CN108178387A - A kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby - Google Patents

A kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby Download PDF

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Publication number
CN108178387A
CN108178387A CN201711424051.7A CN201711424051A CN108178387A CN 108178387 A CN108178387 A CN 108178387A CN 201711424051 A CN201711424051 A CN 201711424051A CN 108178387 A CN108178387 A CN 108178387A
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CN
China
Prior art keywords
iron carbon
draining pump
cathode
anode
electrochemical oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711424051.7A
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Chinese (zh)
Inventor
赵庆卒
邱云涛
方军
许兴中
吴蕾
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Zhejiang Fei Yuan Environmental Engineering Co Ltd
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Zhejiang Fei Yuan Environmental Engineering Co Ltd
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Publication date
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Priority to CN201711424051.7A priority Critical patent/CN108178387A/en
Publication of CN108178387A publication Critical patent/CN108178387A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds

Abstract

The present invention discloses a kind of electrochemical oxidation iron carbon joint processing system of organic wastewater with difficult degradation thereby, it includes electrochemical oxidation reactions device, anode draining pump, iron carbon tower, cathode draining pump, iron carbon tower draining pump, mixing pit, mixing pit draining pump, sedimentation basin, electrochemical oxidation reactions device includes housing, anode, cathode, power supply, the bottom of housing is equipped with water inlet, anode and cathode are equivalent titanium-based porous tubular filter core electrode, one end is immersed in the waste water of housing, and the other end is connected with power supply;Anode is connected by pipeline, anode draining pump with the water inlet of iron carbon tower, the water outlet of iron carbon tower is connected by iron carbon tower draining pump with mixing pit, cathode is also connected by pipeline, cathode draining pump with mixing pit, and mixing pit is connected by mixing pit draining pump with sedimentation basin.The system can remove to economical and efficient persistent organic pollutants, lifting waste water discharge standard, realize the recycling of waste water.

Description

A kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby
Technical field
The invention belongs to field of environment engineering technology, and in particular to a kind of electrochemistry oxygen for handling organic wastewater with difficult degradation thereby Change-iron carbon association system.
Background technology
In recent years, electrochemical oxidation technology has received widespread attention in the process field of organic wastewater with difficult degradation thereby, but higher Operating cost be still important bottleneck during its industrial applications.Electrochemical oxidation electrode used therein is generally board-like or net Shape, in the process of running, yin, yang electrode surface can generate a large amount of bubbles, considerably increase system resistance, and energy consumption is caused to occupy height not Under.Traditional solution mainly by the coating composition on modified electrode surface, increases the liberation of hydrogen and oxygen evolution potential of electrode, so as to It reduces bubble yield or reduces bubble size, but of high cost, and the treatment effect of degradation of organic waste water can not be satisfactory.
Invention content
In view of the deficiencies of the prior art, the present invention proposes a kind of electrochemical oxidation-iron carbon for handling organic wastewater with difficult degradation thereby Association system, acid, the alkali of operation energy consumption and iron carbon reactor which effectively reduces electrochemical oxidation reactions device add expense With, and the treatment effect of organic wastewater with difficult degradation thereby is effectively increased, specific technical solution is as follows:
The electrochemical oxidation of a kind of organic wastewater with difficult degradation thereby-iron carbon joint processing system, which is characterized in that the system includes Electrochemical oxidation reactions device 1, iron carbon tower 8, cathode draining pump 9, iron carbon tower draining pump 10, mixing pit 11, mixes anode draining pump 7 Pond draining pump 12, sedimentation basin 13 are closed, the electrochemical oxidation reactions device 1 includes housing 2, anode 4, cathode 5, power supply 6, described Housing 2 bottom be equipped with water inlet 3, the anode 4 and cathode 5 are equivalent titanium-based porous tubular filter core electrode, One end is immersed in the waste water of the housing 2, and the other end is connected with the power supply 6;The anode 4 passes through pipeline, anode Draining pump 7 is connected with the water inlet of the iron carbon tower 8, the water outlet of the iron carbon tower 8 by iron carbon tower draining pump 10 with The mixing pit 11 is connected, and the cathode 5 is also connected by pipeline, cathode draining pump 9 with the mixing pit 11, described Mixing pit 11 be connected by the mixing pit draining pump 12 with the sedimentation basin 13.
Further, the aperture of the anode 4 and cathode 5 is 50-100 μm.
Further, the power supply 6 is constant voltage dc source.
Further, the power supply 6 is electrochmical power source.
Further, the drain discharge ratio of the anode 4 and cathode 5 is 1:1.
Compared with prior art, beneficial outcomes of the invention are as follows:
(1) it solves the bubble diffusion problem of electrode surface in electrochemical oxidation reactions device, effectively reduces electrochemistry oxygen Change the operation energy consumption of reactor;
(2) highly basic of electrochemical oxidation reactions device cathode and anode generation and strong acid draining are taken full advantage of, effectively reduces iron Acid, the alkali of carbon reactor add expense;
(3) being used in combination by electrochemical oxidation reactions device and iron carbon tower, effectively increases organic wastewater with difficult degradation thereby Treatment effect.
Description of the drawings
Fig. 1 is the structure diagram of the processing system of the present invention;
In figure, 1- electrochemical oxidation reactions devices, 2- housings, 3- water inlets, 4- anodes, 5- cathodes, 6- DC power supplies, 7- sun Pole draining pump, 8- iron carbon towers, 9- cathode draining pumps, 10- iron carbon tower draining pumps, 11- mixing pits, 12- mixing pit draining pumps, 13- Sedimentation basin.
Specific embodiment
Below according to attached drawing and the preferred embodiment detailed description present invention, the objects and effects of the present invention will become brighter In vain, below in conjunction with drawings and examples, the present invention will be described in further detail.It is it should be appreciated that described herein specific Embodiment is only used to explain the present invention, is not intended to limit the present invention.
As shown in Figure 1, a kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby, including electrification Learn oxidation reactor 1, anode draining pump 7, iron carbon tower 8, cathode draining pump 9, iron carbon tower draining pump 10, mixing pit 11, mixing pit Draining pump 12, sedimentation basin 13, electrochemical oxidation reactions device 1 include housing 2, anode 4, cathode 5, power supply 6, and the bottom of housing 2 is set There is water inlet 3, anode 4 and cathode 5 are titanium-based porous tubular filter core electrode, and one end is immersed in the waste water of housing 2, the other end It is connected with power supply 6;Anode 4 is connected by pipeline, anode draining pump 7 with the water inlet of iron carbon tower 8, and the water outlet of iron carbon tower 8 leads to It crosses iron carbon tower draining pump 10 with mixing pit 11 to be connected, cathode 5 is also connected by pipeline, cathode draining pump 9 with mixing pit 11, mixing Pond 11 is connected by mixing pit draining pump 12 with sedimentation basin 13.
Wherein, anode 4 and cathode 5 are completely equivalent titanium-based porous tubular filter core electrode, and the aperture of micropore is 50-100 μ The drain discharge ratio of m, anode 4 and cathode 5 is 1:1;Power supply uses constant voltage dc source or electrochmical power source.
The present invention effectively solves the resistance increase effect of bubble generation, porous tubular filter core using porous tubular filter core electrode Electrode is hollow structure, and in the process of running, waste water uses the pattern of " Zhou Jinzhong goes out ", and the performance of porous tubular filter core electrode is led The effect of water pipe, since external pressure is higher than internal pressure, the bubble that wastewater electrolytic generates does not diffuse in electrode inner surface Main body water phase, the resistance increase effect that bubble can be avoided to generate, effectively reduces system energy consumption.Meanwhile anode can generate highly acid Draining, and cathode can generate strong basicity draining.It is well known that iron carbon tower is also the commonly used equipment for handling organic wastewater with difficult degradation thereby, It needs that acid and alkali tune, the expense that soda acid adds is adjusted to account for the 50-70% of overall running cost in the process of running.Microporous pipe will be used The electrochemical oxidation reactions device of formula filter core electrode is joined together with iron carbon tower, can not only improve the processing effect of difficult organic wastewater Fruit, and the strong acid of electrochemical oxidation generation and highly basic draining can be efficiently used, greatly reduce system operation cost.
The operation principle of electrochemical oxidation-iron carbon association system of the processing organic wastewater with difficult degradation thereby of the present invention is as follows:
In electrochemical oxidation reactions device 1, when DC power supply 6 is powered, anion is moved to anode 4 in waste water, sun from Son is moved to cathode 5, is in the main reaction that 4 surface of anode occurs:
2Cl-=Cl2+2e-
Cl2+H2O=HClO+HCl
HClO=H++ClO-
4 draining of anode contains the HClO of strong oxidizing property, and it is organic can hardly degraded organic substance to be oxidized to degradable small molecule Object or even it is oxidized to CO2
It is in the main reaction that 5 surface of cathode occurs:
2H2O+2e-=H2+2OH-
Na++OH-=NaOH
5 draining of cathode is strong basicity, and salinity is higher.
When the acid effluent of anode 4 is pumped to iron carbon tower 8, following galvanic interaction occurs in tower:
Anode:Fe-2e-=Fe2+
Cathode:2H++2e-=2 [H]=H2
React the nascent state Fe generated2+[H], have high chemism, can aoxidize with reducing waste water in many organic matters, The effects that making organic matter that chain rupture, open loop occur.
When 5 draining of cathode is pumped into mixing pit 11, acid-base neutralization reaction occurs, due to consuming part H in iron carbon tower 8+, So waste water is in alkalinity in mixing pit 11, the key reaction of generation is as follows:
H++OH-=H2O
Fe2++2OH-=Fe (OH)2
Fe3++3OH-=Fe (OH)3
In sedimentation basin 13, the Fe (OH) of generation2With Fe (OH)3Flocculation precipitation reaction occurs, while it is organic to remove part Pollutant.
The system can economical and efficient removal persistent organic pollutants, the water standard of lifting waste water discharge, and advantageous In the recycling for realizing waste water.
Above-mentioned specific embodiment is used for illustrating the present invention rather than limiting the invention, in the essence of the present invention In the protection domain of god and principles and requirements, to any modifications and changes that the present invention makes, protection scope of the present invention is both fallen within.

Claims (5)

1. the electrochemical oxidation of a kind of organic wastewater with difficult degradation thereby-iron carbon joint processing system, which is characterized in that the system includes electricity Chemical oxidation reaction device (1), anode draining pump (7), iron carbon tower (8), cathode draining pump (9), iron carbon tower draining pump (10), mixing Pond (11), mixing pit draining pump (12), sedimentation basin (13), the electrochemical oxidation reactions device (1) include housing (2), anode (4), cathode (5), power supply (6), the bottom of the housing (2) are equipped with water inlet (3), and the anode (4) and cathode (5) are Equivalent titanium-based porous tubular filter core electrode, one end are immersed in the waste water of the housing (2), the other end and the power supply (6) it is connected;The anode (4) is connected by pipeline, anode draining pump (7) with the water inlet of the iron carbon tower (8), described The water outlet of iron carbon tower (8) be connected by iron carbon tower draining pump (10) with the mixing pit (11), the cathode (5) is logical It crosses pipeline, cathode draining pump (9) also with the mixing pit (11) to be connected, the mixing pit (11) passes through the mixing pit Draining pump (12) is connected with the sedimentation basin (13).
2. the processing system of organic wastewater with difficult degradation thereby according to claim 1, which is characterized in that the anode (4) and The aperture of cathode (5) is 50-100 μm.
3. the electrochemical oxidation of organic wastewater with difficult degradation thereby according to claim 1 or 2-iron carbon joint processing system, special Sign is that the power supply (6) is constant voltage dc source.
4. the electrochemical oxidation of organic wastewater with difficult degradation thereby according to claim 1 or 2-iron carbon joint processing system, special Sign is that the power supply (6) is electrochmical power source.
5. the electrochemical oxidation of organic wastewater with difficult degradation thereby according to claim 1-iron carbon joint processing system, feature exist In the drain discharge ratio of the anode (4) and cathode (5) is 1:1.
CN201711424051.7A 2017-12-25 2017-12-25 A kind of electrochemical oxidation-iron carbon association system for handling organic wastewater with difficult degradation thereby Pending CN108178387A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112250255A (en) * 2020-10-19 2021-01-22 张家港市杨舍丝印工艺厂 Wastewater treatment process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101696069A (en) * 2009-10-14 2010-04-21 大连交通大学 Ultra advanced treatment method and device for sewage
CN207294453U (en) * 2017-12-25 2018-05-01 浙江飞源环境工程有限公司 Handle electrochemical oxidation-iron carbon association system of organic wastewater with difficult degradation thereby

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101696069A (en) * 2009-10-14 2010-04-21 大连交通大学 Ultra advanced treatment method and device for sewage
CN207294453U (en) * 2017-12-25 2018-05-01 浙江飞源环境工程有限公司 Handle electrochemical oxidation-iron carbon association system of organic wastewater with difficult degradation thereby

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张艳桥;: "铁炭微电解法处理黄连素废水应用研究" *
李彦生;李永斌;柳志刚;: "电渗透离子交换法深度净化污水的机理及应用初探" *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112250255A (en) * 2020-10-19 2021-01-22 张家港市杨舍丝印工艺厂 Wastewater treatment process

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