Summary of the invention
The purpose of the present invention is intended to provide a kind of independent of the remote constant temperature transmission medical article of large-scale temperature control device energy
Storage device, to avoid need constant temperature store medical article occur quality change.
To achieve the goals above, the present invention adopts the following technical scheme: the present invention provide it is a kind of with fire-proof function
Medical constant-temperature storage device comprising device top and apparatus main body;Described device main body includes at least two layers of cavity shell, institute
Stating two layers of cavity shell is that the first cavity shell and the second cavity shell, above-mentioned shell consist of metal, and the metal is aluminium conjunction
Gold or medical stainless steel;The first cavity shell hollow cavity contains heat-storing material, sets in the second cavity shell hollow cavity
It is set to vacuum;There is insulating layer, the second cavity hull outside and the insulating layer use on the outside of the second cavity housing hollow
Adhesive bonding or mechanical snap;Further include fireprotection layer outside the insulating layer, fire proofing firbre cloth and stone are contained in the fireprotection layer
Ink uses adhesive bonding or mechanical snap between insulating layer and fireprotection layer.
The heat-storing material includes following raw material: ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, on
The content of raw material is stated, in parts by weight, 20-30 parts, 5-10 parts, 50-60 parts, 15-20 parts, 25-35 parts, 25-40 parts;The gold
Belong to a thickness of 0.2-1cm.The preparation of the heat-storing material includes the following steps: a, stirs ethyl alcohol, deionized water at 70-80 DEG C
It mixes 30-50min and forms mixture;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, 40~60min of stirring must be mixed
Close object;C, polytetrafluoroethylene (PTFE) is mixed with said mixture, is continuously heating to 75~85 DEG C, 40~60min of stirring obtains mixture;
D, again said mixture is entered to obtain the heat-storing material in zeolite by vacuum suction.
Since apparatus main body uses the structure of double-layer vacuum cavity shell and external setting insulating layer, thermal insulation property is obtained
It is promoted to great, while apparatus main body is higher using metal structure intensity, and metallic walls are relatively thin also the case where ensuring intensity
Under mitigate installation weight, more particularly, the present invention joined heat-storing material in above-mentioned cavity, and above-mentioned heat-storing material
It is made of using paraffin composite phase change material, paraffin itself has the characteristics that phase-change accumulation energy, that is, passes through the phase co-conversion of solid liquid phase
It completes energy storage and energy release process and maintains temperature in a certain range, but there is very big disadvantage as phase-change material using paraffin merely
End, heat conductivity is lower, and use temperature range is relatively narrow to have limitation, it turns by solid-liquid phase change repeatedly after long-time use
It changes and is easy to appear separation, and remain and solidify with adhesions such as chamber walls, while its own can also volatilize, so that energy storage material be made to go out
It is now lost, reduces its service life, in order to overcome drawbacks described above, the application first avoids waving for heat-storing material using vacuum
Hair also improves the heat-proof quality with the external world, while addition mineral oil etc. improves its heat conductivity in paraffin, promotes the accumulation of heat
The efficiency of the thermal storage and energy accumulation of material also avoids the multi_layer extraction phenomenon occurred after paraffin solidifies repeatedly, additionally by using upper
Its use temperature range can be expanded by stating paraffin composite phase change material, and in order to avoid the adhesion with cavity wall, the present invention is then with boiling
Masonry is carrier, has the characteristics that porous network structure using it, and the heat-storing material is adsorbed in zeolite effectively to solve
Determined heat-storing material and cavity wall easy adhesion the problem of, accumulation of heat is stored up caused by avoiding the loss of heat-storing material after repeated use
Can efficiency the case where being greatly reduced, the present invention determined the raw material of mentioned kind by research experiment repeatedly, match when technique and
Parameter.The present invention is due to being provided with fireprotection layer structure it is possible to prevente effectively from storage article is damaged in the case where the fortuitous events such as fire occur
The appearance loss, while the thermal insulation property that fireprotection layer itself also has certain heat-blocking action to can be further improved device.
The present invention is further preferred, and the modified processing of zeolite, the modification includes the following steps, a, by graphite
100-150 parts of deionized water ultrasonic disperses are added in 15-20 parts of alkene (by weight), form graphene dispersing solution;B, body is pressed again
The zeolite is immersed in above-mentioned dispersion liquid by product than 1:2, and dip time is 15-20 hours, and dipping temperature is that 40-55 is Celsius
Degree;C, drying and processing is finally carried out.
In use, inventor also found the accumulation of heat that the heat-conducting effect for further promoting zeolite can design the present invention
Material generates more excellent effect, through repeatedly practising and screen finally determine the use of graphene dipping mode handle it is described
Zeolite support, graphene itself has excellent heat conductivity, but there are obstacles for graphene uniform dispersion, therefore the present invention passes through
Dipping is attached to graphene uniform in Zeolite support, also improves the intensity of zeolite and corrosion-resistant additionally by aforesaid way
Property, research experiment has obtained final material rate and technological parameter to inventor repeatedly.
The present invention is further preferred, and two layers of cavity shell is included at least at the top of described device, and above-mentioned shell consists of metal,
The metal is aluminium alloy or medical stainless steel, and two layers of cavity enclosure interior is set as vacuum.Or at the top of described device
Its structure and composition is identical as described device main body.In addition, article storage entrance of the present invention is as needed in addition to top except being arranged
Also it can be set on the side wall of other positions such as apparatus main body.
In practical applications, storage device of the present invention can be placed in the place of article required temperature to be stored to storage
Hot material carries out energy storage, and when being detached from above-mentioned place, the heat-storing material in device is maintained by absorbing or releasing energy
Temperature in device is in relative constant state.
The present invention is further preferred, and the first cavity shell is to be flexibly connected with the second cavity shell, and described first is empty
Cavity shell detachably takes out, and the energy storage of heat-storing material is realized by external heating or cold-storage.
The present invention is further preferred, and storage device of the present invention further includes heating element or refrigeration part, above-mentioned component
It is preferred that may be provided between the first cavity shell and the second cavity shell;It is preferred that the first cavity shell and the second cavity shell
In be provided with temperature sensor, temperature sensor is connected with heating element or refrigeration part;It is preferred that the storage device further includes
Electric energy provides component, and electric energy provides component and is connected with temperature sensor and heating element or refrigeration part, electric energy offer portion
Part is external power supply socket or internal cell group interface.
By adding the equipment such as above-mentioned electric energy and sensor, apparatus of the present invention can the longer time the temperature maintained in device
In stable state.The sensor, heating element, power supply etc. can be used commercial product or obtained by the prior art
Beneficial effect of the present invention
Apparatus of the present invention main body using double-layer vacuum cavity shell and external setting insulating layer structure, thermal insulation property and
Apparatus main body intensity is higher, and metallic walls are relatively thin to mitigate installation weight;The present invention can be in passive (situations such as i.e. unregulated power be supported
Under) under the conditions of maintain the temperature in device constant in a certain range in a long time, the present invention is added in the cavity
Using heat-storing material made of paraffin composite phase change material, the efficiency of the thermal storage and energy accumulation of the heat-storing material is promoted, avoids
The multi_layer extraction phenomenon that paraffin occurs after solidifying repeatedly, expands its use temperature range, using zeolite as carrier, effectively solves
The problem of heat-storing material and cavity wall easy adhesion, avoid thermal storage and energy accumulation caused by the loss of heat-storing material after repeated use
The case where efficiency is greatly reduced.In addition the present invention has made modification to zeolite, makes the carrier conductivity of heat durability of phase-change material
Deng be improved significantly, the application field of zeolite is also obviously widened after modification, in terms of the materials such as road, building, medical treatment
Application prospect is extensive.
It is operated normally in 0-55 degree Celsius range using storage device of the invention, can passively maintain its perseverance
Determining temperature-time is more than 100 hours, and the storage device of commercially available ordinary construction (with heat insulation layer) is used to maintain constant temperature
Degree is then within 5 hours, and when temperature is there are when larger drop in ambient temperature and device, then apparatus of the present invention advantage is more
Obviously;If the present apparatus is provided with electric energy temperature control device simultaneously, constant temperature shape can be remained in the continual situation of power supply
State, while apparatus structure of the present invention design is easy to be easy to maintain, raw material and preparation cost are relatively low.Table one is the present invention
Device and the general device performance table of comparisons
|
Thermal coefficient |
Using commercially available material/ordinary construction |
Greater than 0.250W/ (mK) |
Using the application material/structure |
0.020-0.050W/(m·K) |
Embodiment 1: the storage device includes device top and apparatus main body;Described device main body includes at least two layers of sky
Cavity shell, two layers of cavity shell are that the first cavity shell and the second cavity shell, above-mentioned shell consist of metal, the gold
Belong to is aluminium alloy or medical stainless steel;The first cavity shell hollow cavity contains heat-storing material, in the second cavity shell
Vacuum is set as in cavity;There is insulating layer, the second cavity hull outside and the guarantor on the outside of the second cavity housing hollow
Warm layer uses adhesive bonding or mechanical snap;It further include fireprotection layer outside the insulating layer, it is fine containing fire prevention in the fireprotection layer
Wei Bu and graphite use adhesive bonding or mechanical snap between insulating layer and fireprotection layer;The heat-storing material use including with
Lower raw material: ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight, 25
Part, 8 parts, 55 parts, 15 parts, 25 parts, 25 parts;The preparation of the heat-storing material includes the following steps: a, by ethyl alcohol, deionized water
Mixture is formed in 70-80 DEG C of stirring 30-50min;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, stirring 40
~60min obtains mixture;C, polytetrafluoroethylene (PTFE) is mixed with said mixture, is continuously heating to 75~85 DEG C, stirring 40~
60min obtains mixture;D, again said mixture is entered to obtain the heat-storing material in zeolite by vacuum suction;The zeolite warp
Modification, the modification include the following steps, a, are added 100-150 parts for 15-20 parts of graphene (by weight)
Deionized water ultrasonic disperse forms graphene dispersing solution;B, the zeolite is immersed in above-mentioned dispersion liquid by 1:2 by volume again
In, dip time is 15-20 hours, and dipping temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device is thermally conductive
Coefficient is 0.028W/ (mK).
Embodiment 2: the storage device it include at the top of device and apparatus main body;Described device main body includes at least two layers
Cavity shell, two layers of cavity shell are the first cavity shell and the second cavity shell, and above-mentioned shell consists of metal, described
Metal is aluminium alloy or medical stainless steel;The first cavity shell hollow cavity contains heat-storing material, the second cavity shell
Vacuum is set as in hollow cavity;There is insulating layer on the outside of the second cavity housing hollow, the second cavity hull outside with it is described
Insulating layer uses adhesive bonding or mechanical snap;Further include fireprotection layer outside the insulating layer, fire prevention is contained in the fireprotection layer
Fiber cloth and graphite use adhesive bonding or mechanical snap between insulating layer and fireprotection layer;The heat-storing material preferably includes
Following raw material: ethyl alcohol, deionized water, paraffin, mineral oil, polytetrafluoroethylene (PTFE), zeolite, the content of above-mentioned raw materials in parts by weight,
20 parts, 5 parts, 60 parts, 15 parts, 25 parts, 30 parts;The preparation of the heat-storing material includes the following steps: a, by ethyl alcohol, deionization
Water forms mixture in 70-80 DEG C of stirring 30-50min;B, 60~75 DEG C after paraffin and mineral oil, will be warming up to, stirring
40~60min obtains mixture;C, polytetrafluoroethylene (PTFE) is mixed with said mixture, is continuously heating to 75~85 DEG C, stirring 40~
60min obtains mixture;D, again said mixture is entered to obtain the heat-storing material in zeolite by vacuum suction;The zeolite warp
Modification, the modification include the following steps, a, are added 100-150 parts for 15-20 parts of graphene (by weight)
Deionized water ultrasonic disperse forms graphene dispersing solution;B, the zeolite is immersed in above-mentioned dispersion liquid by 1:2 by volume again
In, dip time is 15-20 hours, and dipping temperature is 40-55 degrees Celsius;C, drying and processing is finally carried out.Described device is thermally conductive
Coefficient is 0.021W/ (mK).
Description of the invention and specific embodiment do not constitute limiting to the claimed invention, pass through routine techniques hand
The various changes of section should all be included in claim of the present invention.