CN108185022A - A kind of emulsion oil-in-water of high oxidation stability and preparation method thereof - Google Patents

A kind of emulsion oil-in-water of high oxidation stability and preparation method thereof Download PDF

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Publication number
CN108185022A
CN108185022A CN201711211424.2A CN201711211424A CN108185022A CN 108185022 A CN108185022 A CN 108185022A CN 201711211424 A CN201711211424 A CN 201711211424A CN 108185022 A CN108185022 A CN 108185022A
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oil
lactalbumin
water
xanthans
oxidation stability
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孙婵婵
张民
梁彬
吴涛
刘锐
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Tianjin University of Science and Technology
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Tianjin University of Science and Technology
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/02Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by the production or working-up
    • A23D7/04Working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:Micronized lactalbumin dispersion liquid:20~70 parts;Xanthans system:10~30 parts;Oil phase:10 60 parts.Lactalbumin particle and xanthans form multilayer interfacial film on the surface of grease in this lotion; it can not only the contact with grease such as starvation, prooxidant; it can also prevent to assemble between oil droplet; the oxidation stability and physical stability for keeping lotion higher; therefore it can be used in the protection and transport of fat-soluble sensitive biochemical active constituent, there is preferable application prospect.

Description

A kind of emulsion oil-in-water of high oxidation stability and preparation method thereof
Technical field
The invention belongs to food processing technology field, the emulsion oil-in-water and its system of especially a kind of high oxidation stability Preparation Method.
Background technology
Oil-in-water (O/W) type product emulsion is system form important in food processing, in addition to conventional cream, color It draws outside flavouring, mayonnaise, meat and meat products, many sensibility nutrients, essence, pigment and function factor etc. are also formed as O/ W-type emulsion, and be widely used in food industry.Stability of emulsion is most important property in its many physicochemical property, only Under conditions of reasonable control system stability, product mouthfeel and other functional characteristics just can guarantee.
Biological food macromolecule such as albumen and polysaccharide, is natural and is typically considered safe raw material, can be used to The diversified controlled release system for being suitable for embedding and protecting lipophilic bioactive substance is prepared, such as hydrogel, lotion, microballoon With micro-nano granules etc..Lotion containing protein is being stored in process, there is induction polyunsaturated fatty acid fat always Matter peroxidating stress environment, lipid free radical, hydroperoxides, the secondary oxidation product of activity and work in lipid peroxidation system Property oxygen (ROS) can further attack the amino acid side chain of protein in interfacial film, cause miaow diindyl ring (histidine), indyl The oxidation of the amino acid side chains such as (tryptophan) and sulfydryl (cysteine and methionine) is damaged so as to cause lipid and proteinaceous nutrient It loses, flavor deteriorates, protein processing characteristics (hydration, gelation and interfacial property) conspicuousness reduces, and then leads to lotion Unstability.Therefore, it is urgent problem to be solved in food industry to improve lipid oxidation stability in lotion.Research shows that distribution Accelerate lipid oxidation, therefore, O/W type lotions in oil-water interfaces lipid hydroperoxide and the interaction of water phase transition metal ions Lipid oxidation stability and oil droplet interface physicochemical characteristic are highly relevant.By control oil-water interfaces chemical composition, interfacial thickness with And charge attribute, it can effectively control Oxidation of Fat and Oils.
By retrieval, following several and the relevant patent publication us of present patent application are found:
1st, a kind of high-temperature stable antioxidant emulsion and preparation method thereof (201611171792.4), the invention are first will Antioxidant 1076 (β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester, C35H6203) and anti-oxidant 245 (double β-(3- tertiary butyl-4-hydroxy -5- the aminomethyl phenyls)-propionic esters of triethylene-glycol) mixed dissolution, prepares mixture I.Again Say that emulsifier polyvinyl alcohol 1799 prepares mixtures II after dissolving.Mixtures II is slowly added dropwise into mixed under certain stir speed (S.S.) It closes in object I, Temperature fall is to get product.The present invention provides a kind of preparation method of the antioxidant emulsion of high-temperature stable, letter It is single easy, it is suitble to industrial production, and the emulsion has high oxidation stability.
2nd, a kind of method (201610081428.2) for the antioxidative stabilizer for improving milk, the present invention provides one kind to carry The method of the antioxidative stabilizer of high milk, including by the ratio between quality volume 1:8~12 lycopene is dissolved in ethyl acetate In, it is dissolved at 50 DEG C~70 DEG C and obtains core material solution;It is molten as wall material that the solution for containing maillard reaction product is prepared Liquid;The core material solution is taken to be added in the wall material solution, is stirred, then the method by rotary evaporation, at 35~40 DEG C Low-temperature evaporation goes out organic solvent extra in mixed liquor, so as to obtain the lotion for the solid content for meeting this experimental design, so Lycopene microcapsule is finally made by two-step method in homogeneous again afterwards;By the lycopene microcapsule according to mass percent 0.1%~0.7% is added in milk.Application process of the present invention is simple, has no toxic side effect, and stablizes milk performance, from basic On solve lycopene and be difficult to be applied directly to the defects of liquid dairy product when not soluble in water.
By comparison, there is the difference of essence with above-mentioned patent publication us in present patent application.
Invention content
It is poor it is an object of the invention to be directed to current lotion oxidation stability, in place of overcome the deficiencies in the prior art, provide A kind of emulsion oil-in-water of high oxidation stability and preparation method thereof, lactalbumin particle and xanthans are in grease in the lotion Surface form multilayer interfacial film, can not only the contact with grease such as starvation, prooxidant, moreover it is possible to prevent to gather between oil droplet Collection, the oxidation stability and physical stability for keeping lotion higher, therefore fat-soluble sensitive biochemical can be widely used in The protection of active constituent is neutralized in transport, has preferable application prospect.
To achieve these goals, technical solution of the present invention is as follows:
A kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:20~70 parts;
Xanthans system:10~30 parts;
Oil phase:10-60 parts.
Moreover, the preparation method of the micronized lactalbumin dispersion liquid is as follows:
By PURE WHEY using water dissolution, the lactalbumin dispersion liquid of a concentration of 0.10~0.15g/mL is obtained, adjusts pH To 4.0~8.0;Humid heat treatment 10~40 minutes, are cooled to room temperature in 80~100 DEG C of waters bath with thermostatic control, then in 0~10 DEG C of temperature Degree is lower to be placed 5~24 hours, obtains lactalbumin gel;Obtained lactalbumin gel will be aged using 10000~15000r/ Min carries out micronized and handles 2~9 minutes.
Moreover, the protein content of the lactalbumin powder raw material is 50%~100%.
Moreover, the adjusting pH is adjusted using citric acid or sodium bicarbonate.
Moreover, the preparation method of the xanthans system is as follows:
It is 1 in mass ratio by xanthans and water:25~1:It after 35 mixing, is heat-treated 1~40 minute in 75-100 DEG C, stirring Uniformly to get xanthans system.
Moreover, the oil-based system is food-grade oil.
Moreover, the food-grade oil is edible oil or animal oil.
Moreover, the edible oil is soybean oil, peanut oil, sunflower oil or corn oil, the animal oil is fish oil, butter Or lard.
A kind of preparation method of the emulsion oil-in-water of high oxidation stability as described above, the method is with lactalbumin It is main base with xanthans, using humid heat treatment and Technique for Preparing Fine, with reference to compounded technology and homogeneous technology, height is prepared The emulsion oil-in-water of oxidation stability.
Moreover, it is as follows:
(1) the preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, obtain a concentration of 0.10~ The lactalbumin dispersion liquid of 0.15g/mL adjusts pH to 4.0~8.0;The humid heat treatment 10~40 in 80~100 DEG C of waters bath with thermostatic control Minute, it is cooled to room temperature, is then placed 5~24 hours at a temperature of 0~10 DEG C, obtain lactalbumin gel;It will be aged what is obtained Lactalbumin gel carries out micronized using 10000~15000r/min and handles 2~9 minutes;
(2) the preparation of xanthans system:It is 1 in mass ratio by xanthans and water:25~1:After 35 mixing, in 75-100 DEG C Heat treatment 1~40 minute, stirs evenly to get xanthans system;
(3) the preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthan colloid After system is compounded, stirred 2~10 minutes in 60~400r/min;
(4) oil phase is slowly added into micronized lactalbumin-xanthan under 8000~15000r/min high speed shear rates In glue compound, and continue 2~10 minutes emulsion oil-in-waters to get high oxidation stability of homogeneous.
The advantages of present invention obtains and good effect are:
1st, lactalbumin particle and xanthans form multilayer interfacial film on the surface of grease in lotion of the present invention, can not only The contact with grease such as starvation, prooxidant, moreover it is possible to prevent to assemble between oil droplet, keep the higher oxidation stability of lotion and Physical stability, therefore the protection that can be widely used in fat-soluble sensitive biochemical active constituent is neutralized in transport, is had Preferable application prospect.
2nd, the method for the present invention is using lactalbumin and xanthans as raw material, using humid heat treatment, Technique for Preparing Fine and compounding skill Art prepares micronized lactalbumin-xanthans compound, and oil phase is added in compound to obtain high oxidation through homogenization steady Qualitatively oil-in-water emulsion, this method application process is simple, and raw material is natural, has no toxic side effect, and the lotion of preparation not only has height Oxidation stability, also with high physical stability.
Description of the drawings
Fig. 1 is emulsion intercalation method kinetic index measurement result figure of the present invention;
Fig. 2 is the oil droplet average grain diameter measurement result figure of lotion of the present invention;
Fig. 3 is the Viscosity Factor (a) of lotion of the present invention and the measurement result figure of spring factor (b);
Fig. 4 is measurement result figure of the lotion of the present invention in the peroxide value of storage period.
Specific embodiment
With reference to embodiment, the present invention is further described;Following case study on implementation are illustrative, are not limited , it is impossible to limit protection scope of the present invention with following embodiments.
Reagent used in the present invention is common agents in the art unless otherwise required;Used in the present invention Method, be common method in the art unless otherwise required.
Embodiment 1
A kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:50 parts;
Xanthans system:20 parts;
Oil phase:30 parts.
The preparation method of above-mentioned high oxidation stability oil-in-water emulsion, step are as follows:
(1) preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, a concentration of 0.15g/mL is obtained Lactalbumin dispersion liquid, adjust pH to 6.5;Humid heat treatment 10 minutes, are cooled to room temperature in 80 DEG C of waters bath with thermostatic control, Ran Hou It is placed 15 hours at a temperature of 10 DEG C, obtains lactalbumin gel;To be aged obtained lactalbumin gel using 10000r/min into Row micronized handles 3 minutes to get micronized lactalbumin dispersion liquid.
(2) preparation of xanthans system:It is 1 in mass ratio by xanthans and water:After 25 mixing, 40 points are heat-treated in 75 DEG C Clock is stirred evenly to get xanthans system.
(3) preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthan colloid After system is compounded, 10min is stirred in 400r/min.
(4) preparation of lotion:Under 8000r/min high speed shear rates by oil phase be slowly added to micronized lactalbumin- In xanthans compound, and continue after homogeneous 3min to get the O/W type lotions of high oxidation stability.
Embodiment 2
A kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:70 parts;
Xanthans system:10 parts;
Oil phase:20 parts.
The preparation method of the O/W type lotions of above-mentioned high oxidation stability, step are as follows:
(1) preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, a concentration of 0.10g/mL is obtained Lactalbumin dispersion liquid, adjust pH to 4.0;Humid heat treatment 15 minutes, are cooled to room temperature in 90 DEG C of waters bath with thermostatic control, Ran Hou It is placed 10 hours at a temperature of 4 DEG C, obtains lactalbumin gel;Obtained lactalbumin gel will be aged using 12000r/min progress Micronized handles 6 minutes to get micronized lactalbumin dispersion liquid.
(2) preparation of xanthans system:It is 1 in mass ratio by xanthans and water:After 30 mixing, 20 points are heat-treated in 90 DEG C Clock is stirred evenly to get xanthans system.
(3) preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthan colloid After system is compounded, 5min is stirred in 200r/min.
(4) preparation of lotion:Under 10000r/min high speed shear rates by oil phase be slowly added to micronized lactalbumin- In xanthans compound, and continue stir 5min after to get high oxidation stability oil-in-water emulsion.
Embodiment 3
A kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:20 parts;
Xanthans system:30 parts;
Oil phase:50 parts.
The preparation method of above-mentioned high oxidation stability oil-in-water emulsion, step are as follows:
(1) preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, a concentration of 0.12g/mL is obtained Lactalbumin dispersion liquid, adjust pH to 5.0;Humid heat treatment 10min, is cooled to room temperature in 95 DEG C of waters bath with thermostatic control, then 3 It is placed 10 hours at a temperature of DEG C, obtains lactalbumin gel;Obtained lactalbumin gel will be aged using 15000r/min progress Micronized handles 9 minutes to get micronized lactalbumin dispersion liquid.
(2) preparation of xanthans system:It is 1 in mass ratio by xanthans and water:After 35 mixing, 5 points are heat-treated in 100 DEG C Clock is stirred evenly to get xanthans system.
(3) preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthan colloid After system is compounded, 10min is stirred in 400r/min.
(4) that oil phase is slowly added to micronized lactalbumin-xanthans under 15000r/min high speed shear rates is compound In object, and continue stir 10min after to get high oxidation stability oil-in-water emulsion.
Embodiment 4
A kind of emulsion oil-in-water of high oxidation stability, constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:20~70 parts;
Xanthans system:10~30 parts;
Oil phase:10-60 parts.
More preferably, the preparation method of the micronized lactalbumin dispersion liquid is as follows:
By PURE WHEY using water dissolution, the lactalbumin dispersion liquid of a concentration of 0.10~0.15g/mL is obtained, adjusts pH To 4.0~8.0;Humid heat treatment 10~40 minutes, are cooled to room temperature in 80~100 DEG C of waters bath with thermostatic control, then in 0~10 DEG C of temperature Degree is lower to be placed 5~24 hours, obtains lactalbumin gel;Obtained lactalbumin gel will be aged using 10000~15000r/ Min carries out micronized and handles 2~9 minutes.
More preferably, the protein content of the lactalbumin powder raw material is 50%~100%.
More preferably, the adjusting pH is adjusted using citric acid or sodium bicarbonate.
More preferably, the preparation method of the xanthans system is as follows:
It is 1 in mass ratio by xanthans and water:25~1:It after 35 mixing, is heat-treated 1~40 minute in 75-100 DEG C, stirring Uniformly to get xanthans system.
More preferably, the oil-based system is food-grade oil.
More preferably, the food-grade oil is edible oil or animal oil.
More preferably, the edible oil is soybean oil, peanut oil, sunflower oil or corn oil, and the animal oil is fish oil, Huang Oil or lard.
The preparation method of the emulsion oil-in-water of above-mentioned high oxidation stability, the method is with lactalbumin and xanthans For main base, using humid heat treatment and Technique for Preparing Fine, with reference to compounded technology and homogeneous technology, high oxidation stabilization is prepared The emulsion oil-in-water of property.
More preferably, it is as follows:
(1) the preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, obtain a concentration of 0.10~ The lactalbumin dispersion liquid of 0.15g/mL adjusts pH to 4.0~8.0;The humid heat treatment 10~40 in 80~100 DEG C of waters bath with thermostatic control Minute, it is cooled to room temperature, is then placed 5~24 hours at a temperature of 0~10 DEG C, obtain lactalbumin gel;It will be aged what is obtained Lactalbumin gel carries out micronized using 10000~15000r/min and handles 2~9 minutes;
(2) the preparation of xanthans system:It is 1 in mass ratio by xanthans and water:25~1:After 35 mixing, in 75-100 DEG C Heat treatment 1~40 minute, stirs evenly to get xanthans system;
(3) the preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthan colloid After system is compounded, stirred 2~10 minutes in 60~400r/min;
(4) oil phase is slowly added into micronized lactalbumin-xanthan under 8000~15000r/min high speed shear rates In glue compound, and continue 2~10 minutes emulsion oil-in-waters to get high oxidation stability of homogeneous.
The related test results of the compound fat analogue of the present invention:
The oil-in-water emulsion prepared using lactalbumin and micronized lactalbumin as emulsifier is control, steady using Almightiness type Qualitative analysis instrument is measured stability kinetic index of the lotion in storage period, and the results are shown in Figure 1.Stability power It is higher to learn index (TSI), illustrates that stability of emulsion is poorer.Fig. 1 is shown, using micronized lactalbumin-xanthans compound system Standby lotion has relatively low TSI values, illustrates there is higher storage-stable.
The oil-in-water emulsion prepared using lactalbumin and micronized lactalbumin as emulsifier is control, steady using Almightiness type Qualitative analysis instrument to lotion, analyze by the oil droplet average grain diameter in storage, and the results are shown in Figure 2.It can be seen by result Go out, oil droplet average grain diameter gradually increases in storage in lactalbumin lotion and micronized lactalbumin lotion, illustrates to occur It polymerize between oil droplet.And oil droplet average grain diameter is kept constant in storage in lotion prepared by the method for the present invention, is illustrated simultaneously Unstable phenomenon does not occur.
The oil-in-water emulsion prepared using lactalbumin and micronized lactalbumin as emulsifier is control, utilizes optics miniflow Become analyzer to analyze the rheological behavior of lotion, the results are shown in Figure 3.Viscosity Factors of the Fig. 3 (a) for lotion, Fig. 3 (b) For spring factor.Fig. 3 shows that lotion prepared by the method for the present invention has higher viscoplasticity, this is for preventing oxygen and antioxygen The diffusion of agent is of great significance.
Using grease as control, peroxide value (PV) of the lotion in storage period is measured, as a result as shown in Figure 4.Present invention side For lotion prepared by method in storage, PV values conspicuousness is less than grease, illustrates there is higher oxidation stability.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to preferable The present invention is described in detail in embodiment, it will be understood by those of ordinary skill in the art that, it can be to the technology of the present invention Scheme is modified or replaced equivalently, and without departing from the spirit and scope of technical solution of the present invention, should all be covered in this hair In bright right.

Claims (10)

1. a kind of emulsion oil-in-water of high oxidation stability, it is characterised in that:Its constituent and parts by weight are as follows:
Micronized lactalbumin dispersion liquid:20~70 parts;
Xanthans system:10~30 parts;
Oil phase:10-60 parts.
2. the emulsion oil-in-water of high oxidation stability according to claim 1, it is characterised in that:The micronized whey The preparation method of protein dispersion is as follows:
By PURE WHEY using water dissolution, the lactalbumin dispersion liquid of a concentration of 0.10~0.15g/mL is obtained, adjusts pH to 4.0 ~8.0;Humid heat treatment 10~40 minutes, are cooled to room temperature in 80~100 DEG C of waters bath with thermostatic control, then at a temperature of 0~10 DEG C It places 5~24 hours, obtains lactalbumin gel;To be aged obtained lactalbumin gel using 10000~15000r/min into Row micronized is handled 2~9 minutes.
3. the emulsion oil-in-water of high oxidation stability according to claim 2, it is characterised in that:The PURE WHEY The protein content of raw material is 50%~100%.
4. the emulsion oil-in-water of high oxidation stability according to claim 2, it is characterised in that:The adjusting pH is used Citric acid or sodium bicarbonate are adjusted.
5. the emulsion oil-in-water of high oxidation stability according to claim 1, it is characterised in that:The xanthans system Preparation method it is as follows:
It is 1 in mass ratio by xanthans and water:25~1:It after 35 mixing, is heat-treated 1~40 minute in 75-100 DEG C, stirring is equal It is even to get xanthans system.
6. the emulsion oil-in-water of high oxidation stability according to claim 1, it is characterised in that:The oil-based system is Food-grade oil.
7. the emulsion oil-in-water of high oxidation stability according to claim 6, it is characterised in that:The food-grade oil is Edible oil or animal oil.
8. the emulsion oil-in-water of high oxidation stability according to claim 7, it is characterised in that:The edible oil is big Soya-bean oil, peanut oil, sunflower oil or corn oil, the animal oil are fish oil, butter or lard.
9. a kind of preparation method of such as emulsion oil-in-water of claim 1 to 8 any one of them high oxidation stability, special Sign is:The method is using lactalbumin and xanthans as main base, using humid heat treatment and Technique for Preparing Fine, with reference to compounding The emulsion oil-in-water of high oxidation stability is prepared in technology and homogeneous technology.
10. the preparation method of the emulsion oil-in-water of high oxidation stability according to claim 9, it is characterised in that:Tool Body step is as follows:
(1) the preparation of micronized lactalbumin dispersion liquid:By PURE WHEY using water dissolution, a concentration of 0.10~0.15g/ is obtained The lactalbumin dispersion liquid of mL adjusts pH to 4.0~8.0;Humid heat treatment 10~40 minutes in 80~100 DEG C of waters bath with thermostatic control, It is cooled to room temperature, is then placed 5~24 hours at a temperature of 0~10 DEG C, obtain lactalbumin gel;Obtained whey egg will be aged White gel carries out micronized using 10000~15000r/min and handles 3~9 minutes particles to get more than 72% gross mass Diameter is less than 10 μm of micronized lactalbumin dispersion liquid;
(2) the preparation of xanthans system:It is 1 in mass ratio by xanthans and water:25~1:After 35 mixing, at 75-100 DEG C of heat Reason 1~40 minute, stirs evenly to get xanthans system;
(3) the preparation of micronized lactalbumin-xanthans compound:By micronized lactalbumin dispersion liquid and xanthans system into After row compounding, stirred 2~10 minutes in 60~400r/min;
(4) it is multiple oil phase to be slowly added into micronized lactalbumin-xanthans under 8000~15000r/min high speed shear rates It closes in object, and continues 2~10 minutes emulsion oil-in-waters to get high oxidation stability of homogeneous.
CN201711211424.2A 2017-11-28 2017-11-28 A kind of emulsion oil-in-water of high oxidation stability and preparation method thereof Pending CN108185022A (en)

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CN110742851A (en) * 2019-11-12 2020-02-04 沈阳师范大学 Aerated emulsion and preparation method and application thereof
CN111588654A (en) * 2020-06-08 2020-08-28 大连工业大学 Edible antibacterial oleogel and preparation method thereof
CN112655958A (en) * 2020-12-29 2021-04-16 中华全国供销合作总社济南果品研究院 Glossy ganoderma spore oil protein-polysaccharide composite emulsion and preparation method thereof
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CN114786505A (en) * 2019-10-16 2022-07-22 科劳弗股份有限公司 Protein encapsulation of nutritional and pharmaceutical compositions

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Cited By (7)

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CN109601612A (en) * 2019-01-16 2019-04-12 山东省果树研究所 A kind of pickering emulsion and preparation method thereof loading cinnamon essential oil
CN110200260A (en) * 2019-06-28 2019-09-06 上海海融食品科技股份有限公司 A kind of resistance to baking Ka Shida sauce of floorboard with high oil content oil-in-water type and preparation method thereof
CN114786505A (en) * 2019-10-16 2022-07-22 科劳弗股份有限公司 Protein encapsulation of nutritional and pharmaceutical compositions
CN110742851A (en) * 2019-11-12 2020-02-04 沈阳师范大学 Aerated emulsion and preparation method and application thereof
CN111588654A (en) * 2020-06-08 2020-08-28 大连工业大学 Edible antibacterial oleogel and preparation method thereof
CN112655958A (en) * 2020-12-29 2021-04-16 中华全国供销合作总社济南果品研究院 Glossy ganoderma spore oil protein-polysaccharide composite emulsion and preparation method thereof
CN113475719A (en) * 2021-06-11 2021-10-08 南京农业大学 Sarcoplasmic protein-xanthan gum composite emulsion and preparation method and application thereof

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