CN108144826A - A kind of surface treatment method of titanium or titanium alloy section bar cold stretch - Google Patents
A kind of surface treatment method of titanium or titanium alloy section bar cold stretch Download PDFInfo
- Publication number
- CN108144826A CN108144826A CN201611100813.3A CN201611100813A CN108144826A CN 108144826 A CN108144826 A CN 108144826A CN 201611100813 A CN201611100813 A CN 201611100813A CN 108144826 A CN108144826 A CN 108144826A
- Authority
- CN
- China
- Prior art keywords
- titanium
- titanium alloy
- treatment method
- surface treatment
- metal stock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/102—Pretreatment of metallic substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C9/00—Cooling, heating or lubricating drawing material
- B21C9/02—Selection of compositions therefor
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
- C23C22/03—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions containing phosphorus compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2202/00—Metallic substrate
- B05D2202/30—Metallic substrate based on refractory metals (Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W)
- B05D2202/35—Metallic substrate based on refractory metals (Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W) based on Ti
Abstract
A kind of surface treatment method of titanium or titanium alloy section bar cold stretch is related to a kind of surface treatment method of metal stock before metal cold working, more particularly to a kind of surface treatment method for metal stock in titanium or titanium alloy production pipe, stick, silk cold stretch.The present invention is after with physical method to the cleaning on metal stock surface, metal stock surface is made to form one layer of modified cover film through liquid leaching, then the coating solid lubricant outside modified cover film.The lubricant that the present invention obtains have is firmly combined with base material, stretch friction coefficient it is low, it is wear-resisting the advantages of, it can continuous multimode, the low titanium alloy of aximal deformation value cold working high intensity, plasticity, sticking to mould, demoulding phenomenon does not occur, while lubricant easily removes after processing during cold working.
Description
Technical field
A kind of surface treatment method of titanium or titanium alloy section bar cold stretch is related to metal stock before a kind of metal is cold worked
Surface treatment method, more particularly to it is a kind of for titanium or titanium alloy production pipe, stick, silk stretch process in metal stock table
Surface treatment method.
Background technology
Since metal titanium or titanium alloy has the characteristics that high intensity, corrosion-resistant, low-density, and be widely used in military project, aerospace,
Petrochemical industry and field of metallurgy, but titanium alloy resistance of deformation is big, plasticity is low, is difficult to process.During titanium shape extrusion,
Adherent phenomenon easily occurs, influences section bar surface quality.It therefore, must be first attached to blank progress surface to titanium shape extrusion
Put forth effort to handle, then apply lubricant, prevent from adhering in titanium shape extrusion, reduce coefficient of friction, increase wearability.Generally to titanium-type
Material blank surface lubricated is typically to use to carry out blank air heating to form oxidation film, also has and is plated in blank surface
Copper also coats fluorinated phosphate salt coating in blank surface.It was verified that titanium-type material is cold worked, particularly to deformation
The TC that drag is big, plasticity is low4Titanium alloy is difficult to realize.Therefore, it can only be used at present and hot-working or swaged, processing efficiency and
Lumber recovery is relatively low.
Invention content
During the purpose of the present invention is aiming at above-mentioned existing titanium or titanium alloy cold working, existing surface treatment
The deficiency of method, provide it is a kind of effectively titanium or titanium alloy blank surface can be handled, effectively prevent from adhering to, reduce friction
Coefficient increases wearability, and the surface treatment side of a kind of titanium or titanium alloy section bar cold stretch that lubricant easily removes after processing
Method.
The purpose of the present invention is what is be achieved through the following technical solutions.
A kind of surface treatment method of titanium or titanium alloy section bar cold stretch, including with physical method to metal stock surface
Cleaning, it is characterised in that:A. the metal stock after cleaning is immersed in modification liquid, its surface is made to form one layer of modified covering
Film, the main ingredient of film is Na3TiOF5;B. the blank of one layer of modified cover film of surface band is pulled out airing;C. it will contain 85%
(weight ratio) S-O aquadags, 5%MoS2With kollag behind 10% water ground, it is equably coated in modified treated blank
Surface dries at a temperature of 200-300 DEG C and treats that cold stretch is used.
By titanium or titanium alloy blank carry out surface modification treatment liquid composition be:
Na3PO4.12H2O:30g/l-50g/l,
NaF:20g/l-40g/l,
Ice CH3COOH (36%):50g/l-70g/l.
Compared with the prior art the present invention, there is lubricant to be firmly combined with base material, stretching coefficient of friction is low, wear-resisting epistasis
The advantages of, can continuous multimode, the low titanium alloy of aximal deformation value cold working high intensity plasticity do not glue during cold working
Film demoulds phenomenon, while lubricant easily removes after processing.
Embodiment:
Select two kinds of TC of thickness of 4.6mm and 2.1mm4(Ti-6Ai-4V) wire rod is intended to the above-mentioned wire rod physics of cold working
Method clears up behind its surface to be put into:Na3PO4.12H2O:30g/l-50g/l, NaF:20g/l-40g/l, ice
CH3COOH (36%):In the surface modification treatment liquid that 50g/l-70g/l is made into, its wire surface is made to form one layer of modified covering
Then film pulls the above-mentioned wire rod of one layer of modified cover film of surface band out airing, be then uniformly coated on modified cover film
Contain 85% (weight ratio) S-O aquadags, 5%MoS2With the rear kollag of 10% water, and at a temperature of 200~300 DEG C
After continuous three mould and five mould cold stretch, two kinds of TC of 3.1mm and 1.2mm are made in drying respectively4Silk.Accumulative working modulus is equal
More than 65%, wherein, maximum passage processing capacity is up to 32%, during entire cold stretch, does not occur sticking to mould, demoulds and break
Phenomenon, silk surface quality after stretching with it is functional.
The present invention, the TA of 14.6 × 2.2mm of processing are similarly used the cold stretch of the tube, rod section material of titanium or titanium alloy2
Tubing, for maximum passage processing capacity up to 40%, it is more than 75% to add up processing capacity.
Claims (1)
1. a kind of surface treatment method of titanium or titanium alloy section bar cold stretch, including with physical method to the clear of metal stock surface
Reason, it is characterised in that:
A immerses the metal stock after cleaning in modification liquid, its surface is made to form one layer of modified cover film, modified covering
The main ingredient of film is Na3TiOF5,
The composition of modification liquid is:Na3PO4.12H2O:30g/l-50g/l,
NaF:20g/l-40g/l,
Ice CH3COOH (36%):50g/l-70g/l;
B pulls the blank of one layer of modified cover film of surface band out airing;
C will contain 85% (weight ratio) S-O aquadags, 5%MoS2, 10% water rear kollag, be equably coated in through changing
Property treated blank surface, at a temperature of 200~300 DEG C drying treat that cold stretch is used.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611100813.3A CN108144826A (en) | 2016-12-05 | 2016-12-05 | A kind of surface treatment method of titanium or titanium alloy section bar cold stretch |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611100813.3A CN108144826A (en) | 2016-12-05 | 2016-12-05 | A kind of surface treatment method of titanium or titanium alloy section bar cold stretch |
Publications (1)
Publication Number | Publication Date |
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CN108144826A true CN108144826A (en) | 2018-06-12 |
Family
ID=62470251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201611100813.3A Pending CN108144826A (en) | 2016-12-05 | 2016-12-05 | A kind of surface treatment method of titanium or titanium alloy section bar cold stretch |
Country Status (1)
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CN (1) | CN108144826A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113210448A (en) * | 2021-05-17 | 2021-08-06 | 西北有色金属研究院 | Cold drawing preparation method of TB9 titanium alloy disc wire with lubricating coating |
-
2016
- 2016-12-05 CN CN201611100813.3A patent/CN108144826A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113210448A (en) * | 2021-05-17 | 2021-08-06 | 西北有色金属研究院 | Cold drawing preparation method of TB9 titanium alloy disc wire with lubricating coating |
CN113210448B (en) * | 2021-05-17 | 2022-06-03 | 西北有色金属研究院 | Cold drawing preparation method of TB9 titanium alloy disc wire with lubricating coating |
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PB01 | Publication | ||
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WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180612 |