CN108166321A - A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying - Google Patents
A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying Download PDFInfo
- Publication number
- CN108166321A CN108166321A CN201810006298.5A CN201810006298A CN108166321A CN 108166321 A CN108166321 A CN 108166321A CN 201810006298 A CN201810006298 A CN 201810006298A CN 108166321 A CN108166321 A CN 108166321A
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- CN
- China
- Prior art keywords
- electrolytic capacitor
- capacitor paper
- high intensity
- spraying
- pva
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/02—Methods of beating; Beaters of the Hollander type
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/06—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type
- D21F11/08—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type paper or board consisting of two or more layers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/50—Spraying or projecting
Landscapes
- Paper (AREA)
- Sanitary Thin Papers (AREA)
Abstract
The present invention relates to a kind of preparation methods of electrolytic capacitor paper.A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying, this method include the following steps:1) jute pulp is added be made after water 2~5% mass concentration original slurry material;2) by original slurry material by beater or fiberizer obtain mass concentration 2~5%, 40~60 ° of SR of beating degree, 2~16g of weight in wet base slurry A;3) slurry A is carried out compound through double cylinders, it is compound after by squeezing, coating fluid, coating fluid a concentration of 1~3% are sprayed in page surface by spray pattern after squeezing, coating solution amount is 0.1~1.0g/m2, coating fluid is polycarboxylic acids and PVA, and the mass ratio of polycarboxylic acids and PVA are 1:1~1:4;4) it and then drying, press polish, batches and obtains electrolytic capacitor paper after cutting.The present invention has preferable intensity, good water absorbing properties, good loss value, excellent proof voltage energy, and tensile strength increases more than 0.4kN/m.
Description
Technical field
The present invention relates to a kind of preparation methods of electrolytic capacitor paper.
Background technology
Electrolytic capacitor paper is to prepare one of indispensable raw material of electrolytic capacitor, between capacitor anode and cathode
Play buffer action, prevent anode and cathode is in direct contact and it is short-circuit.
Electrolytic capacitor paper had both belonged to speciality paper scope, also belonged to electronic component, therefore, different from general paper, electricity
Electrolytic capacitor paper has following requirement:(1) purity is high, and the impurity for influencing electrolyte and electrode foil performance will be controlled strictly;(2)
Papery is uniform, and thickness and tightness are uniform, and fiber alignment uniformly, while will be unable to the paper defects such as hole and fibre bundle;(3) have
Necessary electrical strength and mechanical strength;(4) there are good wellability and retentivity to electrolyte;(5) with electrolyte group
During into complex, there is low resistance.
The tightness and thickness of electrolytic capacitor paper are higher, and the loss of the electrolytic capacitor of preparation can be bigger, and prepares low damage
The electrolytic capacitor of consumption generally requires electrolytic capacitor paper to have relatively low a tightness and thickness, but the reduction of tightness and thickness,
The intensity of electrolytic capacitor paper can be caused to decline, the resistance to burr property of electrolytic capacitor paper is reduced, also result in electrolytic capacitor
Production efficiency reduce.At present, it for this problem, is difficult to solve using usual manner.
Invention content
In order to solve the above technical problems, there is opposite high intensity the object of the present invention is to provide one kind and be lost relatively low
Electrolytic capacitor paper preparation method.
To achieve these goals, the present invention uses following technical scheme:
A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying, this method include the following steps:
1) jute pulp is added be made after water 2~5% mass concentration original slurry material;
2) original slurry material is obtained into mass concentration 2~5%, 40~60 ° of SR of beating degree, weight in wet base 2 by beater or fiberizer
The slurry A of~16g;
3) slurry A is carried out compound through double cylinders, it is compound after by squeezing, sprayed after squeezing by spray pattern in page surface
Coating fluid, coating fluid a concentration of 1~3% are applied, coating solution amount is 0.1~1.0g/m2, coating fluid is polycarboxylic acids and PVA, is gathered
The mass ratio of carboxylic acid and PVA are 1:1~1:4;
4) it and then drying, press polish, batches and obtains electrolytic capacitor paper after cutting.
Preferably, the jute pulp include sisal hemp pulp, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose latex,
One or more of pineapple leaves slurry and wingceltis latex.
Preferably, the mass concentration 2~4% of the jute pulp, beating degree 40~50 ° of SR, 8~12g of weight in wet base.
Preferably, the coating solution amount is 0.2~0.6g/m2。
Preferably, the polycarboxylic acids and the mass ratio of PVA are 1:2~1:3.
Preferably, the mashing mode includes the mashing of hollanderbeater free type, single or double mill shiny beating
In one kind.
The present invention is as a result of above-mentioned technical solution, production and spraying coating by body paper, the low tightness of acquisition
High intensity electrolytic capacitor paper, and have preferable intensity, good water absorbing properties, good loss value, excellent proof voltage energy,
Tensile strength increases more than 0.4kN/m.
Specific embodiment
Reference example 1
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out compound, through drying after squeezing, dryer temperature is
145 DEG C, then through press polish, batch and obtain finished product, quantification of 15g/m after cutting2。
Reference example 2
The beating degree and weight in wet base of sisal hemp pulp are respectively 50 ° of SR, 8.8g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out compound, through drying after squeezing, dryer temperature is
150 DEG C, then through press polish, batch and obtain finished product, quantification of 15g/m after cutting2。
Embodiment 1
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight is
0.1g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2。
Embodiment 2
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight is
0.1g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2。
Embodiment 3
The beating degree and weight in wet base of sisal hemp pulp are respectively 50 ° of SR, 8.8g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight is
0.1g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2。
Embodiment 4
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight is
0.3g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2。
Embodiment 5
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight is
0.3g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2。
Embodiment 6
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, using hollanderbeater by free type be beaten into
Row, beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after pass through spray pattern
In page surface spraying polycarboxylic acids and PVA, the mass ratio of polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight is
0.5g/m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2。
The test data of above-mentioned each electrolytic capacitor paper is as follows:
Claims (6)
- A kind of 1. method for preparing low tightness high intensity electrolytic capacitor paper of spraying, which is characterized in that this method includes following Step:1) jute pulp is added be made after water 2~5% mass concentration original slurry material;2) original slurry material is obtained into mass concentration 2~5%, 40~60 ° of SR of beating degree, 2~16g of weight in wet base by beater or fiberizer Slurry A;3) slurry A is carried out compound through double cylinders, is sprayed and applied in page surface by spray pattern by squeezing, after squeezing after compound Cloth liquid, coating fluid a concentration of 1~3%, coating solution amount are 0.1~1.0g/m2, coating fluid be polycarboxylic acids and PVA, polycarboxylic acids Mass ratio with PVA is 1:1~1:4;4) it and then drying, press polish, batches and obtains electrolytic capacitor paper after cutting.
- 2. a kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying according to claim 1, feature exist In jute pulp is included in sisal hemp pulp, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose latex, pineapple leaves slurry and wingceltis latex It is one or more of.
- 3. a kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying according to claim 1, feature exist In, the mass concentration 2~4% of jute pulp, beating degree 40~50 ° of SR, 8~12g of weight in wet base.
- 4. a kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying according to claim 1, feature exist In coating solution amount is 0.2~0.6g/m2。
- 5. a kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying according to claim 1, feature exist In the mass ratio of polycarboxylic acids and PVA are 1:2~1:3.
- 6. method according to claim 1 that prepare low tightness high intensity electrolytic capacitor paper of spraying, which is characterized in that institute The mashing mode stated includes one kind in the mashing of hollanderbeater free type, single or double mill shiny beating.
Priority Applications (1)
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CN201810006298.5A CN108166321A (en) | 2018-01-04 | 2018-01-04 | A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying |
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CN201810006298.5A CN108166321A (en) | 2018-01-04 | 2018-01-04 | A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109137593A (en) * | 2018-09-11 | 2019-01-04 | 浙江凯恩特种材料股份有限公司 | A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized |
CN116479682A (en) * | 2023-04-26 | 2023-07-25 | 株洲时代华先材料科技有限公司 | Capacitor paper and preparation method thereof |
Citations (4)
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CN1793508A (en) * | 2005-12-23 | 2006-06-28 | 浙江凯恩特种材料股份有限公司 | Process for preparing electrolytic capacitor paper |
CN104988809A (en) * | 2015-06-26 | 2015-10-21 | 浙江凯恩特种材料股份有限公司 | High voltage resistant electrolytic capacitor paper and preparation method thereof |
CN105064123A (en) * | 2015-08-07 | 2015-11-18 | 成都易胜科生物科技有限公司 | Multilayer structure electrolytic capacitor paper and preparation method of electrolytic capacitor paper |
WO2017104336A1 (en) * | 2015-12-14 | 2017-06-22 | ニッポン高度紙工業株式会社 | Separator for alkaline batteries, and alkaline battery |
-
2018
- 2018-01-04 CN CN201810006298.5A patent/CN108166321A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1793508A (en) * | 2005-12-23 | 2006-06-28 | 浙江凯恩特种材料股份有限公司 | Process for preparing electrolytic capacitor paper |
CN104988809A (en) * | 2015-06-26 | 2015-10-21 | 浙江凯恩特种材料股份有限公司 | High voltage resistant electrolytic capacitor paper and preparation method thereof |
CN105064123A (en) * | 2015-08-07 | 2015-11-18 | 成都易胜科生物科技有限公司 | Multilayer structure electrolytic capacitor paper and preparation method of electrolytic capacitor paper |
WO2017104336A1 (en) * | 2015-12-14 | 2017-06-22 | ニッポン高度紙工業株式会社 | Separator for alkaline batteries, and alkaline battery |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109137593A (en) * | 2018-09-11 | 2019-01-04 | 浙江凯恩特种材料股份有限公司 | A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized |
CN116479682A (en) * | 2023-04-26 | 2023-07-25 | 株洲时代华先材料科技有限公司 | Capacitor paper and preparation method thereof |
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Application publication date: 20180615 |