CN108161263A - A kind of argon-arc welding-braze welding composite welding method - Google Patents

A kind of argon-arc welding-braze welding composite welding method Download PDF

Info

Publication number
CN108161263A
CN108161263A CN201810157189.3A CN201810157189A CN108161263A CN 108161263 A CN108161263 A CN 108161263A CN 201810157189 A CN201810157189 A CN 201810157189A CN 108161263 A CN108161263 A CN 108161263A
Authority
CN
China
Prior art keywords
welding
solder
magnesium alloy
plate
argon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810157189.3A
Other languages
Chinese (zh)
Other versions
CN108161263B (en
Inventor
张春红
张宁
张信永
师彩云
张欣
王世敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Vocational College of Bioengineering
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810157189.3A priority Critical patent/CN108161263B/en
Publication of CN108161263A publication Critical patent/CN108161263A/en
Application granted granted Critical
Publication of CN108161263B publication Critical patent/CN108161263B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K28/00Welding or cutting not covered by any of the preceding groups, e.g. electrolytic welding
    • B23K28/02Combined welding or cutting procedures or apparatus

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)

Abstract

The present invention provides a kind of argon arc weldings to be brazed complex welding method, this method realizes that magnesium alloy treats the welding of welding plate and copper plate using Mg Nb middle layers, having obstructed two kinds of base materials, directly the caused connector internal stress of welding is larger, causes deformation, and the two is in direct contact and easily forms intermediate compound, influence the intensity of welding point, unfavorable, the excellent combination property of the weldment of acquisition of toughness;And the present invention the defects of overcoming individually using argon arc welding or soldering, has very good effect, industrial application value is wide using argon arc welding and soldering composite welding mode.

Description

A kind of argon-arc welding-braze welding composite welding method
Technical field
The invention belongs to welding technology fields, and in particular to a kind of argon-arc welding-braze welding composite welding method.
Background technology
Material is that the mankind depend on for existence and development, conquer nature and the material base of nature remodeling and human society hair The development of the guide of exhibition, particularly Modern High-Tech, even more dependent on the progress of new material technology.The research and development of new material structures are The mainstay of industrial technology level is improved, if without the development of modern hyperstructure material, does not just have world today's aviation The progress of aerospace industry.And nonferrous materials is most important a kind of material, such as magnesium and aluminium.The wherein rich reserves of magnesium, Compared with other common metals, magnesium has many advantages, such as low-density, high specific strength and can be recycled, and becomes coke of concern Point is known as " 21 century novel environmentally protective engineering material ".
Although magnesium is found have two century-old history, until in the 1990s, in auto industry it is energy saving and Development trend that is quick, growing steadily is presented in the needs of environmental protection, the demand to magnesium and magnesium alloy.And as prepared by magnesium alloy plus The breakthrough of work forming technique etc., be suitble to different requirements novel magnesium alloy developed, such as high-strength Mg-Al alloys and Antiflaming magnesium alloy etc.." magnesium alloy is applied and exploitation " is classified as the emphasis of Material Field in national science and technology development plan by China, closely Over 10 years, the new developmental research level of Mg alloys is significantly improved.At present Mg alloys mainly include Mg-Al-Zn systems, Mg-Al-Mn systems, Mg-Al-Si systems and Mg-Al-Re systems etc.;But in order to meet each mechanical industry department to Mg alloy structure performances Requirement, some novel Mg alloys are developed, such as the wrought magnesium alloy applied to electronic communication product, ultralight, high By force, anti-corrosion Mg-Li alloys and Mg-Re alloys, applied to following aerospace field high temperature Mg alloys Mg-Re-Ca-Zr with And Mg alloys etc. are coagulated soon.And further improving with Mg alloy preparation techniques, occur Mg alloys flame-retarded technology in succession, Mg is closed Mg alloys are greatly facilitated in automobile, boat in golden melt environment-friendly type protection technique and Mg alloy Microarc Oxidation Surface Treatment technologies etc. The application in the fields such as empty space flight.As what magnesium and magnesium alloy were applied in every profession and trade increases rapidly, the connection of magnesium and magnesium alloy is asked Topic causes the very big concern of people, but since the welding performance of magnesium and magnesium alloy is bad, is difficult to realize reliable connection, therefore magnesium The connection of alloy and magnesium alloy and other materials structural member becomes the technical bottleneck that restricts magnesium alloy application and anxious to be resolved Key technology.CN103286402 discloses a kind of gas brazing welding method of magnesium alloy, and solder mixed powder is first made in this method End, then powder is wrapped up, and solder is made through cold drawing method using magnesium ribbon, the straight of final brazing solder can be adjusted as needed Diameter and length, whole process does not carry out melt process to raw material, therefore avoids loss of the raw material during ingot casting is melted, and And without smelting equipment, preparation process is simple.Secondly, which, by many experiments, finally obtains in the selection of material State optimizing components configuration, wherein Na3AlF6As activator, play a part of to melt magnesia in brazing process.Finally, it is of the invention To Mg powder, Zn powder and Al powder using ball-milling treatment, further reducing powder size makes its activation, can improve the strong of sintered body Degree, improves its elongation percentage.
Red copper has high electric conductivity, thermal conductivity and excellent plasticity, and thermal conductivity height makes the worsening condition of local heating, Heat cannot be concentrated, and scatter and disappear fast, this requirement ensures the preheating of base material before welding.Copper also belongs to the higher gold of coefficient of thermal expansion Belong to, 1.5 times higher than mild steel, when welding can generate big deformation or increase welding stress causes crackle.In addition, copper liquid mobility Good, force difference of adhering, when welding, is difficult to control.When temperature is at 550 DEG C or so, the mechanical performance of red copper is remarkably decreased, this is also A reason of defect is generated during welding.In addition, in the welding of red copper, weld seam and fusion area are also easy to produce stomata, main former Because the reaction with hydrogen and oxygen in the decline of the solubility of hydrogen and metallurgical process is related.
In the welding process of magnesium alloy and red copper, on the one hand since the two linear expansion coefficient, thermal conductivity difference are larger, welding It connects and difference is deformed in heating and cooling procedure, connector is caused to form larger internal stress;On the other hand, the two is in direct contact easy formation Intermediate compound influences intensity, the toughness of welding point, so as to influence the quality of entire weldment.
Invention content
The technical problems to be solved by the invention are to provide a kind of argon-arc welding-braze welding composite welding method, and this method can The defects of welding point integrated quality is poor in the welding process of magnesium alloy and red copper is solved well.
To solve the above problems, the technical solution adopted by the present invention is:
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 15-25V, welding process carry out under the argon gas protection that purity is 99.9%;Later to connecing Head is quenched, and quenched welding point is put into cryogenic treatment apparatus, will with the rate of temperature fall of 5 DEG C~10 DEG C/min Temperature in cryogenic treatment apparatus drops to -160 DEG C~-220 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, in sky Reach 25 DEG C in gas;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.1-0.4mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, be covered above brazed seam and solder Brazing flux;Base material is preheating to 450-550 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, molten Melt under brazing flux protection, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder exists Gravity and the lower filling base material gap of capillary force effect are stopped electric arc heated, were prevented in cooling procedure with flame gun baking base material Fast cooling, brazed seam is formed after cooling.
Wherein, the Mg-Nb middle layers are by Mg, Nb and Zn, Zr 1-2 in mass ratio:1-2:0.05-0.1:0.05-0.1 Alloy sheets obtained from carrying out high melt.
Preferably, the Mg-Nb middle layers are by Mg, Nb and Zn, Zr in mass ratio 2: 2: 0.1:0.1 carries out high temperature Alloy sheets obtained from melting.
The ingredient of the magnesium alloy solder wire is identical with the ingredient that magnesium alloy treats welding plate, a diameter of 2-4mm.
The step(2)The linear velocity 100-200cm/min of middle welding, argon flow amount 50-150L/min, torch nozzle from The distance 5-l5mm of welding point.
The step(3)Middle solder is copper manganese silver solder.
Preferably, the ingredient of the copper manganese silver solder is:Copper content 30-45wt%, manganese content 15-35wt%, surplus are Silver.
Compared with prior art, the beneficial effects of the present invention are:
(1)The invention realizes that magnesium alloy treats the welding of welding plate and copper plate using Mg-Nb middle layers, has obstructed two The caused connector internal stress of the direct welding of kind base material is larger, deformation and the two is caused to be in direct contact the intermediate chemical combination of easy formation Object influences the intensity of welding point, unfavorable, the excellent combination property of the weldment of acquisition of toughness;
(2)Mg middle layers and magnesium alloy are in joint shape when the Mg-Nb middle layers of the present invention avoid exclusive use Mg middle layers Into brittle metallic compound, so as to reduce performance;Or Nb forms intermetallic compound with red copper when Nb middle layers are used alone And joint performance is influenced, Nb alloy of the Mg-Nb middle layers due to foring Mg overcomes the above problem well;
(3)The present invention is using argon arc welding and soldering composite welding mode, the defects of overcoming individually using argon arc welding or soldering, tool There is very good effect, industrial application value is wide.
Specific embodiment
Technical scheme of the present invention is further elaborated with reference to embodiment:
Embodiment 1
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 20V, welding process carry out under the argon gas protection that purity is 99.9%;Later Welded Joints into Row quenching, quenched welding point is put into cryogenic treatment apparatus, is filled subzero treatment with the rate of temperature fall of 8 DEG C/min Temperature in putting drops to -180 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, reach 25 DEG C in air;Wherein, The linear velocity 150cm/min of welding, argon flow amount 100L/min, torch nozzle is from welding point distance 10mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.3mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder; Base material is preheating to 500 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, is protected in melting brazing flux Under shield, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and hair The carefully lower filling base material gap of power effect, stops electric arc heated, and toasting base material in cooling procedure with flame gun prevents too fast cooling, cold But brazed seam is formed afterwards;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 35wt%, manganese Content 35wt%, surplus are silver.
Embodiment 2
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 25V, welding process carry out under the argon gas protection that purity is 99.9%;Later Welded Joints into Row quenching, quenched welding point is put into cryogenic treatment apparatus, with the rate of temperature fall of 10 DEG C/min by subzero treatment Temperature in device drops to -200 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, reach 25 DEG C in air;Its In, the linear velocity 160cm/min of welding, argon flow amount 120L/min, torch nozzle is from welding point distance 10mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.3mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder; Base material is preheating to 500 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, is protected in melting brazing flux Under shield, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and hair The carefully lower filling base material gap of power effect, stops electric arc heated, and toasting base material in cooling procedure with flame gun prevents too fast cooling, cold But brazed seam is formed afterwards;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 45wt%, manganese Content 30wt%, surplus are silver.
Embodiment 3
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 20V, welding process carry out under the argon gas protection that purity is 99.9%;Later Welded Joints into Row quenching, quenched welding point is put into cryogenic treatment apparatus, is filled subzero treatment with the rate of temperature fall of 6 DEG C/min Temperature in putting drops to -170 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, reach 25 DEG C in air;Wherein, The linear velocity 120cm/min of welding, argon flow amount 80L/min, torch nozzle is from welding point distance 9mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.2mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder; Base material is preheating to 480 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, is protected in melting brazing flux Under shield, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and hair The carefully lower filling base material gap of power effect, stops electric arc heated, and toasting base material in cooling procedure with flame gun prevents too fast cooling, cold But brazed seam is formed afterwards;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 40wt%, manganese Content 25wt%, surplus are silver.
Embodiment 4
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 15V, welding process carry out under the argon gas protection that purity is 99.9%;Later Welded Joints into Row quenching, quenched welding point is put into cryogenic treatment apparatus, is filled subzero treatment with the rate of temperature fall of 5 DEG C/min Temperature in putting drops to -160 DEG C DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, reach 25 DEG C in air;Its In, the linear velocity 100cm/min of welding, argon flow amount 50L/min, torch nozzle is from welding point distance 5mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.1mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder; Base material is preheating to 450 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, is protected in melting brazing flux Under shield, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and hair The carefully lower filling base material gap of power effect, stops electric arc heated, and toasting base material in cooling procedure with flame gun prevents too fast cooling, cold But brazed seam is formed afterwards;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 45wt%, manganese Content 25wt%, surplus are silver.
Embodiment 5
A kind of argon-arc welding-braze welding composite welding method, the composite welding be by magnesium alloy treat welding plate by Mg-Nb middle layers with Copper plate is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 25V, welding process carry out under the argon gas protection that purity is 99.9%;Later Welded Joints into Row quenching, quenched welding point is put into cryogenic treatment apparatus, with the rate of temperature fall of 10 DEG C/min by subzero treatment Temperature in device drops to -220 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, reach 25 DEG C in air;Its In, the linear velocity 200cm/min of welding, argon flow amount 150L/min, torch nozzle is from welding point distance l5mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.4mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder; Base material is preheating to 550 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, is protected in melting brazing flux Under shield, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and hair The carefully lower filling base material gap of power effect, stops electric arc heated, and toasting base material in cooling procedure with flame gun prevents too fast cooling, cold But brazed seam is formed afterwards;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 40wt%, manganese Content 25wt%, surplus are silver.
Comparative example 1
A kind of argon-arc welding-braze welding composite welding method, the composite welding are that magnesium alloy being treated, welding plate passes through Mg middle layers and purple Copper coin is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Mg middle layers carry out argon to magnesium alloy with magnesium alloy solder wire Arc welding, weldingvoltage 20V, welding process carry out under the argon gas protection that purity is 99.9%;Welded Joints carry out later Quenching, quenched welding point is put into cryogenic treatment apparatus, with the rate of temperature fall of 8 DEG C/min by cryogenic treatment apparatus In temperature drop to -180 DEG C from room temperature, keep the temperature 6 hours, finally weldment taken out, reaches 25 DEG C in air;Wherein, it welds The linear velocity 150cm/min connect, argon flow amount 100L/min, torch nozzle is from welding point distance 10mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Mg middle layers are docked with copper plate, joint gap width 0.3mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder;It uses Base material is preheating to 500 DEG C by flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, under melting brazing flux protection, Its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and capillary masterpiece With lower filling base material gap, stop electric arc heated, toasting base material in cooling procedure with flame gun prevents too fast cooling, shape after cooling Into brazed seam;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 35wt%, manganese content 35wt%, surplus are silver.
Comparative example 2
A kind of argon-arc welding-braze welding composite welding method, the composite welding are that magnesium alloy being treated, welding plate passes through Nb middle layers and purple Copper coin is welded, and is as follows:
(1)The magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2)Spot welding positioning is first carried out on platform position, then treats that welding plate and Nb middle layers carry out argon to magnesium alloy with magnesium alloy solder wire Arc welding, weldingvoltage 20V, welding process carry out under the argon gas protection that purity is 99.9%;Welded Joints carry out later Quenching, quenched welding point is put into cryogenic treatment apparatus, with the rate of temperature fall of 8 DEG C/min by cryogenic treatment apparatus In temperature drop to -180 DEG C from room temperature, keep the temperature 6 hours, finally weldment taken out, reaches 25 DEG C in air;Wherein, it welds The linear velocity 150cm/min connect, argon flow amount 100L/min, torch nozzle is from welding point distance 10mm;
(3)By step(2)The magnesium alloy of argon arc welding treats that welding plate and Nb middle layers are docked with copper plate, joint gap width 0.3mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, and brazing flux is covered above brazed seam and solder;It uses Base material is preheating to 500 DEG C by flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, under melting brazing flux protection, Its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder is in gravity and capillary masterpiece With lower filling base material gap, stop electric arc heated, toasting base material in cooling procedure with flame gun prevents too fast cooling, shape after cooling Into brazed seam;Solder is copper manganese silver solder in the step, and the ingredient of the copper manganese silver solder is:Copper content 35wt%, manganese content 35wt%, surplus are silver.
Finally shear strength test and tensile strength is carried out to soldered fitting to test, shearing strength of joint test method according to GB11363.89 (soldering joint strength test method) is carried out, and the test specimen of postwelding measures on MTS810 testing machine for mechanical properties to be connect The shearing strength of head.During test, the fixture movement speed 0.5mm/s of clamping, 5.0 points of data transfer rate, the second, 18 DEG C of temperature, record connects The load applied during head rupture.
Joint tensile strength test method is that prepared soldered fitting is cut into GB11363-89 (solderings using wire cutting Strength of joint test method) as defined in tensile sample size, make weld seam placed in the middle, and polished cut surface with sand paper.Tension test It is carried out on MTS810 testing machine for mechanical properties, the fixture movement speed 0.5mm/s of clamping, the 5.0 points/second of data transfer rate, temperature 18 DEG C, record the load applied during joint breaking.
Experimental result such as following table:
Shear strength(Mpa) Tensile strength(Mpa)
Embodiment 1 145.9 151.7
Embodiment 2 147.6 157.2
Embodiment 3 142.2 155.4
Embodiment 4 139.3 149.8
Embodiment 5 145.2 156.3
Embodiment 6 137.8 145.7
Comparative example 1 82.3 88.5
Comparative example 2 93.1 97.1
Above-mentioned experimental data is compared, connector has excellent performance when finding embodiment 1-6 using Mg-Nb as middle layer.
A kind of argon-arc welding-braze welding composite welding method provided above the invention implementation has carried out detailed Jie It continues, for those of ordinary skill in the art, the thought of embodiment is created according to the present invention, in specific embodiment and using model There will be changes are placed, in conclusion the content of the present specification should not be construed as the limitation to the invention.

Claims (7)

1. a kind of argon-arc welding-braze welding composite welding method, which is characterized in that the composite welding is that magnesium alloy being treated, welding plate passes through Mg-Nb middle layers are welded with copper plate, are as follows:
(1) magnesium alloy of reticular structure is taken to treat welding plate, the greasy dirt of plate surface to be welded is first removed with acetone, is then beaten with sand paper machinery Mill treats welding plate, its both sides is made to expose metallic luster;
(2) spot welding positioning is first carried out on platform position, then treats that welding plate and Mg-Nb middle layers are carried out to magnesium alloy with magnesium alloy solder wire Argon arc welding, weldingvoltage 15-25V, welding process carry out under the argon gas protection that purity is 99.9%;Later to connecing Head is quenched, and quenched welding point is put into cryogenic treatment apparatus, will with the rate of temperature fall of 5 DEG C~10 DEG C/min Temperature in cryogenic treatment apparatus drops to -160 DEG C~-220 DEG C from room temperature, keeps the temperature 6 hours, finally takes out weldment, in sky Reach 25 DEG C in gas;
(3) magnesium alloy of step (2) argon arc welding is treated that welding plate and Mg-Nb middle layers are docked with copper plate, joint gap Width 0.1-0.4mm, the preseting solder above brazed seam, solder used in amounts ensure to fill up gap, be covered above brazed seam and solder Brazing flux;Base material is preheating to 450-550 DEG C using flame gun, melts brazing flux by heat transfer, after brazing flux is completely melt, molten Melt under brazing flux protection, its fusing is made by the quick heating solder of electric arc electric discharge using tungsten argon arc welding gun so that liquid solder exists Gravity and the lower filling base material gap of capillary force effect are stopped electric arc heated, were prevented in cooling procedure with flame gun baking base material Fast cooling, brazed seam is formed after cooling.
2. welding method according to claim 1, which is characterized in that the Mg-Nb middle layers are by Mg, Nb and Zn, Zr 1-2 in mass ratio:1-2:0.05-0.1:0.05-0.1 carries out alloy sheets obtained from high melt.
3. welding method according to claim 2, which is characterized in that the Mg-Nb middle layers are by Mg, Nb and Zn, Zr In mass ratio 2:2:0.1:0.1 carries out alloy sheets obtained from high melt.
4. welding method according to claim 1, which is characterized in that the ingredient of the magnesium alloy solder wire and magnesium alloy are to be welded The ingredient of plate is identical, a diameter of 2-4mm.
5. according to claim 1-4 any one of them welding methods, which is characterized in that the linear speed welded in the step (2) 100-200cm/min is spent, argon flow amount 50-150L/min, torch nozzle is from welding point distance 5-l5mm.
6. according to claim 1-5 any one of them welding methods, which is characterized in that solder is copper manganese in the step (3) Silver solder.
7. welding method according to claim 6, which is characterized in that the ingredient of the copper manganese silver solder is:Copper content 30- 45wt%, manganese content 15-35wt%, surplus are silver.
CN201810157189.3A 2018-02-24 2018-02-24 Argon arc welding-brazing composite welding method Expired - Fee Related CN108161263B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810157189.3A CN108161263B (en) 2018-02-24 2018-02-24 Argon arc welding-brazing composite welding method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810157189.3A CN108161263B (en) 2018-02-24 2018-02-24 Argon arc welding-brazing composite welding method

Publications (2)

Publication Number Publication Date
CN108161263A true CN108161263A (en) 2018-06-15
CN108161263B CN108161263B (en) 2020-04-24

Family

ID=62511786

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810157189.3A Expired - Fee Related CN108161263B (en) 2018-02-24 2018-02-24 Argon arc welding-brazing composite welding method

Country Status (1)

Country Link
CN (1) CN108161263B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109732236A (en) * 2019-03-22 2019-05-10 周明 A kind of silver-colored or aluminum spectacle-frame low-temperature welding method
CN111872517A (en) * 2020-06-30 2020-11-03 上海交通大学 Mg-Zr intermediate alloy pretreatment method for improving magnesium alloy refinement effect

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101074130A (en) * 2007-07-12 2007-11-21 航天材料及工艺研究所 Method for welding aluminum-copper dissmilar metal
WO2009091049A1 (en) * 2008-01-17 2009-07-23 Nissan Motor Co., Ltd. Method of bonding different metals and bonded structure
CN101506566A (en) * 2006-08-30 2009-08-12 氟石科技公司 Compositions and methods for dissimilar material welding
WO2011155214A1 (en) * 2010-06-10 2011-12-15 ワシマイヤー株式会社 Bonding member and manufacturing method thereof
CN103551759A (en) * 2013-10-15 2014-02-05 大连理工大学 Welding material for connecting magnesium/steel heterogeneous metal and preparation method of welding material
CN103612008A (en) * 2013-11-30 2014-03-05 西安科技大学 Magnesium alloy and copper composite panel manufacturing method based on transient liquid phase diffusion connection
CN105397222A (en) * 2015-12-16 2016-03-16 郑州机械研究所 Flame preheating tungsten electrode argon arc brazing method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101506566A (en) * 2006-08-30 2009-08-12 氟石科技公司 Compositions and methods for dissimilar material welding
CN101074130A (en) * 2007-07-12 2007-11-21 航天材料及工艺研究所 Method for welding aluminum-copper dissmilar metal
WO2009091049A1 (en) * 2008-01-17 2009-07-23 Nissan Motor Co., Ltd. Method of bonding different metals and bonded structure
WO2011155214A1 (en) * 2010-06-10 2011-12-15 ワシマイヤー株式会社 Bonding member and manufacturing method thereof
CN103551759A (en) * 2013-10-15 2014-02-05 大连理工大学 Welding material for connecting magnesium/steel heterogeneous metal and preparation method of welding material
CN103612008A (en) * 2013-11-30 2014-03-05 西安科技大学 Magnesium alloy and copper composite panel manufacturing method based on transient liquid phase diffusion connection
CN105397222A (en) * 2015-12-16 2016-03-16 郑州机械研究所 Flame preheating tungsten electrode argon arc brazing method

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
MAHENDRAN,G ET AL: "Developing diffusion bonding windows for joining AZ31B magnesium and copper alloys", 《INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY》 *
冯振等: "镁-铜异种金属连接技术研究进展", 《焊接》 *
孟圣昊等: "镁/铜异种金属激光填丝熔钎焊接特性分析", 《焊接学报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109732236A (en) * 2019-03-22 2019-05-10 周明 A kind of silver-colored or aluminum spectacle-frame low-temperature welding method
CN109732236B (en) * 2019-03-22 2021-02-26 周明 Low-temperature welding method for silver or aluminum glasses frame
CN111872517A (en) * 2020-06-30 2020-11-03 上海交通大学 Mg-Zr intermediate alloy pretreatment method for improving magnesium alloy refinement effect
CN111872517B (en) * 2020-06-30 2021-07-20 上海交通大学 Mg-Zr intermediate alloy pretreatment method for improving magnesium alloy refinement effect

Also Published As

Publication number Publication date
CN108161263B (en) 2020-04-24

Similar Documents

Publication Publication Date Title
Yan et al. Influence of laser power on microstructure and mechanical property of laser-welded Al/Cu dissimilar lap joints
Liu et al. Electrically assisted friction stir welding for joining Al 6061 to TRIP 780 steel
Zhang et al. Optimised design of electrode morphology for novel dissimilar resistance spot welding of aluminium alloy and galvanised high strength steel
Shao et al. Effect of joining parameters on microstructure of dissimilar metal joints between aluminum and galvanized steel
Guo et al. Study on strengthening mechanism of Ti/Cu electron beam welding
CN102962543B (en) Welding process for red copper and stainless steel dissimilar materials
CN109014471B (en) Consumable electrode inert gas protection arc brazing process for titanium alloy-stainless steel
CN104668880A (en) Bearing steel welding repairing method
CN102528243A (en) Arc welding-brazing method for titanium-aluminum dissimilar alloy TIG (tungsten inert gas) arc preheating
CN108188582A (en) A kind of compound welding with filler wire method of laser-electric arc for being used to prepare magnesium/steel dissimilar metal tailor welded
Song et al. Effect of laser-GTAW hybrid welding heat input on the performance of Mg/Steel butt joint
CN105364269A (en) Fusion welding method for copper plates and alloys thereof
CN110576273A (en) Metal material, process and product for welding LNG (liquefied natural gas) ultralow-temperature stainless steel
Yang et al. Development of novel CsF–RbF–AlF3 flux for brazing aluminum to stainless steel with Zn–Al filler metal
CN104476011A (en) High-entropy alloy welding wire for welding titanium/low-carbon steel in TIG (Tungsten Inert Gas) mode and application
CN108161263A (en) A kind of argon-arc welding-braze welding composite welding method
CN113732563A (en) Transition layer welding wire for preparing titanium-steel gradient composite material CMT and preparation method
CN102971103B (en) The inert gas arc welding comprising nitrogen is used to aluminize the method for metal parts
Li et al. Effect of spiral scan distance on the nanosecond-pulsed-laser lap joint of Al/Cu
Lang et al. Consumable-free dissimilar joining of Mg to steel using a laser-arc hybrid heat source
KR20160146490A (en) A ductile boron bearing nickel based welding material
Yu et al. Microstructures and mechanical property of 5052 aluminum alloy/Q235 steel butt joint achieved by laser beam joining with Sn-Zn filler wire
CN113510354A (en) Plasma arc welding method for high-strength steel-aluminum alloy dissimilar metal assisted by transition layer
Luo et al. Experimental researches on resistance heat aided friction stir welding of Mg alloy
CN105983766A (en) Low-carbon steel and alloy steel welding method

Legal Events

Date Code Title Description
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200706

Address after: 221000 No. 297, Xisanhuan Road, Xuzhou, Jiangsu Province

Patentee after: XUZHOU VOCATIONAL College OF BIOENGINEERING

Address before: 221006 Department of electrical and mechanical engineering, Career Technical College, Career Technical College, No. 297 Sanhuan Road, Xuzhou, Jiangsu

Patentee before: Zhang Chunhong

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20200424