CN108183290A - A kind of SMART METALS air battery system - Google Patents

A kind of SMART METALS air battery system Download PDF

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Publication number
CN108183290A
CN108183290A CN201711453406.5A CN201711453406A CN108183290A CN 108183290 A CN108183290 A CN 108183290A CN 201711453406 A CN201711453406 A CN 201711453406A CN 108183290 A CN108183290 A CN 108183290A
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CN
China
Prior art keywords
threeway
solenoid valve
battery pack
air battery
smart metals
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Pending
Application number
CN201711453406.5A
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Chinese (zh)
Inventor
张树雄
洪磊
张云帆
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Individual
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Individual
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Priority to CN201711453406.5A priority Critical patent/CN108183290A/en
Publication of CN108183290A publication Critical patent/CN108183290A/en
Priority to US16/139,045 priority patent/US11145920B2/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/627Stationary installations, e.g. power plant buffering or backup power supplies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6561Gases
    • H01M10/6563Gases with forced flow, e.g. by blowers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04276Arrangements for managing the electrolyte stream, e.g. heat exchange
    • H01M8/04283Supply means of electrolyte to or in matrix-fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/10Batteries in stationary systems, e.g. emergency power source in plant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/10Fuel cells in stationary systems, e.g. emergency power source in plant
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hybrid Cells (AREA)

Abstract

A kind of SMART METALS air battery system can automatically control the operating of metal-air battery, and energy density height, safety and environmental protection, cost is relatively low, is easily used.This SMART METALS air battery system, control centre (14) starts the second self priming pump (6.2), electrolyte in electrolyte tank (2) is through the 4th tube outlet (fourth), second self priming pump (6.2), 4th threeway (d), radiator (12), 6th threeway (f), 5th solenoid valve (3.5), 8th threeway (h), battery pack (9), 9th threeway (i), 7th threeway (g), third solenoid valve (3.3), 5th threeway (e), third threeway (c), third tube outlet (third) is returned in electrolyte tank (2);When by battery pack (9), battery pack produces electricl energy and external output current electrolyte, and triggering battery pack fan (8) and exhaust fan (11) start.

Description

A kind of SMART METALS air battery system
Technical field
Technical field more particularly to a kind of SMART METALS air battery system the present invention relates to new energy battery, master The metal-air battery of the stand-by power supply as large and medium-sized electrical equipment is directed to, the fortune of metal-air battery can be automatically controlled Turn.
Background technology
Metal fuel air cell (i.e. metal-air battery) be using the oxygen in air as positive active material, using metal as Negative electrode active material using conducting solution as electrolyte, issues biochemical reaction in the catalytic action of catalyst and produces electricl energy A kind of electrochmical power source.
Metal-air battery has many unique advantages, and fuel is metal material, such as aluminium, magnesium, zinc and lithium, sodium Wait metals;Because combust aluminium, magnesium, zinc reserves are very abundant, metal-air battery resource enough can be supplied.Positive active material is empty Oxygen in gas, battery do not have to carry in itself, and the energy size entrained by battery is determined by the amount of negative metal so that this kind of electricity The practical of pond can reach more than 350Wh/kg (at present lithium ion battery be 100Wh/kg) than energy, have the great performance excellent Gesture.Product after reaction can utilize the clean energy resourcies such as wind energy, solar energy, water energy or the electric energy of electric energy areas of well-being again Electrolysis of aluminum oxide (or magnesium hydroxide) becomes metal, is then again mounted to metal-air battery electric discharge, drives electric vehicle.In this way It can realize the large-scale production of concentration, it is possible to reduce pollution reduces discharge, and can realize centrally connected power supply, and dispersion makes With, by lower-cost electric energy transfer to the high place use of the cost of electric energy, the place transfer that electric energy is easily obtained from the energy The place for being difficult to obtain to the energy uses.It can really realize the completely new auto Life of pollution-free zero-emission.It realizes in the process Pollution-free, the green energy resource of zero-emission recycles, and metal-air battery worldwide increasingly draws attention.
Above-mentioned advantage based on metal-air battery, many countries and individual prepare more practical similar production in research Product.When stand-by power supply of the metal-air battery as large and medium-sized electrical equipment, need to put into a large amount of manpower and materials and be tieed up Shield and control, with high costs, use is complicated for operation., in the case where maintenance is simple or non-maintaining, for a long time as redundant electrical power. Such as in places such as mobile communication, safe protection engineering, islands for the demand of electric power, battery system of the present invention has energy density Height, safety and environmental protection, lower-cost feature, the present invention further improve the ease for use, reliability and service life of product.
Invention content
The defects of to overcome the prior art, the technical problem to be solved in the present invention is to provide a kind of SMART METALS air electricity Cell system, metal can be automatically controlled in the requirement of the reuse under good operating mode by realizing metal-air battery The operating of air cell, system take into account that energy density height, safety and environmental protection, cost is relatively low, the characteristics of being easily used simultaneously.
The technical scheme is that:This SMART METALS air battery system, control centre (14) make the second self priming pump (6.2) start, the electrolyte in electrolyte tank (2) is through the 4th tube outlet (fourth), the second self priming pump (6.2), the 4th threeway (d), radiator (12), the 6th threeway (f), the 5th solenoid valve (3.5), the 8th threeway (h), battery pack (9), the 9th threeway (i), 7th threeway (g), third solenoid valve (3.3), the 5th threeway (e), third threeway (c), third tube outlet (third) return to electrolysis In liquid case (2);When by battery pack (9), battery pack produces electricl energy and external output current electrolyte, triggers battery pack fan (8) and exhaust fan (11) starts.
The present invention triggers correlated parts by control centre and acts, and electrolyte is made to be produced electricl energy and external defeated by battery pack Go out electric current, trigger battery pack fan and exhaust fan starts to radiate, therefore the SMART METALS air battery system realizes metal Air cell can automatically control the operating of metal-air battery, system in the requirement of the reuse under good operating mode Take into account that energy density height, safety and environmental protection, cost is relatively low, the characteristics of being easily used simultaneously.
Description of the drawings
Fig. 1 is the overall structure diagram of SMART METALS air battery system according to the present invention.
Specific embodiment
As shown in Figure 1, this SMART METALS air battery system, according to external signal, manually or automatically starts this system, Activation system first pass is the 5th solenoid valve 3.5, third solenoid valve 3.3 is opening, remaining solenoid valve is in off state. Control centre 14 starts the second self priming pump 6.2, and the electrolyte in electrolyte tank 2 is through the 4th tube outlet fourth, the second self priming pump 6.2nd, the 4th threeway d, radiator 12, the 6th threeway f, the 5th solenoid valve 3.5, the 8th threeway h, battery pack 9, the 9th threeway i, Seven threeway g, third solenoid valve 3.3, the 5th threeway e, third threeway c, third tube outlet third are returned in electrolyte tank 2;Electrolysis When by battery pack 9, battery pack produces electricl energy and external output current liquid, and triggering battery pack fan 8 and exhaust fan 11 start.
The present invention triggers correlated parts by control centre and acts, and electrolyte is made to be produced electricl energy and external defeated by battery pack Go out electric current, trigger battery pack fan and exhaust fan starts to radiate, therefore the SMART METALS air battery system can be controlled automatically The operating of metal-air battery processed, energy density height, safety and environmental protection, cost is relatively low, is easily used.
In the process, battery can generate heat during continuous reaction electric discharge.This heat can make electrolyte gradual Heating.
Preferably, the battery pack 9 is equipped with temperature sensor 10, detects the temperature regime of battery pack in real time, works as temperature When degree reaches designated value, start the radiator fan 13 being located on radiator 12, strengthen heat dissipation effect.
Preferably, when temperature reaches limiting temperature, control centre 14 stops the second self priming pump 6.2, and battery pack 9 is being put The hydrogen generated in electric process is discharged through battery pack 9, the 9th threeway i, the 5th tube outlet penta, then is expelled to by exhaust fan 11 Exterior.
It is limited according to external signal or itself working time, system stops output current.Self priming pump is stopped at this time, electricity The radiator fan of pond group exterior will be stopped.Preferably, after control centre 14 stops the second self priming pump 6.2, According to gravity, liquid will flow back in pipeline.So as to terminate the reaction in battery pack 9.In this flow, in order to protect Card pipeline and the liquid of internal battery pack can all flow out, the liquid to deposit in radiator 12 by the 4th threeway d, open Second solenoid valve 3.2, third threeway c, third tube outlet third return to the liquid to deposit in electrolyte tank 2 or in radiator 12 Body returns to electricity by the 6th threeway f, the 4th solenoid valve 3.4 opened, the 5th threeway e, third threeway c, third tube outlet third It solves in liquid case 2.
After battery system is through previous flow discharges, there is high concentration basic electrolyte to remain in internal system, to protect The service life of card system needs to carry out cleaning operation to system with the cleaning solution inside cleaning fluid tank 1.
Preferably, which further includes cleaning fluid tank 1, and electrolyte is all back in electrolyte After case 2, control centre 14 starts the first self priming pump 6.1, and cleaning solution is through the second tube outlet second, the first self priming pump 6.1, second Threeway b, the 5th solenoid valve 3.5, the 8th threeway h, battery pack 9, the 9th threeway i, the 7th threeway g, third solenoid valve 3.3, first Threeway a, the first tube outlet first complete cleaning operation.
Preferably, which, which further includes, neutralizes device 5, is connect with cleaning fluid tank (1).Clear During washing lotion recycles, the meeting of neutral cleaning solution gradually tend to alkalinity because of dilution system inside lye, thus in needs Neutralization operation is constantly carried out with device 5, cleaning solution is made to keep neutral state, until in the case of without neutralization operation, clearly The alkalinity of washing lotion is not further added by being expressed as cleaning operation completion.
Preferably, after cleaning operation, cleaning solution is under the effect of gravity by the 8th threeway h, the 5th solenoid valve 3.5th, the second threeway b, the first battery valve 3.1, the first threeway a, the first tube outlet first be back to inside cleaning fluid tank 1 or Cleaning solution is back under the effect of gravity by the 7th threeway g, third solenoid valve 3.3, the first threeway a, the first tube outlet first Inside cleaning fluid tank 1.
After the cleaned liquid cleaning of system, internal system pipeline and 9 inside of battery pack make in dampness to improve With the service life, it is drying regime to need to keep 9 inside of battery pack, needs to carry out drying operation thus.
Preferably, the 6th solenoid valve 3.6 is connected in one end of the 7th threeway g, the 6th solenoid valve 3.6 is connected with hair-dryer 7; Drying operate in, control centre 14 make the 6th solenoid valve 3.6 open and remaining valve be closed, hair-dryer 7 open after, wind is through blowing Wind turbine 7, the 6th solenoid valve 3.6, the 7th threeway g, the 9th threeway i, battery pack 9, the 8th threeway h, the 7th solenoid valve the 3.7, the 5th Tube outlet penta is discharged.Continued with this to drying, wind turbine is stopped.All valves are closed, and system is in standby mode.
The above is only presently preferred embodiments of the present invention, not makees limitation in any form to the present invention, it is every according to According to any simple modification, equivalent change and modification that the technical spirit of the present invention makees above example, still belong to the present invention The protection domain of technical solution.

Claims (9)

1. a kind of SMART METALS air battery system, it is characterised in that:Control centre (14) starts the second self priming pump (6.2), Electrolyte in electrolyte tank (2) is through the 4th tube outlet (fourth), the second self priming pump (6.2), the 4th threeway (d), radiator (12), the 6th threeway (f), the 5th solenoid valve (3.5), the 8th threeway (h), battery pack (9), the 9th threeway (i), the 7th threeway (g), third solenoid valve (3.3), the 5th threeway (e), third threeway (c), third tube outlet (third) return to electrolyte tank (2) In;When by battery pack (9), battery pack produces electricl energy and external output current electrolyte, triggering battery pack fan (8) and row Fan (11) starts.
2. SMART METALS air battery system according to claim 1, it is characterised in that:The battery pack (9) is equipped with Temperature sensor (10) detects the temperature regime of battery pack in real time, when temperature reaches designated value, starts and is located at radiator (12) radiator fan (13) on.
3. SMART METALS air battery system according to claim 2, it is characterised in that:When temperature reaches limiting temperature When, control centre (14) stops the second self priming pump (6.2), the hydrogen that battery pack (9) generates in discharge process, through battery pack (9), the 9th threeway (i), the discharge of the 5th tube outlet (penta), then exterior is expelled to by exhaust fan (11).
4. SMART METALS air battery system according to claim 3, it is characterised in that:Make second in control centre (14) After self priming pump (6.2) stops, the liquid to deposit in radiator (12) is by the 4th threeway (d), the second solenoid valve opened (3.2), third threeway (c), third tube outlet (third) return to the liquid to deposit in electrolyte tank (2) or in radiator (12) Body is by the 6th threeway (f), the 4th solenoid valve (3.4) opened, the 5th threeway (e), third threeway (c), third tube outlet (the third) it returns in electrolyte tank (2).
5. SMART METALS air battery system according to claim 4, it is characterised in that:The SMART METALS air cell system System further includes cleaning fluid tank (1), and after electrolyte is all back to electrolyte tank (2), control centre (14) makes the first self priming pump (6.1) start, cleaning solution is through the second tube outlet (second), the first self priming pump (6.1), the second threeway (b), the 5th solenoid valve (3.5), the 8th threeway (h), the 9th threeway (i), the 7th threeway (g), third solenoid valve (3.3), the first threeway (a), the first pipe Way outlet (first) completes cleaning operation.
6. SMART METALS air battery system according to claim 5, it is characterised in that:The SMART METALS air cell system System, which further includes, neutralizes device (5), is connect with cleaning fluid tank (1).
7. SMART METALS air battery system according to claim 6, it is characterised in that:After cleaning operation, clearly Washing lotion under the effect of gravity by the 8th threeway (h), the 5th solenoid valve (3.5), the second threeway (b), the first solenoid valve (3.1), First threeway (a), the first tube outlet (first) are back to cleaning fluid tank (1) inside or cleaning solution passes through under the effect of gravity 7th threeway (g), third solenoid valve (3.3), the first threeway (a), the first tube outlet (first) are back in cleaning fluid tank (1) Portion.
8. SMART METALS air battery system according to claim 7, it is characterised in that:After cleaning operation, control Center (14) processed opens the first solenoid valve (3.1).
9. SMART METALS air battery system according to claim 8, it is characterised in that:In one end of the 7th threeway (g) The 6th solenoid valve (3.6) is connected, the 6th solenoid valve (3.6) is connected with hair-dryer (7);In drying operates, control centre (14) Make the unlatching of the 6th solenoid valve (3.6) and remaining valve is closed, after hair-dryer (7) is opened, wind is through hair-dryer (7), the 6th solenoid valve (3.6), the 7th threeway (g), the 9th threeway (i), battery pack (9), the 8th threeway (h), the 7th solenoid valve (3.7), the 5th pipeline Export (penta) discharge.
CN201711453406.5A 2017-12-28 2017-12-28 A kind of SMART METALS air battery system Pending CN108183290A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201711453406.5A CN108183290A (en) 2017-12-28 2017-12-28 A kind of SMART METALS air battery system
US16/139,045 US11145920B2 (en) 2017-12-28 2018-09-23 Unit body of metal air battery and its intelligent control system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711453406.5A CN108183290A (en) 2017-12-28 2017-12-28 A kind of SMART METALS air battery system

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CN108183290A true CN108183290A (en) 2018-06-19

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110299581A (en) * 2019-06-13 2019-10-01 云南创能斐源金属燃料电池有限公司 Aluminum air battery system
CN110931830A (en) * 2019-12-12 2020-03-27 中车株洲电力机车有限公司 Drying device, drying method and drying system of aluminum-air battery system
CN112164844A (en) * 2020-09-27 2021-01-01 蔚蓝(广东)新能源科技有限公司 Metal-air battery capable of discharging for multiple times and implementation method
CN112542599A (en) * 2020-12-28 2021-03-23 郑州佛光发电设备有限公司 Bidirectional self-cleaning system and method for metal-air battery

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US20170170451A1 (en) * 2014-04-29 2017-06-15 Mahle International Gmbh Metal air battery
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CN207611845U (en) * 2017-12-28 2018-07-13 北京颐源新能源科技有限公司 A kind of SMART METALS air battery system

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CN103296338A (en) * 2013-06-20 2013-09-11 北京西区码头商贸有限公司 Aluminum air fuel cell system
CN103531832A (en) * 2013-09-26 2014-01-22 浙江吉利控股集团有限公司 Electric vehicle and aluminum air battery system thereof
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CN104900942A (en) * 2015-04-30 2015-09-09 德阳东深新能源科技有限公司 Integrated aluminum-air fuel cell system, and liquid flow and airflow control method
CN105609898A (en) * 2016-01-28 2016-05-25 四川康成博特机械制造有限公司 Air battery
CN106025447A (en) * 2016-07-13 2016-10-12 张启辉 Metal-air battery system
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CN206806471U (en) * 2017-05-02 2017-12-26 武汉环达电子科技有限公司 A kind of aluminium air-fuel battery and electrolyte management system
CN107492603A (en) * 2017-07-20 2017-12-19 新材料与产业技术北京研究院 Aluminum air battery system
CN207611845U (en) * 2017-12-28 2018-07-13 北京颐源新能源科技有限公司 A kind of SMART METALS air battery system

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110299581A (en) * 2019-06-13 2019-10-01 云南创能斐源金属燃料电池有限公司 Aluminum air battery system
CN110931830A (en) * 2019-12-12 2020-03-27 中车株洲电力机车有限公司 Drying device, drying method and drying system of aluminum-air battery system
CN110931830B (en) * 2019-12-12 2021-06-04 中车株洲电力机车有限公司 Drying device, drying method and drying system of aluminum-air battery system
CN112164844A (en) * 2020-09-27 2021-01-01 蔚蓝(广东)新能源科技有限公司 Metal-air battery capable of discharging for multiple times and implementation method
CN112542599A (en) * 2020-12-28 2021-03-23 郑州佛光发电设备有限公司 Bidirectional self-cleaning system and method for metal-air battery
CN112542599B (en) * 2020-12-28 2021-11-26 郑州佛光发电设备有限公司 Bidirectional self-cleaning system and method for metal-air battery

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Application publication date: 20180619