CN108165067A - A kind of Oil paint medium agent for being intended to improve color stability - Google Patents
A kind of Oil paint medium agent for being intended to improve color stability Download PDFInfo
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- CN108165067A CN108165067A CN201810053413.4A CN201810053413A CN108165067A CN 108165067 A CN108165067 A CN 108165067A CN 201810053413 A CN201810053413 A CN 201810053413A CN 108165067 A CN108165067 A CN 108165067A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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Abstract
The invention discloses a kind of Oil paint medium agents for being intended to improve color stability, are related to oil colour technical field, are made of the raw material of following parts by weight：10 15 parts of polyglycerol, 5 10 parts of ethoxylated trimethylolpropane triacrylate, 5 10 parts of propandiol butyl ether, 15 parts of N hydroxyethyl acrylamides, 15 parts of trihydroxymethylpropanyltri diglycidyl ether, 0.5 2 parts of 0.5 2 part, nanometer rubber powder of hydrolysis of polymaleic anhydride, 0.05 0.5 parts of aluminium polychloride.The made Oil paint medium agent of the present invention it is safe to use; the feature of environmental protection is strong; the color stability of oil colour can be effectively improved; oil colour is made to be firmly attached on whatman; made oil painting remains to farthest keep original color and gloss after long-time is placed; reduce the aberration that oil painting occurs due to long-time is placed, so as to the protection conducive to oil painting.
Description
Technical field：
The present invention relates to oil colour technical fields, and in particular to a kind of oil colour matchmaker for being intended to improve color stability
Jie's agent.
Background technology：
Oil painting is one made on painting canvas linen, cardboard or plank with drip-dry vegetable oil filling colour
It is a to draw kind.The diluent used when drawing a picture is volatile turpentine oil and the linseed oil of dryness etc..Pigment accompanying by picture
There is stronger hardness, gloss can be kept for a long time after picture drying.Covering power and transparent performance by pigment more fully hereinafter table
Existing rendered object, rich in color, match volume is strong.
When oil colour is used to be painted, catalytic agent plays very important effect wherein.Oil colour exists
After drawing, if without the help of catalytic agent, color stability is poor, and color and gloss can drop after a period of time is placed
It is much lower.In drawing, reconciled by catalytic agent, oil colour is enable more steadily to be present on paper, it can be with
The color and gloss of the holding oil colour of some time.Therefore, protection of the Oil paint medium agent for oil painting, be one must
Indispensable substance.
Patent CN 103483899A disclose a kind of Oil paint medium agent, by hexanol, BBP(Butyl Benzyl Phthalate, three
Caproin, pentaerythrite, sorbierite, lauric acid, propylene glycol composition.Although made catalytic agent can significantly improve oil colour
Color stability, since hexanol, BBP(Butyl Benzyl Phthalate and propylene glycol have toxicity, although belonging to low toxicity, but human body
Toxic reaction can be generated after skin contact, therefore the safety in utilization of made catalytic agent is relatively low.
Invention content：
The technical problems to be solved by the invention be to provide it is a kind of it is safe to use, the feature of environmental protection is strong and long conducive to oil painting
What the time preserved is intended to improve the Oil paint medium agent of color stability.
The technical problems to be solved by the invention are realized using following technical solution：
A kind of Oil paint medium agent for being intended to improve color stability, is made of the raw material of following parts by weight：
10-15 parts of polyglycerol, 5-10 parts of ethoxylated trimethylolpropane triacrylate, propandiol butyl ether 5-10
Part, 1-5 parts of N- hydroxyethyl acrylamides, 1-5 parts of trihydroxymethylpropanyltri diglycidyl ether, 0.5-2 parts of hydrolysis of polymaleic anhydride,
0.5-2 parts of rubber powder of nanometer, 0.05-0.5 parts of aluminium polychloride.
Preparation method includes the following steps：
(1) it is ethoxylated trimethylolpropane triacrylate, N- hydroxyethyl acrylamides and aluminium polychloride is abundant
Mixing, and 125-135 DEG C of insulated and stirred reaction is heated to, 0-10 is cooled to the cooling velocity of 5-10 DEG C/min after reaction
DEG C heat preservation stands 0.5-1h, and micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) it adds in trihydroxymethylpropanyltri diglycidyl ether into polyglycerol and hydrolysis of polymaleic anhydride is sufficiently mixed,
And 110-120 DEG C of insulated and stirred 1-2h is heated to the heating rate of 5-10 DEG C/min, then be transferred in 30-40 DEG C of environment and drop naturally
Then temperature is again heated to 110-120 DEG C of insulated and stirred 0.5-1h to 30-40 DEG C with the heating rate of 5-10 DEG C/min, natural
It is cooled to room temperature to get modified poly glycerine；
(3) acrylic resin, propandiol butyl ether and nanometer rubber powder are added in into modified poly glycerine, and is heated to 125-
135 DEG C of insulated and stirred 10-30min, cooled to room temperature is to get Oil paint medium agent.
The nanometer rubber powder selects mortar special-purpose nanometer rubber powder.
The nanometer rubber powder is made of the raw material of following parts by weight：1-5 parts of C5 hydrogenated petroleum resins, hydroxyethyl cellulose
1-5 parts, 1-5 parts of stearyl alcohol glycyrrhetin acid esters, 0.05-1 parts of 1- butyl -3- methylimidazoles bis-trifluoromethylsulfoandimide salt, system
Preparation Method is：Stearyl alcohol glycyrrhetin acid esters and the double trifluoro methylsulphurs of 1- butyl -3- methylimidazoles are added in into C5 hydrogenated petroleum resins
Imide salts using microwave reactor microwave treatment 5min after being sufficiently mixed, continue microwave treatment 5min, interval after being spaced 5min
Microwave treatment 5min again after 5min, then adds in hydroxyethyl cellulose while hot, is uniformly mixed, gained mixture is transferred to -10 DEG C
Sealing and standing 5h in environment, and micro mist is made using micronizer, nanometer powder most is made to get receiving through nano-level grinder afterwards
Rice glue powder.
The operating condition of the microwave reactor is microwave frequency 2450MHz, output power 700W.
By the addition of nanometer rubber powder, the comixing compatibility of catalytic agent and pigment is improved, and enhances the color and luster of oil colour
Stability.
The beneficial effects of the invention are as follows：The made Oil paint medium agent of the present invention it is safe to use, the feature of environmental protection is strong, energy
The color stability of oil colour is enough effectively improved, oil colour is made to be firmly attached on whatman, makees oil painting for a long time
It remains to farthest keep original color and gloss after placement, reduces the aberration that oil painting occurs due to long-time is placed, from
And conducive to the protection of oil painting.
Specific embodiment：
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
(1) 8g ethoxylated trimethylolpropane triacrylates, 3g N- hydroxyethyl acrylamides and 0.5g are polymerize chlorine
Change aluminium to be sufficiently mixed, and be heated to 125-135 DEG C of insulated and stirred reaction, dropped after reaction with the cooling velocity of 5-10 DEG C/min
Temperature to 0-10 DEG C of heat preservation stands 1h, and micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) 3g trihydroxymethylpropanyltri diglycidyl ethers and 0.5g hydrolysis of polymaleic anhydride are added in into 10g polyglycerols
It is sufficiently mixed, and 110-120 DEG C of insulated and stirred 2h is heated to the heating rate of 5-10 DEG C/min, then be transferred to 30-40 DEG C of environment
In be naturally cooling to 30-40 DEG C, 110-120 DEG C of insulated and stirred is then again heated to the heating rate of 5-10 DEG C/min
30min, cooled to room temperature is to get modified poly glycerine；
(3) acrylic resin, 10g propandiol butyl ethers and 1g nanometers of rubber powders are added in into modified poly glycerine, and are heated to
125-135 DEG C of insulated and stirred 15min, cooled to room temperature is to get Oil paint medium agent.
Wherein, nanometer rubber powder selects the mortar special-purpose nanometer rubber powder of Beijing Guo Hao chemical machineries Co., Ltd.
Embodiment 2
(1) 10g ethoxylated trimethylolpropane triacrylates, 5g N- hydroxyethyl acrylamides and 0.5g are polymerize
Aluminium chloride is sufficiently mixed, and is heated to 125-135 DEG C of insulated and stirred reaction, after reaction with the cooling velocity of 5-10 DEG C/min
It is cooled to 0-10 DEG C of heat preservation and stands 1h, micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) 5g trihydroxymethylpropanyltri diglycidyl ethers are added in into 15g polyglycerols and 1g hydrolysis of polymaleic anhydride is filled
Divide mixing, and 110-120 DEG C of insulated and stirred 2h is heated to, then be transferred in 30-40 DEG C of environment with the heating rate of 5-10 DEG C/min
30-40 DEG C is naturally cooling to, 110-120 DEG C of insulated and stirred 30min is then again heated to the heating rate of 5-10 DEG C/min,
Cooled to room temperature is to get modified poly glycerine；
(3) acrylic resin, 10g propandiol butyl ethers and 2g nanometers of rubber powders are added in into modified poly glycerine, and are heated to
125-135 DEG C of insulated and stirred 15min, cooled to room temperature is to get Oil paint medium agent.
Wherein, nanometer rubber powder selects the mortar special-purpose nanometer rubber powder of Beijing Guo Hao chemical machineries Co., Ltd.
Embodiment 3
(1) 8g ethoxylated trimethylolpropane triacrylates, 3g N- hydroxyethyl acrylamides and 0.5g are polymerize chlorine
Change aluminium to be sufficiently mixed, and be heated to 125-135 DEG C of insulated and stirred reaction, dropped after reaction with the cooling velocity of 5-10 DEG C/min
Temperature to 0-10 DEG C of heat preservation stands 1h, and micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) 3g trihydroxymethylpropanyltri diglycidyl ethers and 0.5g hydrolysis of polymaleic anhydride are added in into 10g polyglycerols
It is sufficiently mixed, and 110-120 DEG C of insulated and stirred 2h is heated to the heating rate of 5-10 DEG C/min, then be transferred to 30-40 DEG C of environment
In be naturally cooling to 30-40 DEG C, 110-120 DEG C of insulated and stirred is then again heated to the heating rate of 5-10 DEG C/min
30min, cooled to room temperature is to get modified poly glycerine；
(3) acrylic resin, 10g propandiol butyl ethers and 1g nanometers of rubber powders are added in into modified poly glycerine, and are heated to
125-135 DEG C of insulated and stirred 15min, cooled to room temperature is to get Oil paint medium agent.
The preparation of nanometer rubber powder：2g stearyl alcohol glycyrrhetin acid esters and 0.1g 1- fourths are added in into 5g C5 hydrogenated petroleum resins
Base -3- methylimidazole bis-trifluoromethylsulfoandimide salt utilizes microwave frequency 2450MHz, output power 700W after being sufficiently mixed
Microwave reactor microwave treatment 5min continues microwave treatment 5min after being spaced 5min, is spaced after 5min microwave treatment 5min again,
Then 3g hydroxyethyl celluloses are added in while hot, are uniformly mixed, and gained mixture is transferred to sealing and standing 5h in -10 DEG C of environment, and profit
Micro mist is made with micronizer, nanometer powder most is made to get nanometer rubber powder through nano-level grinder afterwards.
Embodiment 4
(1) 10g ethoxylated trimethylolpropane triacrylates, 5g N- hydroxyethyl acrylamides and 0.5g are polymerize
Aluminium chloride is sufficiently mixed, and is heated to 125-135 DEG C of insulated and stirred reaction, after reaction with the cooling velocity of 5-10 DEG C/min
It is cooled to 0-10 DEG C of heat preservation and stands 1h, micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) 5g trihydroxymethylpropanyltri diglycidyl ethers are added in into 15g polyglycerols and 1g hydrolysis of polymaleic anhydride is filled
Divide mixing, and 110-120 DEG C of insulated and stirred 2h is heated to, then be transferred in 30-40 DEG C of environment with the heating rate of 5-10 DEG C/min
30-40 DEG C is naturally cooling to, 110-120 DEG C of insulated and stirred 30min is then again heated to the heating rate of 5-10 DEG C/min,
Cooled to room temperature is to get modified poly glycerine；
(3) acrylic resin, 10g propandiol butyl ethers and 2g nanometers of rubber powders are added in into modified poly glycerine, and are heated to
125-135 DEG C of insulated and stirred 15min, cooled to room temperature is to get Oil paint medium agent.
The preparation of nanometer rubber powder：1g stearyl alcohol glycyrrhetin acid esters and 0.05g 1- are added in into 3g C5 hydrogenated petroleum resins
Butyl -3- methylimidazole bis-trifluoromethylsulfoandimide salt utilizes microwave frequency 2450MHz, output power 700W after being sufficiently mixed
Microwave reactor microwave treatment 5min, continue microwave treatment 5min after being spaced 5min, be spaced microwave treatment again after 5min
Then 5min adds in 2g hydroxyethyl celluloses while hot, be uniformly mixed, and gained mixture is transferred to sealing and standing 5h in -10 DEG C of environment,
And micro mist is made using micronizer, nanometer powder most is made to get nanometer rubber powder through nano-level grinder afterwards.
Reference examples 1
(1) 10g ethoxylated trimethylolpropane triacrylates, 5g N- hydroxyethyl acrylamides and 0.5g are polymerize
Aluminium chloride is sufficiently mixed, and is heated to 125-135 DEG C of insulated and stirred reaction, after reaction with the cooling velocity of 5-10 DEG C/min
It is cooled to 0-10 DEG C of heat preservation and stands 1h, micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) 5g trihydroxymethylpropanyltri diglycidyl ethers are added in into 15g polyglycerols and 1g hydrolysis of polymaleic anhydride is filled
Divide mixing, and 110-120 DEG C of insulated and stirred 2h is heated to, then be transferred in 30-40 DEG C of environment with the heating rate of 5-10 DEG C/min
30-40 DEG C is naturally cooling to, 110-120 DEG C of insulated and stirred 30min is then again heated to the heating rate of 5-10 DEG C/min,
Cooled to room temperature is to get modified poly glycerine；
(3) acrylic resin, 10g propandiol butyl ethers are added in into modified poly glycerine, and is heated to 125-135 DEG C of heat preservation
15min is stirred, cooled to room temperature is to get Oil paint medium agent.
Reference examples 2
(1) 10g ethoxylated trimethylolpropane triacrylates, 5g N- hydroxyethyl acrylamides and 0.5g are polymerize
Aluminium chloride is sufficiently mixed, and is heated to 125-135 DEG C of insulated and stirred reaction, after reaction with the cooling velocity of 5-10 DEG C/min
It is cooled to 0-10 DEG C of heat preservation and stands 1h, micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) acrylic resin, 10g propandiol butyl ethers and 2g nanometers of rubber powders are added in into 15g polyglycerols, and are heated to
125-135 DEG C of insulated and stirred 15min, cooled to room temperature is to get Oil paint medium agent.
The preparation of nanometer rubber powder：1g stearyl alcohol glycyrrhetin acid esters and 0.05g 1- are added in into 3g C5 hydrogenated petroleum resins
Butyl -3- methylimidazole bis-trifluoromethylsulfoandimide salt utilizes microwave frequency 2450MHz, output power 700W after being sufficiently mixed
Microwave reactor microwave treatment 5min, continue microwave treatment 5min after being spaced 5min, be spaced microwave treatment again after 5min
Then 5min adds in 2g hydroxyethyl celluloses while hot, be uniformly mixed, and gained mixture is transferred to sealing and standing 5h in -10 DEG C of environment,
And micro mist is made using micronizer, nanometer powder most is made to get nanometer rubber powder through nano-level grinder afterwards.
Reference examples 3
(1) 5g trihydroxymethylpropanyltri diglycidyl ethers are added in into 15g polyglycerols and 1g hydrolysis of polymaleic anhydride is filled
Divide mixing, and 110-120 DEG C of insulated and stirred 2h is heated to, then be transferred in 30-40 DEG C of environment with the heating rate of 5-10 DEG C/min
30-40 DEG C is naturally cooling to, 110-120 DEG C of insulated and stirred 30min is then again heated to the heating rate of 5-10 DEG C/min,
Cooled to room temperature is to get modified poly glycerine；
(2) 10g ethoxylated trimethylolpropane triacrylates, 5g N- ethoxys are added in into modified poly glycerine
Acrylamide, 0.5g aluminium polychlorides, 10g propandiol butyl ethers and 2g nanometers of rubber powders, and it is heated to 125-135 DEG C of insulated and stirred
15min, cooled to room temperature is to get Oil paint medium agent.
The preparation of nanometer rubber powder：1g stearyl alcohol glycyrrhetin acid esters and 0.05g 1- are added in into 3g C5 hydrogenated petroleum resins
Butyl -3- methylimidazole bis-trifluoromethylsulfoandimide salt utilizes microwave frequency 2450MHz, output power 700W after being sufficiently mixed
Microwave reactor microwave treatment 5min, continue microwave treatment 5min after being spaced 5min, be spaced microwave treatment again after 5min
Then 5min adds in 2g hydroxyethyl celluloses while hot, be uniformly mixed, and gained mixture is transferred to sealing and standing 5h in -10 DEG C of environment,
And micro mist is made using micronizer, nanometer powder most is made to get nanometer rubber powder through nano-level grinder afterwards.
Embodiment 5
It is utilized respectively embodiment 1-4, reference examples 1-3 and prepares Oil paint medium agent, take identical commercially available red oil colour,
It is coated on oil painting paper, and in identical storage ring after being mixed in a manner that 1g red oil colour adds 5g Oil paint medium agents
It is placed 1 year in border, measures the aberration of oil painting before and after placing, while with 3 made oil colour of patent CN 103483899A embodiments
Catalytic agent is as reference examples 4, and the results are shown in Table 1.
The color stability of 1 Oil paint medium agent of the present invention of table
The basic principles, main features and the advantages of the invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of Oil paint medium agent for being intended to improve color stability, it is characterised in that：By the raw material of following parts by weight
It is made：
10-15 parts of polyglycerol, 5-10 parts of ethoxylated trimethylolpropane triacrylate, 5-10 parts of propandiol butyl ether, N-
1-5 parts of hydroxyethyl acrylamide, 1-5 parts of trihydroxymethylpropanyltri diglycidyl ether, 0.5-2 parts of hydrolysis of polymaleic anhydride, nanometer
0.5-2 parts of rubber powder, 0.05-0.5 parts of aluminium polychloride.
2. the Oil paint medium agent according to claim 1 for being intended to improve color stability, which is characterized in that it is prepared
Method includes the following steps：
(1) ethoxylated trimethylolpropane triacrylate, N- hydroxyethyl acrylamides and aluminium polychloride are sufficiently mixed,
And 125-135 DEG C of insulated and stirred reaction is heated to, 0-10 DEG C of guarantor is cooled to the cooling velocity of 5-10 DEG C/min after reaction
Temperature stands 0.5-1h, and micro mist is made to get acrylic resin through micronizer in gained mixture；
(2) it adds in trihydroxymethylpropanyltri diglycidyl ether into polyglycerol and hydrolysis of polymaleic anhydride is sufficiently mixed, and with
The heating rate of 5-10 DEG C/min is heated to 110-120 DEG C of insulated and stirred 1-2h, then is transferred in 30-40 DEG C of environment and is naturally cooling to
30-40 DEG C, 110-120 DEG C of insulated and stirred 0.5-1h, natural cooling are then again heated to the heating rate of 5-10 DEG C/min
To room temperature to get modified poly glycerine；
(3) acrylic resin, propandiol butyl ether and nanometer rubber powder are added in into modified poly glycerine, and is heated to 125-135 DEG C
Insulated and stirred 10-30min, cooled to room temperature is to get Oil paint medium agent.
3. the Oil paint medium agent according to claim 1 or 2 for being intended to improve color stability, it is characterised in that：Institute
It states nanometer rubber powder and selects mortar special-purpose nanometer rubber powder.
4. the Oil paint medium agent according to claim 1 or 2 for being intended to improve color stability, which is characterized in that institute
Nanometer rubber powder is stated to be made of the raw material of following parts by weight：1-5 parts of C5 hydrogenated petroleum resins, 1-5 parts of hydroxyethyl cellulose, tristearin
1-5 parts of alcohol glycyrrhetin acid esters, 0.05-1 parts of 1- butyl -3- methylimidazoles bis-trifluoromethylsulfoandimide salt, preparation method are：To
Stearyl alcohol glycyrrhetin acid esters and 1- butyl -3- methylimidazole bis-trifluoromethylsulfoandimide salt are added in C5 hydrogenated petroleum resins, is filled
Divide and microwave reactor microwave treatment 5min is utilized after mixing, after continuation microwave treatment 5min after the 5min of interval, interval 5min again
Microwave treatment 5min, then adds in hydroxyethyl cellulose while hot, is uniformly mixed, gained mixture is transferred in -10 DEG C of environment and seals
5h is stood, and micro mist is made using micronizer, nanometer powder most is made to get nanometer rubber powder through nano-level grinder afterwards.
5. the Oil paint medium agent according to claim 4 for being intended to improve color stability, it is characterised in that：It is described micro-
The operating condition of wave reactor is microwave frequency 2450MHz, output power 700W.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810053413.4A CN108165067A (en) | 2018-01-19 | 2018-01-19 | A kind of Oil paint medium agent for being intended to improve color stability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810053413.4A CN108165067A (en) | 2018-01-19 | 2018-01-19 | A kind of Oil paint medium agent for being intended to improve color stability |
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| CN108165067A true CN108165067A (en) | 2018-06-15 |
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| CN201810053413.4A Pending CN108165067A (en) | 2018-01-19 | 2018-01-19 | A kind of Oil paint medium agent for being intended to improve color stability |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113583502A (en) * | 2021-08-04 | 2021-11-02 | 上海马利画材股份有限公司 | Medium agent and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483899A (en) * | 2013-09-18 | 2014-01-01 | 吴江市冰心文教用品有限公司 | Oil paint medium agent |
| CN106752269A (en) * | 2016-12-30 | 2017-05-31 | 安徽真信涂料有限公司 | A kind of aluminium section bar powdery paints dicoration pigment dispersing agent |
-
2018
- 2018-01-19 CN CN201810053413.4A patent/CN108165067A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483899A (en) * | 2013-09-18 | 2014-01-01 | 吴江市冰心文教用品有限公司 | Oil paint medium agent |
| CN106752269A (en) * | 2016-12-30 | 2017-05-31 | 安徽真信涂料有限公司 | A kind of aluminium section bar powdery paints dicoration pigment dispersing agent |
Non-Patent Citations (2)
| Title |
|---|
| 张宇震: "《中国铝酸盐水泥生产与应用》", 31 January 2014, 中国建材工业出版社 * |
| 赵俊会 等: "《高分子化学与物理》", 29 February 2020, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113583502A (en) * | 2021-08-04 | 2021-11-02 | 上海马利画材股份有限公司 | Medium agent and preparation method and application thereof |
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