CN108137966A - For the printing ink composition of non-absorbent surface - Google Patents
For the printing ink composition of non-absorbent surface Download PDFInfo
- Publication number
- CN108137966A CN108137966A CN201580083542.2A CN201580083542A CN108137966A CN 108137966 A CN108137966 A CN 108137966A CN 201580083542 A CN201580083542 A CN 201580083542A CN 108137966 A CN108137966 A CN 108137966A
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- CN
- China
- Prior art keywords
- water
- based ink
- ink
- ink according
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000007639 printing Methods 0.000 title claims abstract description 53
- 239000002250 absorbent Substances 0.000 title claims description 19
- 230000002745 absorbent Effects 0.000 title claims description 18
- 239000000203 mixture Substances 0.000 title abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 77
- 229920000642 polymer Polymers 0.000 claims abstract description 26
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 239000003086 colorant Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003431 cross linking reagent Substances 0.000 claims description 15
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000003002 pH adjusting agent Substances 0.000 claims description 15
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 9
- -1 Ethyl formate silanol Chemical compound 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 8
- 229960002887 deanol Drugs 0.000 claims description 8
- 239000012972 dimethylethanolamine Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 229920006037 cross link polymer Polymers 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004494 ethyl ester group Chemical group 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 abstract description 19
- 239000004814 polyurethane Substances 0.000 abstract description 7
- 229920002635 polyurethane Polymers 0.000 abstract description 7
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 126
- 239000006185 dispersion Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 7
- 239000004909 Moisturizer Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 230000001333 moisturizer Effects 0.000 description 6
- WDQFELCEOPFLCZ-UHFFFAOYSA-N 1-(2-hydroxyethyl)pyrrolidin-2-one Chemical class OCCN1CCCC1=O WDQFELCEOPFLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 229940106691 bisphenol a Drugs 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 150000003673 urethanes Chemical group 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 230000004438 eyesight Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000010 aprotic solvent Substances 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical group CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 108091092920 SmY RNA Proteins 0.000 description 1
- 241001237710 Smyrna Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- VPSLGSSVPWVZFG-UHFFFAOYSA-N butan-2-yl propanoate Chemical compound CCC(C)OC(=O)CC VPSLGSSVPWVZFG-UHFFFAOYSA-N 0.000 description 1
- 229930188620 butyrolactone Natural products 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920006332 epoxy adhesive Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229960000502 poloxamer Drugs 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920003009 polyurethane dispersion Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- ILVGAIQLOCKNQA-UHFFFAOYSA-N propyl 2-hydroxypropanoate Chemical compound CCCOC(=O)C(C)O ILVGAIQLOCKNQA-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- ISXOBTBCNRIIQO-UHFFFAOYSA-N tetrahydrothiophene 1-oxide Chemical compound O=S1CCCC1 ISXOBTBCNRIIQO-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000001060 yellow colorant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
According on one side, a printing ink composition includes a colorant, one or more polymer (such as polyurethane siloxane), a surfactant, water and a solvent.The total solids content of the printing ink composition is less than about 20wt%.In addition, initial surface tension of the ink when applying is less than about 50 dynes per centimeters, and surface tension increase when drying is not to be exceeded 20%.
Description
Technical field
This patent disclosure relates generally to printing ink composition, more particularly relate to one can on non-absorbent surface high print duplication
Printing ink composition in the print system of brush.
Background technology
Water-based ink is used for limited commercial printing application in printing industry.The increased portion of water-based ink usage amount
Divide is due to the environmental problem of generation volatile organic compounds (VOC) when solvent-based ink is dried.For in paper and other
Printing application in absorbent surfaces, moisture are absorbed by surface portion, this causes ink quickly to dry after printing.For non-
Absorbent surfaces, the use of water-based inks generate performance issue sometimes, in addition, when ink is located at the top on surface, it more difficult to
Rapidly to dry these ink.
For using the printing technology of water-based ink, usual coating paper is to prevent paper from deforming in the presence of water.These are applied
The paper of cloth is still absorbability to a certain extent, allows aqueous carrier partial penetration surface.Aqueous based carrier is maintained at table
Non-absorbent surface on face includes plastic foil, metal film and similar surface.In these surfaces, after the printing, to print
Brush material is heat-treated to remove carrier or be exposed to ultraviolet light, but if the physical property of printing ink composition is helpless to oil
On the surface, the ink performance in printing process and after printing can be poor for ink attachment.In such a case, it is desirable to nonabsorbable
Image on surface has long-term durability.Long durability refers to that ink retains on the final product and resists moisture and connects
Touch, highlight, rubbing, scraping and other abrasion ability.In printing process, when printing product is moved through high speed printing
When the subsequent roller and/or other elements of machine, there is the trend interfered by shear stress in ink.
Invention content
An embodiment according to the present invention, water-based ink include：About 3 to about 15wt% one or more polymerizations
Object；About 0.5 to about 12wt% one or more colorants；About 5 to an about 35wt% solvent；About 0.03 to about 1.0wt%
A pH adjusting agent；About 50 to about 80wt% water wherein the viscosity of the water-based ink is about 1 to about 20mPas, makes
The non-absorbent surface into one layer can be applied by obtaining the water-based ink.
Aspect 2：Water-based ink described in aspect 1, wherein the viscosity is about 4 to about 14mPas.
Aspect 3：Water-based ink described in any one of aspect 1 and 2, wherein one kind in one or more polymer
It is urethanes silanol.
Aspect 4：Water-based ink described in any one of aspect 1~3 further includes about 0.1 to an about 5wt% table
Face activating agent.
Aspect 5：Water-based ink described in any one of aspect 1~4 further includes about 1 to an about 20wt% friendship
Join agent.
Aspect 6：Water-based ink described in any one of aspect 1~5, wherein the crosslinking agent is one isocyanate-crosslinked
Agent.
Aspect 7：Water-based ink described in any one of aspect 1 to 6, wherein one kind in one or more polymer
It is a self-crosslinking urethanes silanol.
Aspect 8：Water-based ink described in any one of aspect 1~7, wherein the solvent is selected from 1- (2- ethoxys) -2-
It is one or more in pyrrolidones, alcohol, polyalcohol, glycerine and glycol.
Aspect 9：Water-based ink described in aspect 5, wherein the surfactant is an ethoxylation molecule.
Aspect 10：Water-based ink described in any one of aspect 1~9, wherein the pH adjusting agent is dimethylethanolamine.
Aspect 11：Water-based ink described in any one of aspect 1~10, wherein dynamic of the ink under 25 degrees Celsius
Surface tension is about 20 to about 45 dynes per centimeters.
Aspect 12：A kind of ink, it includes：About 0.5 to an about 10wt% epoxy resin；About 4 to the one of about 30wt%
Solvent；With one or more metallochromes, wherein the viscosity of the ink is about 1 to about 20mPas so that the ink
The non-absorbent surface into one layer can be applied.
Aspect 13：Ink described in aspect 12, wherein the viscosity is about 4 to about 14mPas.
Aspect 14：Ink described in any one of aspect 1277 and 13, wherein the solvent is dimethyl sulfoxide.
Aspect 15：Ink described in any one of aspect 12~14, wherein the epoxy resin is a bisphenol-A asphalt mixtures modified by epoxy resin
Fat.
Aspect 16：Ink described in any one of aspect 12~15, wherein dynamic table of the ink under 25 degrees Celsius
Face tension is about 20 to about 35 dynes per centimeters.
Aspect 17：A kind of method for high speed variable printing includes the following steps：One water-based ink is provided, it is described
Water-based ink includes：About 3 to about 15wt% one or more polymer；About 0.5 to an about 12wt% pigment；About 5 to about
A solvent of 35wt%；About 0.03 to an about 1.0wt% pH adjusting agent；About 50 to about 80wt% water, wherein the water
The viscosity of property ink is about 1 to about 20mPas；With the non-absorbent substrates being applied to the water-based ink in first layer
On.
Aspect 18：Method described in aspect 17, the method is further included is applied to other multiple layers by the water-based ink
In step.
Aspect 19：Method described in any one of aspect 17 and 18, wherein the water-based ink also includes about 0.1 to about
A surfactant of 5.0wt%.
Aspect 20：Method described in any one of aspect 17~19, the method further includes heating so that the water
One or more crosslinked polymers of property ink.
A printing ink composition includes a colorant according to another aspect, one or more polymer (include polyurethane silica
Alkane), water and a solvent.The total solids content of the printing ink composition is less than about 20wt%.In addition, the ink application when
Initial surface tension is less than about 50 dynes per centimeters, and surface tension increase when drying is not to be exceeded 20%.
The printing ink composition for being adapted for application to a non-absorbent surface according to another aspect, includes about 0.5wt% to about
A colorant of 12wt%, a polyurethane siloxane and a water-based solvent of about 3wt% to about 15wt%.In addition, the ink
Initial surface tension when applying is less than about 50 dynes per centimeters, and surface tension increase when drying is not to be exceeded 20%.
A printing ink composition includes a colorant, an epoxy resin and an aprotic solvent according to another aspect,.The oil
Ink can additionally comprise a metallic pigments, and the initial surface tension in application is less than about 40 dynes per centimeters, and when drying
Surface tension increase is not to be exceeded 20%.
By considering following detailed description and drawings, other aspects and advantages of the present invention will be apparent, wherein
Identical numerical chracter represents identical structure in the whole instruction.
Specific embodiment
The printing ink composition of the application includes a colorant, a polyurethane siloxane, a solvent, water and an optional crosslinking
Agent.The total solids content of the printing ink composition is less than about 20wt%, and the weight ratio of the colorant and polyurethane is about 2：1~
1：2.In addition, initial surface tension of the ink in application is less than about 50 dynes per centimeters, and surface tension when drying
Increase is not to be exceeded 20%.
This printing ink composition is suitable for various high speed printing systems.One nonabsorbable printed medium, such as metal foil, pottery
Porcelain, plastics, height coating paper or other similar substrates receive ink using various printing processes.
The printing ink composition has a viscosity, printing ink composition can be applied to substrate using various printing processes
On.Range of viscosities can be from about 1.0 to 20.0cP, and preferably from about 4.0 to about 6.0cP, and preferred viscosities may depend in part on
The requirement of used print system.
One importance of the present composition is that the initial surface tension of the ink is less than 50 dynes per centimeters.
Under this surface tension, the ink will be suitably dispersed on non-absorbent surface.The surface tension is preferably smaller than 40 and reaches
Because/centimetre.The surface tension of ink will not dramatically increase when another importance is dry.If have been found that dry
Surface tension variations are excessive, then physical property of the ink on non-absorbent surface reduces.Particularly, if surface is opened when dry
Power variation is excessive, and more than 20%, then the solvent resistance of the ink on non-absorbent surface, rub resistance and levelability cannot enable
People is satisfied with.
The suitable surfactant for providing above-mentioned surface tension properties is included by silicones, ethylene oxide (EO) and epoxy
The non-ionic compound of propane (PO) composition, is such as purchased from Momentive Performance Products (New York Albany)
Silwet Hydrostable 212, fluorinated nonionic surfactants, such as be purchased from Croda Industrial
Multiwet VE-LQ- (AP) of Chemicals (England east Yorkshire) etc..These surfactants can with about 0.1 to
3.0wt%, the amount more preferably less than 1.0wt% exist.
In other embodiments, surfactant or surface modifier can include such as nonionic surfactant,
Such as poloxamer, ethoxylated acetylenic glycol, ethoxylated alcohol or other ethoxylated surfactants.Any kind of surface
Activating agent may include with the property needed for assigning in the printing ink composition, including anionic, non-ionic, cationic
Type or other kinds of surfactant.In addition, levelling agent can also act as surface modification when its content is up to about 2.5wt%
Agent.
The ethoxylated acetylenic diol-based surfactants used is suitble to include Air Products'400
Series of surfactants：Respectively420th, 440,465 and 485.Air Products' (Allentown, PA)400 series of surfactants are by making different amounts of ethylene oxide and 2,4,7,9- tetramethyl -5- decine -4,7-
Glycol be (Air Products' 104, it is a kind of among two symmetrical hydrophobic groupings with hydrophilic segment it is non-from
Subtype molecule) react obtained.
The ethoxylation based surfactants used is suitble to include Air Products' (Allentown, PA)Series of surfactants.Ethoxylated alcohol is by ethylene oxide and chain length in C9~C15Range
The base catalyzed condensation of interior alcohol reacts to prepare.
In one embodiment, the printing ink composition can be in the heating ring of about 120 degrees Fahrenheits (about 50 degrees Celsius)
It is printed under border.
In another embodiment, printing ink composition can be printed onto in substrate and be heated by pressing plate.The pressure
Plate can be heated to the temperature of about 100 degrees Fahrenheits (about 40 degrees Celsius) or the temperature of about 120 degrees Fahrenheits (about 50 degrees Celsius).So
Substrate is heated to more than the temperature about ten minutes of 220 degree of Fahrenheit (about 100 degrees Celsius) afterwards to unseal and realize crosslinking.Then
By ink solidification 10 minutes under about 300 degrees Fahrenheits (about 150 degrees Celsius).
Suitable thickness is obtained by printing multilayer before curing.The printing ink composition can be arranged to thickness and exist
Layer in about 5 microns to about 15 micron ranges.Desired ink thickness can be by the way that multilayer ink to be printed onto in substrate to obtain
.In some embodiments, the thickness can be preferably up to about 30 layers, more excellent by printing up to about 50 layers in substrate
Up to about 15 layers of ink is selected to obtain, although the quantity of layer depends on various factors, for example, the selected mode for applying ink,
The fluid-solid content and mass flowrate of printing ink composition.
Polymer (polyurethane siloxane) serves as adhesive to stablize the colorant on printed medium and make final products
Long durability enhances.Instant durability refers to that printing ink composition is rapidly incorporated into printed medium and can pass through high speed printing
Machine and be not transfer to the ability in printer elements.
The polymer for being suitable for the printing ink composition of the application includes with silanol group or can be prepared by hydrolyzing
The ester-polyurethane resin emulsion of the group of silanol group, this polyurethane resin are included by Mitsui Chemicals, Inc (Japan
Tokyo) manufactureWS-5000、WS-5100、WS-4000 andWS-
6021.These are self-crosslinkable polyurethane dispersions, as moisture evaporation forms siloxanes key.Polymer can by heating and/
Or it hydrolyzes and self-crosslinking.Polymer can also be crosslinked by one or more crosslinking agents or catalyst.
In certain embodiments, suitable crosslinking agent includes the isocyanates of sealing end, and heating can be crosslinked.Properly
Crosslinking agent be Baxenden Chemicals Limited (Lancashire, England)Aqua BI
201.This crosslinking agent unseals between 110 to 120 degrees Celsius.
Certain embodiments include epoxy adhesive.Suitable epoxy resin includes Dow Chemical Company
The DER 684-EK40 of (Midland, Michigan).The resin is by making epoxychloropropane form bisphenol-A with bisphenol-a reaction
Diglycidyl ether and formed.
The colorant can be commercially available any convention pigment or dyestuff.The example of suitable colorant include but
It is not limited to：Carbon black colorant, such as the Pro- of FujiFilm (New Castle, DE)Black APD1000；Magenta
Toner, such as the Cab-O- of Cabot Corp. (Boston, MA)465；Cyan colorant, as Cabot Corp. (Boston,
MA Cab-O-)450 or 452；Or yellow colorants, such as the Cab-O- of Cabot Corp. (Boston, MA)
470；The opaque infrared transmission dyestuff of vision, the Epolight of such as Epolin, Inc. (Newark, New Jersey)
7527A；The white color agents being made of titanium dioxide, as Lever Colors' (Bensalem, Pennsylvania)
Cyclojet White Ti-7510 and Cyclojet White TI-7530；Opacifier, as Grace (Columbia,
Maryland)AS 40；With the metallochrome containing aluminium, silver or gold, such as Eckart GmbH
(Hartenstein, Germany)SB11025 andSB11028。
The opaque infrared transmission dyestuff of the vision (such as Epolight 7527A) should transmit the wavelength more than 80%
Light more than 850nm, and the wavelength that should transmit 5-15% is less than the light of 550nm.
The total solids content of the printing ink composition is less than about 20wt%.The printing ink composition can include about 0.5 to about
A colorant of 12wt% and about 3 to about 15wt% a polymer (polyurethane siloxane) and a crosslinking agent.Colorant is opposite
It can be about 2 in the ratio of polymer and crosslinking agent：1 to about 1：In the range of 2.
Printing ink composition described herein can comprise water as solvent.The composition can also include water-soluble organic
Compound is as cosolvent.Suitable water solubility or miscible organic component includes：Glycerine；Alcohols, such as methanol, ethyl alcohol, positive third
Alcohol, isopropanol, n-butanol, sec-butyl alcohol or the tert-butyl alcohol；Amides, such as dimethylformamide or dimethylacetylamide；Carboxylic acid；Ester
Class, such as ethyl acetate, methyl lactate, ethyl lactate, propyl lactate and ethylene carbonate；Ethers, such as butoxy ethanol, tetrahydrochysene
Furans or dioxane；Glycols, such as propylene glycol and diethylene glycol (DEG)；Diol ester；Glycol ethers, such as propylene glycol monomethyl ether, dipropylene glycol
Methyl ether；Ketone, such as acetone, diacetone or methyl ethyl ketone；Lactams, such as acyl in N- isopropyls caprolactam or N- ethyls penta
Amine, 2-Pyrrolidone, N-Methyl pyrrolidone or N- (2- ethoxys) -2-Pyrrolidone；Lactone, such as butyrolactone；Organic sulfur
Compound；Sulfone class, such as dimethyl sulfoxide (DMSO)；Organic sulfoxide, such as dimethyl sulfoxide (DMSO) or tetramethylene sulfoxide；And its derivative is mixed with it
Object.
In printing ink composition other be expected components include a solvent, a preservative (such as Arch Biocides (Smyrna,
GA)GXL), a moisturizer (such as propylene glycol), a biocide, a colorant, a polymer, a levelling agent, one
Salt, an inorganic compound, an organic compound, water, a viscosity modifier (such as Dow Chemical Company (Midland,
MI)CRT30), a pH adjusting agent (such as diethanol amine or triethanolamine) and/or its arbitrary combination.
The present invention is further illustrated in following embodiment, but should not be construed as what is limit the invention in any way certainly
Range.
Embodiment 1
It prepares for the black ink composition of the present invention, with following formulas：
35.7wt% carbon black dispersions (Fuji APD 1000Carbon Black) (14% solid),
The deionized water of 28.4wt%,
19.0wt% polymeric dispersions (AC WS-4000) (29% solid),
The moisturizer (2- hydroxyethyl-pyrrolidones) of 15.0wt%,
1.0wt% polymeric dispersions (AC WS-5000) (30% solid),
0.8wt% surfactants (Hydrostable 212) and
The pH adjusting agent (dimethylethanolamine) of 0.08wt%
Water and hydroxyethyl-pyrrolidone (HEP) are vigorously mixed and are slowly added into very much polymer, pH adjusting agent and face
Material.Later, surfactant is added in.By additional a period of time be vigorously mixed the time after, it is common with Printing ink producing field
Typical filter system known to technical staff is by ink fine filtering.
Viscosity of the ink under 32 degrees Celsius is 5.13cP, pH 9.08.As measured by using SensaDyne tensometers
, the surface tension under 25 degrees Celsius is 36.0 dynes per centimeters.
Embodiment 2
It prepares for the black infrared transmission printing ink composition of the present invention, is formulated as follows：
42.9wt% deionized waters,
25.0wt% polymeric dispersions (AC WS-4000) (solid content 29%),
17.0wt% moisturizer (2- hydroxyethyl-pyrrolidones),
10.0wt% colloidal silica dispersions (AS-40) (solid content 40%)),
The opaque infrared transmission dye solution (hydroxyethyl hydroxyethyl of 20%Epolight 7527A of 5.0wt% visions
Ketone solution) and
0.1wt%pH conditioning agents (dimethylethanolamine)
Dye solution and HEP are vigorously mixed and are slowly added into very much polymer.After one section is vigorously mixed, add in
Deionized water.Then, pH adjusting agent is added in, then adds in crosslinking agent.After mixing a period of time, silica dispersion is added in,
Ink is filtered after being vigorously mixed using one section.
Viscosity of the ink under 32 degrees Celsius is 4.50cP, pH 9.72.Surface tension at 25 degrees Celsius is reached for 56.0
Because/centimetre.
Embodiment 3
It prepares for the first white ink composition of the present invention, is formulated as follows：
33.7wt% deionized waters,
19.7wt% moisturizer (2- hydroxyethyl-pyrrolidones),
14.8wt% titanium oxide dispersion (Cyclojet White TI-7510),
12.7wt% polymeric dispersions (AC WS-4000) (solid content 29%),
11.9wt% cross-linking agent dispersions (BI 201) (solid content 40%),
6.4wt% colloidal silica dispersions (AS-40) (solid content 40%),
0.4%pH conditioning agents (dimethylethanolamine, 50% aqueous solution),
0.3wt% surfactants (Hydrostable 212) and
0.3wt% preservatives (GXL)
Titanium oxide dispersion and silica dispersion are slightly mixed, and are slowly added into very much polymer and crosslinking
Agent.After slight mixing, deionized water, HEP and preservative are added in, again after slight mixing, adds in pH adjusting agent.Then, it adds in
Surfactant filters ink after mixing.
The solid content of printing ink composition is 16.4% solid.Viscosity of the liquid ink at 32 degrees Celsius is
4.92cP, pH 9.2.Surface tension at 25 degrees Celsius is 43.68 dynes per centimeters.
Embodiment 4
It prepares for the second white ink composition of the present invention, is formulated as follows：
44.5wt% deionized waters,
23.4wt% polymeric dispersions (AC WS-4000) (solid content 29%),
15.4wt% titanium oxide dispersion (Cyclojet White TI-7530),
7.7wt% moisturizer (2- hydroxyethyl-pyrrolidones),
3.0wt% surface tension modifiers (2- butoxy ethyl ketone),
3.4wt% moisturizer (ethylene glycol),
1.7wt% levelling agents (Hydrostable 212),
0.7wt% surfactants (465),
0.1wt%pH conditioning agents (dimethylethanolamine) and
0.08wt% preservatives ((GXL)
The solid content of printing ink composition is 14.7%.Viscosity of the liquid ink at 32 degrees Celsius is 6.03cP, and pH is
8.6.Surface tension at 25 degrees Celsius is 31.44 dynes per centimeters.
Embodiment 5
It prepares for the metal ink composition of the present invention, is formulated as follows：
85.4wt% aluminium dispersions (EckartSB11028),
9.5wt% solvents (dimethyl sulfoxide) and
(DER 684-EK40 epoxy resin, 20%) solid content in dimethyl sulfoxide is to 5.1wt% polymer solutions
Aluminium dispersion, polymer and aprotic solvent are slightly mixed.After slight mixing a period of time, ink is filtered.
The solid content of printing ink composition is 4%.Viscosity of the ink at 32 degrees Celsius is 4.98cP.At 25 degrees Celsius
Dynamic surface tension is 31.8 dynes per centimeters, and static surface tension is 29.7 dynes per centimeters.
All formulas of Examples 1 to 5 are all generated with acceptable instant and long durability valuable printing
Ink.
Industrial feasibility
All references cited herein is hereby incorporated herein by (including publications, patent applications and patents)
In, degree individually and is particularly pointed out such as each bibliography and is incorporated by reference into and completely explains herein
It states.
(particularly in the following claims) uses in the description of the present invention term " one ", "one" and
" described " and similar reference are to be interpreted as covering odd number and plural number, unless otherwise indicated or significantly and contradicted by context.
Unless otherwise stated, the numberical range enumerated herein be only one be individually recited fall into the range it is each individually
The simplification method of numerical value, each individually numerical value is incorporated in specification, as they are individually enumerated herein.It retouches herein
All methods stated can perform in any suitable order, unless otherwise indicated herein or be apparently contradicted in the context.
Unless stated otherwise, otherwise provided herein is any and all embodiment or the use of exemplary language (for example, " such as ") only anticipate
The present invention is being better described, and without limitation on the scope of the present invention.Any language in specification is all not necessarily to be construed as
Indicate any element being not claimed, this is essential for the practice of the present invention.In view of the explanation of front, to this hair
Bright many modifications will be apparent those skilled in the art.It should be understood that embodiment described is only
Illustratively, it is not construed as limiting the scope of the invention.
Claims (according to the 19th article of modification of treaty)
1. a water-based ink, it includes：
About 3 to about 15wt% one or more polymer；
About 0.5 to about 12wt% one or more colorants；
About 5 to an about 35wt% solvent；
About 0.03 to an about 1.0wt% pH adjusting agent；With
About 50 to about 80wt% water, wherein the viscosity of the water-based ink about 1 is to about 20mPas so that the water-based ink
The non-absorbent surface into one layer can be applied, one kind in one or more of which polymer is urethanes silicon
Alkanol, wherein the pH adjusting agent is dimethylethanolamine, wherein the solvent includes ethylene glycol and wherein described ink 25
Dynamic surface tension under degree Celsius is about 20 to about 45 dynes per centimeters.
2. water-based ink according to claim 1, which is characterized in that the viscosity is about 4 to about 14mPas.
3. water-based ink according to claim 1, which is characterized in that further include about 0.1 to an about 5wt% surface
Activating agent.
4. water-based ink according to claim 1, which is characterized in that further include about 1 to an about 20wt% crosslinking
Agent.
5. water-based ink according to claim 4, which is characterized in that the crosslinking agent is an isocyanate crosslinking.
6. water-based ink according to claim 1, which is characterized in that one kind in one or more polymer is certainly
Crosslinking urethane ethyl ester silanol.
7. water-based ink according to claim 1, which is characterized in that the solvent is selected from 1- (2- ethoxys) -2- pyrroles
It is one or more in alkanone, alcohol, polyalcohol, glycerine and glycol.
8. water-based ink according to claim 4, which is characterized in that the surfactant is an ethoxylation molecule.
9. an ink, it includes：
About 0.5 to an about 10wt% epoxy resin；
About 4 to an about 30wt% solvent；With
One or more metallochromes, wherein the viscosity of the ink is about 1 to about 20mPas so that the ink can be with
Apply to the non-absorbent surface in one layer.
10. ink according to claim 9, which is characterized in that the viscosity is about 4 to about 14mPas.
11. ink according to claim 9, which is characterized in that the solvent is dimethyl sulfoxide.
12. ink according to claim 9, which is characterized in that the epoxy resin is a bisphenol A epoxide resin.
13. ink according to claim 9, which is characterized in that dynamic surface tension of the ink under 25 degrees Celsius
It is about 20 to about 35 dynes per centimeters.
14. a kind of method for high speed variable printing includes the following steps：
A water-based ink is provided, the water-based ink includes：
About 3 to about 15wt% one or more polymer；
About 0.5 to an about 12wt% pigment；
About 5 to an about 35wt% solvent；
About 0.03 to an about 1.0wt% pH adjusting agent；With
About 50 to about 80wt% water, wherein the viscosity of the water-based ink is about 1 to about 20mPas, one or more of which
One kind in polymer is urethanes silanol, wherein the pH adjusting agent is dimethylethanolamine, wherein described molten
Agent is about 20 to about 45 dynes per centimeters including the dynamic surface tension of ethylene glycol and wherein described ink under 25 degrees Celsius；With
The water-based ink is applied on the non-absorbent substrates in first layer.
15. according to the method for claim 14, which is characterized in that the method, which further includes, is applied to the water-based ink
Step in other multiple layers.
16. according to the method for claim 14, which is characterized in that the water-based ink also includes about 0.1 to about 5.0wt%
A surfactant.
17. according to the method for claim 14, which is characterized in that the method further includes heating so that described aqueous
One or more crosslinked polymers of ink.
Claims (20)
1. a water-based ink, it includes：
About 3 to about 15wt% one or more polymer；
About 0.5 to about 12wt% one or more colorants；
About 5 to an about 35wt% solvent；
About 0.03 to an about 1.0wt% pH adjusting agent；With
About 50 to about 80wt% water, wherein the viscosity of the water-based ink about 1 is to about 20mPas so that the water-based ink
The non-absorbent surface into one layer can be applied.
2. water-based ink according to claim 1, which is characterized in that the viscosity is about 4 to about 14mPas.
3. water-based ink according to claim 1, which is characterized in that one kind in one or more polymer is ammonia
Base Ethyl formate silanol.
4. water-based ink according to claim 1, which is characterized in that further include about 0.1 to an about 5wt% surface
Activating agent.
5. water-based ink according to claim 1, which is characterized in that further include about 1 to an about 20wt% crosslinking
Agent.
6. water-based ink according to claim 5, which is characterized in that the crosslinking agent is an isocyanate crosslinking.
7. water-based ink according to claim 1, which is characterized in that one kind in one or more polymer is certainly
Crosslinking urethane ethyl ester silanol.
8. water-based ink according to claim 1, which is characterized in that the solvent is selected from 1- (2- ethoxys) -2- pyrroles
It is one or more in alkanone, alcohol, polyalcohol, glycerine and glycol.
9. water-based ink according to claim 5, which is characterized in that the surfactant is an ethoxylation molecule.
10. water-based ink according to claim 1, which is characterized in that the pH adjusting agent is dimethylethanolamine.
11. water-based ink according to claim 1, which is characterized in that dynamic surface of the ink under 25 degrees Celsius
Tension is about 20 to about 45 dynes per centimeters.
12. an ink, it includes：
About 0.5 to an about 10wt% epoxy resin；
About 4 to an about 30wt% solvent；With
One or more metallochromes, wherein the viscosity of the ink is about 1 to about 20mPas so that the ink can be with
Apply to the non-absorbent surface in one layer.
13. ink according to claim 12, which is characterized in that the viscosity is about 4 to about 14mPas.
14. ink according to claim 12, which is characterized in that the solvent is dimethyl sulfoxide.
15. ink according to claim 12, which is characterized in that the epoxy resin is a bisphenol A epoxide resin.
16. ink according to claim 12, which is characterized in that dynamic surface tension of the ink under 25 degrees Celsius
It is about 20 to about 35 dynes per centimeters.
17. a kind of method for high speed variable printing includes the following steps：
A water-based ink is provided, the water-based ink includes：
About 3 to about 15wt% one or more polymer；
About 0.5 to an about 12wt% pigment；
About 5 to an about 35wt% solvent；
About 0.03 to an about 1.0wt% pH adjusting agent；With
About 50 to about 80wt% water, wherein the viscosity of the water-based ink is about 1 to about 20mPas；With
The water-based ink is applied on the non-absorbent substrates in first layer.
18. according to the method for claim 17, which is characterized in that the method, which further includes, is applied to the water-based ink
Step in other multiple layers.
19. according to the method for claim 17, which is characterized in that the water-based ink also includes about 0.1 to about 5.0wt%
A surfactant.
20. according to the method for claim 17, which is characterized in that the method further includes heating so that described aqueous
One or more crosslinked polymers of ink.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2015/053544 WO2017058233A1 (en) | 2015-10-01 | 2015-10-01 | Ink composition for use on non-absorbent surfaces |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108137966A true CN108137966A (en) | 2018-06-08 |
Family
ID=54293410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580083542.2A Pending CN108137966A (en) | 2015-10-01 | 2015-10-01 | For the printing ink composition of non-absorbent surface |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3356478A1 (en) |
| CN (1) | CN108137966A (en) |
| WO (1) | WO2017058233A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134420A (en) * | 2010-01-26 | 2011-07-27 | 精工爱普生株式会社 | White ink composition |
| CN103998540A (en) * | 2011-12-22 | 2014-08-20 | 伊斯曼柯达公司 | Inkjet ink composition |
| CN104742552A (en) * | 2013-12-25 | 2015-07-01 | 精工爱普生株式会社 | Image recording method |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103780A (en) * | 1998-04-16 | 2000-08-15 | Westvaco Corporation | Ink jet inks |
| EP1180540A1 (en) * | 2000-08-14 | 2002-02-20 | Westvaco Corporation | Ink jet inks |
| US20030055135A1 (en) * | 2001-09-17 | 2003-03-20 | Westvaco Corporation | Pigmented ink jet inks |
| KR100808250B1 (en) * | 2006-06-14 | 2008-02-29 | 삼성전자주식회사 | Ink composition, and ink cartridge including the same |
| KR101156889B1 (en) * | 2006-09-15 | 2012-06-21 | 가부시키가이샤 리코 | Recording ink, inkjet recording method and inkjet recording apparatus |
| EP2099869B1 (en) * | 2006-10-31 | 2013-05-01 | Sensient Colors Inc. | Modified pigments and methods for making and using the same |
| CN102673206B (en) * | 2007-08-20 | 2014-10-08 | 摩尔·华莱士北美公司 | Apparatus and methods for controlling application of a substance to a substrate |
| JP5459460B2 (en) * | 2007-12-05 | 2014-04-02 | セイコーエプソン株式会社 | Aqueous white ink composition for inkjet and recorded matter using the same |
| WO2009137747A1 (en) * | 2008-05-08 | 2009-11-12 | E. I. Du Pont De Nemours And Company | Inkjet inks containing crosslinked polyurethanes |
| JP5837765B2 (en) * | 2011-06-02 | 2015-12-24 | 株式会社松井色素化学工業所 | Ink for inkjet printing |
| JP2014019842A (en) * | 2012-07-23 | 2014-02-03 | Seiko Epson Corp | Ink jet composition, ink jet recording apparatus, and recorded article |
| JP6472947B2 (en) * | 2013-10-25 | 2019-02-20 | セイコーエプソン株式会社 | Ink jet ink composition, recording method, and recorded matter |
| US20150119510A1 (en) * | 2013-10-30 | 2015-04-30 | Xerox Corporation | Inkjet ink containing polystyren copolymer latex suitable for indirect printing |
-
2015
- 2015-10-01 CN CN201580083542.2A patent/CN108137966A/en active Pending
- 2015-10-01 WO PCT/US2015/053544 patent/WO2017058233A1/en active Application Filing
- 2015-10-01 EP EP15779148.4A patent/EP3356478A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134420A (en) * | 2010-01-26 | 2011-07-27 | 精工爱普生株式会社 | White ink composition |
| CN103998540A (en) * | 2011-12-22 | 2014-08-20 | 伊斯曼柯达公司 | Inkjet ink composition |
| CN104742552A (en) * | 2013-12-25 | 2015-07-01 | 精工爱普生株式会社 | Image recording method |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁: "《新型粘合剂与涂料化学品》", 31 May 2000, 中国建材工业出版社 * |
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|---|---|
| EP3356478A1 (en) | 2018-08-08 |
| WO2017058233A1 (en) | 2017-04-06 |
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