CN108178918A - A kind of jade stone composition and preparation method thereof - Google Patents
A kind of jade stone composition and preparation method thereof Download PDFInfo
- Publication number
- CN108178918A CN108178918A CN201711403948.1A CN201711403948A CN108178918A CN 108178918 A CN108178918 A CN 108178918A CN 201711403948 A CN201711403948 A CN 201711403948A CN 108178918 A CN108178918 A CN 108178918A
- Authority
- CN
- China
- Prior art keywords
- jade stone
- microballoon
- jade
- stone composition
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to resin combination technical fields, and in particular to a kind of jade stone composition and preparation method thereof.The jade stone composition includes matrix resin, light diffusion microballoon, antioxidant, light stabilizer, ultra-violet absorber and toner etc., the composition of the present invention is made to be presented finely dispersed natural jade perception, and nano inorganic light diffusing agent can make the composition of the present invention have many advantages, such as haze, high refractive index due to its dimensional effect.And the jade composition of the present invention can also be used as the interlayer of double glazing, jade effect is made to have three-dimensional sense, and can protect jade composition well, reduces its physical damage or the possibility of chemical oxidation.
Description
Technical field
The present invention relates to resin combination technical fields, and in particular to a kind of jade stone composition and preparation method thereof.
Background technology
For ancients' jade weared by baron to show the moral of gentleman, modern also regards it as the symbol for increasing fortune and social status, Chinese's Vegetarian gelatin
The heart remain the same from beginning to end.Take a broad view Now Domestic, various jades spread all over market, and price is also from the accessory down to several members to up to ten million
Gu Yu all has.
With the continuous development of technology, aesthetic resin can realize multi-effect, and the silver that such as paints, electrosilvering, pearly-lustre is red, sudden strain of a muscle is silver-colored
Black and starry sky flicker and other effects, in addition, the aesthetic resin of imitative natural effect also develops constantly, the aesthetic resin of jade stone
Constantly it is developed.The resinoid is generally all made of raw materials such as matrix resin, optical auxiliary agents, processing aids, but general
The color sense of jade can only be showed, can not copy the dim sense of jade.
And in optical auxiliary agents, organic optical auxiliary agent cost is higher, and inorganic optical auxiliary agent dispersibility is poor, the optics of formation
Effect is barely satisfactory.
Invention content
In order to overcome shortcoming and defect in the prior art, the purpose of the present invention is to provide a kind of combinations of jade stone
Object, which not only has the color sense of jade, also with the dim optics sense of jade, and uniform in effect, no
There are lofty parts.
The purpose of the present invention is achieved through the following technical solutions：
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
The present invention is using the load with the preferable transparent polypropylene amide of matrix resin compatibility as nano inorganic light diffusing agent
Body effectively solves the problems, such as that nano inorganic light diffusing agent is easy to reunite, is difficult to disperse and incompatible with matrix resin etc., makes this hair
Bright composition is presented finely dispersed natural jade perception, and nano inorganic light diffusing agent can be made due to its dimensional effect
The composition of the present invention has many advantages, such as haze, high refractive index；In addition polyacrylamide can also be used as reinforcing filler, realize
With the complementation of the mechanical performance of matrix resin.
The jade composition of the present invention can also be used as the interlayer of double glazing, and jade effect is made to have three-dimensional sense, and
Jade composition can be protected well, reduce its physical damage or the possibility of chemical oxidation.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 50-90 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, polyacrylamide in the polyacrylamide solution
Mass percent be 10%-20%；(2), nano inorganic light diffusing agent is added in step (1) and obtains polyacrylamide solution
In, homogeneous is stirred, forms suspension, the dosage of the nano inorganic light diffusing agent is the 4wt%- of polyacrylamide solution
6wt%；(3) it adds in absolute ethyl alcohol toward the suspension and it is made to be cooled to 20-25 DEG C, then stood, filtered, washed successively
It washs, be dried to get to the diffusion microballoon, the wherein dosage of absolute ethyl alcohol is the 30wt%-50wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 27-58 μm, BET specific surface area 18-87m2/g。
Light produced by the present invention spreads microballoon using porous copolymer of acrylamide as stephanoporate framework, which has structure
The advantages that stabilization, good mechanical performance, strong translucidus, and because its porous knot of three-dimensional network with diverse microcosmic scale
Structure, the nano inorganic light diffusing agent for being easy to reunite can spread in it and pass through chemical bonds and stephanoporate framework formation one is whole
Body realizes the complementation of performance.
Wherein, the nano inorganic light diffusing agent for nano-titanium dioxide, nano silicon dioxide and nano barium sulfate extremely
Few one kind.The refractive index of nano-titanium dioxide is 2.5-2.7, and the refractive index of nano silicon dioxide is 1.4-1.55, nanometer sulfuric acid
The refractive index of barium is 1.6-1.7, and the refractive index of microcrystalline cellulose is 1.6-1.7, and the refractive index of pure PET resin is 1.46 or so,
In order to which jade stone composition is made to have excellent light scattering effect, therefore the inorganic matter for selecting several refractive index different is compounded
Form the light diffusion microballoon of nucleocapsid.
Preferably, the nano inorganic light diffusing agent is pressed by nano-titanium dioxide, nano silicon dioxide and nano barium sulfate
Weight ratio 3-5:1-2:The ratio composition of 2-4, the grain size of nano-titanium dioxide is 30-50nm, and the grain size of nano silicon dioxide is
70-80nm, the grain size of nano barium sulfate is 30-40nm.This, which preferably compounds nano inorganic light diffusing agent, can improve light scattering
Effect, and the selection of specified particle diameter can reduce absorbability of the inorganic light diffusing agent to light, the combination of specified particle diameter can be with
The each component for improving nano inorganic light diffusing agent is uniformly dispersed in stephanoporate framework.
Wherein, described matrix resin is at least one in ABS resin, PA resins, PP resins, PET resin and PMMA resins
Kind.Preferably, described matrix resin is PA resins.
Wherein, the antioxidant is made of antioxidant 1010 and irgasfos 168, it is preferable that by antioxidant 1010 and is resisted
Oxygen agent 168 is by weight 1:1 ratio composition, antioxidant can improve the inoxidizability of master batch and PETG resins, so as to carry
Both high durability.
Wherein, the light stabilizer is bis- (1,2,2,6,6- pentamethyl -4- piperidyls) sebacates and/or poly- (4- hydroxyls
Base -2,2,6,6- tetramethyl -1- piperidines succinates).Preferably, the light stabilizer is by bis- (1,2,2,6,6- pentamethyl -4-
Piperidyl) sebacate and poly- (4- hydroxyls -2,2,6,6- tetramethyl -1- piperidines succinates) are by weight 1:1 ratio is mixed
It is combined into.The light stabilizer of the present invention can effectively inhibit the photooxidation droping of matrix resin, and with the ultraviolet suction of benzotriazole
It receives agent to be used in combination, has good synergistic effect, can significantly improve the photostability of plastics, and is basic to the mechanical property of plastics
Without influence.
Wherein, the ultra-violet absorber is 2- cyano -3,3 '-diphenylacrylate -2- ethylhexyls and/or 2- (2-
- 3 tertiary butyl -5- aminomethyl phenyls of hydroxyl) -5- chlorinated benzotriazoles.Preferably, the ultra-violet absorber is by 2- cyano -3,3 ' -
- 5- chlorinated benzotriazoles are by weight by diphenylacrylate -2- ethylhexyls and 2- (- 3 tertiary butyl -5- aminomethyl phenyls of 2- hydroxyls)
1:1 ratio mixing composition.The ultra-violet absorber of the present invention.The ultra-violet absorber of the present invention can consumingly absorb ultraviolet
Line reduces destruction of the ultraviolet light to polyester resin, improves the service life of plastics.
Wherein, the toner is titanium dioxide and/or ethylenebis stearic amide powder.Titanium dioxide has high whiteness, bloom
The characteristics such as pool, and ethylenebis stearic amide powder can also improve combination of the present invention to play lubricant effect as lubricant
The surface gloss of object, the two compounding effect is more preferably.Preferably, the toner is by titanium dioxide and ethylenebis stearic amide powder
By weight 2:1 ratio composition.
The present invention also provides a kind of preparation methods of jade stone composition：Each raw material is weighed by proportioning to be mixed
It closes, is then squeezed in flakes to get to the jade stone composition.This method is simple and efficient, at low cost, efficient, easily
In industrial production.
The beneficial effects of the present invention are：The present invention using with the preferable transparent polypropylene amide of matrix resin compatibility as
The carrier of nano inorganic light diffusing agent effectively solves nano inorganic light diffusing agent and is easy to reunite, is difficult to disperse and and matrix resin
Incompatible the problem of waiting, make the composition of the present invention finely dispersed natural jade perception be presented, and nano inorganic light is spread
Agent can make the composition of the present invention have many advantages, such as haze, high refractive index due to its dimensional effect；In addition polyacrylamide
Reinforcing filler is can also be used as, realizes the complementation with the mechanical performance of matrix resin.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 70 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, the matter of polyacrylamide in the polyacrylamide solution
It is 15% to measure percentage；(2), nano inorganic light diffusing agent is added in step (1) and obtained in polyacrylamide solution, stirred
Homogeneous is mixed, forms suspension, the dosage of the nano inorganic light diffusing agent is the 5wt% of polyacrylamide solution；(3) toward described
Suspension add in absolute ethyl alcohol simultaneously it is made to be cooled to 23 DEG C, then stood, be filtered, washed successively, be dried to get to
The diffusion microballoon, the wherein dosage of absolute ethyl alcohol are the 40wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 48 μm, BET specific surface area 87m2/g。
Preferably, the nano inorganic light diffusing agent is pressed by nano-titanium dioxide, nano silicon dioxide and nano barium sulfate
Weight ratio 4:1.5:3 ratio composition, the grain size of nano-titanium dioxide is 40nm, and the grain size of nano silicon dioxide is 75nm, is received
The grain size of nano-barium sulfate is 35nm.
Wherein, described matrix resin is PA resins.
Wherein, the antioxidant is by antioxidant 1010 and irgasfos 168 by weight 1:1 ratio composition.
Wherein, the light stabilizer by bis- (1,2,2,6,6- pentamethyl -4- piperidyls) sebacates and it is poly- (4- hydroxyls -
2,2,6,6- tetramethyl -1- piperidines succinates) by weight 1:1 ratio mixing composition.
Wherein, the ultra-violet absorber is by 2- cyano -3,3 '-diphenylacrylate -2- ethylhexyls and 2- (2- hydroxyls
- 3 tertiary butyl -5- aminomethyl phenyls of base) -5- chlorinated benzotriazoles by weight 1:1 ratio mixing composition.
Wherein, the toner is by titanium dioxide and ethylenebis stearic amide powder by weight 2:1 ratio composition.
The present embodiment additionally provides a kind of preparation method of jade stone composition：Each raw material is weighed by proportioning to carry out
Then mixing is squeezed in flakes to get to the jade stone composition.
Embodiment 2
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 50-90 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, polyacrylamide in the polyacrylamide solution
Mass percent be 10%；(2), nano inorganic light diffusing agent is added in step (1) and obtained in polyacrylamide solution, into
Row stirring homogeneous, forms suspension, and the dosage of the nano inorganic light diffusing agent is the 4wt% of polyacrylamide solution；(3) it is past
The suspension adds in absolute ethyl alcohol and it is made to be cooled to 20 DEG C, is then stood, be filtered, washed, is dried successively, i.e.,
The diffusion microballoon is obtained, the wherein dosage of absolute ethyl alcohol is the 30wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 27 μm, BET specific surface area 18m2/g。
Preferably, the nano inorganic light diffusing agent is pressed by nano-titanium dioxide, nano silicon dioxide and nano barium sulfate
Weight ratio 3:1:2 ratio composition, the grain size of nano-titanium dioxide are 30nm, and the grain size of nano silicon dioxide is 70nm, nanometer
The grain size of barium sulfate is 30nm.
Wherein, described matrix resin is PA resins.
Wherein, the antioxidant is by antioxidant 1010 and irgasfos 168 by weight 1:2 ratio composition.
Wherein, the light stabilizer is bis- (1,2,2,6,6- pentamethyl -4- piperidyls) sebacates.
Wherein, the ultra-violet absorber be 2- cyano -3,3 '-diphenylacrylate -2- ethylhexyls.
Wherein, the toner is titanium dioxide.
The present embodiment additionally provides a kind of preparation method of jade stone composition：Each raw material is weighed by proportioning to carry out
Then mixing is squeezed in flakes to get to the jade stone composition.
Embodiment 3
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 90 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, the matter of polyacrylamide in the polyacrylamide solution
It is 20% to measure percentage；(2), nano inorganic light diffusing agent is added in step (1) and obtained in polyacrylamide solution, stirred
Homogeneous is mixed, forms suspension, the dosage of the nano inorganic light diffusing agent is the 6wt% of polyacrylamide solution；(3) toward described
Suspension add in absolute ethyl alcohol simultaneously it is made to be cooled to 25 DEG C, then stood, be filtered, washed successively, be dried to get to
The diffusion microballoon, the wherein dosage of absolute ethyl alcohol are the 50wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 36 μm, BET specific surface area 56m2/g。
Preferably, the nano inorganic light diffusing agent is pressed by nano-titanium dioxide, nano silicon dioxide and nano barium sulfate
Weight ratio 5:2:4 ratio composition, the grain size of nano-titanium dioxide are 50nm, and the grain size of nano silicon dioxide is 80nm, nanometer
The grain size of barium sulfate is 40nm.
Wherein, described matrix resin is PA resins.
Wherein, the antioxidant is by antioxidant 1010 and irgasfos 168 by weight 2:1 ratio composition.
Wherein, the light stabilizer is poly- (4- hydroxyls -2,2,6,6- tetramethyl -1- piperidines succinates).
Wherein, the ultra-violet absorber is 2- (- 3 tertiary butyl -5- aminomethyl phenyls of 2- hydroxyls) -5- chlorinated benzotriazoles.
Wherein, the toner is ethylenebis stearic amide powder.
The present embodiment additionally provides a kind of preparation method of jade stone composition：Each raw material is weighed by proportioning to carry out
Then mixing is squeezed in flakes to get to the jade stone composition.
Embodiment 4
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 60 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, the matter of polyacrylamide in the polyacrylamide solution
It is 13% to measure percentage；(2), nano inorganic light diffusing agent is added in step (1) and obtained in polyacrylamide solution, stirred
Homogeneous is mixed, forms suspension, the dosage of the nano inorganic light diffusing agent is the 4.5wt% of polyacrylamide solution；(3) toward institute
Stating suspension and adding in absolute ethyl alcohol and makes it be cooled to 21 DEG C, then stood, be filtered, washed successively, be dried to get
To the diffusion microballoon, the wherein dosage of absolute ethyl alcohol is the 35wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 27 μm, BET specific surface area 66m2/g。
Preferably, the nano inorganic light diffusing agent is nano-titanium dioxide, and the grain size of nano-titanium dioxide is 40nm.
Wherein, described matrix resin is PA resins.
Wherein, the antioxidant is by antioxidant 1010 and irgasfos 168 by weight 1:1 ratio composition.
Wherein, the light stabilizer by bis- (1,2,2,6,6- pentamethyl -4- piperidyls) sebacates and it is poly- (4- hydroxyls -
2,2,6,6- tetramethyl -1- piperidines succinates) by weight 1:1 ratio mixing composition.
Wherein, the ultra-violet absorber is by 2- cyano -3,3 '-diphenylacrylate -2- ethylhexyls and 2- (2- hydroxyls
- 3 tertiary butyl -5- aminomethyl phenyls of base) -5- chlorinated benzotriazoles by weight 1:1 ratio mixing composition.
Wherein, the toner is by titanium dioxide and ethylenebis stearic amide powder by weight 2:1 ratio composition.
The present embodiment additionally provides a kind of preparation method of jade stone composition：Each raw material is weighed by proportioning to carry out
Then mixing is squeezed in flakes to get to the jade stone composition.
Embodiment 5
A kind of jade stone composition includes the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent,
Shell is transparent polypropylene amide.
Wherein, the preparation method of the light diffusion microballoon is：(1), a certain amount of N,N-dimethylformamide is taken to be warming up to
It 80 DEG C, dissolves the polyacrylamide, forms polyacrylamide solution, the matter of polyacrylamide in the polyacrylamide solution
It is 18% to measure percentage；(2), nano inorganic light diffusing agent is added in step (1) and obtained in polyacrylamide solution, stirred
Homogeneous is mixed, forms suspension, the dosage of the nano inorganic light diffusing agent is the 5.5wt% of polyacrylamide solution；(3) toward institute
Stating suspension and adding in absolute ethyl alcohol and makes it be cooled to 24 DEG C, then stood, be filtered, washed successively, be dried to get
To the diffusion microballoon, the wherein dosage of absolute ethyl alcohol is the 45wt% of suspension.
Wherein, the grain size of the light diffusion microballoon is 43 μm, BET specific surface area 43m2/g。
Preferably, the nano inorganic light diffusing agent is nano barium sulfate, and the grain size of nano barium sulfate is 35nm.
Wherein, described matrix resin is PP resins.
Wherein, the antioxidant is by antioxidant 1010 and irgasfos 168 by weight 1:1 ratio composition.
Wherein, the light stabilizer by bis- (1,2,2,6,6- pentamethyl -4- piperidyls) sebacates and it is poly- (4- hydroxyls -
2,2,6,6- tetramethyl -1- piperidines succinates) by weight 1:1 ratio mixing composition.
Wherein, the ultra-violet absorber is by 2- cyano -3,3 '-diphenylacrylate -2- ethylhexyls and 2- (2- hydroxyls
- 3 tertiary butyl -5- aminomethyl phenyls of base) -5- chlorinated benzotriazoles by weight 1:1 ratio mixing composition.
Wherein, the toner is by titanium dioxide and ethylenebis stearic amide powder by weight 2:1 ratio composition.
The present embodiment additionally provides a kind of preparation method of jade stone composition：Each raw material is weighed by proportioning to carry out
Then mixing is squeezed in flakes to get to the jade stone composition.
Comparative example 1
This comparative example 1 and embodiment 1 difference lies in：
A kind of jade stone composition includes the raw material of following parts by weight：
The light diffusing agent is by nano-titanium dioxide, nano silicon dioxide and nano barium sulfate by weight 4:1.5:3
Ratio forms, and the grain size of nano-titanium dioxide is 40nm, and the grain size of nano silicon dioxide is 75nm, and the grain size of nano barium sulfate is
35nm。
The jade composition uniform in color of 1-5 of the embodiment of the present invention, it is whole dim with obvious effects, and with the dim of embodiment 1
Moon bright effect is the most apparent, and comparative example 1 phenomena such as color spot, aberration occurs since light diffusing agent cannot disperse well.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other manner,
Any obvious replacement is not departed under the premise of present inventive concept within protection scope of the present invention.
Claims (10)
1. a kind of jade stone composition, it is characterised in that：Include the raw material of following parts by weight：
Wherein, the light diffusion microballoon is nucleocapsid microballoon, and the core of nucleocapsid microballoon is nano inorganic light diffusing agent, and shell is
Transparent polypropylene amide.
2. a kind of jade stone composition according to claim 1, it is characterised in that：The preparation method of the light diffusion microballoon
For：(1), a certain amount of n,N-Dimethylformamide is taken to be warming up to 50-90 DEG C, dissolves the polyacrylamide, forms polypropylene
Amide solution, the mass percent of polyacrylamide is 10%-20% in the polyacrylamide solution；(2), by nano inorganic
Light diffusing agent is added in step (1) and is obtained in polyacrylamide solution, is stirred homogeneous, forms suspension, the nanometer nothing
The dosage of machine light diffusing agent is the 4wt%-6wt% of polyacrylamide solution；(3) it adds in absolute ethyl alcohol toward the suspension and makes
It is cooled to 20-25 DEG C, is then stood, is filtered, washed successively, is dried to get to the diffusion microballoon, wherein without
The dosage of water-ethanol is the 30wt%-50wt% of suspension.
3. a kind of jade stone composition according to claim 1 or 2, it is characterised in that：The grain size of the light diffusion microballoon
It is 27-58 μm, BET specific surface area 18-87m2/g。
4. a kind of jade stone composition according to claim 1 or 2, it is characterised in that：The nano inorganic light diffusing agent
At least one for nano-titanium dioxide, nano silicon dioxide and nano barium sulfate.
5. a kind of jade stone composition according to claim 1, it is characterised in that：Described matrix resin is ABS resin, PA
At least one of resin, PP resins, PET resin and PMMA resins.
6. a kind of jade stone composition according to claim 1, it is characterised in that：The antioxidant is by antioxidant 1010
It is formed with irgasfos 168.
7. a kind of jade stone composition according to claim 1, it is characterised in that：The light stabilizer for it is bis- (1,2,2,
6,6- pentamethyl -4- piperidyls) sebacate and/or poly- (4- hydroxyls -2,2,6,6- tetramethyl -1- piperidines succinates).
8. a kind of jade stone composition according to claim 1, it is characterised in that：The ultra-violet absorber is 2- cyanogen
Base -3,3 '-diphenylacrylate -2- ethylhexyls and/or 2- (- 3 tertiary butyl -5- aminomethyl phenyls of 2- hydroxyls) -5- chloro benzos
Triazole.
9. a kind of jade stone composition according to claim 1, it is characterised in that：The toner is titanium dioxide and/or Asia
The double stearic amide powder of ethyl.
10. a kind of preparation method of jade stone composition described in any one of claim 1-9, it is characterised in that：By proportioning
It weighs each raw material to be mixed, then be squeezed in flakes to get to the jade stone composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711403948.1A CN108178918A (en) | 2017-12-22 | 2017-12-22 | A kind of jade stone composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711403948.1A CN108178918A (en) | 2017-12-22 | 2017-12-22 | A kind of jade stone composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108178918A true CN108178918A (en) | 2018-06-19 |
Family
ID=62546703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711403948.1A Pending CN108178918A (en) | 2017-12-22 | 2017-12-22 | A kind of jade stone composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108178918A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110079085A (en) * | 2019-06-03 | 2019-08-02 | 合复新材料科技(无锡)有限公司 | A kind of transparent nylon composite material with wear-resisting ageing-resistant yellowing-resistant, preparation method and its application in communication apparatus rear cover |
| CN113292833A (en) * | 2021-04-19 | 2021-08-24 | 昆山市诚泰电气股份有限公司 | Jade-imitating panel lamp and preparation process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134383A (en) * | 2011-01-28 | 2011-07-27 | 暨南大学 | Light scattering polycarbonate composition for light emitting diode (LED) lighting and use thereof |
| US20130071453A1 (en) * | 2007-12-17 | 2013-03-21 | Milan F. Sojka | Compositions Comprising Solid Particles Entrapped In Collapsed Polymeric Microspheres, And Methods Of Making The Same |
| CN104479283A (en) * | 2014-12-15 | 2015-04-01 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with bowlder effect and preparation method thereof |
| CN106512873A (en) * | 2015-09-09 | 2017-03-22 | 中国科学院理化技术研究所 | Method for packaging large-batch nanoparticles, obtained micro-nano composite microspheres and application thereof |
-
2017
- 2017-12-22 CN CN201711403948.1A patent/CN108178918A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130071453A1 (en) * | 2007-12-17 | 2013-03-21 | Milan F. Sojka | Compositions Comprising Solid Particles Entrapped In Collapsed Polymeric Microspheres, And Methods Of Making The Same |
| CN102134383A (en) * | 2011-01-28 | 2011-07-27 | 暨南大学 | Light scattering polycarbonate composition for light emitting diode (LED) lighting and use thereof |
| CN104479283A (en) * | 2014-12-15 | 2015-04-01 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with bowlder effect and preparation method thereof |
| CN106512873A (en) * | 2015-09-09 | 2017-03-22 | 中国科学院理化技术研究所 | Method for packaging large-batch nanoparticles, obtained micro-nano composite microspheres and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110079085A (en) * | 2019-06-03 | 2019-08-02 | 合复新材料科技(无锡)有限公司 | A kind of transparent nylon composite material with wear-resisting ageing-resistant yellowing-resistant, preparation method and its application in communication apparatus rear cover |
| CN113292833A (en) * | 2021-04-19 | 2021-08-24 | 昆山市诚泰电气股份有限公司 | Jade-imitating panel lamp and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105153830B (en) | Nano-negative ion functional form inner-wall emulsion paint and preparation method thereof | |
| CN100395297C (en) | Emulsion coating of negative ion and preparation method | |
| CN107722354B (en) | Modified Nano TiO2Particle, preparation method, purposes and PC/ASA composite material and preparation method comprising it | |
| CN103649140B (en) | ASA-based graft copolymer composition | |
| CN104497673B (en) | A kind of oil colour of graphene-containing | |
| CN108178918A (en) | A kind of jade stone composition and preparation method thereof | |
| CN103554704A (en) | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof | |
| CN102690600A (en) | Environment-friendly water-based paint and preparation method thereof | |
| CN105820433A (en) | Polypropylene edge banding and preparation method | |
| CN105038550A (en) | Coating material having health functions and specially used for leather | |
| CN108276750A (en) | A kind of smooth diffusion master batch and PET film and preparation method | |
| CN102977511B (en) | Smalt for PVC (Poly Vinyl Chloride) plastic processing | |
| CN107149809A (en) | A kind of sterilizing and air filtration core and preparation method thereof | |
| CN104725934B (en) | A kind of preparation method containing the cork paper water color ink carrying silver meerschaum anti-biotic material | |
| CN101056505B (en) | Abrasion-proof portable electronic device casing | |
| CN105949866A (en) | Organic-inorganic hybrid nano-silicon dispersoid and preparation method thereof | |
| CN101647765B (en) | Attapulgite beach sunscreen cream | |
| CN106675152B (en) | Matting modifier for powder coating, application thereof, and matting powder coating containing same | |
| CN101293976A (en) | Nano-composite emulsion product and preparation method thereof | |
| CN106752368A (en) | A kind of high viscosity dye-type black neutral ink | |
| CN106700391A (en) | Functional master batch for improving weather resistance of ABS (acrylonitrile butadiene styrene copolymers) | |
| CN103432958B (en) | Calcium carbonate surface-active agent | |
| CN108976848A (en) | Nano rare earth zeolite coating | |
| CN106700763A (en) | Eyesight-improving interior wall water paint and preparation method thereof | |
| KR102187044B1 (en) | Preparing method of anti bacterial synthetic marbl |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180619 |