CN108148245A - A kind of high density modified poly ethylene special color parent material - Google Patents

A kind of high density modified poly ethylene special color parent material Download PDF

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Publication number
CN108148245A
CN108148245A CN201611111933.3A CN201611111933A CN108148245A CN 108148245 A CN108148245 A CN 108148245A CN 201611111933 A CN201611111933 A CN 201611111933A CN 108148245 A CN108148245 A CN 108148245A
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CN
China
Prior art keywords
polyethylene
high density
area
special color
modified poly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611111933.3A
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Chinese (zh)
Inventor
丁磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Green Valley Biotechnology Co Ltd
Original Assignee
Qingdao Green Valley Biotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Green Valley Biotechnology Co Ltd filed Critical Qingdao Green Valley Biotechnology Co Ltd
Priority to CN201611111933.3A priority Critical patent/CN108148245A/en
Publication of CN108148245A publication Critical patent/CN108148245A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00Masterbatches

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Polyethylene (PE) is one of five big synthetic resin.Polyethylene is broadly divided into linear low density polyethylene (LLDPE), low density polyethylene (LDPE) (LDPE), high density polyethylene (HDPE) (HDPE) three categories.Polyethylene is odorless, it is nontoxic, feel ceraceous, with excellent resistance to low temperature (minimum temperature in use is up to 70~100 DEG C), chemical stability is good, is resistant to the erosion (intolerant to the acid with oxidizing property) of most of soda acids, common solvent is not dissolved under room temperature, water imbibition is small, and electrical insulation capability is excellent;But polyethylene is very sensitive for environmental stress (chemistry and mechanism), and heat-resistant aging is poor.Therefore by modified come the shortcomings that changing polyethylene.This product produces a kind of special color masterbatch of polyethylene, improves the deficiency of conventional polyethylene.The present invention provides a kind of high density modified poly ethylene special color parent materials and preparation method thereof.

Description

A kind of high density modified poly ethylene special color parent material
Technical field
The invention belongs to polythene material production technical fields, improve the original deficiency of polyethylene.It produces and meets social need The product asked.
Background technology
Polyethylene abbreviation PE English names:Polyethylene polyethylene (PE) is one of five big synthetic resin.Polyethylene It is broadly divided into linear low density polyethylene (LLDPE), low density polyethylene (LDPE) (LDPE), high density polyethylene (HDPE) (HDPE) three categories. Polyethylene is odorless, nontoxic, feel ceraceous, has excellent resistance to low temperature (minimum reachable -70~-100 DEG C of temperature in use),Change It learnsStability is good, is resistant to the erosion (intolerant to the acid with oxidizing property) of most of soda acids, does not dissolve in common solvent under room temperature, inhaleWaterProperty is small,ElectricityExcellent insulating property;But polyethylene for environmental stress (chemistry withMachineryEffect) it is very sensitive, heat-proof aging Property is poor.Therefore by modified come the shortcomings that changing polyethylene.This product produces a kind of special color masterbatch of polyethylene, and it is poly- to improve tradition The deficiency of ethylene.
Invention content
The purpose of the present invention is to provide a kind of high density modified poly ethylene special color parent materials and preparation method thereof.
Its raw material of high density modified poly ethylene special color parent material matches by mass percentage is:High density polyethylene materials:30- 50th, titanium dioxide:10.0, calcium carbonate:15th, talcum powder:10th, mica powder:10th, kaolin:10th, silica:10th, dispersed lubricant (TAS-2A):2.0th, UV absorbers (2-hydroxy-4-n-octoxybenzophenone):8.0th, light stabilizer:8.0th, antioxidant (copolymer of ethylene-octene):10.0, colorant:6.0.
The preparation method of the material is:Various raw materials are 3-5 minutes dry-mixed in super mixer, then it is placed in twin-screw extrusion Through melting extrusion, cooling, pelletizing, packed products in machine;Wherein, one area's temperature of double screw extruder be 90-100 DEG C, two Area is 160-190 DEG C, and 3rd area are 200-210 DEG C, and 4th area are 205-210 DEG C;5th area are 190-200 DEG C, and the residence time is 1-2 points Clock, pressure 10-15Mpa.
Specific embodiment
Embodiment
(1) raw material matches by mass percentage is:High density polyethylene materials:30-50, titanium dioxide:10.0, calcium carbonate:15th, it is sliding Mountain flour:10th, mica powder:10th, kaolin:10th, silica:10th, dispersed lubricant (TAS-2A):2.0th, UV absorbers (2-hydroxy-4-n-octoxybenzophenone):8.0th, light stabilizer:8.0th, antioxidant (copolymer of ethylene-octene):10.0、 Colorant:6.0.
(2) preparation method is:Various raw materials are 3-5 minutes dry-mixed in super mixer, then be placed in double screw extruder and pass through Melting extrusion, cooling, pelletizing, packed products;Wherein, one area's temperature of double screw extruder is 90-100 DEG C, and 2nd area are 160-190 DEG C, 3rd area are 200-210 DEG C, and 4th area are 205-210 DEG C;5th area are 190-200 DEG C, and the residence time is 1-2 minutes, Pressure is 10-15Mpa.
Experimental result

Claims (2)

1. a kind of high density modified poly ethylene special color parent material, which is characterized in that raw material matches by mass percentage is:It is highly dense Spend polyethylene raw material:30-50, titanium dioxide:10.0, calcium carbonate:15th, talcum powder:10th, mica powder:10th, kaolin:10th, titanium dioxide Silicon:10th, dispersed lubricant (TAS-2A):2.0th, UV absorbers (2-hydroxy-4-n-octoxybenzophenone):8.0th, light is steady Determine agent:8.0th, antioxidant (copolymer of ethylene-octene):10.0, colorant:6.0.
2. high density modified poly ethylene special color parent material according to claim 1, which is characterized in that preparation method For:It is first that various raw materials are 3-5 minutes dry-mixed in super mixer, then be placed in double screw extruder through melting extrusion, cooling, Pelletizing, packed products;Wherein, one area's temperature of double screw extruder is 90-100 DEG C, and 2nd area are 160-190 DEG C, and 3rd area are 200-210 DEG C, 4th area are 205-210 DEG C;5th area are 190-200 DEG C, and the residence time is 1-2 minutes, pressure 10-15Mpa.
CN201611111933.3A 2016-12-06 2016-12-06 A kind of high density modified poly ethylene special color parent material Pending CN108148245A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611111933.3A CN108148245A (en) 2016-12-06 2016-12-06 A kind of high density modified poly ethylene special color parent material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611111933.3A CN108148245A (en) 2016-12-06 2016-12-06 A kind of high density modified poly ethylene special color parent material

Publications (1)

Publication Number Publication Date
CN108148245A true CN108148245A (en) 2018-06-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611111933.3A Pending CN108148245A (en) 2016-12-06 2016-12-06 A kind of high density modified poly ethylene special color parent material

Country Status (1)

Country Link
CN (1) CN108148245A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109721810A (en) * 2018-12-06 2019-05-07 安徽集虹材料科技有限公司 Long-acting weather-proof Masterbatch of one kind and preparation method thereof
CN110003556A (en) * 2019-04-12 2019-07-12 南京运昶高分子材料有限公司 A kind of weatherable master batch and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109721810A (en) * 2018-12-06 2019-05-07 安徽集虹材料科技有限公司 Long-acting weather-proof Masterbatch of one kind and preparation method thereof
CN110003556A (en) * 2019-04-12 2019-07-12 南京运昶高分子材料有限公司 A kind of weatherable master batch and preparation method thereof

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Application publication date: 20180612

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