CN108135212A - Chewing gum with crosslinked hydrocolloid and coupling agent - Google Patents

Chewing gum with crosslinked hydrocolloid and coupling agent Download PDF

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Publication number
CN108135212A
CN108135212A CN201680057841.3A CN201680057841A CN108135212A CN 108135212 A CN108135212 A CN 108135212A CN 201680057841 A CN201680057841 A CN 201680057841A CN 108135212 A CN108135212 A CN 108135212A
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China
Prior art keywords
chewing gum
chewing
gum base
agent
gum
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CN201680057841.3A
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Chinese (zh)
Inventor
刘京萍
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WM Wrigley Jr Co
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WM Wrigley Jr Co
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Publication of CN108135212A publication Critical patent/CN108135212A/en
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/08—Chewing gum characterised by the composition containing organic or inorganic compounds of the chewing gum base
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Confectionery (AREA)

Abstract

The present invention provides the compositions for the chewing gum base that can include hydrocolloid and coupling agent.The present invention also provides the methods of manufacture matrix and chewing-gum preparation.

Description

Chewing gum with crosslinked hydrocolloid and coupling agent
Cross reference to related applications
This application claims the priority of U.S.Provisional Serial 62/235,354 submitted for 30th in September in 2015, The provisional application is integrally incorporated herein.
Technical field
Subject matter disclosed herein is related to the chewing gum base composition of the removeability with improved slave surface substrate.This Matrix contains hydrocolloid and coupling agent disclosed in text.
Background technology
The conventional chewing gum matrix with good chewing texture is usually shown at ambient temperature to various under body temperature The good adhesion of base material.As a result, in chewing gum industry and entire society, chewing gum discarding is all a problem.Therefore, it is necessary to It improves conventional matrix and chews group from undesirable surface and the removeability of base material to increase chewing gum.
Known commercial chewing gum contains soluble part and insoluble part.The insoluble part mainly contain matrix and Hydrophobic components, such as chew with polymer, tackifier, plasticizer, lipid, filler, emulsifier and other additives.Cause This, hydrophily flavoring agent is difficult in mastication processes discharge from hydrophobicity matrix with continuous fashion.
It is continuously needed and improves base formulation to improve chewing gum removeability, while it is special to obtain ideal flavoring agent release Sign.Subject matter disclosed herein solves these needs, and following article is discussed in detail.
Invention content
Subject matter disclosed herein is related to the chewing gum base comprising one or more hydrocolloids and one or more coupling agents.
In some embodiments, one or more hydrocolloids are selected from croscarmellose sodium, hydroxyacetic acid Sodium starch, crospovidone, with the crosslinked polymer based on acrylic acid of polyalkenyl polyether, the grafting of starch-polyacrylic acid sodium Copolymer and Sodium Polyacrylate.
In some embodiments, one or more hydrocolloids are selected from the diacetyl tartrate of monoglyceride (DATEM), the citrate of monoglyceride, succinylated monoglycerides, hydroxy-end capped butadiene, hydroxy stearic acid-poly- second Diol copolymer, acrylic acid-chain alkyl acrylate copolymer, styrene-isoprene-phenylethene, styrene-fourth two Alkene-styrene, ethylene-propylene-ethylene and ethane-acetic acid ethyenyl ester-ethylene block copolymer.
In some embodiments, the chewing gum base contains about 1 weight % to the hydrocolloid of about 60 weight %.At certain In a little embodiments, the chewing gum base contains about 1 weight % to the hydrocolloid of about 35 weight %.In certain embodiments In, the chewing gum base contains about 1 weight % to the coupling agent of about 15 weight %.
In some embodiments, the chewing gum base includes one or more selected from following component：Elastomer, second Alkenyl polymer, elastomer elasticizer, filler, softening agent, wax and combinations thereof.
In addition, subject matter disclosed herein is related to including the chewing-gum preparation for the chewing gum base that theme is disclosed herein.
Front has broadly outlined the feature and technological merit of the application, subsequent detailed so as to more fully understand Thin description.The additional features and advantage of the application are described below, form the theme of claims hereof.This field It is to be understood by the skilled artisans that disclosed concept and specific embodiment can be easily used as changing or designed for realizing this The basis of the other structures of the identical purpose of application.It should also be realized by those skilled in the art that such equivalent constructions do not take off From the spirit and scope illustrated in such as claim.It is considered as the application to be better understood with from following description Distinctive novel feature and other objects and advantages about both its organizing and operating methods.
Specific embodiment
As described above, so far, there remain a need in the art of to have increased removeability and the release of ideal flavoring agent The chewing gum base of feature.Subject matter disclosed herein solves this need by the rubber-based composition containing hydrocolloid and coupling agent It will.
1. definition
The term used in this specification in the context of disclosure theme and use each term it is specific on Hereinafter usually there is its ordinary meaning in the art.Hereafter or in elsewhere in this specification discuss certain arts Language, in the composition of the disclosed theme of description and method and how to manufacture and using them when provides volume to practitioner Outer guidance.
As used herein, it when term "comprising" is used together, is counted when in claim and/or specification without specific The use of the denotion object of amount can represent "one", but it is also with " one or more ", " at least one " and " one or being more than One " meaning it is consistent.In addition, term " having ", " comprising ", " containing " and "comprising" are interchangeable, and this field skill Art personnel recognize that these terms are open-ended terms.
Term " about " " about " refers to acceptable error model in the particular value determined by those of ordinary skill in the art In enclosing, how this measures or determines the value if will partly depend on, that is, the limitation of measuring system.For example, the reality according to this field It tramples, " about " can be represented in the standard deviation at 3 times or more than 3 times.Optionally, " about " set-point can be represented at most 20%th, preferably up to 10%, more preferably up to 5% and the range even more preferably from most 1%.
As used herein, term " chewing gum " refers to the flavoring substance for being intended for use in chewing.The term used herein Further include bubble gum and the confectionary products containing chewing gum.In some embodiments, gum formats include but not limited to piece, Item, medicine ball, hollow ball, cutting wrappage (cut and wrap) and pellet or pillow object.Unless otherwise stated, All percentages used herein are all weight percent.As used herein, chewing gum contains water-insoluble matrix part and water Dissolubility incremental portion.
As used herein, term " chewing gum chews group " refers to remainder of the chewing-gum preparation after chewing.
As used herein, term " hydrocolloid " refer to be formed when being dispersed in water gel or viscosity dispersion one kind or Multiple polymers.
As used herein, term " coupling agent " can be used interchangeably with " surfactant ", and refer to increase not phase Hold the anchored compound between component (such as polymer and filler).
As used herein, term " cold flow " refers to rubber-based composition or chewing-gum preparation at a temperature of common (such as environment) VISCOUS FLOW.
2. rubber-based composition
Subject matter disclosed herein is related to the composition of chewing gum, and relates more specifically to chewing gum base, can wrap Include hydrocolloid and coupling agent.As provided herein, the addition of hydrocolloid and coupling agent can improve chewing gum and/or chewing gum chews group Removeability from various surfaces.
In general, chewing gum compositions include (i) water soluble bulk portion, (ii) water-insoluble flavoring agent and (iii) water are not Insoluble chewable base portion.In mastication processes, the water soluble bulk portion is with a part of water-insoluble flavoring agent one It dissipates together in the section time.However, in entire mastication processes, water-insoluble matrix part is retained in mouth, is formed so-called Chewing gum chews group.Generated chewing gum, which chews group, to be difficult to once dry surface or base material (such as pavement etc.) is adhered to The adhesiveness material removed.
Substantially, it is complicated amorphous polymer blend that chewing gum, which chews group,.Unique viscoelastic properties causes chewing gum The group of chewing behaves like cold flow under ambient enviroment.During being chewed using saliva, water is inevitably introduced into chewing gum and chews group In.The hydrone that can move freely can behave like plasticizer and increase the mobility of cold flow, and other polarity in saliva Molecule increases the surface energy for the group of chewing.It may be that chewing gum chews a molecule that chewing gum, which chews adherency of the group on various surfaces or base material, In the intrapore physical interlock of porous substrate and/or chewing gum and surface or the result of the surface tension of the interface of base material.
2.1 hydrocolloids and coupling agent
Subject matter disclosed herein specifically provides the rubber-based composition containing hydrocolloid and coupling agent, to improve from surface Removeability.
Hydrocolloid
In the certain embodiments of subject matter disclosed herein, the hydrocolloid is crosslinking hydrocolloid.In specific embodiment party In formula, crosslinking hydrocolloid includes but not limited to croscarmellose sodium, sodium starch glycollate, crospovidone, with gathering The crosslinked polymer based on acrylic acid of alkenyl polyether, starch-polyacrylic acid sodium graft copolymer, Sodium Polyacrylate and its group It closes.In some embodiments, the amount of the crosslinking hydrocolloid in matrix is about 1% to about 60%w/w, about 1% to about 35%w/ W, in the range of about 1% to about 20%w/w, about 1% to about 10%w/w.In an alternative embodiment, the crosslinking glue in matrix The amount of body can about 10% to about 60%w/w, about 10% to about 50%w/w, about 10% to about 30%w/w or about 10% to In the range of about 25%w/w.In specific non-limiting embodiment, the amount of the crosslinking hydrocolloid in matrix is about 60%w/ W, about 47.7%w/w, about 19.7%w/w, about 19.6%w/w or about 4.4%w/w.
In subject matter disclosed herein, water can be changed by the crosslinking hydrocolloid from working fluid " can demould (de- Moldable) " solid or gel.This transformation can reduce plasticising of the small polar molecule (such as water) as hydrophobic polymer The ability of agent.Super absorbent polymer is swollen very good, and can reach hundreds times of polymer weight itself.It is crosslinked water The volume change of colloidal particle generates stress in its vicinity.Variation (the example for passing through molecular conformation depending on the elasticity of matrix, stress Such as push back cold flow) and partly adapted to or lead to disintegration (cut-out cold flow).In both cases, it is crosslinked hydrocolloid particle Drastically volume change can all reduce adherency between the group of chewing and base material.Similarly, after water evaporation, it is crosslinked hydrocolloid particle High convergency can increase stress, make chewing gum chew group and base material unsticking, and thus increase chewing gum chew group removeability.
In the specific embodiment of published subject, the crosslinking hydrocolloid is high-hydrophilic.In certain embodiment party In formula, the crosslinking hydrocolloid serves as the absorbent of hydrophilic composition.This can increase the general polarity of chewing gum base and increasing Add the holding capacity of hydrophily flavor molecules.
Coupling agent
Since conventional chewing gum matrix is mainly made of hydrophobic combination, so high-hydrophilic hydrocolloid and hydrophobic elastomeric Body matrix is naturally unmixing.Subject matter disclosed herein, which discloses, can include coupling agent to increase crosslinking hydrocolloid and conventional matrix Compatibility.This coupling agent include but not limited to surfactant, polymeric surfactant, thermoplastic block copolymers, Elastomer and combinations thereof.In some embodiments, coupling agent can about 0% to about 20%w/w or 0.5% to about 20%w/ W, the amount in the range of about 1% to about 15%w/w or about 1% to about 10%w/w exists.
In some embodiments, the surfactant includes but not limited to the diacetyl tartrate of monoglyceride (DATEM), the citrate and succinylated monoglycerides of monoglyceride.In some embodiments, the surfactant Amount with about 0.1% to about 15%w/w, about 0.5% to about 10%w/w or about 0.5% to about 3%w/w is present in composition In.In specific non-limiting embodiment, the surfactant is with about 3.6%w/w, about 6.94%w/w or about The amount of 1.26%w/w is present in composition.
In some embodiments, polymeric surfactant can be incorporated to as coupling agent in rubber-based composition to increase It is crosslinked the compatibility of hydrocolloid and conventional matrix.In some embodiments, polymeric surfactant includes but not limited to hydroxyl Butadiene, hydroxy stearic acid-ethylene glycol copolymer, the acrylic acid-chain alkyl acrylate copolymer of base sealing end.Certain In embodiment, polymeric surfactant is with about 1% to about 20% or about 1% to about 18%w/w or about 3% to about 10% The amount of w/w is present in composition.In specific non-limiting embodiment, polymeric surfactant is with about 15.9%w/ W, the amount of about 4.4%w/w or about 7%w/w are present in composition.
In other embodiments, thermoplastic block copolymers can be used as physics coupling agent will be crosslinked hydrocolloid particle lock It is scheduled in chewing gum base.In some embodiments, the thermoplastic block that the composition can include alone or in combination is total to Polymers, surfactant and polymeric surfactant.In some embodiments, block copolymer includes but not limited to benzene second Alkene-isoprene styrene, s-B-S, ethylene-propylene-ethylene, ethane-acetic acid ethyenyl ester-ethylene are embedding Section copolymer.In some embodiments, block copolymer is deposited with the amount of about 0% to about 20%w/w or about 1 to about 10%w/w It is in composition.In specific non-limiting embodiment, block copolymer is present in combination with the amount of about 4.4%w/w In object.
In some embodiments, coupling agent can be the diacetyl tartrate of monoglyceride.In other embodiment In, coupling agent is the citrate of monoglyceride.In other embodiments, coupling agent is succinylated monoglycerides.At it In its embodiment, coupling agent is hydroxy stearic acid-ethylene glycol copolymer.In other embodiments, coupling agent is hydroxyl The 1,3- butadiene of sealing end.
2.2. other ingredients in matrix
Insoluble gum base usually contains elastomer (natural and/or synthesis), polymer, elastomer solvent, and (or elastomer increases Mould agent), filler, softening agent, wax, lipid and other optional members such as colorant and antioxidant any combinations.Various glue Based component can provide the ability for changing the chew characteristics of chewing gum made of matrix.
Elastomer provides the cohesion property as rubber for chewing gum, according to the chemical constitution of this ingredient and it can Changed with how to be mixed with other ingredients.Natural elastomer can include natural rubber, such as smoke or liquid emulsion and silver Chrysanthemum glue；Natural gum, such as gelutong (jelutong), Lai Kaiou glue (lechi caspi), tonka-bean gummy (perillo), Massaranduba balata (massaranduba balata), the sub- glue of massaranduba chocolate (massaranduba chocolate), Nice Perrault glue (nispero), Lao Xindingha glue (rosindinha), tunny gum (chicle), gutta-percha (gutta Percha), ancient Taka too glue (gutta kataiu), Niger's gutta-percha (niger gutta), spy exert glue (tenu), Chilte (Qi Erte glue), Gorgon euryale thatch palm glue (chiquibul), Hong Kong gutta-percha (gutta hang kang).In certain implementations In mode, the rubber-based composition can include about 0% to about 30%w/w or about 0% to about 5%w/w natural elastomer.
Synthetic elastomer can include high molecular weight elastomer, such as butadiene-styrene copolymer and isobutene-isoamyl Diene copolymers.Synthetic elastomer can include but is not limited to polyisoprene, polyisobutene, polyvinyl acetate, styrene Butadiene rubber, vinyl acetate-laurate copolymer, poly- dl- lactides, glycolic-lactide copolymer or its Mixture.In some embodiments, rubber-based composition can include about 3% to about 75%w/w or about 5% to about 75%w/w's Synthetic elastomer.In some embodiments, rubber-based composition can include about 25% to about 60%w/w synthetic elastomer. In other embodiment, rubber-based composition can include about 3 weight % to the synthetic elastomer of about 25 weight %.In specific non-limit In property embodiment processed, rubber-based composition can include about 4.9%, about 10%, about 12.7%, about 20.2%, about 22.3% or about The synthetic elastomer of 23.9%w/w.
Sometimes serving as the polymer of elastomer may include polybutadiene, polyvinyl such as polyvinyl acetate, poly- second Alkene, vinyl copolymer elastomer such as vinyl acetate/vinyl laurate, vinyl acetate/stearic acid vinyl ester, ethylene/second Vinyl acetate, polyvinyl alcohol or its mixture.These polymer are worked as and butadiene-styrene copolymer and isobutene-isoamyl two It puts up the best performance when alkene copolymer is applied in combination.
Vinyl polymerization and copoly type elastomer provide resistance to bond, and the chewing for changing the chewing gum made of these matrixs is special Property, and it is provided with the hydrophily of the sensory perception beneficial to final chewing gum.For copoly type, it is respectively present in lauric acid second Enester/vinyl acetate (VLNA), stearic acid vinyl ester/vinyl acetate (VSNA) or Ethylene/vinyl acetate (EVA) copolymerization The amount of vinyl laurate, stearic acid vinyl ester or ethylene in object usually can be about the 10% to about 60%w/w of copolymer In the range of.The ball softening point (ball and ring softeningpoint) of these polymer can be at about 50 DEG C extremely In the range of 120 DEG C.The average molecular weight of these polymer can be in the range of about 2,000 to about 80,000.In certain realities It applies in mode, is disclosed herein in the matrix and chewing gum of theme to be used for, the molecular weight of these polymer such as polyvinyl acetate There can be the average molecular weight of about 8,000 to about 52,000.In some embodiments, the molecular weight of these polymer can be with In the range of about 10,000 to about 35,000.Optionally, for bubble gum base, polymer can have about 30,000 to about Molecular weight in the range of 60,000.The usual quick release flavoring agent of polyvinyl, and use and show small crystallization knot The isoparaffin wax (iso-alkanic wax) of structure can extend flavoring agent release with these polyvinyls.
The firmness of elastomer solvent (sometimes referred to as elastomer elasticizer) changeable matrix.When in for matrix, they The specificity of chain fracture (plasticizing) and its different softening point lead to different degrees of finished product chewing gum between elastomer molecules Firmness.When being desirable to provide more elastic multi-body chain and being exposed to the alkane hydrocarbon chain of wax, this is also important.Elastomer solvent includes day Right rosin ester, such as the glyceride of part hydrogenated rosin, the glyceride of newtrex, the glyceride of part dimerization colophonium, rosin Glyceride, the glyceride of toll oil rosin, the pentaerythritol ester of part hydrogenated rosin, partially hydrogenated rosin methyl ester, rosin Pentaerythritol ester, synthetic elastomer plasticizer as derived from australene, nopinene and/or (R)-4-isopropenyl-1-methyl-1-cyclohexene terpene resin and Its mixture.Used elastomer solvent can be the combination of a type or more than one type.In general, a type with Another type of ratio depends on respective softening point, respectively the influence to flavoring agent release and each pair The corresponding sticky degree that chewing gum generates.
The ball softening point of above-mentioned rosin ester type can be in the range of about 60 DEG C to about 120 DEG C.Terpene resin it is soft Changing point can be in the range of about 60 DEG C to about 130 DEG C, and average molecular weight is about 500 to 2, and 000.Once in a while, terpenes and pine Both fragrant ester resins can be used together.In some embodiments, rubber-based composition can include about 5% to about 25%w/w's The combination of terpenes and rosin ester.In other embodiments, rubber-based composition can include about 10% to about 20%w/w terpenes and The combination of rosin ester.In some embodiments, rubber-based composition can include about the terpenes of 15.4%w/w.In certain embodiment party In formula, rubber-based composition can include about the terpenes of 16.5%w/w.In some embodiments, rubber-based composition can include about The terpenes of 20.8%w/w.
The filler used in matrix changes the quality of matrix and helps to process.Filler includes carbonate or precipitation Carbonate type such as magnesium carbonate and calcium carbonate, the lime stone ground and silicate types such as magnesium silicate and alumina silicate, clay, oxidation Aluminium, talcum and titanium oxide, one-lime phosphate, Dicalcium Phosphate and tricalcium phosphate, cellulosic polymer such as ethyl, methylcellulose and Timber or its mixture.In some embodiments, rubber-based composition can include about 0% to about 40%w/w filler or about 0% to about 15%w/w filler.
Softening agent changes quality, makes the hydrophobicity of matrix and hydrophilic component miscible, and can further be plasticized glue The synthetic elastomer of base.Softening agent includes completely hydrogenated cottonseed oil, soybean oil, palm oil, palm-kernel oil, coconut oil, safflower Oil etc. and monoglyceride, diglyceride, acetylated monoglyceride, the monoglyceride of distillation and diglyceride and de-oiling or " powdered " lecithin.Glyceride and lecithin are sometimes referred to as emulsifier.In some embodiments, rubber-based composition includes About 5% to about 55%w/w or about 15% to about 45%w/w softening agent, including tackifier, lipid and plasticizer.
Pertroleum wax contributes to the curing of the finished product chewing gum made of matrix and improves pot-life and quality.Wax exists Crystalline size during hardening also improves the release of flavoring agent.The crystalline size of those high waxes of isoparaffin content is less than normal chain The high wax of Determination of Alkane Content, particularly those waxes with normal paraffin hydrocarbons of the carbon number less than 30.Crystalline size is smaller, flavoring agent release It is slower, this is because compared with the wax with larger crystalline size, obstruction bigger that flavoring agent is escaped from this wax.
Synthetic wax is produced by atypical pertroleum wax mode of production.Synthetic wax can be included containing branched paraffin simultaneously With the wax and polyethylene and Fischer-Tropsch (Fischer-Tropsch) type wax of monomer (such as, but not limited to propylene) copolymerization.Poly- second Alkene wax is not belonging to same category with polyethylene (polymer of vinyl monomer).
Lipid includes but not limited to alkanoic acid or monoenoic acid or carbon chain lengths are C4-C24Polyunsaturated fatty acid or it is mixed The monoglyceride and/or diglyceride and/or triglycerides of conjunction object, hydrogenation and partially hydrogenated monoenoic acid and polyunsaturated fat The monoglyceride and/or diglyceride and/or triglycerides of acid, the acetylated glycerides of aliphatic acid, lecithin, paraffin, crystallite Wax and native paraffin such as beeswax and Brazil wax, and combinations thereof.In some embodiments, lipid is with about 5% to about 45%w/w Amount exist.
Other optional compositions such as antioxidant and colorant can also be used in matrix.Antioxidant extends matrix, finished product Chewing gum or its respectively pot-life of component (including fat and flavored oils) and storage.It is suitable for the invention matrix or mouth is fragrant Antioxidant in sugar includes butylated hydroxyanisol (BHA), butylated hydroxytoluene (BHT), beta carotene, tocopherol, Acidulant such as vitamin C, propylgallate, it is other synthesis and Natural Types or its mixture, in free-flowing grind or Pulverised form.In some embodiments, colorant and brightening agent include but not limited to FD＆C type dyes and color lake, fruit and vegetable Dish extract, titanium dioxide or its mixture.In some embodiments, rubber-based composition contain it is optional it is a small amount of (about 1% or Miscellaneous ingredients less), such as colorant, antioxidant etc..
In some embodiments, rubber-based composition is substantially free of natural elastomer and filler.
3. chewing gum
Subject matter disclosed herein includes the chewing-gum preparation for including above-disclosed rubber-based composition.Also contemplate manufacture mouth The method of fragrant sugar preparation.
3.1 preparation
In some embodiments, above-disclosed rubber-based composition can be incorporated into chewing-gum preparation.In certain realities It applies in mode, chewing-gum preparation can include one of disclosed water-insoluble matrix composition and water soluble bulk portion.
The water-soluble portion of chewing gum generally includes incremental agent (also referred to as bulk sweetener) and a small amount of accessory constituent, Such as flavoring agent (including sensitizer, such as physiological cooling agents, warm agent and tingling agent), high intensity sweetner, colorant are water-soluble Property softening agent, acidulant, filler and adhesive.In general, water-soluble portion, sensitizer and flavoring agent disappear in mastication processes It dissipates, and matrix is retained in entire mastication processes in mouth.
In some embodiments, incremental agent or bulk sweetener can include both sugar and sugar alcohol.Bulk sweetener can About the 5% to about 95%w/w of chewing gum is accounted for, more typically accounts for about the 20% of chewing gum to about 80%w/w, and more generally account for About the 30% of chewing gum is to about 60%w/w.Sugared sweetener generally include it is commonly known containing saccharic composition in chewing gum art, including But it is not limited to sucrose, dextrose, maltose, dextrin, dry inverted sugar, fructose, galactolipin, corn-syrup solids alone or in combination Deng.Sugar-free sweetener includes but not limited to sugar alcohol alone or in combination, such as D-sorbite, mannitol, xylitol, hydrogenation shallow lake Powder hydrolysate, maltitol, antierythrite, isomalt etc..
In some embodiments, if it is desired, various flavoring agents can also be used.In some embodiments, it seasons Agent can be used with the amount of about the 0.1% of chewing gum to about 15%w/w and preferably about the 0.2% of chewing gum to about 5%w/w. In some embodiments, flavoring agent is with about the 0.1% of chewing-gum preparation to about 10.0%w/w or about 0.5% to about 3.0%w/ Amount in the range of w exists.In some embodiments, flavoring agent exists with the amount of the about 0.9%w/w of chewing-gum preparation.It adjusts Taste agent can include essential oil, synthetic flavorings or its mixture, the oil including but not limited to from plant and fruit, such as citrus Oil, fruit essence, Fructus Piperis peppermint oil, Spearmint Oil 56, other peppermint oils, caryophyllus oil, wintergreen, fennel etc..It can also use Artificial flavoring and component.Natural and artificial flavoring can by it is any it is sensuously acceptable in a manner of combine.The one of flavoring agent As classification include sensitizer, i.e., assign the chemical substance of physiological sensation, such as freshener, warm agent and tingling in the oral cavity Agent.The example of freshener includes menthol, WS-23, WS-3, WS-5, isopulegol, menthol ester such as menthyl succinate, breast Sour menthyl ester and glutaric acid menthyl ester etc..Warm and tingling agent float (jambu) and spilanthol including capsaicine, pipering, the Yan. In some embodiments, tackifier include but not limited to natural rosin ester, such as the glyceride of part hydrogenated rosin, polymerization pine Fragrant glyceride, the glyceride of part dimerization colophonium, the glyceride of rosin, the pentaerythritol ester of part hydrogenated rosin, rosin Methyl esters and partially hydrogenated methyl esters, the pentaerythritol ester or mixture of rosin；Synthetic resin, such as derived from australene, β-pinane The terpene resin of alkene and/or (R)-4-isopropenyl-1-methyl-1-cyclohexene, vinylite, polyethylene, poly- dl- polylactide resins and combinations thereof. In the case of fruity chewing gum, acid such as citric acid, malic acid or the adipic acid of at most about 3%w/w can be added to provide acid Taste.
In some embodiments, chewing gum component will include one or more high intensity sweetners.As used herein, art Language " high intensity sweetner " refers to any substance at least more twentyfold than sucrose sweet tea.These sweeteners include saccharin, honey element, Ah This Ba Tian, alitame, neotame, other sweeteners based on peptide, Sucralose, acesulfame-K, stevioside are (including purification Object such as stevioside glycosides A), glycyrrhizin, neohesperidin dihydrochalcone and its mixture.In some embodiments, at least one Partial high intensity sweetner can be encapsulated.This be encapsulated can be by being granulated, reuniting, squeezing out and grinding, be spray-dried, flow Change that bed is encapsulated or any other known way produces.In some embodiments, suitable sugar alcohol includes D-sorbite, sweet dew Sugar alcohol, xylitol, hydrogenated starch hydrolysates, maltitol etc., with and combinations thereof.In some embodiments, sugar-free mouth is fragrant Combination of the sugar comprising high-potency sweetener with sugar alcohol (such as Aspartame and D-sorbite).Dosage level will be depending on sweetener Effect is encapsulated the degree of (if present) and validity and the organoleptic feature needed for product.In general, sweetener can be about 0.005% to about 5%w/w range uses.Sweetener can down to about 0.005%w/w or down to about 0.05%w/w or down to The horizontal of about 0.2%w/w uses.It is fragrant for mouth that sweetener can be up to about 5%w/w or the level of about 3%w/w or about 2%w/w In sugar composite.In some embodiments, high intensity sweetner can be with the water of about 0.1% to about 1.0% of chewing gum component It is flat to exist.
In some embodiments, filler includes but not limited to magnesium carbonate and calcium carbonate, the lime stone and silicic acid ground Salt type such as magnesium silicate and alumina silicate, clay, aluminium oxide, talcum and titanium oxide, one-lime phosphate, Dicalcium Phosphate and tricresyl phosphate Calcium, cellulosic polymer such as ethyl, methylcellulose and timber or its mixture, and combinations thereof.
In some embodiments, plasticizer includes but not limited to glycerol triacetate, triethyl citrate, acetyl lemon Triethylenetetraminehexaacetic acid ester, wood rosin methyl esters and combinations thereof.Plasticizer may be used as softening agent.In some embodiments, plasticizer is with about Amount in the range of 0% to about 15%w/w exists.
In some embodiments, softening agent is added in chewing gum to optimize the chewability and mouth feel of the gum of chewing gum. In some embodiments, softening agent (being also referred to as plasticizer or plasticiser in the art) can account for about the 0% of chewing-gum preparation To about 15%w/w or about 0.5% to about 15.0%w/w.Softening agent includes but not limited to glycerine, lecithin and combinations thereof.This Outside, those of edulcorant aqueous solution for example containing D-sorbite, hydrogenated starch hydrolysates, corn syrup and combinations thereof can be used Make the softening agent and adhesive in chewing-gum preparation.In some embodiments, chewing-gum preparation contains the glycerine of about 1%w/w. In some embodiments, chewing-gum preparation contains the glycerine of about 1.4%w/w.
If necessary to low-calorie chewing gum, then low caloric bulking agents can be used.The example of low caloric bulking agents Including：Dextrosan；Oligofructose (Raftilose)；Inulin (Raftilin)；Fructooligosaccharide (NutraFlora)；Palatinose Oligosaccharides (palatinose oligosaccharide)；Guar gum hydrolysate (BeneFiber)；Or indigestible dextrin (Fibersol).However, it is possible to use other low caloric bulking agents.
In some embodiments, rubber-based composition as disclosed herein can be incorporated into sugarfree chewing gum formulations In.In some embodiments, sugar-free sweetener can be included with sweetened characteristic but without the component of commonly known sugar. In certain embodiments, example includes but not limited to high-potency sweetener and/or sugar alcohol.
The combination of sugar and/or sugar-free sweetener can be used in chewing gum.In addition, softening agent can also provide additional sweet tea Taste, for example, with sugar or sugar alcohol aqueous solution.
In some embodiments, water-soluble sweetening agent part is the sugar of the about 50%w/w of final chewing gum, about 10%w/ The mixture of the dextrose monohydrate of w and/or the corn syrup of about 17%w/w.In some embodiments, the preparation packet Containing about 60%w/w sucrose and/or about 17%w/w corn syrup.In some embodiments, the preparation includes about 58.7%w/ W sucrose and/or about 17%w/w corn syrup.
In some embodiments, insoluble gum base composition accounts for about the 5% to about 95%w/w of chewing-gum preparation.At certain In a little embodiments, insoluble gum base composition accounts for about the 10% to about 50%w/w or about 20% to about 35% of chewing-gum preparation w/w。
3.2 manufacturing method
Subject matter disclosed herein includes the manufacturing method of the chewing-gum preparation comprising rubber-based composition discussed above.
In some embodiments, it is crosslinked hydrocolloid and coupling agent can be in a mixer in about 60 DEG C to about 120 DEG C of temperature It is blended in advance about 10 minutes to about 30 minutes in the case of presence or absence of lipid soln is melted in the range of degree, then with normal Rule mode is mixed with other matrixs or chewing gum component.In some embodiments, the ratio of hydrocolloid and lipid is crosslinked about 3:0.5 or about 2:In the range of 1.
In some embodiments, hydrocolloid and coupling agent are crosslinked or its mixture being blended in advance can be known in the art Usual manner directly combined with other glue group compositions.In some embodiments, matrix can be by by a certain amount of elasticity Body, tackifier, crosslinking hydrocolloid, coupling agent, thermoplastic block copolymers and filler are added to the Sigma (sigma) of heating It is prepared in paddle blenders, wherein front and rear paddle speed ratio is about 2:1.The primary quantity of ingredient can pass through mixing kettle Displacement volume determines the consistency to obtain appropriate.
In some embodiments, after Initial Composition is uniformly agglomerating, by the tackifier of surplus, crosslinking hydrocolloid/ Coupling agent, lipid, filler, plasticizer etc. sequentially add, the melting agglomerate until obtaining substantially uniformity.In certain embodiments In, depending on preparation, this can usually be completed in about 1 to about 4 hour.In some embodiments, final agglomerate temperature can With between about 60 DEG C to about 150 DEG C or between about 80 DEG C to about 120 DEG C.In some embodiments, finished product is melted into agglomerate It is discharged into from mixing kettle in the pan of coating or lining, squeezes out or be cast as any desired shape and is allowed to cool and consolidates Change.In some embodiments, synthetic elastomer, synthetic resin, plasticizer, filler and/or cocoa power can be added to In mixing vessel.In some embodiments, by being heated to about softening ingredient between 220 ℉ and about 250 ℉, then at this At a temperature of mixing time enough to ensure homogeneous lump, normally about 1 to about 2 hour.In some embodiments, it can will roll into a ball Block or matrix are configured to plate or pellet and are allowed to cool, and are subsequently used for manufacture chewing gum.Optionally, melting agglomerate can be used directly In chewing gum manufacturing process.
In some embodiments, the crosslinking hydrocolloid/idol being blended in advance can also be added in when chewing gum is prepared and started Join agent composition.
In some embodiments, by the way that various chewing gum components are added sequentially to commercial mixer known in the art In manufacture chewing gum.In some embodiments, after each ingredient is sufficiently mixed, micelle can be discharged from mixer and into Shape is required shape, such as by rolling in flakes and cutting into inch strips, and extrusion is blocking or is cast as pellet.
In some embodiments, by melt matrix first and add it to mixed in the mixer of operation it is each into Point.In some embodiments, matrix can melt in mixer itself.In some embodiments, it can add at this time Toner or emulsifier.In some embodiments, softening agent such as glycerine and syrup and a part of increment can be added at this time Agent.In some embodiments, then the incremental agent of other parts can be added in mixer.In certain embodiments In, flavoring agent adds in together with back-page incremental agent.It in some embodiments, can be in addition last part increment Agent and flavoring agent add in the sweetener being coated twice later.
In some embodiments, it can apply to the chewing gum of extrusion and be coated.In some embodiments, this is to pass through Pan coating is carried out to the chewing gum block of expansion to complete.In panning procedure, core (such as chewing gum block of expansion) is existed It rolls in pan, while for example applies coating syrup (being usually sugar or sugar alcohol solution) by spraying or pouring into a mould.In coating sugar Between the application of slurry, preferably pellet is dried by the way that the air stream of heating and/or drying is made to pass across or through pellet bed.Formation is permitted Multiple coatings usually replace the formation to accelerate coating with the application of powdered coating materials or inert filler.It can apply Last layer of polishing compound, such as Brazil wax.In addition to sugared (sucrose), preferred coating material include maltitol, Isomalt, xylitol, D-sorbite and antierythrite, but other materials can also be used.Other than coating material, Coating syrup can also include film forming agent such as Arabic gum, high intensity sweetner, flavoring agent and colorant.
Embodiment
Subject matter disclosed herein is better understood with by reference to following embodiment, the embodiment is as disclosed master The example of topic provides, not as limitation.
Embodiment 1：The validity test of coupling agent
Present embodiments provide the assessment to coupling agent in the case where the polymer composition of theme is disclosed herein.
A. it prepares
1 gram of (g) croscarmellose sodium is added in eight centrifuge tubes with 10ml aqueous solutions.It shakes using It is violent to swing device (wrist oscillator, Burrell company of Pittsburgh of Pennsylvania (Burrell Co., Pittsburgh, PA)) After shaking half an hour, 10ml toluene is added in pipe and formed two layers.Then, the coupling agent described in table 1 is separately added into often In a pipe, and pipe is placed into ultrasonic bath (solid-state/ultrasonic wave T-28B, New Jersey Kearney L＆R manufacture public affairs at room temperature Take charge of (L＆R Manufacturing Company, Kearny, NJ)) in half an hour.Then by pipe in centrifuge (Beckman TJ- 6) it is centrifuged 15 minutes at a high speed and at 25 DEG C in.
B. it analyzes
Table 1 provides the validity of each coupling agent.
The validity of 1. various coupling agents of table.
C. result
It is shown in table 1 the result shows that, DATEM, the citrate of monoglyceride, succinylation monoglyceride and hydroxyl Stearic acid-ethylene glycol copolymer makes highly effective in terms of crosslinking CMC gel stabilities in hydrophobicity toluene solution.
Embodiment 2：The croscarmellose sodium and the citric acid of monoglyceride being blended in advance in cotmar Ester
Present embodiments provide the preparation of the polymer composition of published subject.
It is being set as 100 DEG C of matrix mixer (Plastograph, from New Jersey Luo Xieer parks Brabender Company (Brabender Corp., Rochelle Park, N.J.)) in, by croscarmellose sodium (degree of substitution 0.7, Ac-Di-Sol, Delaware State FMC Corp. of Newark (FMC Corporation, Newark, DE)), the citric acid of monoglyceride Ester (GRINDSTED CITREM, Danisco Coulter Corp of the U.S. (Danisco Cultor USA, Inc.)) and hydrogenated cotton seeds Oily (CSO FLK, Humko companies) mixes 15 minutes.The weight percent of these three components is 60.0%, 3.6% and respectively 36.4%.
Embodiment 3：The croscarmellose sodium and the diacetyl tartrate of monoglyceride being blended in advance
It present embodiments provides and polymer composition is prepared by the method described in embodiment 2, but coupling agent is The diacetyl tartrate (PANODAN, Danisco Coulter Corp of the U.S.) of monoglyceride.
Embodiment 4：The croscarmellose sodium being blended in advance and hydroxy-end capped polybutadiene
It present embodiments provides and polymer composition is prepared by the method described in embodiment 2, but coupling agent is (2000 grams/mol, Krasol LBH2000 of molecular weight, Pennsylvania's west chester are husky for hydroxy-end capped 1,3-butadiene More agate companies (Sartomer Company, West Chester, PA)).These three component (croscarmellose sodium, idols Join agent and cotmar) weight percent be 47.7%, 15.9% and 36.4% respectively.
Embodiment 5：The preparation of chewing-gum preparation
In the present embodiment, 6 kinds of chewing-gum preparations (A-F) are prepared using the mixture being blended in advance in embodiment 4, As described in Table 2.
2. chewing-gum preparation of table
% (weight) A B C D E F
Isoprene-isobutene 4.9 10.0 10.0 10.0 10.0 10.0
SBS block copolymer 4.4 - - - - -
Polyvinyl acetate 22.3 23.9 23.9 23.9 23.9 23.9
Terpene resin 15.4 16.5 16.5 16.5 16.5 16.5
Croscarmellose sodium 19.7 19.6 -
Crospovidone 19.6
Sodium starch glycollate 19.6
Carbomer resin 9.6
The citrate of monoglyceride 1.26 1.26 1.26 1.26
Glyceryl monostearate 5.3 5.6 5.6 5.6 5.6 5.6
Hydroxy-end capped polybutadiene 7.0
Cocoa power 0.54 0.58 0.58 0.58 0.58 0.58
Hard fat 11.7 12.5 12.5 12.5 12.5 12.5
Shortening agent 4.4 4.7 4.7 4.7 4.7 4.7
Lecithin 4.4 4.8 4.8 4.8 4.8 4.8
Calcium carbonate 0.26 0.53 0.53 0.53 10.5 21.4
BHT 0.02 0.03 0.03 0.03 0.03
The polymer used in formulation C has about 100 μ μm of granularity (Polyplasdone XL, New Jersey Wei En cities ISP technology companies (ISP Technologies, Inc., Wayne, NJ)).The polymer used in preparation D is by potato starch Prepare and contain 2.8-4.2% sodium (Primojel, Dutch DMV international corporations of van gogh city (DMV International, Veghel,The Netherlands)).The average equivalent of each carboxyl of the sample used in preparation E is 76 (carbomers 974P, joslyn hi-voltage Nuo Yu company (Noveon, Inc, Cleveland, OH)).
Embodiment 6：The preparation of chewing gum compositions
In the present embodiment, 3 kinds of chewing-gum preparations (G-I) are prepared using the mixture being blended in advance in embodiment 4, As described in Table 3.
3. chewing-gum preparation of table
% (weight) G H I
Isoprene-isobutene 12.7 10.0 10.0
Polyvinyl acetate 30.2 23.9 23.9
Terpene resin 20.8 16.5 16.5
Croscarmellose sodium 19.7
Sodium starch glycollate 13.9
The citrate of monoglyceride 6.94
Glyceryl monostearate 7.15 5.6 5.6
N- cocoyl sarcosines 6.94
Cocoa power 0.58 0.58 0.58
Hard fat 15.9 12.5 12.5
Shortening agent 5.9 4.7 4.7
Lecithin 6.0 4.8 4.8
Calcium carbonate 0.67 0.53 0.53
BHT 0.03 0.03 0.03
Embodiment 7：Compare the preparation of matrix
In the present embodiment, control matrix of the preparation G manufactures without crosslinking hydrocolloid and coupling agent in table 3.
Embodiment 8：Chewing gum is prepared from the matrix containing crosslinking hydrocolloid and coupling agent
In the present embodiment, using preparation G-I as described in Example 6, chewing-gum preparation is manufactured according to table 4.Preparation is It is prepared by usual manner well known by persons skilled in the art.
4. chewing-gum preparation of table
% (weight) 8A 8B 8C 8D Control
A 20.7 -
G 17.6
H 20.7
I 20.7
Embodiment 6 20.7
Croscarmellose sodium 4.4
Hydroxylated lecithin 1.4
Sucrose 60 58.7 60 60 60
Corn syrup 17 17 17 17 17
Glycerine 1.4 1.4 1.4 1.4
Flavoring agent 0.9 0.9 0.9 0.9 0.9
Embodiment 9：The removeability test of chewing gum
The removeability of each in the chewing-gum preparation 8A-8D that manufactures in embodiment 8 such as is present embodiments provided to survey Examination.
A. it prepares
The gum sample of preparation 8A-8D as described in Example 8 and control are washed with water.Through what is chewing by each Chewing gum is chewed group and is taken out from water, and place it on concrete surface, and the top of group is chewed with release paper covering chewing gum.So Afterwards by chewing gum chew group be clipped between 2 concrete blocks and with weight (>120 pounds) compacting.Sample between concrete block is existed It is heated 24 hours under 90 ℉.After removing concrete block and release paper, make sample aging 3 days at ambient temperature.Using mechanical clear It sweeps machine (Tennant 5700XP) and chews a sample from concrete block removal chewing gum.
B. it analyzes
The percentage of each gum sample removed from concrete block is had recorded in table 5.
The removal analysis of table 5.
Chewing gum chews group Remove area %
8A 80
8B 98
8C 94
8D 98
Control 0
C. result
It is in table 5 the result shows that, the chewing gum each tested is chewed group and be can remove, and compareing gum sample can not go It removes.
Although subject matter disclosed herein and its advantage is described in detail, however, it is understood that will by right not departing from In the case of the spirit and scope for seeking the published subject of restriction, various changes, replacement and change can be made herein.This Outside, scope of the present application is not limited to process, machine, manufacture, composition of matter, means, method described in this specification With the specific embodiment of step.As those of ordinary skill in the art will easily recognize according to the disclosure of subject matter disclosed herein Know, can according to subject matter disclosed herein come utilize presently, there are or in the future exploitation to corresponding embodiment party as described herein Formula perform substantially the same function or the process for realizing substantially the same result, machine, manufacture, composition of matter, means, Method or step.Therefore, claim is intended to include such process, machine, manufacture, composition of matter, hand within its scope Section, method or step.
The application refers to patent, patent application publication, product description and scheme in the whole text, and the disclosure of which is for all mesh By reference be incorporated herein entirety.

Claims (8)

1. a kind of chewing gum base, it includes one or more hydrocolloids and one or more coupling agents.
2. chewing gum base according to claim 1 is selected from following hydrocolloid it includes one or more：It is crosslinked carboxylic first Base sodium cellulosate, sodium starch glycollate, crospovidone, and the crosslinked polymer based on acrylic acid of polyalkenyl polyether, Starch-polyacrylic acid sodium graft copolymer and Sodium Polyacrylate.
3. according to claim 1 to 2 any one of them chewing gum base, following coupling is selected from it includes one or more Agent：The diacetyl tartrate (DATEM) of monoglyceride, the citrate of monoglyceride, succinylated monoglycerides, hydroxyl envelope The butadiene at end, hydroxy stearic acid-ethylene glycol copolymer, acrylic acid-chain alkyl acrylate copolymer, styrene-different Isoprene-styrene, s-B-S, ethylene-propylene-ethylene and ethane-acetic acid ethyenyl ester-ethylene block are common Polymers.
4. chewing gum base according to any one of claims 1 to 3 contains about 1% to about 60%w/w hydrocolloids.
5. chewing gum base according to any one of claims 1 to 4 contains about 1% to about 35%w/w hydrocolloids.
6. according to claim 3 to 5 any one of them chewing gum base, contain about 1% to about 15%w/w coupling agents.
7. chewing gum base according to any one of claims 1 to 6, also comprising it is one or more selected from it is following into Point：Elastomer, polyvinyl, elastomer elasticizer, filler, softening agent, wax and combinations thereof.
8. a kind of chewing-gum preparation, it includes according to preceding claims any one of them chewing gum base.
CN201680057841.3A 2015-09-30 2016-09-30 Chewing gum with crosslinked hydrocolloid and coupling agent Pending CN108135212A (en)

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