CN108185604A - A kind of changeable colour umbrella and umbrella cloth manufacturing method - Google Patents

A kind of changeable colour umbrella and umbrella cloth manufacturing method Download PDF

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Publication number
CN108185604A
CN108185604A CN201711451691.7A CN201711451691A CN108185604A CN 108185604 A CN108185604 A CN 108185604A CN 201711451691 A CN201711451691 A CN 201711451691A CN 108185604 A CN108185604 A CN 108185604A
Authority
CN
China
Prior art keywords
umbrella
discoloration
polymer matrix
variable colour
transparent polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711451691.7A
Other languages
Chinese (zh)
Inventor
杨学太
骆燕明
唐孝康
孙彬
黄松香
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUANZHOU DITE INDUSTRIAL PRODUCTS DESIGN Co Ltd
Original Assignee
QUANZHOU DITE INDUSTRIAL PRODUCTS DESIGN Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUANZHOU DITE INDUSTRIAL PRODUCTS DESIGN Co Ltd filed Critical QUANZHOU DITE INDUSTRIAL PRODUCTS DESIGN Co Ltd
Priority to CN201711451691.7A priority Critical patent/CN108185604A/en
Publication of CN108185604A publication Critical patent/CN108185604A/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45B—WALKING STICKS; UMBRELLAS; LADIES' OR LIKE FANS
    • A45B25/00—Details of umbrellas
    • A45B25/02—Umbrella frames
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45B—WALKING STICKS; UMBRELLAS; LADIES' OR LIKE FANS
    • A45B25/00—Details of umbrellas
    • A45B25/18—Covers; Means for fastening same
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/404—Multi-coloured

Abstract

The invention discloses a kind of discoloration umbrellas, including umbrella stand and umbrella cloth, umbrella cloth is made of discoloration umbrella material, the discoloration umbrella material includes discoloration material layer, discoloration material layer includes blue variable colour material, green colourshift material, transparent polymer matrix and bearing bed, wherein, transparent polymer matrix is the film compound that organic film and non-organic film are combined, blue variable colour material, green colourshift material is attached to transparent polymer matrix both sides, by sunlight, or rainwater drenches, umbrella surface is more than single color burn variation, it can also realize the transformation of different colours, so that umbrella more creates an aesthetic feeling when in use, improve the interest of consumer.

Description

A kind of changeable colour umbrella and umbrella cloth manufacturing method
Technical field
The present invention relates to and rain gear technical field more particularly to a kind of changeable colour umbrella and umbrella cloth manufacturing method.
Background technology
Umbrella is that a kind of can be used with sunshade or the life for the preventing wetting that keeps off the rain auxiliary in daily life using commonplace Tool, some are artificial to make umbrella more beautiful, then increases a variety of different patterns on umbrella cover or somewhat by stealthy figure Case displays after rainwater drenches from heightening the color, relatively simple, does not also have a coloured significant change, on color Still it is more single.
Invention content
In view of the problems of the existing technology, the present invention provides a kind of discoloration umbrella, including umbrella stand and umbrella cloth, umbrella cloth by Change colour umbrella material composition, which includes discoloration material layer, and discoloration material layer includes blue variable colour material, green Off-color material, transparent polymer matrix and bearing bed, wherein, transparent polymer matrix is organic film and non-organic film phase With reference to film compound, blue variable colour material, green colourshift material are attached to transparent polymer matrix both sides.
Specifically, blue variable colour material, green colourshift material, transparent polymer matrix are located above the bearing bed.
Specifically, blue variable colour material is staggeredly uniformly distributed with green colourshift material.
Specifically, organic film and non-organic film are by NiO, WO3、V2O5、WO3One or more compositions.
Specifically, bearing bed is synthesized by ion polyvinyl chloride and is fixed on umbrella support.
Specifically, blue variable colour material and green colourshift material are also organic chelated comprising oxidation-reduction type compound, metal Object.
Specifically, transparent polymer matrix is also comprising ultra-violet absorber, with the total of 10 parts by weight transparent polymer matrix On the basis of weight, the content of ultra-violet absorber is 0-6 parts by weight.
In view of the problems of the existing technology, the present invention also provides it is a kind of change colour umbrella umbrella cloth manufacturing method, including Following step：
S101, high temperature polymerization ion polyvinyl chloride are synthesized and are molded, and make bearing bed, and suitable for without the umbrella cover shape of umbrella size Shape；
S102, blue variable colour material, green colourshift material are attached to the transparent polymer matrix both sides, blue variable colour material Positioned at the top, and pass through one-shot forming technique and be fixed on above bearing bed, the blue variable colour material and green colourshift material It is horizontally staggered and is uniformly distributed so that the position that blue variable colour material is not covered with is become by green colourshift material blocks or green The position that color material is not covered with is by blue variable colour material blocks；
S103, the discoloration umbrella completed by UV irradiations, the irradiation time are 1 hour or more.
Compared with prior art, the advantage of the invention is that：By drenching for sunlight or rainwater, umbrella surface More than single color burn variation, can also realize the transformation of different colours so that umbrella more creates an aesthetic feeling when in use, carries The interest of high consumption person.
Description of the drawings
Fig. 1 is a kind of discoloration umbrella material structure schematic diagram for the umbrella that changes colour of the present invention.
Fig. 2 is a kind of umbrella cloth manufacturing method flow chart for the umbrella that changes colour of the present invention.
Specific embodiment
With reference to the accompanying drawings and detailed description, the present invention is furture elucidated.
As shown in Figure 1, an embodiment of the present invention provides a kind of discoloration umbrella, including umbrella stand and umbrella cloth, umbrella cloth is by discoloration rain Umbrella material forms, which includes discoloration material layer 1, and discoloration material layer 1 includes blue variable colour material, green colourshift Material, transparent polymer matrix 2 and bearing bed 3, wherein, transparent polymer matrix 2 is organic film and non-organic film phase With reference to film compound, blue variable colour material, green colourshift material are attached to 2 both sides of transparent polymer matrix.
In the embodiment, discoloration material layer WO3(colourless tungsten oxide), using the electrochromism mechanism of WO3 films, I.e. because the effect of extra electric field, electronics and cationic ore deposit are injected in WO3 simultaneously from film both sides respectively, electronics is captured by W atoms Localized modes are formed, metal ions M+be then resident forms navy blue tungsten bronze compound MxWO3 " in this region to be existed in MxWO3 The W ion of different valence state, transition of the electronics between neighbouring different valence state W atoms cause WO3 film colors to change.Its electricity Chemical process is shown below：
WO3(colourless tungsten oxide)+xM++xe-⇆MxWO3（Navy blue tungsten bronze compound）
W5+（A）+W6+（B）+hv⇆W6++MxW0 6+（Black）
MxWO3+MxW0 6++H2O=Mx +HWO4（Wolframic acid hyrate）
M is generally H, Li, Na, Ag etc. in formula, and 0<x<HxWO3 is formed behind 1, such as H injections.
Specifically, blue variable colour material, green colourshift material, transparent polymer matrix are located at 3 top of bearing bed.
Specifically, blue variable colour material is staggeredly uniformly distributed with green colourshift material.
Specifically, organic film and non-organic film are by NiO, WO3、V2O5、WO3One or more compositions.
Specifically, bearing bed is synthesized by ion polyvinyl chloride and is fixed on umbrella support.
Specifically, blue variable colour material and green colourshift material are also organic chelated comprising oxidation-reduction type compound, metal Object.
Specifically, transparent polymer matrix is also comprising ultra-violet absorber, with the total of 10 parts by weight transparent polymer matrix On the basis of weight, the content of ultra-violet absorber is 0-6 parts by weight.
As shown in Fig. 2, the embodiment of the present invention additionally provides a kind of umbrella cloth manufacturing method for the umbrella that changes colour, including following steps Suddenly：
S101, high temperature polymerization ion polyvinyl chloride are synthesized and are molded, and make bearing bed, and suitable for without the umbrella cover shape of umbrella size Shape；
S102, blue variable colour material, green colourshift material are attached to the transparent polymer matrix both sides, blue variable colour material Positioned at the top, and pass through one-shot forming technique and be fixed on above bearing bed, the blue variable colour material and green colourshift material It is horizontally staggered and is uniformly distributed so that the position that blue variable colour material is not covered with is become by green colourshift material blocks or green The position that color material is not covered with is by blue variable colour material blocks；
S103, it is irradiated by UV and completes discoloration umbrella, the irradiation time is 1 hour or more.

Claims (8)

1. a kind of discoloration umbrella, including umbrella stand and umbrella cloth, it is characterised in that：Umbrella cloth is made of discoloration umbrella material, the discoloration Umbrella material includes discoloration material layer, and the discoloration material layer includes blue variable colour material, green colourshift material, transparent polymer Matrix and bearing bed, wherein, the transparent polymer matrix is the film chemical combination that organic film and non-organic film are combined Object, the blue variable colour material, green colourshift material are attached to the transparent polymer matrix both sides.
2. a kind of discoloration umbrella according to claim 1, it is characterised in that：The blue variable colour material, green colourshift material Material, transparent polymer matrix are located above the bearing bed.
3. a kind of discoloration umbrella according to claim 1, it is characterised in that：The blue variable colour material and green colourshift material Material is staggeredly uniformly distributed.
4. a kind of discoloration umbrella according to claim 1, it is characterised in that：The organic film and non-organic film by NiO、WO3、V2O5、WO3One or more compositions.
5. a kind of discoloration umbrella according to claim 1, it is characterised in that：The bearing bed is synthesized by ion polyvinyl chloride And it is fixed on umbrella support.
6. a kind of discoloration umbrella according to claim 1, it is characterised in that：The blue variable colour material and green colourshift material Material is also comprising oxidation-reduction type compound, metal organic chelate.
7. a kind of discoloration umbrella according to claim 1, it is characterised in that：The transparent polymer matrix is also comprising ultraviolet Light absorbers, on the basis of the total weight of 10 parts by weight transparent polymer matrix, the content of ultra-violet absorber is 0-6 weight Part.
8. a kind of umbrella cloth manufacturing method for the umbrella that changes colour, it is characterised in that：Include the following steps：
S101, high temperature polymerization ion polyvinyl chloride are synthesized and are molded, and make bearing bed, and suitable for without the umbrella cover shape of umbrella size Shape；
S102, blue variable colour material, green colourshift material are attached to the transparent polymer matrix both sides, blue variable colour material Positioned at the top, and pass through one-shot forming technique and be fixed on above bearing bed, the blue variable colour material and green colourshift material It is horizontally staggered and is uniformly distributed so that the position that blue variable colour material is not covered with is become by green colourshift material blocks or green The position that color material is not covered with is by blue variable colour material blocks；
S103, the discoloration umbrella completed by UV irradiations, the irradiation time are 1 hour or more.
CN201711451691.7A 2017-12-28 2017-12-28 A kind of changeable colour umbrella and umbrella cloth manufacturing method Pending CN108185604A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711451691.7A CN108185604A (en) 2017-12-28 2017-12-28 A kind of changeable colour umbrella and umbrella cloth manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711451691.7A CN108185604A (en) 2017-12-28 2017-12-28 A kind of changeable colour umbrella and umbrella cloth manufacturing method

Publications (1)

Publication Number Publication Date
CN108185604A true CN108185604A (en) 2018-06-22

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CN201711451691.7A Pending CN108185604A (en) 2017-12-28 2017-12-28 A kind of changeable colour umbrella and umbrella cloth manufacturing method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111650798A (en) * 2020-07-03 2020-09-11 泉州夏宇伞业有限公司 Electrochromic transparent umbrella cloth and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201045920Y (en) * 2006-12-12 2008-04-16 林进辉 Umbrella with transmutability superficies pattern
CN101819007A (en) * 2010-03-29 2010-09-01 中国人民解放军总后勤部军需装备研究所 Transmission type electrochromic device-based color-changing camouflage fabric and preparation method thereof
CN102918454A (en) * 2010-05-27 2013-02-06 埃西勒国际通用光学公司 Method of manufacturing an electrochromic article
CN202800425U (en) * 2012-08-02 2013-03-20 慈溪市兰星塑胶实业有限公司 Discoloring film umbrella
CN106805413A (en) * 2015-11-27 2017-06-09 襄阳市第四十二中学 Transparent umbrella

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201045920Y (en) * 2006-12-12 2008-04-16 林进辉 Umbrella with transmutability superficies pattern
CN101819007A (en) * 2010-03-29 2010-09-01 中国人民解放军总后勤部军需装备研究所 Transmission type electrochromic device-based color-changing camouflage fabric and preparation method thereof
CN102918454A (en) * 2010-05-27 2013-02-06 埃西勒国际通用光学公司 Method of manufacturing an electrochromic article
CN202800425U (en) * 2012-08-02 2013-03-20 慈溪市兰星塑胶实业有限公司 Discoloring film umbrella
CN106805413A (en) * 2015-11-27 2017-06-09 襄阳市第四十二中学 Transparent umbrella

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111650798A (en) * 2020-07-03 2020-09-11 泉州夏宇伞业有限公司 Electrochromic transparent umbrella cloth and manufacturing method thereof
CN111650798B (en) * 2020-07-03 2022-09-23 泉州夏宇伞业有限公司 Electrochromic transparent umbrella cloth and manufacturing method thereof

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Application publication date: 20180622