CN108189518A - Graphene electromagnetic shield cloth and its manufacturing method - Google Patents
Graphene electromagnetic shield cloth and its manufacturing method Download PDFInfo
- Publication number
- CN108189518A CN108189518A CN201711480538.7A CN201711480538A CN108189518A CN 108189518 A CN108189518 A CN 108189518A CN 201711480538 A CN201711480538 A CN 201711480538A CN 108189518 A CN108189518 A CN 108189518A
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- cloth
- graphene
- layer
- adhesive film
- composite material
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- 239000004744 fabric Substances 0.000 title claims abstract description 183
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 124
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 123
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 27
- 239000002313 adhesive film Substances 0.000 claims abstract description 70
- 239000002131 composite material Substances 0.000 claims abstract description 59
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910052802 copper Inorganic materials 0.000 claims abstract description 40
- 239000010949 copper Substances 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 26
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005751 Copper oxide Substances 0.000 claims abstract description 20
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 5
- 238000005488 sandblasting Methods 0.000 claims abstract description 4
- 230000003746 surface roughness Effects 0.000 claims abstract description 4
- 239000000853 adhesive Substances 0.000 claims description 40
- 230000001070 adhesive effect Effects 0.000 claims description 40
- 229920000642 polymer Polymers 0.000 claims description 35
- 238000007731 hot pressing Methods 0.000 claims description 22
- 230000005298 paramagnetic effect Effects 0.000 claims description 18
- 239000002105 nanoparticle Substances 0.000 claims description 17
- 239000013528 metallic particle Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000010451 perlite Substances 0.000 claims description 10
- 235000019362 perlite Nutrition 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 238000004026 adhesive bonding Methods 0.000 claims description 3
- 238000005422 blasting Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- -1 graphite Alkene Chemical class 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000002585 base Substances 0.000 description 21
- 238000012360 testing method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 9
- 229920000914 Metallic fiber Polymers 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 229940112669 cuprous oxide Drugs 0.000 description 2
- 230000005291 magnetic effect Effects 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002739 metals Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
- B32B37/1018—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/087—Oxides of copper or solid solutions thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
- C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/212—Electromagnetic interference shielding
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Laminated Bodies (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Abstract
The invention discloses a kind of graphene electromagnetic shield cloth and its manufacturing methods,The electromagnetic shield cloth from bottom to top includes preventing puncturing layer successively,Base cloth layer,Copper oxide,Layers of copper,First adhesive film,First graphene composite material layer of cloth,Second adhesive film and the second graphene composite material layer of cloth,Base cloth layer is blended cloth,First adhesive film and the second adhesive film include graphene powder,The resistance value of first graphene composite material layer of cloth is more than the resistance value of the second graphene composite material layer of cloth,The resistance value of first adhesive film is more than the resistance value of second adhesive film,The resistance value and the resistance value of the first adhesive film of first graphene composite material layer of cloth are essentially identical,The resistance value and the resistance value of the second adhesive film of second graphene composite material layer of cloth are essentially identical,Layers of copper passes through surface sand-blasting process,Its surface roughness is more than Ra0.05.Graphene electromagnetic shield cloth shield effectiveness of the invention is good, durability is good, while excellent in mechanical performance, use scope are wide.
Description
Technical field
The present invention relates to a kind of electromagnetic shield cloth and its manufacturing method, more particularly to a kind of graphene electromagnetic shield cloth and its
Manufacturing method.
Background technology
Electromagnetic shield cloth is actually a kind of product of comparative maturity, and the popular electromagnetic shield cloth of existing market is divided into
Two kinds of metallic fiber and silver fiber, it by diameter is about 0.008 millimeter that cloth, which is, wherein used by metallic fiber electromagnetic shield cloth
Metallic fiber (metallic fiber for containing 8 or so per wires) and cotton etc. is blended is made into, can be to 100-3000MHz
Electromagnetic wave within (civilian common frequency) is effectively shielded, and shielding rate is at 30 decibels or so.This cloth not only has good
Good gas permeability, but also can wash, it is current most practical domestic electromagnetic shielding cloth fabric.Also it is exactly silver fiber,
This cloth, which employs silver-plated technology, makes silver fiber well and the fusion of other fibers (cotton, terylene etc.), and it is fine not only to have metal
The advantages of tieing up cloth, and quality is more soft.But this two type shieldings cloth there is also it is very big the defects of, both shielding cloth power
Poor performance, not acid and alkali-resistance, non-refractory are learned, so, when using this two type shieldings cloth, it is impossible to fold shielding cloth, cannot approach
Chemical reagent, need far from acid or alkali environment, will be far from high temperature source.So this very harsh use condition determines this screen
It covers cloth and is only used for civil field, in industrial circle and military field, this shielding cloth is no any use.
Also there are other types of shielding cloths, such as existing technical literature CN106567178A in the prior art to disclose one
Kind Multifunctional electromagnetic shielding cloth, this shielding cloth uses stainless steel fibre instead of silver fiber, but actually this electromagnetic screen
Cover the cloth still shielding cloth based on metallic fiber, so this shielding cloth is not still resistant to bending, and its capability of electromagnetic shielding compared with
Difference, it is impossible to meet the needs of certain special dimensions.For another example existing technical literature CN205522734U discloses a kind of electromagnetic shielding
Cloth, this electromagnetic shield cloth has been abandoned metallic fiber and the blended preparation method of other organic fibers, in electromagnetic shield cloth
Be individually added into one layer of metallic fibrous layer, even if but carried out this transformation, the metallic fibrous layer still not bend resistance, and by
It is non-conductive in the surface of this shielding cloth, so shield effectiveness is poor.For another example existing technical literature CN2720576Y discloses one
Kind electromagnetic shield cloth, this electromagnetic shield cloth do not use metallic fiber, are changed to using electrodeposition of metals, so overcoming metal fibre
The defects of dimension is not resistant to bending, but the prior art is the plating metal multilayer film directly in base fabric, so metal film and base fabric
Between binding force it is poor, due to the difference of lattice structure between metal film, the defects of there is also force difference is combined, and base fabric belongs to
How rough surface ensures that plating is still uniformly insoluble problem.So this shielding cloth due to coating not
Uniformly, cause shield effectiveness poor, and due to combining force difference between film layer, so durability is poor.
The information for being disclosed in the background technology part is merely intended to increase the understanding of the general background to the present invention, without answering
When being considered as recognizing or imply that information composition has been the prior art well known to persons skilled in the art in any form.
Invention content
The purpose of the present invention is to provide a kind of graphene electromagnetic shield cloth, the shortcomings that so as to overcome the prior art.
To achieve the above object, the present invention provides a kind of graphene electromagnetic shield cloth, electromagnetic shield cloth from bottom to top according to
It is secondary to puncture layer, base cloth layer, copper oxide, layers of copper, the first adhesive film, the first graphene composite material layer of cloth, the second glue including anti-
Film layer and the second graphene composite material layer of cloth, base cloth layer are blended cloths, and the first adhesive film and the second adhesive film include stone
Black alkene powder, the resistance value of the first graphene composite material layer of cloth are more than the resistance value of the second graphene composite material layer of cloth, the
The resistance value of one adhesive film is more than the resistance value of the second adhesive film, resistance value and the first glue of the first graphene composite material layer of cloth
The resistance value of film layer is essentially identical, the resistance value of the second graphene composite material layer of cloth and the basic phase of resistance value of the second adhesive film
Together, layers of copper passes through surface sand-blasting process, and the surface roughness of layers of copper is more than Ra0.05.
Preferably, in above-mentioned technical proposal, base cloth layer is the blended cloth of aramid fiber and Fypro.
Preferably, in above-mentioned technical proposal, the anti-layer that punctures is glass fabric, and the thickness of glass fabric is 1-5mm.
Preferably, in above-mentioned technical proposal, by weight, the first adhesive film and the second adhesive film respectively include graphite
1-10 parts of alkene powder, 1-10 parts of perlite powder, 40-60 parts of solvent, 20-80 parts of thermoplastic polymer adhesive, amorphous
1-10 parts of state paramagnetic nanoparticles metallic particles, the first adhesive film are different from the ingredient of the second adhesive film.
Preferably, in above-mentioned technical proposal, the first graphene composite material layer of cloth is the first graphene polymer glue of dipping
The glass fabric of glutinous agent, by weight, the first graphene polymer adhesive includes 1-10 parts of graphene powder, solvent
40-60 parts, 20-80 parts of polymer adhesive, 1-10 parts of amorphous state paramagnetic nanoparticles metallic particles.
Preferably, in above-mentioned technical proposal, the second graphene composite material layer of cloth is the second graphene polymer glue of dipping
The glass fabric of glutinous agent, by weight, the second graphene polymer adhesive includes 1-10 parts of graphene powder, solvent
40-60 parts, 20-80 parts of polymer adhesive, 1-10 parts of amorphous state paramagnetic nanoparticles metallic particles, wherein, the second graphene gathers
The ingredient for closing object adhesive is different from the ingredient of the first graphene polymer adhesive.
Preferably, in above-mentioned technical proposal, the thickness of copper oxide is 20-50nm.
The present invention also provides a kind of manufacturing method of graphene electromagnetic shield cloth, which includes：Prepare anti-puncture
Layer and base cloth layer；Non-conductive adhesive is coated on layer in anti-puncture, then base cloth layer is layed in and prevents puncturing on layer, with laggard
Row hot-pressing processing obtains first layer stack；Using magnetically controlled sputter method in first layer stack deposited oxide layers of copper；Utilize magnetic control
Sputtering method copper layer on copper oxide, and blasting treatment is carried out to the layers of copper, obtain the second laminated body；Prepare first
Graphene composite material layer of cloth and the second graphene composite material layer of cloth：Various raw materials are put into instead first, in accordance with material rate
Answer in kettle, be then stirred, it is to be mixed uniformly after, graphene polymer adhesive is obtained, then by graphene polymer glue
Glutinous agent is poured into dipping tank, and glass fibre is arranged in dipping tank and is impregnated；Prepare the first adhesive film and the second adhesive film；By suitable
Sequence stacks the second laminated body, the first adhesive film, the first graphene composite material layer of cloth, the second adhesive film and the second graphene and answers
Condensation material layer of cloth obtains stacked body, and then stacked body is put into vacuum hotpressing machine and carries out hot pressing, which includes four ranks
Section, wherein, first stage temperature is 100-150 DEG C, pressure 5-10MPa, duration 10-30s, and second stage temperature is
200-300 DEG C, pressure 10-20MPa, duration 10-20min, phase III temperature is 100-200 DEG C, pressure 10-
20MPa, duration 3-5min, fourth stage temperature are 50-70 DEG C, pressure 5-10MPa, duration 3-5min,
Obtain graphene electromagnetic shield cloth.
Preferably, in above-mentioned technical proposal, the thickness of copper oxide is 20-50nm.
Preferably, in above-mentioned technical proposal, the thickness of layers of copper is 100-200nm.
Compared with prior art, the present invention has the advantages that：
1st, the present invention deposits one layer of copper oxide on base cloth layer, and inventor has found that the binding force of copper oxide and base cloth layer is big
In layers of copper and the binding force of base cloth layer, and the lattice structure similarity of copper oxide and copper is higher, so boundary therebetween
Face residual stress is smaller, thus solves the defects of metal layer is with base cloth layer combination force difference in the prior art；2nd, inventor has found,
When wave frequency is higher, the vortex that shielding cloth generates concentrates on shielding cloth outer layer, and outer layer resistance value is set as smaller value,
It can so that outer layer eddy-current loss is larger, enhance effectiveness.By the resistance value of middle layer graphene composite material layer of cloth
Be designed as it is relatively low can stop that vortex passes through material interface, so as to which effectiveness be prevented to be deteriorated, simultaneously because middle layer stone
The resistance value of black alkene composite material layer of cloth can be relatively low, so middle layer graphene composite material layer of cloth can be including more non-
Conductive particles so that the mechanical property of middle layer graphene composite material layer of cloth is stronger；3rd, in the first adhesive film, the first graphene
Amorphous state paramagnetic nanoparticles metal is added in composite material layer of cloth, the second adhesive film and the second graphene composite material layer of cloth
Grain can effectively reduce the resistance value of above layers, simultaneously because the specific surface area of amorphous nano particle is larger, it can be effective
Increase the interface gross area in adhesive so that the mechanical property of glued membrane and layer of cloth is greatly improved, and due to metal
Particle is paramagnetic, so will not magnetize under the action of alternating electromagnetism wave, so will not be because of addition metallic particles
And shield effectiveness is caused to deteriorate；4th, four stage hot pressings are proposed for the special layers structure of the present invention so that product mechanics
Better performances.
Description of the drawings
Fig. 1 is the schematic diagram of graphene electromagnetic shield cloth according to the present invention.
Main appended drawing reference explanation：
11- prevents puncturing layer, 12- base cloth layers, 13- copper oxides, 14- layers of copper, the first adhesive films of 15-, the first graphenes of 16-
Composite material layer of cloth, the second adhesive films of 17-, 18- the second graphene composite material layer of cloths.
Specific embodiment
Below in conjunction with the accompanying drawings, the specific embodiment of the present invention is described in detail, it is to be understood that the guarantor of the present invention
Shield range is not restricted by specific implementation.
Unless otherwise explicitly stated, otherwise in entire disclosure and claims, term " comprising " or its change
It changes such as "comprising" or " including " etc. and will be understood to comprise stated element or component, and do not exclude other members
Part or other component parts.
Present invention does not require the sources of chemical reagent, and all chemical reagent that the present invention uses all are can be from chemical industry shop
Or the chemicals of Online Shopping, the glass fabric and blended fabric that the present invention uses can be bought from network, it can also
It is manufactured based on method well known in the art.The present invention it is so-called " on " refer to shielding cloth on the outside of namely external environment, institute of the present invention
Claim " under " refer to shielding cloth inside namely internal environment.For example, if the shielding cloth using the application makes military account
Paulin, then be except tent alleged by the present invention " on ", be within tent alleged by the present invention " under ".It is real carrying out shield effectiveness
When testing, the comparative example 1 that the present invention uses is the shielding cloth that embodiment 1 is introduced in CN106567178A, and comparative example 2 is
Shielding cloth disclosed in CN2720576Y embodiments 2.
Embodiment 1
Electromagnetic shield cloth from bottom to top includes anti-puncturing layer, base cloth layer, copper oxide, layers of copper, the first adhesive film, the successively
One graphene composite material layer of cloth, the second adhesive film and the second graphene composite material layer of cloth, base cloth layer are blended cloths, first
Adhesive film and the second adhesive film include graphene powder, and the resistance value of the first graphene composite material layer of cloth is more than the second graphite
The resistance value of alkene composite material layer of cloth, the resistance value of the first adhesive film are more than the resistance value of the second adhesive film, and the first graphene is answered
The resistance value of condensation material layer of cloth and the resistance value of the first adhesive film are essentially identical, the resistance value of the second graphene composite material layer of cloth
Essentially identical with the resistance value of the second adhesive film, layers of copper passes through surface sand-blasting process, and the surface roughness of layers of copper is more than Ra0.05.
In parts by weight, the first adhesive film includes 1 part of graphene powder, 10 parts of perlite powder, 40 parts of solvent, thermoplasticity polymerization
80 parts of object adhesive, 1 part of amorphous state paramagnetic nanoparticles metallic particles, the second adhesive film include 10 parts of graphene powder, expansion treasure
Pearl rock powder end 1 part, 60 parts of solvent, 80 parts of thermoplastic polymer adhesive, 10 parts of amorphous state paramagnetic nanoparticles metallic particles.First
Graphene composite material layer of cloth is the glass fabric for impregnating the first graphene polymer adhesive, by weight, the first stone
Black alkene polymer adhesive includes 1 part of graphene powder, 60 parts of solvent, 80 parts of polymer adhesive, amorphous state paramagnetic nanoparticles
1 part of metallic particles.Second graphene composite material layer of cloth is the glass fabric for impregnating the second graphene polymer adhesive, is pressed
Parts by weight meter, the second graphene polymer adhesive include 10 parts of graphene powder, 60 parts of solvent, 20 parts of polymer adhesive,
10 parts of amorphous state paramagnetic nanoparticles metallic particles.The thickness of copper oxide is 20-50nm.Preparation method is specially：Prepare anti-stab
Broken layer and base cloth layer；Non-conductive adhesive is coated on layer in anti-puncture, then base cloth layer is layed in and prevents puncturing on layer, then
Hot-pressing processing is carried out, obtains first layer stack；Using magnetically controlled sputter method in first layer stack deposited oxide layers of copper；Utilize magnetic
Sputtering method copper layer on copper oxide is controlled, and blasting treatment is carried out to the layers of copper, obtains the second laminated body；Prepare the
One graphene composite material layer of cloth and the second graphene composite material layer of cloth：Various raw materials are put into first, in accordance with material rate
In reaction kettle, be then stirred, it is to be mixed uniformly after, graphene polymer adhesive is obtained, then by graphene polymer
Adhesive is poured into dipping tank, and glass fibre is arranged in dipping tank and is impregnated；Prepare the first adhesive film and the second adhesive film；It presses
Sequence stacks the second laminated body, the first adhesive film, the first graphene composite material layer of cloth, the second adhesive film and the second graphene
Composite material layer of cloth obtains stacked body, and then stacked body is put into vacuum hotpressing machine and carries out hot pressing, which includes four ranks
Section, wherein, first stage temperature is 100 DEG C, pressure 10MPa, duration 30s, and second stage temperature is 200 DEG C, pressure
Power is 20MPa, duration 20min, and phase III temperature is 100 DEG C, pressure 20MPa, duration 5min, the 4th
Phase temperature obtains graphene electromagnetic shield cloth for 50 DEG C, pressure 10MPa, duration 5min.The thickness of layers of copper is
100-200nm。
Embodiment 2
Electromagnetic shield cloth from bottom to top includes preventing puncturing layer, base cloth layer, layers of copper, the first adhesive film, the first graphene successively
Composite material layer of cloth, the second adhesive film and the second graphene composite material layer of cloth, it is corresponding in manufacturing method to reduce deposited oxide
The step of copper, remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 3
Electromagnetic shield cloth from bottom to top include successively it is anti-puncture layer, base cloth layer, copper oxide, layers of copper, the second adhesive film with
And the second graphene composite material layer of cloth, corresponding reduce prepares and the first adhesive film is laminated and the first graphene is answered in manufacturing method
The step of condensation material layer of cloth, remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 4
It is 50nm to adjust copper oxide thickness.Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 5
It is 35nm to adjust copper oxide thickness.Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 6
It is 10nm to adjust copper oxide thickness.Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 7
It is 70nm to adjust copper oxide thickness.Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 8
The thickness for adjusting layers of copper is 200nm.Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 9
The thickness for adjusting layers of copper is 300nm.Remaining parameter, condition, manufacturing method are same as Example 1.
The product test shield effectiveness and durability prepared to embodiment 1-9.The wherein test frequency range of shield effectiveness
It is 0.1MHz-40GHz, test method is method well known in the art, and details are not described herein again, it should be pointed out that the present invention is closed
The heart is overall performance of the shielding cloth in test spectral range, so only marking the shielding in the range of test frequency in result
Efficiency minimum.Durability test is as follows：The shielding cloth being prepared is folded 100 times, is then toasted in 80 DEG C of baking ovens
10h followed by, rinses shielding cloth 20 times using the diluted acid that pH value is 1 or so, then again folds shielding cloth 100 times, then will
Shielding cloth is cleaned up and is dried, then the remaining percentage of the shield effectiveness for the shielding cloth that test processes are crossed.For example, it is false
If the shield effectiveness of untreated shielding cloth is 60dB, the shield effectiveness of processed shielding cloth is 30dB, then according to the invention
Definition, durability 50%.Table 1 is listed in the test result of embodiment 1-9.
Table 1
| Shield effectiveness | Durability | |
| Embodiment 1 | More than 60dB | About 90% |
| Embodiment 2 | More than 45dB | About 50% |
| Embodiment 3 | More than 50dB | About 85% |
| Embodiment 4 | More than 60dB | About 90% |
| Embodiment 5 | More than 60dB | About 90% |
| Embodiment 6 | More than 40dB | About 50% |
| Embodiment 7 | More than 40dB | About 50% |
| Embodiment 8 | More than 60dB | About 90% |
| Embodiment 9 | More than 55dB | About 60% |
| Comparative example 1 | More than 30dB | About 30% |
| Comparative example 2 | More than 60dB | About 40% |
By 1 result of table as it can be seen that the prior art can be far above according to the shield effectiveness according to shielding cloth produced by the present invention
In existing shielding cloth (such as comparative example 1 is visible with comparative example 1) or shielding cloth produced by the present invention at least have it is remote
Higher than the durability (such as comparative example 1 is visible with comparative example 2) of prior art shielding cloth.Simultaneously as embodiment 2 is not wrapped
Cuprous oxide layer is included, the copper layer directly in base fabric, so layers of copper is uneven, there are microcosmic discontinuous, although leading to layers of copper
Macroscopical conductivity it is still very low, but the conductivity difference of microcosmic upper layers of copper everywhere is very big, certain position resistance values of layers of copper
It is very high, it is especially poor in shortwave frequency range effectiveness.And since there is no cuprous oxide layer, so layers of copper and base fabric knot
It closes loosely, the easy delamination of the two, so after multiple bending, shield effectiveness reduces more.The performance of embodiment 6,7
Similar explanation can be done.For embodiment 3, due to lacking the first graphene composite material layer of cloth and the first adhesive film, so
Shield effectiveness is poor, and the concrete reason for generating this phenomenon is not clear, but actually embodiment 3 is only in high frequency section
The shield effectiveness of (more than 25GHz) is poor, so it may be to be answered due to lacking the first graphene of high resistance that inventor, which speculates,
Condensation material layer of cloth and the first adhesive film, so vortex is constantly permeated to layers of copper, but due to from the second graphene composite material
Layer of cloth endosmosis needs, across several interfaces, to cause the electron transport on microcosmic hindered to layers of copper, so while implementing
The macroscopic resistance value of example 3 is close with embodiment 1, but shield effectiveness is poor.
Embodiment 10
It adjusts the first adhesive film and includes 10 parts of graphene powder, 10 parts of perlite powder, 60 parts of solvent, thermoplastic poly
80 parts of object adhesive, 1 part of amorphous state paramagnetic nanoparticles metallic particles are closed, the second adhesive film includes 10 parts of graphene powder, expansion
10 parts of perlite powder, 60 parts of solvent, 20 parts of thermoplastic polymer adhesive, 10 parts of amorphous state paramagnetic nanoparticles metallic particles,
Remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 11
The first adhesive film and the second adhesive film are adjusted all without amorphous state paramagnetic nanoparticles metallic particles, remaining parameter,
Condition, manufacturing method are same as Example 1.
Embodiment 12
It adjusts the first adhesive film and includes 20 parts of perlite powder, the second adhesive film includes perlite powder 20
Part, remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 13
The first adhesive film and the second adhesive film are adjusted without expanded perlite, remaining parameter, condition, manufacturing method with
Embodiment 1 is identical.
Embodiment 14
It is the glass fabric for impregnating the first graphene polymer adhesive to adjust the first graphene composite material layer of cloth, is pressed
Parts by weight meter, the first graphene polymer adhesive include 10 parts of graphene powder, 40 parts of solvent, 80 parts of polymer adhesive,
1 part of amorphous state paramagnetic nanoparticles metallic particles.Second graphene composite material layer of cloth is the second graphene polymer gluing of dipping
The glass fabric of agent, by weight, the second graphene polymer adhesive include 10 parts of graphene powder, 40 parts of solvent,
20 parts of polymer adhesive, 10 parts of amorphous state paramagnetic nanoparticles metallic particles.Remaining parameter, condition, manufacturing method with implementation
Example 1 is identical.
Embodiment 15
It adjusts the first graphene polymer adhesive and the second graphene polymer adhesive and is all free of amorphous state paramagnetic
Property nano-metal particle, remaining parameter, condition, manufacturing method are same as Example 1.
The product test shield effectiveness and durability prepared to embodiment 10-15.Test condition and related description can join
See the narration before specification.Test result is listed in table 2.
Table 2
If glued membrane will be caused to become insulator from 2 result of table as it can be seen that adding in excessive expanded perlite in adhesive film, from
And being electrically connected between the first graphene composite material layer of cloth, the second graphene composite material layer of cloth and layers of copper is obstructed, cause to shield
Cover effect variation.But due to the excellent humidification of expanded perlite so that the durability of shielding cloth, which has, significantly to be carried
It rises.
Embodiment 16
It is 150 DEG C that adjustment hot compression parameters, which are first stage temperature, pressure 5MPa, duration 10s, second stage temperature
It is 300 DEG C, pressure 10MPa, duration 10min to spend, and phase III temperature is 200 DEG C, pressure 10MPa, when continuing
Between for 3min, fourth stage temperature is 70 DEG C, pressure 10MPa, duration 3min, remaining parameter, condition, manufacturing method
It is same as Example 1.
Embodiment 17
The hot pressing of four stages is adjusted as the hot pressing of three stages, three stages were respectively that first stage temperature is 100 DEG C, and pressure is
10MPa, duration 30s, second stage temperature are 200 DEG C, pressure 20MPa, duration 20min, the phase III
Temperature is 50 DEG C, pressure 10MPa, duration 5min, remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 18
The hot pressing of four stages is adjusted as the hot pressing of three stages, three stages were respectively that first stage temperature is 200 DEG C, and pressure is
20MPa, duration 20min, second stage temperature are 100 DEG C, pressure 20MPa, duration 5min, the phase III
Temperature is 50 DEG C, pressure 10MPa, duration 5min, remaining parameter, condition, manufacturing method are same as Example 1.
Embodiment 19
The hot pressing of four stages is adjusted as the hot pressing of three stages, three stages were respectively that first stage temperature is 100 DEG C, and pressure is
10MPa, duration 30s, second stage temperature are 200 DEG C, pressure 20MPa, duration 20min, the phase III
Temperature is 100 DEG C, pressure 20MPa, duration 5min, remaining parameter, condition, manufacturing method are same as Example 1.
The product test shield effectiveness and durability prepared to embodiment 16-19.Test condition and related description can join
See the narration before specification.Test result is listed in table 3.
Table 3
| Shield effectiveness | Durability | |
| Embodiment 1 | More than 60dB | About 90% |
| Embodiment 16 | More than 60dB | About 90% |
| Embodiment 17 | More than 40dB | About 60% |
| Embodiment 18 | More than 45dB | About 75% |
| Embodiment 19 | More than 45dB | About 65% |
By 3 result of table as it can be seen that the hot pressing of four stages is vital for the product of the present invention, concrete reason may
It is：First stage hot pressing can essentially exclude the water in stacked body, and under high pressure, high temperature and vacuum state, water can be with
Rapid evaporation comes out so that there is no microdefects in glued membrane and composite material cloth.Second stage hot pressing is actually tradition
So that glued membrane in thermoplastic resin softening hot pressing, in this stage, thermoplastic resin flow is best, can fill
The higher position of glued membrane both sides irregularity degree.In phase III hot pressing, thermoplastic resin flow is deteriorated, and resin surface can become
Height, in this stage, resin will not be from the higher position outflow of glued membrane both sides irregularity degree, and can fill glued membrane both sides irregularity degree
Relatively low position.In fourth stage hot pressing, the small-molecule substance of first three stage hot pressing generation can be promoted by low temperature and pressure
It excludes, reduces the microscopic bubble in composite material.
The description of the aforementioned specific exemplary embodiment to the present invention is in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed
And variation.The purpose of selecting and describing the exemplary embodiment is that explain that the specific principle of the present invention and its reality should
With so that those skilled in the art can realize and utilize the present invention a variety of different exemplary implementations and
Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (10)
1. a kind of graphene electromagnetic shield cloth, it is characterised in that：The electromagnetic shield cloth from bottom to top include successively it is anti-puncture layer,
Base cloth layer, copper oxide, layers of copper, the first adhesive film, the first graphene composite material layer of cloth, the second adhesive film and the second graphite
Alkene composite material layer of cloth, the base cloth layer are blended cloths, and first adhesive film and the second adhesive film include graphene powder,
The resistance value of the first graphene composite material layer of cloth is more than the resistance value of the second graphene composite material layer of cloth, described
The resistance value of first adhesive film be more than second adhesive film resistance value, the resistance value of the first graphene composite material layer of cloth with
The resistance value of first adhesive film is essentially identical, the resistance value of the second graphene composite material layer of cloth and second glue
The resistance value of film layer is essentially identical, and the layers of copper passes through surface sand-blasting process, and the surface roughness of the layers of copper is more than Ra0.05.
2. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：The base cloth layer is aramid fiber and polyamides
The blended cloth of amine fiber.
3. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：It is described to prevent that it is glass fabric to puncture layer,
The thickness of the glass fabric is 1-5mm.
4. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：By weight, first adhesive film
And second adhesive film respectively includes 1-10 parts of graphene powder, 1-10 parts of perlite powder, 40-60 parts of solvent,
20-80 parts of thermoplastic polymer adhesive, 1-10 parts of amorphous state paramagnetic nanoparticles metallic particles, first adhesive film with it is described
The ingredient of second adhesive film is different.
5. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：The first graphene composite material layer of cloth
It is the glass fabric for impregnating the first graphene polymer adhesive, by weight, the first graphene polymer gluing
Agent includes 1-10 parts of graphene powder, 40-60 parts of solvent, 20-80 parts of polymer adhesive, amorphous state paramagnetic nanoparticles metal
1-10 parts of grain.
6. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：The second graphene composite material layer of cloth
It is the glass fabric for impregnating the second graphene polymer adhesive, by weight, the second graphene polymer gluing
Agent includes 1-10 parts of graphene powder, 40-60 parts of solvent, 20-80 parts of polymer adhesive, amorphous state paramagnetic nanoparticles metal
1-10 parts of grain, wherein, the ingredient of the second graphene polymer adhesive and the first graphene polymer adhesive
Ingredient is different.
7. graphene electromagnetic shield cloth as described in claim 1, it is characterised in that：The thickness of the copper oxide is 20-
50nm。
8. a kind of manufacturing method of such as graphene electromagnetic shield cloth of one of claim 1-7, it is characterised in that：The manufacturer
Method includes：
Prepare to prevent puncturing layer and base cloth layer；
Non-conductive adhesive is coated on layer in anti-puncture, then by the base cloth layer be layed in it is described it is anti-puncture on layer, with
After carry out hot-pressing processing, obtain first layer stack；
Using magnetically controlled sputter method in the first layer stack deposited oxide layers of copper；
It deposits the layers of copper on copper oxide using magnetically controlled sputter method, and blasting treatment is carried out to the layers of copper, obtain the
Two laminated bodies；
Prepare the first graphene composite material layer of cloth and the second graphene composite material layer of cloth：It will be each first, in accordance with material rate
Kind of raw material is put into reaction kettle, is then stirred, it is to be mixed uniformly after, graphene polymer adhesive is obtained, then by institute
It states graphene polymer adhesive to pour into dipping tank, glass fibre is arranged in the dipping tank and is impregnated；
Prepare the first adhesive film and the second adhesive film；
Second laminated body, first adhesive film, the first graphene composite material layer of cloth, described are stacked in order
Two adhesive films and the second graphene composite material layer of cloth, obtain stacked body, the stacked body then are put into Vacuum Heat
Hot pressing is carried out in press, which includes four-stage, wherein, first stage temperature is 100-150 DEG C, pressure 5-10MPa,
Duration is 10-30s, and second stage temperature is 200-300 DEG C, pressure 10-20MPa, duration 10-20min, the
Three phase temperatures are 100-200 DEG C, pressure 10-20MPa, duration 3-5min, and fourth stage temperature is 50-70 DEG C,
Pressure is 5-10MPa, duration 3-5min, obtains the graphene electromagnetic shield cloth.
9. graphene electromagnetic shield cloth as claimed in claim 8, it is characterised in that：The thickness of the copper oxide is 20-
50nm。
10. graphene electromagnetic shield cloth as claimed in claim 8, it is characterised in that：The thickness of the layers of copper is 100-
200nm。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109151683A (en) * | 2018-09-05 | 2019-01-04 | 深圳市烽火宏声科技有限公司 | Manufacturing method, loudspeaker and the electronic equipment of loudspeaker radiator structure |
| CN109750493A (en) * | 2019-01-18 | 2019-05-14 | 中国航发北京航空材料研究院 | A kind of preparation method of graphene electromagnetic shielding composite material |
| CN112410750A (en) * | 2019-08-22 | 2021-02-26 | 中国科学院苏州纳米技术与纳米仿生研究所 | Graphene film copper-clad heat sink and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6044949A (en) * | 1983-08-20 | 1985-03-11 | Riken Ii M C Kk | Translucent screen plate for display device |
| US20130169488A1 (en) * | 2011-12-28 | 2013-07-04 | Samsung Electronics Co., Ltd. | Magnetic substance and composite material for antennas employing the same |
| CN103287020A (en) * | 2013-03-26 | 2013-09-11 | 大连理工大学 | A self-healing anti-corrosion coating of copper 8-hydroxyquinoline / BTA / epoxy resin on the surface of a copper substrate and a preparation method thereof |
| CN106243379A (en) * | 2016-07-23 | 2016-12-21 | 天津大学 | A kind of electromagnetic shielding foamed composite based on graphene oxide and polymer and preparation method |
| CN107189708A (en) * | 2017-07-17 | 2017-09-22 | 苏州城邦达力材料科技有限公司 | A kind of conductive adhesive film with metal high-bond and preparation method thereof |
-
2017
- 2017-12-29 CN CN201711480538.7A patent/CN108189518B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6044949A (en) * | 1983-08-20 | 1985-03-11 | Riken Ii M C Kk | Translucent screen plate for display device |
| US20130169488A1 (en) * | 2011-12-28 | 2013-07-04 | Samsung Electronics Co., Ltd. | Magnetic substance and composite material for antennas employing the same |
| CN103287020A (en) * | 2013-03-26 | 2013-09-11 | 大连理工大学 | A self-healing anti-corrosion coating of copper 8-hydroxyquinoline / BTA / epoxy resin on the surface of a copper substrate and a preparation method thereof |
| CN106243379A (en) * | 2016-07-23 | 2016-12-21 | 天津大学 | A kind of electromagnetic shielding foamed composite based on graphene oxide and polymer and preparation method |
| CN107189708A (en) * | 2017-07-17 | 2017-09-22 | 苏州城邦达力材料科技有限公司 | A kind of conductive adhesive film with metal high-bond and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109151683A (en) * | 2018-09-05 | 2019-01-04 | 深圳市烽火宏声科技有限公司 | Manufacturing method, loudspeaker and the electronic equipment of loudspeaker radiator structure |
| CN109750493A (en) * | 2019-01-18 | 2019-05-14 | 中国航发北京航空材料研究院 | A kind of preparation method of graphene electromagnetic shielding composite material |
| CN109750493B (en) * | 2019-01-18 | 2021-09-14 | 中国航发北京航空材料研究院 | Preparation method of graphene electromagnetic shielding composite material |
| CN112410750A (en) * | 2019-08-22 | 2021-02-26 | 中国科学院苏州纳米技术与纳米仿生研究所 | Graphene film copper-clad heat sink and preparation method thereof |
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| Publication number | Publication date |
|---|---|
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