CN108163942A - A kind of multi-function sewage treating agent and preparation method for high COD sewage - Google Patents

A kind of multi-function sewage treating agent and preparation method for high COD sewage Download PDF

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Publication number
CN108163942A
CN108163942A CN201711415827.9A CN201711415827A CN108163942A CN 108163942 A CN108163942 A CN 108163942A CN 201711415827 A CN201711415827 A CN 201711415827A CN 108163942 A CN108163942 A CN 108163942A
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China
Prior art keywords
sewage
treating agent
parts
function
water
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Pending
Application number
CN201711415827.9A
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Chinese (zh)
Inventor
肖铁亮
肖培苗
肖胜兰
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Guangzhou Murphy Instrument Co Ltd
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Guangzhou Murphy Instrument Co Ltd
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Priority to CN201711415827.9A priority Critical patent/CN108163942A/en
Publication of CN108163942A publication Critical patent/CN108163942A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • C02F2103/24Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof from tanneries
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/26Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
    • C02F2103/28Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour

Abstract

The invention discloses a kind of multi-function sewage treating agent and preparation method for high COD sewage, the processing component that the method for the present invention uses includes sepiolite original ore powder, bodied ferric sulfate, aluminium polychloride, anhydrous ferric trichloride, sodium hydroxide.The multi-function sewage treating agent is compounded by plurality of raw materials, plays compound action, and medicament described in the technology of the present invention adapts to processing refuse landfill effusion, wastewater from chemical industry, dyeing waste water, paper waste, leather waste water, electroplating wastewater, breeding wastewater and food wastewater etc..Sewage-treating agent preparation process of the present invention is simple, adaptable.Without heating, drying, refine, filter, the production that repeatedly other supplementary means such as mixing complete product.Production cost is reduced, reduces the investment of human resources and other every capital construction resources.

Description

A kind of multi-function sewage treating agent and preparation method for high COD sewage
Technical field
The present invention relates to technical field of sewage, and in particular to a kind of multi-functional sewage for high COD sewage is handled Agent and preparation method.
Background technology
Industry and sanitary sewage belong to containing a certain amount of noxious material, the great waste water to environmental hazard, it is unprocessed or Handling underproof sewage, at will discharge will become pollution sources, very harmful to living environment, for human health, it is necessary to and When to industry and sanitary sewage handle.But existing processing method, some operating cost is higher, the facilities and equipment that has is answered Long processing period that is miscellaneous, having, also certain methods easily generate secondary pollution.Therefore, there is an urgent need to a kind of new dirts in reality Method for treating water solves these practical problems.
City refuse landfill effusion (biochemical outlet water at tail end) is one of current stain disease most intractable on the market, this Invention emphasis is directed to the purified treatment of the stain disease.
It is single for the water treatment agent function of city refuse landfill effusion (biochemical outlet water at tail end) currently on the market, valency Lattice are expensive, and sewage disposal process is complicated, and long processing period, dosage is big, and sludge quantity is more, and cost performance is not high, and proprietor is also eager Seek a kind of effective quality-high and inexpensive medicament simple for process.
Invention content
To achieve the above object, the present invention provides a kind of high COD city refuse landfills leakage is handled with sepiolite powder The scheme of liquid (biochemical outlet water at tail end).Sepiolite miberal powder is mixed other effective ingredients by different proportion and prepares not homology by the present invention The stain disease treatment agent of row.Applicant groped, studies by more than ten years, and find different stain diseases carry out experiment repeatedly and Detection, successful formulation go out simple, of low cost, the effective stain disease treatment agent of preparation method.
One of the objects of the present invention is to provide a kind of multi-function sewage treating agents.
It is still another object of the present invention to provide a kind of sewage water treatment methods.
The technical solution used in the present invention is:
A kind of multi-function sewage treating agent is made of the component of following parts by weight:40-80 parts of sepiolite original ore powder gathers Close 10-30 parts of sulfuric acid iron powder, 30-40 parts of anhydrous ferric trichloride powder, 10-30 parts of aluminium polychloride, 10-20 parts of sodium hydroxide.
Further, above-mentioned sewage-treating agent is made of the component of following parts by weight:Sepiolite original ore powder 50~70 Part, 15~25 parts of polyaluminum sulfate iron powder, 33~37 parts of anhydrous ferric trichloride powder, 15~25 parts of aluminium polychloride, sodium hydroxide 13 ~17 parts.
A kind of preparation method of multi-function sewage treating agent weighs raw material, by raw material by formula described in any one of the above embodiments It is uniformly mixed to get multi-function sewage treating agent.
A kind of sewage water treatment method, includes the following steps:
The multi-function sewage treating agent described in any one of the above embodiments of sewage weight 0.1%~0.25% will be added in sewage, It stirs and evenly mixs;PH adjusting agent is added in, pH value is adjusted to 6.7~7.4;It stands, goes to precipitate.
Further, the pH adjusting agent is NaOH.
Further, the mixing time is 3~5 minutes.
Further, the time of repose is 3~5 minutes.
Further, the sewage is sewage of the COD contents in more than 1300mg/L.
Further, the sewage is sewage of the COD contents in more than 1800mg/L.
Further, the sewage include city refuse landfill effusion, wastewater from chemical industry, dyeing waste water, paper waste, Leather waste water, electroplating wastewater, breeding wastewater, food wastewater.
The beneficial effects of the invention are as follows:
By simply compounding, play the effect of respectively peculiar acts synergistically the multi-function sewage treating agent of the present invention, Integrated wastewater processing capacity is excellent, and efficient with decontaminating, decolorizing effect is excellent, and settling velocity is fast, is applicable in water temperature and pH range Extensively, the pollutants such as COD, SS in sewage, coloration, organophosphor, total phosphorus, heavy metal can be effectively removed, also have remarkable result to deodorization, It is a kind of to integrate decoloration, flocculation, deodorization, the multi-functional comprehensive stronger coagulating treatment agent of removal COD, BOD etc., effect Better than in the single flocculant of tradition, coagulant, decolorising agent.Sewage-treating agent preparation process of the present invention is simple simultaneously, adaptability By force.Without heating, drying, refine, filter, the production that repeatedly other supplementary means such as mixing complete product.Reduce life Cost is produced, reduces the investment of human resources and other every capital construction resources.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
A kind of multi-function sewage treating agent of Examples 1 to 4
The formula of the multi-function sewage treating agent of Examples 1 to 4 is (dosage represents mass fraction):
Group Sepiolite original ore powder Polyaluminum sulfate iron powder Anhydrous ferric trichloride powder Aluminium polychloride Sodium hydroxide
Embodiment 1 50 20 33 15 15
Embodiment 2 70 15 35 25 10
Embodiment 3 40 30 30 30 20
Embodiment 4 80 10 40 10 17
Preparation method:
Raw material sepiolite original ore powder, polyaluminum sulfate iron powder, anhydrous ferric trichloride powder, aluminium polychloride are weighed by above-mentioned formula And sodium hydroxide, raw material is stirred into 3~5min, is uniformly mixed to get multi-function sewage treating agent.
A kind of 5 sewage water treatment method of embodiment
Test address:Hunan Province's Shaoyang City refuse landfill
Sewage source:Hunan Province Shaoyang City refuse landfill garbage leaching liquid biochemistry end secondary clarifier effluent.
Lab scale step:
A. beaker water sampling 500ml (being in bronzing), the pH value 7.2 of sewage;
B. addition weight is the multi-function sewage treating agent of the present invention of water sample weight 0.2%, is stirred 3-5 minutes;
C. pH adjusting agent NaOH solution is added, water sample pH value is transferred to 7 or so;
D. it stands, sludge settling is complete after 3-5 minutes, you can observe that Colority of Sewage Water close to clear water, completes the dirt of this medicament Water treatment procedure.
Supernatant (water outlet) is taken to detect, testing result is as shown in table 1.
1 multi-function sewage treating agent of the present invention of table handles the small-scale experiment result (unit of garbage leaching liquid:mg/L)
Testing index Raw water Water outlet Removal rate %
COD 1516 284 81.2%
Ammonia nitrogen 32 22 31.30%
SS 150 8 94.66%
Coloration 260 12 95.38%
Total phosphorus 63 2.08 96.99%
Sludge reflux is tested:
The sludge precipitated in above-mentioned lab scale is collected, is dried, obtains 1.3g sludge, addition newly takes 500ml penetrating fluid biochemistry end It in water outlet, stirs 3 minutes, detection raw water and the water outlet after addition sludge, detection data are as shown in table 2 below after placing 30 minutes.
2 sludge reflux test result (unit of table:mg/L)
Testing index Raw water Water outlet Removal rate %
COD 1516 745 50.9%
Ammonia nitrogen 32 25 22%
pH 7.4 7.3
From Table 2, it can be seen that gained precipitating sludge non-secondary pollution after treating sewage by sewage treating agent of the present invention, and have There is the secondary effect used.
A kind of 6 sewage water treatment method of embodiment
Test address:Hunan Province's Shaoyang City refuse landfill
Sewage source:Hunan Province Shaoyang City refuse landfill garbage leaching liquid biochemistry end secondary clarifier effluent.
Pilot scale step:
A. mobile pilot plant (lorry supporting type) is provided for oneself, sewage pump draws water;
B. water sample (being in bronzing) is extracted to pilot scale reactive tank, 10 ton hour of flow, the pH value 7.2 of sewage with sewage pump;
C. Luo rod-type pulvis controller control dosage is opened, control addition weight is the present invention of water sample weight 0.2% Multi-function sewage treating agent, pilot plant stirring;
D. after stirring 3-5 minutes, diaphragm pump is opened, adds pH adjusting agent sodium hydroxide;Water sample pH value is transferred to 7 or so;
E. water sample, which is flow in pilot plant, fully reacts, precipitates, and water outlet water intaking, water quality is limpid, and it is 7.3 to measure pH value, Complete this medicament sewage disposal process.Entire work flow was taken no more than 45 minutes.
Multi-function sewage treating agent of the present invention passes through the time of reactive tank using flow automatic stirring in above-mentioned pilot plant test About 8 minutes, reaction tank stored full water about 30 minutes, water discharging time about 45 minutes.Totally 3 days pilot scale time;Daily to inspect by random samples 3 times, every 3 is small When sampling observation it is primary;The results are shown in Table 3 for water quality detection.
3 multi-function sewage treating agent of the present invention of table handles the pilot plant test result (unit of garbage leaching liquid:mg/L)
Testing index Raw water Water outlet Removal rate %
COD 1380 268 80.6%
Ammonia nitrogen 24 16 33.3%
pH 7.89 7.34
SS 170 8 95.3%
Coloration 280 12 95.7%
Total phosphorus 37 0.34 99.1%
From table 3 it is observed that multi-function sewage treating agent of the present invention is good to the treatment effect of garbage leaching liquid.In three days The effluent color dilution of examination becomes faint yellow from dark brown, eliminates raw water stench, is provided for the processing of later stage qualified discharge reliable Technical support, the big reduction of operation cost of user's stain disease per ton, the use of multi-function sewage treating agent of the present invention have been included in The project technical reform scheme of user, is carrying out construction reformation, will put into effect.
7 contrast experiment of embodiment
Method:
Experimental group:By multi-function sewage treating agent of the present invention;
Contrast groups 1:Sewage-treating agent used from by multi-function sewage treating agent of the present invention it is unique unlike, by sepiolite Original ore powder is changed to the sepiolite powder after commercially available purification.
Contrast groups 2:Sewage-treating agent used is by the modified sepiolite original ore powder of acid, polyaluminum sulfate iron powder, anhydrous tri-chlorination Iron powder and aluminium polychloride composition, without sodium hydroxide, each Ingredient Amount is same as the present application.
According to the method shown in embodiment 6, with above-mentioned different sewage inorganic agent to Hunan Province's Shaoyang City refuse landfill rubbish Rubbish effusion biochemistry end secondary clarifier effluent is handled, and compares each group treated result.As shown in table 4.
4 different sewage inorganic agent of table is to the handling result (unit of refuse landfill garbage leaching liquid:mg/L)
8 same type medicament experimental result of embodiment, Cost comparisons
Method:By multi-function sewage treating agent of the present invention, aluminium polychloride (reagent), bodied ferric sulfate (reagent), sulfuric acid Ferrous (Fenton), Dongguan contain long board COD removers and carry out place's amount to Hunan Province's Shaoyang City refuse landfill garbage leaching liquid respectively, Compare it treated result.
5 different sewage sewage-treating agent of table handles effect, the cost deck watch's (unit of garbage leaching liquid:mg/L)
The results are shown in Table 5 for different reagent processing, there it can be seen that the processing of multi-function sewage treating agent of the present invention Effect is best, and water quality is most limpid.The operation cost of user's stain disease per ton is greatly reduced.
In conclusion multi-function sewage treating agent of the present invention has the characteristics that:
1st, raw material are easy to get, ample supply and prompt delivery;
2nd, multi-function sewage treating agent preparation process of the present invention is simple, quick, is suitble to industrialized production, without using acid;
3rd, multi-function sewage treating agent of the present invention need not add PAM, you can realize efficient wastewater treatment efficiency;
4th, multi-function sewage treating agent of the present invention is during treated sewage, and settling velocity is fast (3~5min), not by pH shadows It rings;
5th, for multi-function sewage treating agent of the present invention after treated sewage, precipitating sludge amount is few, only currently on the market other 30%~45% or so of medicament sludge quantity;
6th, after treated sewage, gained sludge non-secondary pollution, data will not rebound multi-function sewage treating agent of the present invention, And also have effects that purify sewage again;
7th, it is easy to use using multi-function sewage treating agent of the present invention in treated sewage, floor space can be saved, save energy Consumption, less manpower;
8th, multi-function sewage treating agent of the present invention treated sewage to noxious pollutant index removal rate height, to COD, SS, Coloration, total phosphorus, deodorization etc. have good effect, and removal rate is respectively up to 81.2%, 95%, 95%, 99%.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification, Equivalent substitute mode is should be, is included within protection scope of the present invention.

Claims (10)

1. a kind of multi-function sewage treating agent, which is characterized in that be made of the component of following parts by weight:Sepiolite original ore powder 40-80 parts, 10-30 parts of polyaluminum sulfate iron powder, 30-40 parts of anhydrous ferric trichloride powder, 10-30 parts of aluminium polychloride, sodium hydroxide 10-20 parts.
2. sewage-treating agent according to claim 1, which is characterized in that be made of the component of following parts by weight:Hai Pao 50~70 parts of stone original ore powder, 15~25 parts of polyaluminum sulfate iron powder, 33~37 parts of anhydrous ferric trichloride powder, aluminium polychloride 15~25 Part, 13~17 parts of sodium hydroxide.
3. a kind of preparation method of multi-function sewage treating agent, which is characterized in that match by claim 1~2 any one of them Side weighs raw material, and raw material is uniformly mixed to get multi-function sewage treating agent.
4. a kind of sewage water treatment method, which is characterized in that include the following steps:
Claim 1~2 any one of them multi-functional sewage that sewage weight 0.1%~0.25% is added in sewage is handled Agent stirs and evenly mixs;PH adjusting agent is added in, pH value is adjusted to 6.7~7.4;It stands, goes to precipitate.
5. according to the method described in claim 4, it is characterized in that, the pH adjusting agent is NaOH.
6. according to the method described in claim 4, it is characterized in that, the mixing time is 3~5 minutes.
7. according to the method described in claim 4, it is characterized in that, the time of repose is 3~5 minutes.
8. according to the method described in claim 4, it is characterized in that, the sewage is dirt of the COD contents in more than 1300mg/L Water.
9. according to the method described in claim 8, it is characterized in that, the sewage is dirt of the COD contents in more than 1800mg/L Water.
10. according to the method described in claim 8, it is characterized in that, the sewage includes city refuse landfill effusion, change Work waste water, dyeing waste water, paper waste, leather waste water, electroplating wastewater, breeding wastewater, food wastewater.
CN201711415827.9A 2017-12-25 2017-12-25 A kind of multi-function sewage treating agent and preparation method for high COD sewage Pending CN108163942A (en)

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Application Number Priority Date Filing Date Title
CN201711415827.9A CN108163942A (en) 2017-12-25 2017-12-25 A kind of multi-function sewage treating agent and preparation method for high COD sewage

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109292926A (en) * 2018-10-08 2019-02-01 中机铸材科技(福建)有限公司 Wastewater treatment method in discarded sodium silicate process cast used sand treatment process
CN110272169A (en) * 2019-07-24 2019-09-24 辽东学院 A kind of microorganism water purification method
CN115286063A (en) * 2022-09-09 2022-11-04 湖北众净环保科技有限公司 Sewage treatment agent based on polyaluminium chloride and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104108775A (en) * 2014-07-10 2014-10-22 杭州电子科技大学 Composite reagent for treating recycled water of printing and dyeing wastewater and application method of composite reagent
CN106379984A (en) * 2016-11-18 2017-02-08 郑州丽福爱生物技术有限公司 Municipal wastewater treatment reagent and preparation process thereof
CN106830121A (en) * 2017-02-27 2017-06-13 合肥智慧龙图腾知识产权股份有限公司 A kind of domestic sewage treating compound and preparation method thereof
CN107262049A (en) * 2017-06-16 2017-10-20 郴州金通信息科技有限公司 A kind of material modified preparation method of sepiolite and application in the treatment of waste water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104108775A (en) * 2014-07-10 2014-10-22 杭州电子科技大学 Composite reagent for treating recycled water of printing and dyeing wastewater and application method of composite reagent
CN106379984A (en) * 2016-11-18 2017-02-08 郑州丽福爱生物技术有限公司 Municipal wastewater treatment reagent and preparation process thereof
CN106830121A (en) * 2017-02-27 2017-06-13 合肥智慧龙图腾知识产权股份有限公司 A kind of domestic sewage treating compound and preparation method thereof
CN107262049A (en) * 2017-06-16 2017-10-20 郴州金通信息科技有限公司 A kind of material modified preparation method of sepiolite and application in the treatment of waste water

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109292926A (en) * 2018-10-08 2019-02-01 中机铸材科技(福建)有限公司 Wastewater treatment method in discarded sodium silicate process cast used sand treatment process
CN110272169A (en) * 2019-07-24 2019-09-24 辽东学院 A kind of microorganism water purification method
CN115286063A (en) * 2022-09-09 2022-11-04 湖北众净环保科技有限公司 Sewage treatment agent based on polyaluminium chloride and preparation method thereof
CN115286063B (en) * 2022-09-09 2023-09-22 湖北众净环保科技有限公司 Sewage treatment agent based on polyaluminium chloride and preparation method thereof

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Application publication date: 20180615