CN105419042A - Polyethylene (PE) weathering-resistant color master batch and preparation method thereof - Google Patents
Polyethylene (PE) weathering-resistant color master batch and preparation method thereof Download PDFInfo
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- CN105419042A CN105419042A CN201410450267.0A CN201410450267A CN105419042A CN 105419042 A CN105419042 A CN 105419042A CN 201410450267 A CN201410450267 A CN 201410450267A CN 105419042 A CN105419042 A CN 105419042A
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Abstract
The invention relates to a polyethylene (PE) weathering-resistant color master batch and a preparation method thereof, wherein the raw materials comprise, by weight, 45-85 parts of a polyethylene raw material, 2.0-3.0 parts of titanium dioxide powder, inorganic fillers such as 175 parts of calcium carbonate, 170 parts of talc powder, 170 parts of mica powder, 170 parts of kaolin and 1.0-2.0 parts of a silica 170TAS-2A dispersion lubricant, 8.0-10.0 parts of an ultraviolet light absorber 2-hydroxy-4-n-octyloxy benzophenone, 8.0-10.0 parts of a light stabilizer, 10.0-14.0 parts of an ethylene-octene copolymer, and 4.0-6.0 parts of a coloring agent. The present invention provides a special weathering-resistant color master batch with the characteristic of polyethylene mechanical property improving, wherein the special weathering-resistant color master batch has characteristics of simple production, low cost, and environmental protection.
Description
Technical field
The invention belongs to polythene material production technical field and a kind of preparation method thereof.
Background technology
Polyethylene-abbreviation PE English name: Polyethylene polyethylene (PE) is one of five large synthetic resins.Polyethylene is mainly divided into linear low density polyethylene (LLDPE), Low Density Polyethylene (LDPE), high density polyethylene(HDPE) (HDPE) three major types.Polyethylene odorless, nontoxic, feel ceraceous, has excellent resistance to low temperature (minimum use temperature can reach-70 ~-100 DEG C),
chemistrygood stability, the erosion (the not resistance to acid with oxidizing property) of the most of soda acid of ability, is insoluble to common solvent under normal temperature, inhales
waterproperty is little,
electricityexcellent insulating property; But polyethylene for environmental stress (chemistry with
machineryeffect) be very sensitive, heat-resistant aging is poor.Therefore by look mother, poly shortcoming is changed to its modification.
Summary of the invention
This one side is to provide a kind of dedicated weather-proof look mother improving polyethylene weathering resistant.
Polyethylene (PE) weather-proof look mother be made up of the raw material of following weight ratio:
Polyethylene raw material: 45-85
Titanium dioxide: 2.0-3.0
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 1.0-2.0
Ultraviolet absorbers Octabenzone: 8.0-10.0
Photostabilizer: 8.0-10.0
The multipolymer of ethylene-octene: 10.0-14.0
Tinting material: 4.0-6.0;
The polyethylene weather-proof look mother of the raw material composition of above weight ratio is used for poly production, can change and obviously improve poly weathering resistance.
Another aspect of the present invention is to provide a kind of method of producing above polyethylene (PE) weather-proof look mother, the method is: first above-mentioned various raw material is dry mixed 3-5 minute in super mixer, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packaging final prod; Wherein, twin screw extruder one district temperature is 90-100 DEG C, and 2nd district are 160-190 DEG C, and 3rd district are 200-210 DEG C, and 4th district are 205-210 DEG C; 5th district are 190-200 DEG C, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Embodiment
Be described further invention below by embodiment, once embodiment is only that the present invention will be described but not is limited it.
Embodiment 1:
(1) clicking weight score, to take each raw material respectively as follows:
Polyethylene raw material: 45
Titanium dioxide: 2.0
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 1.0
Ultraviolet absorbers Octabenzone: 8.0
Photostabilizer: 8.0
The multipolymer of ethylene-octene: 10.0
Tinting material: 4.0.
(2) working method is: first above-mentioned various raw material is dry mixed 3-5 minute in super mixer, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packaging final prod; Wherein, twin screw extruder one district temperature is 90-100 DEG C, and 2nd district are 160-190 DEG C, and 3rd district are 200-210 DEG C, and 4th district are 205-210 DEG C; 5th district are 190-200 DEG C, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Experimental result:
Can find out that poly weathering resistance improves by above experimental data.
Embodiment 2:
(1) clicking weight score, to take each raw material respectively as follows:
Polyethylene raw material: 85
Titanium dioxide: 3.0
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 2.0
Ultraviolet absorbers Octabenzone: 10.0
Photostabilizer: 10.0
The multipolymer of ethylene-octene: 14.0
Tinting material: 6.0.
(2) working method is: first above-mentioned various raw material is dry mixed 3-5 minute in super mixer, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packaging final prod; Wherein, twin screw extruder one district temperature is 90-100 DEG C, and 2nd district are 160-190 DEG C, and 3rd district are 200-210 DEG C, and 4th district are 205-210 DEG C; 5th district are 190-200 DEG C, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Experimental result:
Can find out that poly weathering resistance improves by above experimental data.
Embodiment 3:
(1) clicking weight score, to take each raw material respectively as follows:
Polyethylene raw material: 65
Titanium dioxide: 2.5
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 1.0
Ultraviolet absorbers Octabenzone: 9.0
Photostabilizer: 9.0
The multipolymer of ethylene-octene: 12.0
Tinting material: 5.0.
(2) working method is: first above-mentioned various raw material is dry mixed 3-5 minute in super mixer, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packaging final prod; Wherein, twin screw extruder one district temperature is 90-100 DEG C, and 2nd district are 160-190 DEG C, and 3rd district are 200-210 DEG C, and 4th district are 205-210 DEG C; 5th district are 190-200 DEG C, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Experimental result:
Can find out that poly weathering resistance improves by above experimental data.The known embodiment 3 of contrast simultaneously passing through 3 embodiments is preferred weight ratio.
By using this dedicated weather-proof look female, can effectively improve poly performance, improving weathering resistance.
Claims (3)
1. the weather-proof look of polyethylene is female, it is characterized in that being made up of the raw material of following weight ratio:
Polyethylene raw material: 45-85
Titanium dioxide: 2.0-3.0
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 1.0-2.0
Ultraviolet absorbers Octabenzone: 8.0-10.0
Photostabilizer: 8.0-10.0
The multipolymer of ethylene-octene: 10.0-14.0
Tinting material: 4.0-6.0.
2. the weather-proof look of polyethylene according to claim 1 is female, it is characterized in that the preferred weight ratio of raw material is:
Polyethylene raw material: 65
Titanium dioxide: 2.5
Inorganic fill: calcium carbonate 175, talcum powder 170, mica powder 170, kaolin 170, silica 1 70
TAS-2A dispersed lubricant: 1.0
Ultraviolet absorbers Octabenzone: 9.0
Photostabilizer: 9.0
The multipolymer of ethylene-octene: 12.0
Tinting material: 5.0.
3. produce the weather-proof look mother's of polyethylene of claim 1 or 2 method, it is characterized in that: first above-mentioned various raw material is dry mixed 3-5 minute in super mixer, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packaging final prod; Wherein, twin screw extruder one district temperature is 90-100 DEG C, and 2nd district are 160-190 DEG C, and 3rd district are 200-210 DEG C, and 4th district are 205-210 DEG C; 5th district are 190-200 DEG C, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107458067A (en) * | 2017-08-01 | 2017-12-12 | 安徽安凯汽车股份有限公司 | A kind of combined engine Sound-proof material and its production method |
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2014
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107458067A (en) * | 2017-08-01 | 2017-12-12 | 安徽安凯汽车股份有限公司 | A kind of combined engine Sound-proof material and its production method |
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Application publication date: 20160323 |