CN108190255A - A kind of Medical constant-temperature storage device - Google Patents

A kind of Medical constant-temperature storage device Download PDF

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Publication number
CN108190255A
CN108190255A CN201810181758.8A CN201810181758A CN108190255A CN 108190255 A CN108190255 A CN 108190255A CN 201810181758 A CN201810181758 A CN 201810181758A CN 108190255 A CN108190255 A CN 108190255A
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parts
cavity housing
heat
storage device
zeolite
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CN201810181758.8A
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CN108190255B (en
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不公告发明人
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Anhui Wan Li Food LLC
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/38Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/06Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063Materials absorbing or liberating heat during crystallisation; Heat storage materials

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention is intended to provide a kind of Medical constant-temperature storage device, the storage device is mainly used for article such as drug that constant temperature is needed to store in medical space etc. or bioactive substance such as biological detection sample etc., it can maintain the constant temperature in storage device for a long time, from the variation and influence of ambient temperature, so as to ensure that deposit quality does not change, suitable for storage and long-distance transportation of medical article etc..First cavity housing hollow cavity of the storage device contains heat-storing material, and the heat-storing material includes following raw material:Ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite.

Description

A kind of Medical constant-temperature storage device
Technical field
The present invention or invention are related to a kind of Medical constant-temperature storage device, which is mainly used for needing in medical space Article such as drug of constant temperature storage etc. or bioactive substance such as biological detection sample etc., can maintain storage device for a long time Interior constant temperature, from the variation and influence of ambient temperature, so as to ensure that deposit quality does not change, suitable for doctor Treat storage and long-distance transportation of article etc..
Background technology
Medical article such as drug, bioactive substance (biological detection sample etc.) needs depositing in specific temperature all the time It can be played by, which being preserved under the conditions of storage, should have effect, but because ambient temperature variation often causes above-mentioned material to go bad Failure, and then influence its using effect or even poison.And current storing mode relies primarily on thermostatic chamber and is stored, i.e., it is logical Crossing the temperature control equipments such as air-conditioning makes interior be in opposite temperature constant state, but this mode is dependent on the large-scale temperature adjusting such as air-conditioning Equipment cost is higher, and in the case where lacking above-mentioned large-scale temperature control equipment and supporting, when in face of medical article road farther out Transhipment transport and during the not perfect situation of electric power facility, need the medical article that constant temperature is stored that can significantly rise in way risk, and By carrying the transport vehicle transports of temperature control equipment, cost is higher, and when have the feelings that can not use above-mentioned vehicle and equipment Condition occurs.It can be seen that a kind of storage device for breaking away from the large-scale temperature control device that places one's entire reliance upon at present of design can just solve the above problems, It needs a kind of the temperature of the maintenances store things of longer time to be in a perseverance under conditions of large-scale temperature control device is detached from Device in the range of constant temperature degree.
Invention content
The purpose of the present invention is intended to provide a kind of independent of the remote constant temperature transmission medical article of large-scale temperature control device energy Storage device, to avoid need constant temperature store medical article occur quality change.
To achieve these goals, the present invention adopts the following technical scheme that:The present invention provides a kind of Medical constant-temperature storage dress It puts, including device top and apparatus main body;Described device main body includes at least two layers of cavity housing, two layers of cavity housing For the first cavity housing and the second cavity housing, above-mentioned housing is made of metal, and the metal is aluminium alloy or medical stainless steel; The first cavity housing hollow cavity contains heat-storing material, and vacuum is set as in the second cavity housing hollow cavity;Described There is insulating layer, the second cavity hull outside uses adhesive bonding or machinery with the insulating layer on the outside of two cavity housing hollows Occlusion;The heat-storing material includes following raw material:Ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, it is above-mentioned The content of raw material, in parts by weight, 20-30 parts, 5-10 parts, 50-60 parts, 15-20 parts, 25-35 parts, 25-40 parts;The gold Category thickness is 0.2-1cm;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred at 70-80 DEG C It mixes 30-50min and forms mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring must be mixed Close object;C, polytetrafluoroethylene (PTFE) with said mixture is mixed, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture; D, again said mixture is entered to obtain the heat-storing material in zeolite by vacuum suction.
Since apparatus main body employs the structure of double-layer vacuum cavity housing and external setting insulating layer, heat-insulating property obtains It is promoted to great, while apparatus main body is higher using metal structure intensity, and metallic walls are relatively thin also in the situation for ensuring intensity Under mitigate installation weight, more particularly, the present invention adds heat-storing material in above-mentioned cavity, and above-mentioned heat-storing material It is made of using paraffin composite phase change material, paraffin has the characteristics that phase-change accumulation energy in itself, that is, passes through the phase co-conversion of solid liquid phase It completes energy storage and energy release process and maintains temperature in a certain range, but there is very big disadvantage as phase-change material using paraffin merely End, heat conductivity is relatively low, and use temperature range is relatively narrow to have limitation, it turns by solid-liquid phase change repeatedly after long-time use It changes and is susceptible to separation, and remain and cure, while its own can also volatilize with adhesions such as chamber walls, so as to go out energy storage material It is now lost, reduces its service life, in order to overcome drawbacks described above, the application first avoids waving for heat-storing material using vacuum Hair also improves the heat-proof quality with the external world, while addition mineral oil etc. improves its heat conductivity in paraffin, promotes the accumulation of heat The efficiency of the thermal storage and energy accumulation of material also avoids the multi_layer extraction phenomenon occurred after paraffin cures repeatedly, additionally by using upper Its use temperature range can be expanded by stating paraffin composite phase change material, and in order to avoid the adhesion with cavity wall, it is of the invention then with boiling Masonry is carrier, has the characteristics that porous network structure using it, by heat-storing material absorption so as to effectively solve in zeolite The problem of heat-storing material and the cavity wall of having determined easy adhesion, caused by avoiding the loss of heat-storing material after repeated use accumulation of heat store up Can efficiency situation about being greatly reduced, the present invention determines the raw material of mentioned kind by research experiment repeatedly, with when technique and Parameter.
Of the invention further preferably the modified processing of zeolite, the modification includes the following steps, a, by graphite 15-20 parts of alkene (by weight) adds in 100-150 parts of deionized water ultrasonic disperses, forms graphene dispersing solution;B, body is pressed again Product ratio 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, and dipping temperature is Celsius for 40-55 Degree;C, drying and processing is finally carried out.
In use, inventor also found the accumulation of heat that the heat-conducting effect for further promoting zeolite can design the present invention Material generates more excellent effect, through repeatedly practising and screen the final mode for determining the use of graphene dipping handle it is described Zeolite support, graphene has excellent heat conductivity in itself, but graphene uniform disperses there are obstacle, therefore the present invention passes through Dipping makes graphene uniform be attached in Zeolite support, and the intensity of zeolite and corrosion-resistant is also improved additionally by aforesaid way Property, research experiment has obtained final material rate and technological parameter to inventor repeatedly.
Of the invention that two layers of cavity housing is further preferably included at least at the top of described device, above-mentioned housing is made of metal, The metal is aluminium alloy or medical stainless steel, and two layers of cavity enclosure interior is set as vacuum.Or at the top of described device Its structure and composition is identical with described device main body.In addition, article storage entrance of the present invention is as needed in addition to top is arranged on It can also be arranged on the side wall of other positions such as apparatus main body.
In practical applications, storage device of the present invention can be placed in the place of article required temperature to be stored to storing Hot material carries out energy storage, and when being detached from above-mentioned place, the heat-storing material in device is maintained by absorbing or releasing energy Temperature in device is in relative constant state.
Of the invention further preferably the first cavity housing is to be flexibly connected with the second cavity housing, first sky Cavity shell detachably takes out, and the energy storage of heat-storing material is realized by external heating or cold-storage.
Of the invention further preferred, storage device of the present invention further includes heating element or refrigeration part, above-mentioned component It is preferred that it may be provided between the first cavity housing and the second cavity housing;It is preferred that the first cavity housing and the second cavity housing In be provided with temperature sensor, temperature sensor is connected with heating element or refrigeration part;It is preferred that the storage device further includes Electric energy provides component, and electric energy provides component and is connected with temperature sensor and heating element or refrigeration part, the electric energy offer portion Part is external power supply socket or internal cell group interface.
By the additional equipment such as above-mentioned electric energy and sensor, apparatus of the present invention can the longer time the temperature maintained in device In stable state.The sensor, heating element, power supply etc. can be used commercial product or obtained by the prior art.
Advantageous effect of the present invention
Apparatus of the present invention main body using double-layer vacuum cavity housing and external setting insulating layer structure, heat-insulating property and Apparatus main body intensity is higher, and metallic walls are relatively thin to mitigate installation weight;The present invention can be in passive (situations such as i.e. unregulated power be supported Under) under the conditions of maintain the temperature in device constant in a certain range in a long time, the present invention added in the cavity Using heat-storing material made of paraffin composite phase change material, the efficiency of the thermal storage and energy accumulation of the heat-storing material is promoted, avoid The multi_layer extraction phenomenon that paraffin occurs after curing repeatedly, expands its use temperature range, using zeolite as carrier, effectively solves The problem of heat-storing material easy with cavity wall adhesion, avoid thermal storage and energy accumulation caused by the loss of heat-storing material after repeated use The situation that efficiency is greatly reduced.In addition the present invention has made modification to zeolite, makes the carrier conductivity of heat durability of phase-change material Deng be improved significantly, the application field of zeolite is also significantly widened after modification, in terms of the materials such as road, building, medical treatment Application prospect is extensive.
Storage device using the present invention normal operation in 0-55 degree Celsius ranges can passively maintain its perseverance Temperature-time is determined more than 100 hours, and the storage device of commercially available ordinary construction (there is heat insulation layer) is used to maintain constant temperature Degree is then within 5 hours, and when temperature is there are during larger drop in ambient temperature and device, then apparatus of the present invention advantage is more Significantly;If the present apparatus is provided with electric energy temperature control device simultaneously, constant temperature shape is remained in the case that power supply is continual State, while apparatus structure of the present invention design is easy to be easy to maintain, raw material and manufacturing cost are relatively low.
Table one is apparatus of the present invention and the general device performance table of comparisons
Thermal conductivity factor
Using commercially available material/ordinary construction More than 0.250W/ (mK)
Using the application material/structure 0.022-0.055W/(m·K)
Description of the drawings
Below in conjunction with the drawings and the specific embodiments, the invention will be further described.
Fig. 1 is a kind of structure diagram of specific embodiment of the present invention.
In figure, 1 is at the top of device, 2 be the first cavity housing, and 3 be the second cavity housing, and 4 be apparatus main body.
In addition the other materials such as insulating layer in described device on the outside of heat-storing material and apparatus main body and structure in figure not It is shown specifically, above structure and material can be configured with reference to description according to the usual manner of this field.
Specific embodiment
Embodiment 1:The storage device includes at the top of device and apparatus main body;Described device main body includes at least two layers of sky Cavity shell, two layers of cavity housing are made of for the first cavity housing and the second cavity housing, above-mentioned housing metal, the gold Belong to for aluminium alloy or medical stainless steel;The first cavity housing hollow cavity contains heat-storing material, in the second cavity housing Vacuum is set as in cavity;There is insulating layer, the second cavity hull outside and the guarantor on the outside of the second cavity housing hollow Warm layer uses adhesive bonding or mechanical snap;The heat-storing material, which uses, includes following raw material:Ethyl alcohol, deionized water, paraffin, Mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 25 parts, 8 parts, 55 parts, 15 parts, 25 parts, 25 Part;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred 30-50min at 70-80 DEG C and is formed Mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring obtains mixture;C, by poly- four Vinyl fluoride is mixed with said mixture, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;It d, again will be above-mentioned mixed Object is closed to enter to obtain the heat-storing material in zeolite by vacuum suction;The modified processing of zeolite, the modification include Graphene 15-20 parts (by weight) a, is added in 100-150 parts of deionized water ultrasonic disperses, forms graphite by following steps Alkene dispersion liquid;B, again by volume 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, dipping Temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device thermal conductivity factor is 0.032 W/ (mK)..
Embodiment 2:The storage device it include at the top of device and apparatus main body;Described device main body includes at least two layers Cavity housing, two layers of cavity housing are the first cavity housing and the second cavity housing, and above-mentioned housing is made of metal, described Metal is aluminium alloy or medical stainless steel;The first cavity housing hollow cavity contains heat-storing material, the second cavity housing Vacuum is set as in hollow cavity;There is insulating layer on the outside of the second cavity housing hollow, the second cavity hull outside with it is described Insulating layer uses adhesive bonding or mechanical snap;The heat-storing material preferably includes following raw material:Ethyl alcohol, deionized water, stone Wax, mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 20 parts, 5 parts, 60 parts, 15 parts, 25 parts, 30 parts;The preparation of the heat-storing material, includes the following steps:A, ethyl alcohol, deionized water are stirred into 30-50min shapes at 70-80 DEG C Resulting mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring obtains mixture;C, by poly- four Vinyl fluoride is mixed with said mixture, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;It d, again will be above-mentioned mixed Object is closed to enter to obtain the heat-storing material in zeolite by vacuum suction;The modified processing of zeolite, the modification include Graphene 15-20 parts (by weight) a, is added in 100-150 parts of deionized water ultrasonic disperses, forms graphite by following steps Alkene dispersion liquid;B, again by volume 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, and dip time is 15-20 hours, leaching Stain temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device thermal conductivity factor is 0.023W/ (mK).
Description of the invention and specific embodiment do not form limiting to the claimed invention, pass through routine techniques hand The various changes of section should all be included in claim of the present invention.

Claims (3)

1. a kind of Medical constant-temperature storage device, it is characterised in that:It includes at the top of device and apparatus main body;Described device main body is extremely Include two layers of cavity housing less, two layers of cavity housing is the first cavity housing and the second cavity housing, and above-mentioned housing is by gold Belong to and forming, the metal is aluminium alloy or medical stainless steel;The first cavity housing hollow cavity contains heat-storing material, and described Vacuum is set as in two cavity housing hollow cavities;There is insulating layer, the second cavity housing on the outside of the second cavity housing hollow Outside uses adhesive bonding or mechanical snap with the insulating layer;The heat-storing material preferably includes following raw material:Ethyl alcohol is gone Ionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 20-30 parts, 5-10 parts, 50-60 parts, 15-20 parts, 25-35 parts, 25-40 parts.
2. a kind of Medical constant-temperature storage device according to claim 1, it is characterised in that:The preparation of the heat-storing material, Include the following steps:A, ethyl alcohol, deionized water are stirred into 30-50min at 70-80 DEG C and forms mixture;B, by paraffin and mineral After oil mixing, 60~75 DEG C are warming up to, 40~60min of stirring obtains mixture;C, polytetrafluoroethylene (PTFE) is mixed with said mixture, 75~85 DEG C are continuously heating to, 40~60min of stirring obtains mixture;D, said mixture is entered by vacuum suction in zeolite again Obtain the heat-storing material.
3. a kind of Medical constant-temperature storage device according to claim 1 or 2, it is characterised in that:The modified place of zeolite Reason, the modification include the following steps, graphene 15-20 parts (by weight) a, is added in 100-150 parts of deionizations Water ultrasonic disperse forms graphene dispersing solution;B, again by volume 1:2 are immersed in the zeolite in above-mentioned dispersion liquid, dipping Time is 15-20 hours, and dipping temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.
CN201810181758.8A 2018-03-07 2018-03-07 A kind of Medical constant-temperature storage device Active CN108190255B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113375492A (en) * 2021-05-31 2021-09-10 中国科学院理化技术研究所 Vacuum heat-insulation type heat storage/cooling device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202115883U (en) * 2011-07-01 2012-01-18 中国人民解放军军事医学科学院卫生装备研究所 Heat-insulation box for field operations
CN102381520A (en) * 2011-10-08 2012-03-21 大连海事大学 Passive constant temperature system applied to thermal-insulating container
CN105462381A (en) * 2015-12-03 2016-04-06 苏州科技学院 Temperature and humidity regulating type composite coating material and preparation method thereof
US20160262979A1 (en) * 2013-05-16 2016-09-15 Sandy Wengreen Storage systems and methods for medicines
CN206528842U (en) * 2016-12-29 2017-09-29 中原工学院 A kind of peasant household open air multifunction constant temperature case

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202115883U (en) * 2011-07-01 2012-01-18 中国人民解放军军事医学科学院卫生装备研究所 Heat-insulation box for field operations
CN102381520A (en) * 2011-10-08 2012-03-21 大连海事大学 Passive constant temperature system applied to thermal-insulating container
US20160262979A1 (en) * 2013-05-16 2016-09-15 Sandy Wengreen Storage systems and methods for medicines
CN105462381A (en) * 2015-12-03 2016-04-06 苏州科技学院 Temperature and humidity regulating type composite coating material and preparation method thereof
CN206528842U (en) * 2016-12-29 2017-09-29 中原工学院 A kind of peasant household open air multifunction constant temperature case

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113375492A (en) * 2021-05-31 2021-09-10 中国科学院理化技术研究所 Vacuum heat-insulation type heat storage/cooling device
CN113375492B (en) * 2021-05-31 2022-04-22 中国科学院理化技术研究所 Vacuum heat-insulation type heat storage/cooling device

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