Invention content
In view of the deficiencies of the prior art, the present invention proposes a kind of electrochemical oxidation-iron carbon for handling organic wastewater with difficult degradation thereby
Association system, acid, the alkali of operation energy consumption and iron carbon reactor which effectively reduces electrochemical oxidation reactions device add expense
With, and the treatment effect of organic wastewater with difficult degradation thereby is effectively increased, specific technical solution is as follows:
The electrochemical oxidation of a kind of organic wastewater with difficult degradation thereby-iron carbon joint processing system, which is characterized in that the system includes
Electrochemical oxidation reactions device 1, iron carbon tower 8, cathode draining pump 9, iron carbon tower draining pump 10, mixing pit 11, mixes anode draining pump 7
Pond draining pump 12, sedimentation basin 13 are closed, the electrochemical oxidation reactions device 1 includes housing 2, anode 4, cathode 5, power supply 6, described
Housing 2 bottom be equipped with water inlet 3, the anode 4 and cathode 5 are equivalent titanium-based porous tubular filter core electrode,
One end is immersed in the waste water of the housing 2, and the other end is connected with the power supply 6;The anode 4 passes through pipeline, anode
Draining pump 7 is connected with the water inlet of the iron carbon tower 8, the water outlet of the iron carbon tower 8 by iron carbon tower draining pump 10 with
The mixing pit 11 is connected, and the cathode 5 is also connected by pipeline, cathode draining pump 9 with the mixing pit 11, described
Mixing pit 11 be connected by the mixing pit draining pump 12 with the sedimentation basin 13.
Further, the aperture of the anode 4 and cathode 5 is 50-100 μm.
Further, the power supply 6 is constant voltage dc source.
Further, the power supply 6 is electrochmical power source.
Further, the drain discharge ratio of the anode 4 and cathode 5 is 1:1.
Compared with prior art, beneficial outcomes of the invention are as follows:
(1) it solves the bubble diffusion problem of electrode surface in electrochemical oxidation reactions device, effectively reduces electrochemistry oxygen
Change the operation energy consumption of reactor;
(2) highly basic of electrochemical oxidation reactions device cathode and anode generation and strong acid draining are taken full advantage of, effectively reduces iron
Acid, the alkali of carbon reactor add expense;
(3) being used in combination by electrochemical oxidation reactions device and iron carbon tower, effectively increases organic wastewater with difficult degradation thereby
Treatment effect.
Specific embodiment
Below according to attached drawing and the preferred embodiment detailed description present invention, the objects and effects of the present invention will become brighter
In vain, below in conjunction with drawings and examples, the present invention will be described in further detail.It is it should be appreciated that described herein specific
Embodiment is only used to explain the present invention, is not intended to limit the present invention.
As shown in Figure 1, a kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby, including electrification
Learn oxidation reactor 1, anode draining pump 7, iron carbon tower 8, cathode draining pump 9, iron carbon tower draining pump 10, mixing pit 11, mixing pit
Draining pump 12, sedimentation basin 13, electrochemical oxidation reactions device 1 include housing 2, anode 4, cathode 5, power supply 6, and the bottom of housing 2 is set
There is water inlet 3, anode 4 and cathode 5 are titanium-based porous tubular filter core electrode, and one end is immersed in the waste water of housing 2, the other end
It is connected with power supply 6;Anode 4 is connected by pipeline, anode draining pump 7 with the water inlet of iron carbon tower 8, and the water outlet of iron carbon tower 8 leads to
It crosses iron carbon tower draining pump 10 with mixing pit 11 to be connected, cathode 5 is also connected by pipeline, cathode draining pump 9 with mixing pit 11, mixing
Pond 11 is connected by mixing pit draining pump 12 with sedimentation basin 13.
Wherein, anode 4 and cathode 5 are completely equivalent titanium-based porous tubular filter core electrode, and the aperture of micropore is 50-100 μ
The drain discharge ratio of m, anode 4 and cathode 5 is 1:1;Power supply uses constant voltage dc source or electrochmical power source.
The present invention effectively solves the resistance increase effect of bubble generation, porous tubular filter core using porous tubular filter core electrode
Electrode is hollow structure, and in the process of running, waste water uses the pattern of " Zhou Jinzhong goes out ", and the performance of porous tubular filter core electrode is led
The effect of water pipe, since external pressure is higher than internal pressure, the bubble that wastewater electrolytic generates does not diffuse in electrode inner surface
Main body water phase, the resistance increase effect that bubble can be avoided to generate, effectively reduces system energy consumption.Meanwhile anode can generate highly acid
Draining, and cathode can generate strong basicity draining.It is well known that iron carbon tower is also the commonly used equipment for handling organic wastewater with difficult degradation thereby,
It needs that acid and alkali tune, the expense that soda acid adds is adjusted to account for the 50-70% of overall running cost in the process of running.Microporous pipe will be used
The electrochemical oxidation reactions device of formula filter core electrode is joined together with iron carbon tower, can not only improve the processing effect of difficult organic wastewater
Fruit, and the strong acid of electrochemical oxidation generation and highly basic draining can be efficiently used, greatly reduce system operation cost.
The operation principle of electrochemical oxidation-iron carbon association system of the processing organic wastewater with difficult degradation thereby of the present invention is as follows:
In electrochemical oxidation reactions device 1, when DC power supply 6 is powered, anion is moved to anode 4 in waste water, sun from
Son is moved to cathode 5, is in the main reaction that 4 surface of anode occurs:
2Cl-=Cl2+2e-
Cl2+H2O=HClO+HCl
HClO=H++ClO-
4 draining of anode contains the HClO of strong oxidizing property, and it is organic can hardly degraded organic substance to be oxidized to degradable small molecule
Object or even it is oxidized to CO2。
It is in the main reaction that 5 surface of cathode occurs:
2H2O+2e-=H2+2OH-
Na++OH-=NaOH
5 draining of cathode is strong basicity, and salinity is higher.
When the acid effluent of anode 4 is pumped to iron carbon tower 8, following galvanic interaction occurs in tower:
Anode:Fe-2e-=Fe2+
Cathode:2H++2e-=2 [H]=H2
React the nascent state Fe generated2+[H], have high chemism, can aoxidize with reducing waste water in many organic matters,
The effects that making organic matter that chain rupture, open loop occur.
When 5 draining of cathode is pumped into mixing pit 11, acid-base neutralization reaction occurs, due to consuming part H in iron carbon tower 8+,
So waste water is in alkalinity in mixing pit 11, the key reaction of generation is as follows:
H++OH-=H2O
Fe2++2OH-=Fe (OH)2
Fe3++3OH-=Fe (OH)3
In sedimentation basin 13, the Fe (OH) of generation2With Fe (OH)3Flocculation precipitation reaction occurs, while it is organic to remove part
Pollutant.
The system can economical and efficient removal persistent organic pollutants, the water standard of lifting waste water discharge, and advantageous
In the recycling for realizing waste water.
Above-mentioned specific embodiment is used for illustrating the present invention rather than limiting the invention, in the essence of the present invention
In the protection domain of god and principles and requirements, to any modifications and changes that the present invention makes, protection scope of the present invention is both fallen within.