CN108164658A - A kind of novel fire resistant corrosion-resisting resin - Google Patents
A kind of novel fire resistant corrosion-resisting resin Download PDFInfo
- Publication number
- CN108164658A CN108164658A CN201810063886.2A CN201810063886A CN108164658A CN 108164658 A CN108164658 A CN 108164658A CN 201810063886 A CN201810063886 A CN 201810063886A CN 108164658 A CN108164658 A CN 108164658A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- fire resistant
- novel fire
- resistant corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
The present invention provides a kind of novel fire resistant corrosion-resisting resin, is made of by weight following raw material：45.9 48.5 parts of epoxy resin,12.1% 16.2 part of organic acid,It is crosslinked 34 36 parts of diluent,0.018 0.025 parts of polymerization inhibitor,0.2 0.3 parts of catalytic isomerization agent,Epoxy resin is added in reaction kettle,When being heated to 70 DEG C,Add in polymerization inhibitor,After stirring evenly,It adds in organic acid stirring and is warming up to 70 DEG C,Add catalyst reaction,It polymerize 23 hours in the environment of 80 120 DEG C,It is subsequently cooled to 80 90 DEG C,Add in crosslinking diluent,It polymerize 23 hours under 80 90 DEG C of environment,It is cooled to room temperature,Obtain resin,Breach the use temperature range of currently known resin material,With good corrosion-and high-temp-resistant,Low viscosity,Impregnability is good,Room temperature curing,It is non-toxic,It can be widely applied to the use of various corrosion-and high-temp-resistant industry resins.
Description
Technical field
The present invention relates to synthesis of polymer material and modification, the protection of isomery and high-temperature corrosion environment and production methods
Technical field, specially a kind of novel fire resistant corrosion-resisting resin.
Background technology
Resin material well known to existing market, it is resistance to the high temperature resistant of resin material in certain requirement height and adverse circumstances
Burn into low viscosity, impregnability, room temperature curing, nontoxicity require it is higher and higher, with the continuous development and industry of corrosion and protection
The raising of change degree, the application field of anti-corrosion material is also increasingly wider, and applying working condition, medium become increasingly complex, temperature in use
Higher and higher, traditional macromolecular antiseptic material has been unable to meet requirement.
Invention content
The purpose of the present invention is to provide a kind of novel fire resistant corrosion-resisting resin, for solving what is mentioned in background technology
Defect..
The invention is realized by the following technical scheme：A kind of novel fire resistant corrosion-resisting resin, by following raw material by weight
Part composition：45.9-48.5 parts of epoxy resin, 12.1%-16.2 parts of organic acid, 34-36 parts of diluent of crosslinking, polymerization inhibitor 0.018-
0.2-0.3 parts of 0.025 part, catalytic isomerization agent compositions.
A kind of novel fire resistant corrosion-resisting resin, is prepared by the following method：Epoxy resin is added in reaction kettle, heating
During to 70 DEG C, polymerization inhibitor is added in, after stirring evenly, organic acid stirring is added in and is warming up to 70 DEG C, add catalyst reaction,
It polymerize 2-3 hours in the environment of 80-120 DEG C, is subsequently cooled to 80-90 DEG C, crosslinking diluent is added in, under 80-90 DEG C of environment
Polymerization 2-3 hours, is cooled to room temperature, obtains resin, breach the use temperature range of currently known resin material, optimizes
The resin base fiber reinforced composite material of design, has high specific strength and specific stiffness, and designability is strong.Fatigue crack-resistant performance
Good, high temperature resistant, corrosion-resistant, good stability of the dimension, have good good corrosion-and high-temp-resistant, low viscosity, impregnability, room temperature curing,
Nontoxicity can be widely applied to the use of various corrosion-and high-temp-resistant industry resins.
Further, above-mentioned epoxy resin includes：E-44、E-51、F-44、F-51.
Further, above-mentioned organic acid includes：Methacrylic acid, acrylic acid, butenoic acid.
Further, above-mentioned crosslinking diluent includes：It is styrene, methyl styrene, vinyltoluene, chlorostyrene, double
Cyclopentadiene acrylate.
Further, above-mentioned polymerization inhibitor includes：Hydroquinone, tert-butyl catechol, 1,4-benzoquinone.
Further, above-mentioned catalytic isomerization agent includes：Benzyl dimethylamine, pyridine, diethylenetriamine, triethanolamine, diamino
Base diphenyl-methane, 4,4- diaminodiphenylsulfones, boron trifluoride, Benzylmagnesium chloride amine, and the polymerization that catalyst is above-mentioned many kinds of substance
Object.The ratio of catalytic isomerization agent is A：B=3:2,（Wherein A is included：6.5 parts of benzyl dimethylamine, 1.5 parts of diethylenetriamine, three second
1.5 parts of hydramine, 0.5 part of pyridine, B is included：2.5 parts of diaminodiphenylmethane, 0.5 part of diaminodiphenylsulfone, boron trifluoride 4.5
Part, 2.5 parts of Benzylmagnesium chloride amine）.
The present invention has the advantages that：The present invention, which develops a kind of novel fire resistant corrosion-resisting resin of offer, can break through mesh
The use temperature range of preceding tradition resin material, synthesis thermosetting resin is as nonmetallic anti-corrosion material, with its excellent physics
Mechanical property and corrosion-resistant, long-life and convenient processing performance, continuous development and industrialization degree with corrosion and protection
Raising, applying working condition, medium become increasingly complex, and temperature in use is also higher and higher, develops towards compared with operation at high temperature, improves and uses
The concentration and range of medium, the technique for improving anti-corrosion material, be domestic external anticorrosive material development trend.It can be in high temperature and high temperature
It is used under corrosive environment, has good process, workability, low viscosity, impregnability are good, room temperature is inside and outside cure, cure nontoxicity
, it can be widely applied to oil, chemical industry, metallurgy, electric power, space flight, aviation, national defence, heat exchange, pharmacy, plumbing, municipal works
Etc. industries novel fire resistant corrosion-resisting resin.
Specific embodiment
It elaborates with reference to embodiment to the present invention：
Embodiment 1
Resin Composition provided in this embodiment includes：Epoxy resin, organic acid, crosslinking diluent, polymerization inhibitor, catalytic isomerization agent.
Composition by weight between each component of resin provided in this embodiment is：45.9-48.5 parts of epoxy resin has
0.2-0.3 parts of 12.1%-16.2 parts of machine acid, 34-36 parts of diluent of crosslinking, 0.018-0.025 parts of polymerization inhibitor, catalytic isomerization agent groups
Into.
In the present embodiment, above-mentioned each component is as shown in the table by weight：
A kind of novel fire resistant corrosion-resisting resin of the present embodiment, preparation method are as follows：
Epoxy resin is added in reaction kettle, when being heated to 70 DEG C, adds in polymerization inhibitor, after stirring evenly, adds in organic acid stirring
70 DEG C are warming up to, adds catalyst reaction, polymerize 2 ~ 3 hours in the environment of 80 ~ 120 DEG C, is subsequently cooled to 80 ~ 90 DEG C,
Crosslinking diluent is added in, is polymerize 2 ~ 3 hours under 80 ~ 90 DEG C of environment, is cooled to room temperature, obtains resin.
Embodiment 2
Resin Composition provided in this embodiment includes：Epoxy resin, organic acid, crosslinking diluent, polymerization inhibitor, catalytic isomerization agent.
Composition by weight between each component of resin provided in this embodiment is：45.9-48.5 parts of epoxy resin has
0.2-0.3 parts of 12.1%-16.2 parts of machine acid, 34-36 parts of diluent of crosslinking, 0.018-0.025 parts of polymerization inhibitor, catalytic isomerization agent groups
Into.
In the present embodiment, above-mentioned each component is as shown in the table by weight：
A kind of novel fire resistant corrosion-resisting resin of the present embodiment, preparation method are as follows：
Epoxy resin is added in reaction kettle, when being heated to 70 DEG C, adds in polymerization inhibitor, after stirring evenly, adds in organic acid stirring
70 DEG C are warming up to, adds catalyst reaction, polymerize 2 ~ 3 hours in the environment of 80 ~ 120 DEG C, is subsequently cooled to 80 ~ 90 DEG C,
Crosslinking diluent is added in, is polymerize 2 ~ 3 hours under 80 ~ 90 DEG C of environment, is cooled to room temperature, obtains resin.
Embodiment 3
Resin Composition provided in this embodiment includes：Epoxy resin, organic acid, crosslinking diluent, polymerization inhibitor, catalytic isomerization agent.
Composition by weight between each component of resin provided in this embodiment is：45.9-48.5 parts of epoxy resin has
0.2-0.3 parts of 12.1%-16.2 parts of machine acid, 34-36 parts of diluent of crosslinking, 0.018-0.025 parts of polymerization inhibitor, catalytic isomerization agent groups
Into.
In the present embodiment, above-mentioned each component is as shown in the table by weight：
A kind of novel fire resistant corrosion-resisting resin of the present embodiment, preparation method are as follows：
Epoxy resin is added in reaction kettle, when being heated to 70 DEG C, adds in polymerization inhibitor, after stirring evenly, adds in organic acid stirring
70 DEG C are warming up to, adds catalyst reaction, polymerize 2 ~ 3 hours in the environment of 80 ~ 120 DEG C, is subsequently cooled to 80 ~ 90 DEG C,
Crosslinking diluent is added in, is polymerize 2 ~ 3 hours under 80 ~ 90 DEG C of environment, is cooled to room temperature, obtains resin.
Require supplementation with contrast test：
By Comparability test generation as a result, when micro- stomata propellant accounting is bigger, permeable effect is good, diminishing mist, noise reduction
Audio fruit is better, and when light stabilizer, antioxidant accounting are bigger, the weather resistance of water-permeable brick plate material is better, can extend production
Product service life.
Compared with prior art, the beneficial effects of the invention are as follows a kind of of offer can break through making for current conventional resins material
It with temperature range, can be used under high temperature and high-temperature corrosion environment, there is good process, workability, low viscosity, impregnability
Good, the inside and outside curing of room temperature, cure it is avirulent, can be widely applied to oil, chemical industry, metallurgy, electric power, space flight, aviation, national defence,
The novel fire resistant corrosion-resisting resin of the industries such as heat exchange, pharmacy, plumbing, municipal works.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, that is made any repaiies
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of novel fire resistant corrosion-resisting resin, which is characterized in that be made of by weight following raw material：Epoxy resin
45.9-48.5 parts, 12.1%-16.2 parts of organic acid, crosslinking 34-36 parts of diluent, 0.018-0.025 parts of polymerization inhibitor, catalytic isomerization
0.2-0.3 parts of agent.
2. a kind of novel fire resistant corrosion-resisting resin according to claim 1, which is characterized in that add in epoxy resin
In reaction kettle, when being heated to 70 DEG C, polymerization inhibitor is added in, after stirring evenly, organic acid stirring is added in and is warming up to 70 DEG C, add and urge
Agent is reacted, and polymerize 2 ~ 3 hours in the environment of 80 ~ 120 DEG C, is subsequently cooled to 80 ~ 90 DEG C, is added in and is crosslinked diluent, 80 ~
It polymerize 2 ~ 3 hours under 90 DEG C of environment, is cooled to room temperature, obtains resin.
3. according to a kind of requirement of claim 1 and 2 novel fire resistant corrosion-resisting resin, which is characterized in that the epoxy
Resin includes：E-44、E-51、F-44、F-51.
4. according to a kind of requirement of claim 1 and 2 novel fire resistant corrosion-resisting resin, which is characterized in that described organic
Acid includes：Methacrylic acid, acrylic acid, butenoic acid.
5. according to a kind of requirement of claim 1 and 2 novel fire resistant corrosion-resisting resin, which is characterized in that the crosslinking
Diluent includes：Styrene, methyl styrene, vinyltoluene, chlorostyrene, dicyclopentadiene acrylate.
6. according to a kind of requirement of claim 1 and 2 novel fire resistant corrosion-resisting resin, which is characterized in that the inhibition
Agent includes：Hydroquinone, tert-butyl catechol, 1,4-benzoquinone.
7. according to a kind of requirement of claim 1 and 2 novel fire resistant corrosion-resisting resin, which is characterized in that the catalysis
The ratio of isomery agent is A：B=3:2,（Wherein A is included：6.5 parts of benzyl dimethylamine, 1.5 parts of diethylenetriamine, triethanolamine 1.5
Part, 0.5 part of pyridine, B is included：2.5 parts of diaminodiphenylmethane, 0.5 part of diaminodiphenylsulfone, 4.5 parts of boron trifluoride, benzyl chloride
Change 2.5 parts of amine）.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810063886.2A CN108164658A (en) | 2018-01-23 | 2018-01-23 | A kind of novel fire resistant corrosion-resisting resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810063886.2A CN108164658A (en) | 2018-01-23 | 2018-01-23 | A kind of novel fire resistant corrosion-resisting resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108164658A true CN108164658A (en) | 2018-06-15 |
Family
ID=62515665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810063886.2A Pending CN108164658A (en) | 2018-01-23 | 2018-01-23 | A kind of novel fire resistant corrosion-resisting resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108164658A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1467262A (en) * | 2002-06-28 | 2004-01-14 | 兰州思特创新科技有限责任公司 | High temperature corrosion-resisting resin |
| KR20130134449A (en) * | 2012-05-31 | 2013-12-10 | 주식회사 케이씨씨 | Flame-retardant vinyl ester resin composition and compound for molding glass fiber reinforced plastic telephone pole |
| CN105885011A (en) * | 2014-09-05 | 2016-08-24 | 薛俊峰 | High temperature oxidation resistant modified epoxy resin and preparation method thereof |
-
2018
- 2018-01-23 CN CN201810063886.2A patent/CN108164658A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1467262A (en) * | 2002-06-28 | 2004-01-14 | 兰州思特创新科技有限责任公司 | High temperature corrosion-resisting resin |
| KR20130134449A (en) * | 2012-05-31 | 2013-12-10 | 주식회사 케이씨씨 | Flame-retardant vinyl ester resin composition and compound for molding glass fiber reinforced plastic telephone pole |
| CN105885011A (en) * | 2014-09-05 | 2016-08-24 | 薛俊峰 | High temperature oxidation resistant modified epoxy resin and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103059304B (en) | Preparation and application of long-acting anticorrosion temperature-resistant coating | |
| CN106753138B (en) | Single-component epoxy insulation die bond adhesive for LED and preparation method thereof | |
| CN102604384B (en) | Universal refrigerant resistant solvent-free impregnating resin for high and low voltage motor and preparation method thereof | |
| CN101649194B (en) | Compound multivalent metallic ion crosslinking agent and production method and use method thereof | |
| CN105820717A (en) | Epoxy powder coating with toughness and high temperature resistance | |
| CN104449418A (en) | Ultrahigh-strength acrylate structural adhesive with wide adhesion and preparation method of ultrahigh-strength acrylate structural adhesive | |
| CN113278343B (en) | Temperature-resistant anticorrosive coating and preparation method thereof | |
| CN112080187A (en) | Graphene modified solvent-free epoxy anticorrosive paint for oil casing corrosion prevention and preparation method thereof | |
| CN107936778B (en) | Preparation method of high-temperature-resistant pipeline anticorrosion epoxy powder coating | |
| CN101508764B (en) | High-performance pnenolic aldehyde amine hardener for epoxy resin and preparation thereof | |
| CN103305094A (en) | Composite organic coating based on phenolic epoxy vinyl resin and preparation method thereof | |
| CN110857375A (en) | Conductive anticorrosive paint and preparation method and application thereof | |
| CN102010567A (en) | Non-halogen and non- phosphate epoxy resin composition and coverage membrane prepared by same | |
| CN107722830B (en) | A kind of preparation method of weatherability Environment-friendlyanti-corrosive anti-corrosive paint | |
| CN105086853B (en) | Photovoltaic module fluid sealant and preparation method thereof | |
| CN103073933B (en) | Corrosion-resistant, fouling-resistant and self-cleaning coating for phosphorus chemical industry material delivery pipeline | |
| CN110746575A (en) | Preparation method of environment-friendly high-temperature-resistant epoxy impregnating resin | |
| CN108164658A (en) | A kind of novel fire resistant corrosion-resisting resin | |
| CN111607041B (en) | Corrosion-resistant bisphenol A epoxy resin and preparation method thereof | |
| CN103305092A (en) | Anticorrosive coating and preparation method thereof | |
| CN101457132A (en) | High toughness epoxy adhesive | |
| CN104371625A (en) | High-performance epoxy adhesive for wind power equipment | |
| CN104893507A (en) | Epoxy powder primer of 3PP (three-layer polypropylene) coating for high-temperature medium delivery pipe and preparation method of epoxy powder primer | |
| CN110760232A (en) | Nano silicon-carbon modified graphene special anticorrosive paint and preparation method thereof | |
| CN110194924A (en) | A kind of anti-corrosive powder paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 250000 7-501C 12, 750 Xinyu Road, Ji'nan High-tech Zone, Shandong. Applicant after: Shandong Pyroxene Energy Engineering Co., Ltd. Address before: 250000 7-501C 12, 750 Xinyu Road, Ji'nan High-tech Zone, Shandong. Applicant before: Shandong pyroxene New Energy Technology Co., Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180615 |