Invention content
The purpose of the present invention is intended to provide a kind of independent of the remote constant temperature transmission medical article of large-scale temperature control device energy
Storage device, to avoid need constant temperature store medical article occur quality change.
To achieve these goals, the present invention adopts the following technical scheme that:The present invention provides a kind of Medical constant-temperature storage dress
It puts, including device top and apparatus main body;Described device main body includes at least two layers of cavity housing, two layers of cavity housing
For the first cavity housing and the second cavity housing, above-mentioned housing is made of metal, and the metal is aluminium alloy or medical stainless steel;
The first cavity housing hollow cavity contains heat-storing material, and vacuum is set as in the second cavity housing hollow cavity;Described
There is insulating layer, the second cavity hull outside uses adhesive bonding or machinery with the insulating layer on the outside of two cavity housing hollows
Occlusion;The heat-storing material includes following raw material:Ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, it is above-mentioned
The content of raw material, in parts by weight, 20-30 parts, 5-10 parts, 50-60 parts, 15-20 parts, 25-35 parts, 25-40 parts;The gold
Category thickness is 0.2-1cm;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred at 70-80 DEG C
It mixes 30-50min and forms mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring must be mixed
Close object;C, polytetrafluoroethylene (PTFE) with said mixture is mixed, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;
D, again said mixture is entered to obtain the heat-storing material in zeolite by vacuum suction.
Since apparatus main body employs the structure of double-layer vacuum cavity housing and external setting insulating layer, heat-insulating property obtains
It is promoted to great, while apparatus main body is higher using metal structure intensity, and metallic walls are relatively thin also in the situation for ensuring intensity
Under mitigate installation weight, more particularly, the present invention adds heat-storing material in above-mentioned cavity, and above-mentioned heat-storing material
It is made of using paraffin composite phase change material, paraffin has the characteristics that phase-change accumulation energy in itself, that is, passes through the phase co-conversion of solid liquid phase
It completes energy storage and energy release process and maintains temperature in a certain range, but there is very big disadvantage as phase-change material using paraffin merely
End, heat conductivity is relatively low, and use temperature range is relatively narrow to have limitation, it turns by solid-liquid phase change repeatedly after long-time use
It changes and is susceptible to separation, and remain and cure, while its own can also volatilize with adhesions such as chamber walls, so as to go out energy storage material
It is now lost, reduces its service life, in order to overcome drawbacks described above, the application first avoids waving for heat-storing material using vacuum
Hair also improves the heat-proof quality with the external world, while addition mineral oil etc. improves its heat conductivity in paraffin, promotes the accumulation of heat
The efficiency of the thermal storage and energy accumulation of material also avoids the multi_layer extraction phenomenon occurred after paraffin cures repeatedly, additionally by using upper
Its use temperature range can be expanded by stating paraffin composite phase change material, and in order to avoid the adhesion with cavity wall, it is of the invention then with boiling
Masonry is carrier, has the characteristics that porous network structure using it, by heat-storing material absorption so as to effectively solve in zeolite
The problem of heat-storing material and the cavity wall of having determined easy adhesion, caused by avoiding the loss of heat-storing material after repeated use accumulation of heat store up
Can efficiency situation about being greatly reduced, the present invention determines the raw material of mentioned kind by research experiment repeatedly, with when technique and
Parameter.
Of the invention further preferably the modified processing of zeolite, the modification includes the following steps, a, by graphite
15-20 parts of alkene (by weight) adds in 100-150 parts of deionized water ultrasonic disperses, forms graphene dispersing solution;B, body is pressed again
Product ratio 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, and dipping temperature is Celsius for 40-55
Degree;C, drying and processing is finally carried out.
In use, inventor also found the accumulation of heat that the heat-conducting effect for further promoting zeolite can design the present invention
Material generates more excellent effect, through repeatedly practising and screen the final mode for determining the use of graphene dipping handle it is described
Zeolite support, graphene has excellent heat conductivity in itself, but graphene uniform disperses there are obstacle, therefore the present invention passes through
Dipping makes graphene uniform be attached in Zeolite support, and the intensity of zeolite and corrosion-resistant is also improved additionally by aforesaid way
Property, research experiment has obtained final material rate and technological parameter to inventor repeatedly.
Of the invention that two layers of cavity housing is further preferably included at least at the top of described device, above-mentioned housing is made of metal,
The metal is aluminium alloy or medical stainless steel, and two layers of cavity enclosure interior is set as vacuum.Or at the top of described device
Its structure and composition is identical with described device main body.In addition, article storage entrance of the present invention is as needed in addition to top is arranged on
It can also be arranged on the side wall of other positions such as apparatus main body.
In practical applications, storage device of the present invention can be placed in the place of article required temperature to be stored to storing
Hot material carries out energy storage, and when being detached from above-mentioned place, the heat-storing material in device is maintained by absorbing or releasing energy
Temperature in device is in relative constant state.
Of the invention further preferably the first cavity housing is to be flexibly connected with the second cavity housing, first sky
Cavity shell detachably takes out, and the energy storage of heat-storing material is realized by external heating or cold-storage.
Of the invention further preferred, storage device of the present invention further includes heating element or refrigeration part, above-mentioned component
It is preferred that it may be provided between the first cavity housing and the second cavity housing;It is preferred that the first cavity housing and the second cavity housing
In be provided with temperature sensor, temperature sensor is connected with heating element or refrigeration part;It is preferred that the storage device further includes
Electric energy provides component, and electric energy provides component and is connected with temperature sensor and heating element or refrigeration part, the electric energy offer portion
Part is external power supply socket or internal cell group interface.
By the additional equipment such as above-mentioned electric energy and sensor, apparatus of the present invention can the longer time the temperature maintained in device
In stable state.The sensor, heating element, power supply etc. can be used commercial product or obtained by the prior art.
Advantageous effect of the present invention
Apparatus of the present invention main body using double-layer vacuum cavity housing and external setting insulating layer structure, heat-insulating property and
Apparatus main body intensity is higher, and metallic walls are relatively thin to mitigate installation weight;The present invention can be in passive (situations such as i.e. unregulated power be supported
Under) under the conditions of maintain the temperature in device constant in a certain range in a long time, the present invention added in the cavity
Using heat-storing material made of paraffin composite phase change material, the efficiency of the thermal storage and energy accumulation of the heat-storing material is promoted, avoid
The multi_layer extraction phenomenon that paraffin occurs after curing repeatedly, expands its use temperature range, using zeolite as carrier, effectively solves
The problem of heat-storing material easy with cavity wall adhesion, avoid thermal storage and energy accumulation caused by the loss of heat-storing material after repeated use
The situation that efficiency is greatly reduced.In addition the present invention has made modification to zeolite, makes the carrier conductivity of heat durability of phase-change material
Deng be improved significantly, the application field of zeolite is also significantly widened after modification, in terms of the materials such as road, building, medical treatment
Application prospect is extensive.
Storage device using the present invention normal operation in 0-55 degree Celsius ranges can passively maintain its perseverance
Temperature-time is determined more than 100 hours, and the storage device of commercially available ordinary construction (there is heat insulation layer) is used to maintain constant temperature
Degree is then within 5 hours, and when temperature is there are during larger drop in ambient temperature and device, then apparatus of the present invention advantage is more
Significantly;If the present apparatus is provided with electric energy temperature control device simultaneously, constant temperature shape is remained in the case that power supply is continual
State, while apparatus structure of the present invention design is easy to be easy to maintain, raw material and manufacturing cost are relatively low.
Table one is apparatus of the present invention and the general device performance table of comparisons
| Thermal conductivity factor |
Using commercially available material/ordinary construction | More than 0.250W/ (mK) |
Using the application material/structure | 0.022-0.055W/(m·K) |
Embodiment 1:The storage device includes at the top of device and apparatus main body;Described device main body includes at least two layers of sky
Cavity shell, two layers of cavity housing are made of for the first cavity housing and the second cavity housing, above-mentioned housing metal, the gold
Belong to for aluminium alloy or medical stainless steel;The first cavity housing hollow cavity contains heat-storing material, in the second cavity housing
Vacuum is set as in cavity;There is insulating layer, the second cavity hull outside and the guarantor on the outside of the second cavity housing hollow
Warm layer uses adhesive bonding or mechanical snap;The heat-storing material, which uses, includes following raw material:Ethyl alcohol, deionized water, paraffin,
Mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 25 parts, 8 parts, 55 parts, 15 parts, 25 parts, 25
Part;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred 30-50min at 70-80 DEG C and is formed
Mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring obtains mixture;C, by poly- four
Vinyl fluoride is mixed with said mixture, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;It d, again will be above-mentioned mixed
Object is closed to enter to obtain the heat-storing material in zeolite by vacuum suction;The modified processing of zeolite, the modification include
Graphene 15-20 parts (by weight) a, is added in 100-150 parts of deionized water ultrasonic disperses, forms graphite by following steps
Alkene dispersion liquid;B, again by volume 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, dipping
Temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device thermal conductivity factor is 0.032 W/ (mK)..
Embodiment 2:The storage device it include at the top of device and apparatus main body;Described device main body includes at least two layers
Cavity housing, two layers of cavity housing are the first cavity housing and the second cavity housing, and above-mentioned housing is made of metal, described
Metal is aluminium alloy or medical stainless steel;The first cavity housing hollow cavity contains heat-storing material, the second cavity housing
Vacuum is set as in hollow cavity;There is insulating layer on the outside of the second cavity housing hollow, the second cavity hull outside with it is described
Insulating layer uses adhesive bonding or mechanical snap;The heat-storing material preferably includes following raw material:Ethyl alcohol, deionized water, stone
Wax, mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 20 parts, 5 parts, 60 parts, 15 parts, 25 parts,
30 parts;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred into 30-50min shapes at 70-80 DEG C
Resulting mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring obtains mixture;C, by poly- four
Vinyl fluoride is mixed with said mixture, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;It d, again will be above-mentioned mixed
Object is closed to enter to obtain the heat-storing material in zeolite by vacuum suction;The modified processing of zeolite, the modification include
Graphene 15-20 parts (by weight) a, is added in 100-150 parts of deionized water ultrasonic disperses, forms graphite by following steps
Alkene dispersion liquid;B, again by volume 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, leaching
Stain temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device thermal conductivity factor is 0.023W/ (mK).
Description of the invention and specific embodiment do not form limiting to the claimed invention, pass through routine techniques hand
The various changes of section should all be included in claim of the present invention.