CN108188598A - Quasi-molecule laser annealing equipment - Google Patents

Quasi-molecule laser annealing equipment Download PDF

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Publication number
CN108188598A
CN108188598A CN201711449637.9A CN201711449637A CN108188598A CN 108188598 A CN108188598 A CN 108188598A CN 201711449637 A CN201711449637 A CN 201711449637A CN 108188598 A CN108188598 A CN 108188598A
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CN
China
Prior art keywords
film layer
substrate
laser
quasi
reflectance coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711449637.9A
Other languages
Chinese (zh)
Inventor
张伟彬
谢锐
曾凡林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan China Star Optoelectronics Semiconductor Display Technology Co Ltd
Original Assignee
Wuhan China Star Optoelectronics Semiconductor Display Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan China Star Optoelectronics Semiconductor Display Technology Co Ltd filed Critical Wuhan China Star Optoelectronics Semiconductor Display Technology Co Ltd
Priority to CN201711449637.9A priority Critical patent/CN108188598A/en
Priority to PCT/CN2018/074344 priority patent/WO2019127810A1/en
Priority to US15/996,396 priority patent/US20190198364A1/en
Publication of CN108188598A publication Critical patent/CN108188598A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/268Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/70Auxiliary operations or equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/70Auxiliary operations or equipment
    • B23K26/702Auxiliary equipment
    • B23K26/703Cooling arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67098Apparatus for thermal treatment
    • H01L21/67115Apparatus for thermal treatment mainly by radiation

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Health & Medical Sciences (AREA)
  • Power Engineering (AREA)
  • Toxicology (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Electromagnetism (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

The present invention provides a kind of quasi-molecule laser annealing equipment, for carrying out laser annealing to substrate, including line customer, focusing lens and laser, line customer is set between substrate and laser, focusing lens are between line customer and laser, and in the light path of the laser beam irradiation substrate of laser, the focus of focusing lens is in the light path of the laser beam directive substrate of laser and on substrate, line customer is equipped with the reflection cavity connected through chamber and with through chamber through line customer, reflection cavity includes the surface equipped with reflectance coating, the surface of reflection cavity is towards substrate, the laser beam that laser generates is passed through after being focused on by focusing lens through chamber directive substrate, laser beam after focusing is reflexed to reflectance coating by substrate, again substrate is reflected back into through reflectance coating.The quasi-molecule laser annealing equipment of the present invention solves the technical issues of line customer temperature raising.

Description

Quasi-molecule laser annealing equipment
Technical field
The present invention relates to display technology field, more particularly to a kind of quasi-molecule laser annealing equipment.
Background technology
Quasi-molecule laser annealing (ELA) technology extensive utilization to semicon industry.Existing ELA equipment processing procedure is usual For laser beam after optics into focus with inclination angle by being irradiated on silicon substrate, and a laser beam part is absorbed by silicon, one Divide and be reflected on line customer by silicon fiml.And line customer almost all is absorbed by the energy of reflected light, and luminous energy is turned Thermal energy is turned to, the utilization rate in turn resulting in energy is not high and the temperature of line customer can be caused to increase, so as to influence quasi-molecule The service life of laser annealing apparatus.
Invention content
The purpose of the present invention is to provide a kind of quasi-molecule laser annealings, solve the raised technology of line customer temperature Problem.
The present invention provides a kind of quasi-molecule laser annealing equipment, for carrying out laser annealing to substrate, is consumed including line Device, focusing lens and laser, the line customer are set between the substrate and the laser, the focusing lens Between the line customer and the laser, and the light of the laser beam irradiation substrate positioned at the laser On the road, in the light path of substrate and positioned at described described in the laser beam directive of the focus of the focusing lens in the laser On substrate, the line customer be equipped with through the line customer through chamber and with it is described connect through chamber it is anti- Chamber is penetrated, the reflection cavity includes the surface equipped with reflectance coating, the laser that the surface is generated towards the substrate, the laser Beam passes through described through substrate described in chamber directive after being focused on by the focusing lens, the substrate is by the laser after focusing Beam reflexes to the reflectance coating, then is reflected back into the substrate through the reflectance coating.
Wherein, the surface of the reflection cavity includes circular arc camber, and the reflectance coating is arc film, and the reflectance coating fits in The circular arc camber, described in the laser beam directive of the center of the circular arc camber in the laser in the light path of substrate simultaneously On the substrate.
Wherein, the reflectance coating includes the first film layer and the second film layer of intersecting setting, and described first thin Film layer is located at the outermost layer and innermost layer of the reflectance coating, and the first film layer has first refractive index, second film Layer has the second refractive index, and the first refractive index is more than second refractive index.
Wherein, the first film layer is equal with the thickness of second film layer.
Wherein, the first film layer and the thickness of second film layer are the whole of the optical maser wavelength a quarter Several times.
Wherein, the first film layer include silicon nitride film layer, titanium deoxid film layer, five oxidation two tantalum film layer, Zirconia film layer, lanthanium titanate film layer, hafnia film layer and zinc selenide film layer.
Wherein, second film layer includes magnesium fluoride film layer, silicon oxide film layer, aluminum oxide film layer and titanium nitride Film layer.
Wherein, the quasi-molecule laser annealing equipment includes energy meter, and the energy meter is for detection by the reflectance coating The energy of the laser of reflection.
Wherein, the quasi-molecule laser annealing equipment includes supporter, substrate described in the support body supports.
Wherein, the substrate is amorphous silicon substrate
In conclusion the reflectance coating of the present invention reflects the reflected beams for reaching the reflectance coating, realize described in reduction Absorption of the line customer to laser solves the technical issues of line customer temperature raising, and then eliminates to institute State the cooling device of line customer;It is irradiated on the substrate, improves again by the laser beam that the reflectance coating reflects simultaneously The utilization rate of the laser beam.
Description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention, for those of ordinary skill in the art, without creative efforts, can be with Other attached drawings are obtained according to these attached drawings.
Fig. 1 is the structure diagram for the quasi-molecule laser annealing equipment that invention embodiment provides.
Fig. 2 is the structure diagram of the reflectance coating in Fig. 1.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without creative efforts Embodiment shall fall within the protection scope of the present invention.
The present invention provides a kind of quasi-molecule laser annealing equipment, for carrying out laser annealing to substrate 10, disappears including line Consume device 20, focusing lens 30 and laser 40, the line customer 20 between the substrate 10 and the laser 40, The focusing lens 30 are between the line customer 20 and the laser 40, and swashing positioned at the laser 40 Light beam is irradiated in the light path of the substrate 10, and the focuses of the focusing lens 30 is in the laser beam directive of the laser 40 In the light path of the substrate 10 and on the substrate 10, the line customer 20 is equipped with through the line customer 20 through chamber 201 and with the reflection cavity 202 connected through chamber 201, the reflection cavity 202 include be equipped with reflectance coating 50 Surface 203, towards the substrate 10, the laser beam that the laser 40 generates passes through the focusing lens on the surface 203 Across described through substrate 10 described in 201 directive of chamber after 30 focusing, the substrate 10 reflexes to the laser beam after focusing The reflectance coating 50, then it is reflected back into the substrate 10 through the reflectance coating 50.The reflectance coating 50 of the present invention will reach described anti- The reflection laser beam reflection of film 50 is penetrated, the absorption for reducing the line customer 20 to laser is realized, solves the line The technical issues of 20 temperature of customer increases, and then eliminate the cooling device to the line customer 20;It is described simultaneously The laser beam that reflectance coating 50 reflects is irradiated to again on the substrate 10, improves the utilization rate of the laser beam.
In the present embodiment, the substrate 10 is amorphous silicon substrate, and laser is carried out through the quasi-molecule laser annealing equipment After annealing, 10 crystallization of substrate is polycrystalline silicon substrate.The substrate 10 is supported by supporter 60.The gathering eyeglass 30 Convex lens.The laser beam after focusing irradiates the substrate 10 with the direction for the vertical line of the substrate 10 being in 7 degree.It is described It is the cavity for penetrating through the line customer 20 to cross chamber 201, and the reflection cavity 202 is fan-shaped chamber.The chamber 201 that penetrates is described In line customer 20 for the laser 30 generate laser beam by chamber;The reflection cavity 202 disappears for the line Consume in device 20 supply by the laser beam that the substrate 10 reflects by chamber, and the reflection cavity 202 disappears for the line Consume device 20 in supply by the laser beam that the reflectance coating 50 reflects by chamber.
In the present embodiment, the surface 203 of the reflection cavity 202 be circular arc camber, the reflectance coating 50 be arc film, institute It states reflectance coating 50 and fits in the circular arc camber, the center of the circular arc camber reaches the substrate after the laser beam focus 10 position.Specifically, the reflectance coating 30 of arc fits in the circular arc camber of the line customer 20, and the circular arc Described in the laser beam directive of the center of curved surface in the laser 40 in the light path of substrate 10 and on the substrate 10, I.e. the center of the reflectance coating 50 of arc is also described in the laser beam directive in the laser 40 in the light path of substrate 10 And on the substrate 10, the reflectance coating 50 of the arc realizes the laser that will be reflected to the reflectance coating 50 The reverse direction that beam reaches the reflectance coating 50 along the laser beam is reflected into the substrate 10, and reflected by the reflectance coating 50 The laser beam can be irradiated to the center of the reflectance coating 50, you can be irradiated on the substrate 10 with the laser The laser beam that device 40 is sent out is irradiated to the same position of the substrate 10, improves the utilization rate of the laser beam.And due to The laser beam during reflection, decay by the energy of the laser beam, when the laser reflected by the reflectance coating 50 When beam is irradiated to the substrate 10, the energy very little, and then the laser beam is again by the substrate 10 of the laser beam When reflected illumination is to the laser 40, the energy of the laser will not impact the laser 40 smaller.
Referring to Fig. 2, the reflectance coating 50 includes 501 and second film layer 502 of the first film layer of intersecting setting, And the first film layer 501 is located at the outermost layer and innermost layer of the reflectance coating 50, the first film layer 501 has first Refractive index, second film layer 502 have the second refractive index, and the first refractive index is more than second refractive index.Specifically Include 501 and second film layer 502 of the first film layer for, the reflectance coating 50, the first film layer 501 and described second thin 502 intersecting of film layer, and the innermost layer of the reflectance coating 50 and outermost layer are the first film layer 501, i.e., it is described The laser beam that substrate 10 reflects contacts first with the first film layer 501 with first refractive index, due to described the The refractive index of one film layer 501 is more than the refractive index of second film layer 502, reaches the part of the first film layer 501 Laser reflects, and part reflects, and the laser beam into second film layer 502 is reflected and reflected again, until Proceed to the first film layer 501 contacted with the circular arc camber of the reflection cavity 202.Since the laser beam occurs repeatedly Reflection and refraction, therefore the laser beam for reaching the line customer 20 is seldom, and energy ratio is relatively low, therefore the line customer The energy of 20 laser beams absorbed is less, and the most laser beam is reflected into the reflection cavity 202, and anti-again It is emitted back towards to the substrate 10.The first film layer 501 and the intersecting of second film layer 502 of the present invention realizes The laser beam reflection of the reflectance coating 50 is up to, and reflectivity realizes up to more than 90% and reduces the line customer The absorption of 20 pairs of laser solves the technical issues of 20 temperature of line customer raising, while eliminates the beam The cooling device of customer 20 is flowed, and the energy of the laser is reasonably utilized, improves the utilization rate of the laser beam.
In the present embodiment, the first film layer 501 is equal with the thickness of second film layer 502.And described The thickness of one film layer 501 and second film layer 502 is the integral multiple of the optical maser wavelength a quarter.Specifically, The first film layer 501 is equal with the thickness of second film layer 502 and is the just whole of the optical maser wavelength a quarter Several times.Due under these conditions, the reflected light vector sum direction of vibration all same in each film layer of stacking, therefore synthesize described The amplitude of reflected light increases with the increase of the film number of plies, and energy also increases, therefore is reflected and be irradiated to by the reflectance coating 50 The energy of the laser beam on the substrate 10 is still higher, further improves the utilization rate of the laser beam.And then with The increase of the film number of plies, is reduced after refraction into the refraction light of the line customer 20, to the line customer 20 Influence is smaller, and eliminates the cooling device of the line customer 20.
In the present embodiment, the first film layer 501 includes silicon nitride film layer, titanium deoxid film layer, five oxidations Two tantalum thin film layers, zirconia film layer, lanthanium titanate film layer, hafnia film layer and zinc selenide film layer.Second film Layer 502 includes magnesium fluoride film layer, silicon oxide film layer, aluminum oxide film layer and titanium nitride thin film layer.It is therefore thin described first During the intersecting of film layer 501 and second film layer 502, the first film layer 501 can be silicon nitride film Layer, titanium deoxid film layer, five oxidation two tantalum film layer, zirconia film layer, lanthanium titanate film layer, hafnia film layer and selenium Change a kind of or wherein arbitrary several combination in zinc film layer.Second film layer 502 can be magnesium fluoride film layer, A kind of or wherein arbitrary several combination in silicon oxide film layer, aluminum oxide film layer and titanium nitride thin film layer.
The quasi-molecule laser annealing equipment includes energy meter (not shown), and the energy meter is reflected for detecting The laser energy.Specifically, the energy meter is set in the line customer 20 close to the position of the reflectance coating 50 It puts, the energy meter determines the reflectance coating for detecting the energy of the laser after being reflected by the reflectance coating 50 The first film layer described in 50 501 and the number of plies of second film layer 502.
The above disclosure is only the preferred embodiments of the present invention, cannot limit the right model of the present invention with this certainly It encloses, one of ordinary skill in the art will appreciate that realizing all or part of flow of above-described embodiment, and will according to right of the present invention Made equivalent variations are sought, still falls within and invents covered range.

Claims (10)

1. a kind of quasi-molecule laser annealing equipment, for carrying out laser annealing to substrate, which is characterized in that consumed including line Device, focusing lens and laser, the line customer are set between the substrate and the laser, the focusing lens Between the line customer and the laser, and the light of the laser beam irradiation substrate positioned at the laser On the road, in the light path of substrate and positioned at described described in the laser beam directive of the focus of the focusing lens in the laser On substrate, the line customer be equipped with through the line customer through chamber and with it is described connect through chamber it is anti- Chamber is penetrated, the reflection cavity includes the surface equipped with reflectance coating, the laser that the surface is generated towards the substrate, the laser Beam passes through described through substrate described in chamber directive after being focused on by the focusing lens, the substrate is by the laser after focusing Beam reflexes to the reflectance coating, then is reflected back into the substrate through the reflectance coating.
2. quasi-molecule laser annealing equipment according to claim 1, which is characterized in that the surface of the reflection cavity includes circle Arc surface, the reflectance coating are arc film, and the reflectance coating fits in the circular arc camber, and the center of the circular arc camber is in institute It states described in the laser beam directive of laser in the light path of substrate and on the substrate.
3. quasi-molecule laser annealing equipment according to claim 2, which is characterized in that the reflectance coating includes intersecting The first film layer and the second film layer of setting, and the first film layer is located at the outermost layer and innermost layer of the reflectance coating, The first film layer has first refractive index, and second film layer has the second refractive index, and the first refractive index is more than Second refractive index.
4. quasi-molecule laser annealing equipment according to claim 3, which is characterized in that the first film layer and described the The thickness of two film layers is equal.
5. quasi-molecule laser annealing equipment according to claim 4, which is characterized in that the first film layer and described the The thickness of two film layers is the integral multiple of the optical maser wavelength a quarter.
6. according to claim 3-5 any one of them quasi-molecule laser annealing equipment, which is characterized in that the first film layer Including silicon nitride film layer, titanium deoxid film layer, five oxidation two tantalum film layer, zirconia film layer, lanthanium titanate film layer, oxygen Change hafnium film layer and zinc selenide film layer.
7. according to claim 3-5 any one of them quasi-molecule laser annealing equipment, which is characterized in that second film layer Including magnesium fluoride film layer, silicon oxide film layer, aluminum oxide film layer and titanium nitride thin film layer.
8. quasi-molecule laser annealing equipment according to claim 7, which is characterized in that the quasi-molecule laser annealing equipment Including energy meter, the energy meter is used to detect the energy of the laser reflected by the reflectance coating.
9. quasi-molecule laser annealing equipment according to claim 8, which is characterized in that the quasi-molecule laser annealing equipment Including supporter, substrate described in the support body supports.
10. quasi-molecule laser annealing equipment according to claim 9, which is characterized in that the substrate is amorphous silicon substrate.
CN201711449637.9A 2017-12-27 2017-12-27 Quasi-molecule laser annealing equipment Pending CN108188598A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201711449637.9A CN108188598A (en) 2017-12-27 2017-12-27 Quasi-molecule laser annealing equipment
PCT/CN2018/074344 WO2019127810A1 (en) 2017-12-27 2018-01-26 Excimer laser annealing equipment
US15/996,396 US20190198364A1 (en) 2017-12-27 2018-06-01 Excimer laser annealing apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711449637.9A CN108188598A (en) 2017-12-27 2017-12-27 Quasi-molecule laser annealing equipment

Publications (1)

Publication Number Publication Date
CN108188598A true CN108188598A (en) 2018-06-22

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CN201711449637.9A Pending CN108188598A (en) 2017-12-27 2017-12-27 Quasi-molecule laser annealing equipment

Country Status (2)

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CN (1) CN108188598A (en)
WO (1) WO2019127810A1 (en)

Citations (6)

* Cited by examiner, † Cited by third party
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CN1731635A (en) * 2004-08-13 2006-02-08 中国科学院长春光学精密机械与物理研究所 Organic micro-cavity laser in electric pump Pu and preparation method thereof
JP2011204912A (en) * 2010-03-25 2011-10-13 Japan Steel Works Ltd:The Method for manufacturing laser anneal processed body, and laser annealing apparatus
CN103614541A (en) * 2013-10-31 2014-03-05 中国科学院宁波材料技术与工程研究所 Laser impact strengthening device aiming at workpiece surface and laser impact strengthening processing method
CN203579009U (en) * 2013-11-15 2014-05-07 深圳市大族激光科技股份有限公司 Optical isolation system and optical isolator
CN103934568A (en) * 2013-01-22 2014-07-23 三星显示有限公司 Laser annealing apparatus
CN205692801U (en) * 2016-06-29 2016-11-16 昆山国显光电有限公司 A kind of quasi-molecule laser annealing device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3751772B2 (en) * 1999-08-16 2006-03-01 日本電気株式会社 Semiconductor thin film manufacturing equipment
CN201017855Y (en) * 2007-01-24 2008-02-06 中华映管股份有限公司 Heat annealing equipment
CN203589031U (en) * 2013-10-15 2014-05-07 昆山工研院新型平板显示技术中心有限公司 Anti-laser-damage thin film structure for AMOLED polymer substrate
CN106785817B (en) * 2017-03-24 2020-03-06 京东方科技集团股份有限公司 Optical equipment and excimer laser annealing system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1731635A (en) * 2004-08-13 2006-02-08 中国科学院长春光学精密机械与物理研究所 Organic micro-cavity laser in electric pump Pu and preparation method thereof
JP2011204912A (en) * 2010-03-25 2011-10-13 Japan Steel Works Ltd:The Method for manufacturing laser anneal processed body, and laser annealing apparatus
CN103934568A (en) * 2013-01-22 2014-07-23 三星显示有限公司 Laser annealing apparatus
CN103614541A (en) * 2013-10-31 2014-03-05 中国科学院宁波材料技术与工程研究所 Laser impact strengthening device aiming at workpiece surface and laser impact strengthening processing method
CN203579009U (en) * 2013-11-15 2014-05-07 深圳市大族激光科技股份有限公司 Optical isolation system and optical isolator
CN205692801U (en) * 2016-06-29 2016-11-16 昆山国显光电有限公司 A kind of quasi-molecule laser annealing device

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