 part of 1.5 parts of parts by weight water and foaming agent;
(3)Cement based sizing is mixed with the scene of foam:It will(1)In step gained cement based sizing with(2)It is formed in step Foam uniformly mix, formed filler.
Embodiment 2
With above-described embodiment 1, difference lies in:Filler and its weight fraction are:60 parts of cement, 15 parts of solid waste, 1.5 parts of hydrophober, 0.2 part of plasticiser, 26.5 parts of water, 0.2 part of foaming agent.Wherein solid waste is discharged for mechanism sandstone industry Acquisition object of the original state mountain flour after ball mill grinding, 200 mesh percent of pass are more than 95%.
Preparation methods steps(2)Middle frothing solution composition is, by the 0.2 part of mixing of 1.5 parts of parts by weight water and foaming agent It is formed uniformly frothing solution.
Embodiment 3
With above-described embodiment 1, difference lies in:Filler and its weight fraction are:50 parts of cement, 30 parts of solid waste, 2 parts of hydrophober, 0.3 part of plasticiser, 36.5 parts of water, 0.5 part of foaming agent.The burning that wherein solid waste is discharged by steel industry Tie desulfurization ash and the tufa stone original state mountain flour in parts by weight 1 of mechanism sandstone industry discharge:Through ball mill grinding after 1 mixing Gains, 200 mesh percent of pass are more than 95%;
Preparation methods steps(2)Middle frothing solution composition is to be uniformly mixed 0.3 part of 1.5 parts of parts by weight water and foaming agent Form frothing solution.
Experimental example
According to《Highway engineering foam concrete application technology specification》(DB33T996-2015), to filler of the invention Fluidity, wet density, dry density, 28d compression strength, water absorption rate and coefficient of softing are tested;It uses for reference《Normal concrete is long-term Performance and endurance quality experimental method standard》(GB/T 50082), resisting erosion of sulfate grade, dry contraction to filler Value is tested;The performance test results of above-described embodiment are as shown in the table:
Above description is not limitation of the present invention, and the present invention is also not limited to the example above.The art it is common Technical staff is in the essential scope of the present invention, the variations, modifications, additions or substitutions made, should also belong to the protection of the present invention Range.

Claims (5)

1. a kind of filler for being suitable for discarded underground people's air defense hole processing, it is characterised in that mainly by following raw material and its weight Number forms:40-60 parts of cement, 15-35 parts of solid waste, 0.6-2 parts of hydrophober, 0.1-0.3 parts of plasticiser, water 21.5- 59 parts and 0.05-0.5 parts of foaming agent.
2. a kind of filler for being suitable for discarded underground people's air defense hole processing according to claim 1, it is characterised in that:Institute The cement stated is not less than 42.5 grades of common portland cement for strength grade;The hydrophober is white powder stearic acid Calcium;The plasticiser be solid content be 40% and water-reducing rate be more than 25% poly carboxylic acid series water reducer;The foaming agent is Commercially available composite foamable agent.
3. a kind of filler for being suitable for discarded underground people's air defense hole processing according to claim 1, it is characterised in that:Institute The solid waste stated is sintering desulfuration lime-ash either tufa stone original state mountain flour or by sintering desulfuration lime-ash and tufa stone original state By the mixture that mass ratioes is waited to mix, the sintering desulfuration lime-ash and the tufa stone original state mountain flour are mountain flour 200 mesh percent of pass are more than 95% powder.
4. a kind of filler for being suitable for discarded underground people's air defense hole processing according to claim 3, it is characterised in that:Institute The sintering desulfuration lime-ash that the sintering desulfuration lime-ash stated is given off by steel industry;The tufa stone original state mountain flour is Machine-made Sand The tufa stone original state mountain flour that stone industry is discharged.
5. a kind of system of filler for being suitable for discarded underground people's air defense hole processing according to any one of claim 1-4 Preparation Method, it is characterised in that include the following steps:
(1)Cement based sizing prepares and transport:In parts by weight by 40-60 parts of cement, 15-35 parts of solid waste, hydrophober 20-35 parts of 0.5-2 parts, 0.1-0.3 parts of plasticiser and water mix in Concrete Mixing Station, and cement is made in stirring 3-5min After based sizing, transported using mortar stirring tank vehicle to discarded underground people's air defense hole engineering site, it is spare;
(2)It is prepared by engineering site foam:In discarded underground people's air defense hole, engineering site uses foaming machine compressed air, and will compression Air and frothing solution mixing, it is spare to be made foam, and wherein frothing solution composition is in parts by weight by 1.5 parts of water and foaming agent 0.05-0.5 parts are uniformly mixed formation;
(3)Cement based sizing is mixed with the scene of foam:It will(1)In step gained cement based sizing with(2)It is formed in step Foam uniformly mix, formed filler.
CN201810185296.7A 2018-03-07 2018-03-07 A kind of filler for being suitable for discarded underground people's air defense hole processing and preparation method thereof Pending CN108191349A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112851207A (en) * 2020-12-04 2021-05-28 广东盛瑞科技股份有限公司 Foam light soil material for waste civil air defense engineering and on-site preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5494514A (en) * 1994-06-14 1996-02-27 Goodson & Associates, Inc. Weather resistant soil cement
CN105000845A (en) * 2015-06-29 2015-10-28 河南华泰建材开发有限公司 Light foamed soil for abutment back backfilling and construction method
CN106746818A (en) * 2016-12-29 2017-05-31 宁波工程学院 A kind of concrete admixture, preparation method and the concrete containing the admixture

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5494514A (en) * 1994-06-14 1996-02-27 Goodson & Associates, Inc. Weather resistant soil cement
CN105000845A (en) * 2015-06-29 2015-10-28 河南华泰建材开发有限公司 Light foamed soil for abutment back backfilling and construction method
CN106746818A (en) * 2016-12-29 2017-05-31 宁波工程学院 A kind of concrete admixture, preparation method and the concrete containing the admixture

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112851207A (en) * 2020-12-04 2021-05-28 广东盛瑞科技股份有限公司 Foam light soil material for waste civil air defense engineering and on-site preparation method thereof

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Address after: 315016 Fenghua Road, Jiangbei District, Ningbo, Zhejiang 201

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Application publication date: 20180622