CN108130744A - A kind of memory leather and its production method - Google Patents

A kind of memory leather and its production method Download PDF

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Publication number
CN108130744A
CN108130744A CN201711383686.7A CN201711383686A CN108130744A CN 108130744 A CN108130744 A CN 108130744A CN 201711383686 A CN201711383686 A CN 201711383686A CN 108130744 A CN108130744 A CN 108130744A
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CN
China
Prior art keywords
production method
dry
finished product
remembering
leather
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711383686.7A
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Chinese (zh)
Inventor
吴平
王志明
张凤
陈利安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan Fu Xin New Material Ltd By Share Ltd
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Kunshan Fu Xin New Material Ltd By Share Ltd
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Priority to CN201711383686.7A priority Critical patent/CN108130744A/en
Publication of CN108130744A publication Critical patent/CN108130744A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses a kind of production method for remembering leather, it is characterized in that, include the following steps:1)Wet-mixing dispensing;2)Wet method bass produces;3)Dry mixed dispensing;4)Dry method veneer;5)Embossing;6)Water is rubbed;7)Product inspection.The advantageous effect that the present invention is reached:By finished product made from this production method because of wire base fabric characteristic, the full three-dimensional sense of leather surface decorative pattern is strong, and decorative pattern fixed effect is good, keeps permanent.

Description

A kind of memory leather and its production method
Technical field
The present invention relates to a kind of memory leather and its production methods, belong to synthetic leather production method technical field.
Background technology
At present, synthetic leather product is increasingly becoming the trend of following prevalence, synthetic leather be widely used in production luggage, clothes, The products such as footwear.Present people increasingly pay close attention to the aesthetic measure of leather, in order to which synthetic leather is made to disclosure satisfy that people to leather surface The demand of aesthetic feeling can be embossed leather, the processing such as spray paint, make full, highlighted, the saturating sense of surface flower pattern of synthetic leather.It is existing Have in technology, synthetic leather is mainly made of base cloth layer, wet method bass layer, dry method overlay coating, at the embossing of synthetic leather, spray paint There are many technical difficulties in reason, easily there is the defects of brightness is low, three-dimensional sense is poor in the finished surface processed, it is impossible to meet people Demand to high-quality.
Invention content
To solve the deficiencies in the prior art, it the purpose of the present invention is to provide a kind of memory leather and its production method, makes Memory leather the full three-dimensional sense of surface detail it is strong, decorative pattern fixed effect is good, can keep permanent.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that:
A kind of memory leather, it is characterized in that, including base cloth layer, the side of the base cloth layer, which is fixed, is fitted with wet method bass layer;It is described Wet method bass layer is equipped with dry method overlay coating;The dry method overlay coating fixation fits in wet method bass layer backwards to the side of base cloth layer Surface;Surface skin lamina is provided on the dry method overlay coating, the surface skin lamina fixation fits in the dry method overlay coating back of the body To the surface of the side of wet method bass layer;The raw material of the wet method bass layer uses the textile fibre cloth of comprising metal wire ingredient.
A kind of production method for remembering leather, it is characterized in that, include the following steps:
1)Wet-mixing dispensing:
A, 5-10kg dimethylformamides and 0.5-2kg mill bases are stirred 80-100 minutes, mixture A is then obtained by filtration, treats With;
B, 100-120kg dimethylformamides and 20-30kg wood powders are stirred 20-30 minutes, and fully 30-40 points of swelling Then clock adds in the mixture A and stirs evenly, obtains mixture B, for use;
C, 100kg polyurethane wet resins are added in the mixture B of step b formation, stir 30-40 minutes, deaeration 40-50 Minute, obtain slurry C;
2)Wet method bass produces:Slurry C painting is scraped on the textile fibre cloth of comprising metal wire ingredient, immerses dimethylformamide water Solidified in solution then by squezzing process, washed again and obtain wet method bass D after being dried;
3)Dry mixed dispensing:By 100kg polyurethane dry method resin, 15-20kg dimethylformamides, 15-20kg butanone, 15- It is stirred after 20kg toluene, 0.5-1.0kg auxiliary agents and the mixing of 3-5kg toners, obtains slurry E.
4)Dry method veneer:Slurry E paintings are scraped in release paper, by adhesive bonding wet method bass D, by dry heel Release paper detaches, and obtains semi-finished product F;
5)Embossing:Semi-finished product F is heated, then acts on what is heated using hydraulic pressure by chilled water in knurling rolls On semi-finished product F, semi-finished product G is obtained;
6)Water is rubbed:Semi-finished product G is divided into 30-40 meters/section, is put into the boarding machine of 40-60 DEG C of water, squezzing after line takes out is rubbed and dries It is dry;
7)Finished product inspection.
A kind of production method of aforementioned memory leather, which is characterized in that the step(2)In, dimethylformamide is water-soluble The mass percentage concentration of liquid is 18-22%.
A kind of production method of aforementioned memory leather, which is characterized in that the step(2)In, squezzing process is at least set Have together.
A kind of production method of aforementioned memory leather, which is characterized in that the step(2)In, linear velocity for 18-20 meters/ min。
A kind of production method of aforementioned memory leather, which is characterized in that the step(3)In, mixing time is 10-15 points Clock.
A kind of production method of aforementioned memory leather, which is characterized in that the step(4)In, oven temperature 90-110 DEG C, the speed of baking oven is 20-25 meters/min.
A kind of production method of aforementioned memory leather, which is characterized in that the step(5)In, F heating temperatures are 170- 180 DEG C, speed is 12-15 meters/min.
A kind of production method of aforementioned memory leather, which is characterized in that the step(5)In, knurling rolls are with nickel roller Or the knurling rolls of silica gel, the temperature of cooling water is 3-5 DEG C.
A kind of production method of aforementioned memory leather, which is characterized in that the step(6)In, the line time is rubbed as 20-40 points Clock, drying temperature are 70-90 DEG C.
The advantageous effect that the present invention is reached:By finished product made from this production method because of wire base fabric characteristic, leather The full three-dimensional sense of surface detail is strong, and decorative pattern fixed effect is good, keeps permanent.
Specific embodiment
The invention will be further described below.Following embodiment is only used for the technical side for clearly illustrating the present invention Case, and be not intended to limit the protection scope of the present invention and limit the scope of the invention.
A kind of memory leather of the present invention, including base cloth layer, the side of base cloth layer, which is fixed, is fitted with wet method bass layer.It is wet Method bass layer is equipped with dry method overlay coating, and the fixation of dry method overlay coating fits in table of the wet method bass layer backwards to the side of base cloth layer Face.Surface skin lamina is provided on dry method overlay coating, the fixation of surface skin lamina fits in dry method overlay coating backwards to wet method bass layer Side surface.The raw material of wet method bass layer uses the textile fibre cloth of comprising metal wire ingredient.
Its production method, includes the following steps:
1)Wet-mixing dispensing:
A, 5-10kg dimethylformamides and 0.5-2kg mill bases are stirred 80-100 minutes, mixture A is then obtained by filtration, treats With;
B, 100-120kg dimethylformamides and 20-30kg wood powders are stirred 20-30 minutes, and fully 30-40 points of swelling Then clock adds in the mixture A and stirs evenly, obtains mixture B, for use;
C, 100kg polyurethane wet resins are added in the mixture B of step b formation, stir 30-40 minutes, deaeration 40-50 Minute, obtain slurry C;
2)Wet method bass produces:
Slurry C painting is scraped on weaving measuring fiber, is immersed in the dimethylformamide in water that mass percentage concentration is 18-22% Solidified then by least one of squezzing process, washed again and obtain wet method bass D, centerline velocities after being dried For 18-20 meters/min;
3)Dry mixed dispensing:
By 100kg polyurethane dry method resin, 15-20kg dimethylformamides, 15-20kg butanone, 15-20kg toluene, 0.5- High-speed stirred after 1.0kg auxiliary agents and the mixing of 3-5kg toners, mixing time is 10-15 minutes, obtains slurry E.
4)Dry method veneer:
Slurry E paintings are scraped in release paper, by adhesive bonding wet method bass D, detaches, obtains by dry followed by release paper Semi-finished product F, in drying process, oven temperature is 90-110 DEG C, and the speed of baking oven is 20-25 meters/min;
5)Embossing:
Semi-finished product F is heated, hydraulic pressure is then utilized by 3-5 DEG C of chilled water in the knurling rolls with nickel roller or silica gel It acts on the semi-finished product F heated, obtains semi-finished product G;Wherein, F heating temperatures be 170-180 DEG C, speed for 12-15 meters/ min;
6)Water is rubbed:
Semi-finished product G is divided into 30-40 meters/section, is put into the boarding machine of 40-60 DEG C of water, line is rubbed 20-40 minutes, is rolled after taking-up Water is dried, and drying temperature is 70-90 DEG C;
7)Product inspection.
Embodiment 1:
1)Wet-mixing dispensing:5kg dimethylformamides and 0.5kg mill bases are stirred 80 minutes, mixture is then obtained by filtration A, for use.100kg dimethylformamides and 20kg wood powders are stirred 20 minutes, and are fully swollen 30 minutes, is then added in mixed It closes object A to stir evenly, obtains mixture B, for use.100kg polyurethane wet resins are added to the mixture B of step b formation In, stirring 30 minutes, deaeration 40 minutes obtain slurry C.
2)Wet method bass produces:Slurry C painting is scraped on weaving measuring fiber, immerses the diformazan that mass percentage concentration is 18% Solidified in base formyl amine aqueous solution then by least one of squezzing process, washed again and obtain wet method after being dried Bass D, centerline velocities are 18 meters/min.
3)Dry mixed dispensing:By 100kg polyurethane dry method resin, 15kg dimethylformamides, 15kg butanone, 15kg first High-speed stirred after benzene, 0.5kg auxiliary agents and the mixing of 3kg toners, mixing time is 10 minutes, obtains slurry E.
4)Dry method veneer:Slurry E paintings are scraped in release paper, by adhesive bonding wet method bass D, by dry heel Release paper detaches, and obtains semi-finished product F, and in drying process, oven temperature is 90 DEG C, and the speed of baking oven is 20 meters/min.
5)Embossing:Semi-finished product F is heated, is then utilized in the knurling rolls with nickel roller or silica gel by 3 DEG C of chilled waters Hydraulic pressure is acted on the semi-finished product F heated, obtains semi-finished product G;Wherein, F heating temperatures be 170 DEG C, speed for 12 meters/ min;
6)Water is rubbed:Semi-finished product G is divided into 30 meters/section, is put into the boarding machine of 40 DEG C of water, rubs line 20 minutes, squezzing after taking-up Drying, drying temperature are 70 DEG C, and finished product is because of wire base fabric characteristic, and the full three-dimensional sense of leather surface decorative pattern is strong, decorative pattern sizing Effect is good.
7)Carry out product inspection.
Embodiment 2
1)Wet-mixing dispensing:By 10kg dimethylformamides and 2kg mill bases high-speed stirred 100 minutes, then it is obtained by filtration mixed Object A is closed, for use.120kg dimethylformamides and 30kg wood powders are stirred 30 minutes, and are fully swollen 40 minutes, Ran Houjia Enter the mixture A to stir evenly, obtain mixture B, for use.100kg polyurethane wet resins are added to step b formation In mixture B, stirring 40 minutes, deaeration 50 minutes obtain slurry C.
2)Wet method bass produces:Slurry C painting is scraped on weaving measuring fiber, immerses the diformazan that mass percentage concentration is 22% Solidified in base formyl amine aqueous solution then by least one of squezzing process, washed again and obtain wet method after being dried Bass D, centerline velocities are 20 meters/min.
3)Dry mixed dispensing:By 100kg polyurethane dry method resin, 20kg dimethylformamides, 20kg butanone, 20kg first It is stirred after benzene, 1.0kg auxiliary agents and the mixing of 5kg toners, mixing time is 15 minutes, obtains slurry E.
4)Dry method veneer:Slurry E paintings are scraped in release paper, by adhesive bonding wet method bass D, by dry heel Release paper detaches, and obtains semi-finished product F, and in drying process, oven temperature is 110 DEG C, and the speed of baking oven is 25 meters/min.
5)Embossing:Semi-finished product F is heated, is then utilized in the knurling rolls with nickel roller or silica gel by 5 DEG C of chilled waters Hydraulic pressure is acted on the semi-finished product F heated, obtains semi-finished product G;Wherein, F heating temperatures be 180 DEG C, speed for 15 meters/ min。
6)Water is rubbed:Semi-finished product G is divided into 40 meters/section, is put into the boarding machine of 60 DEG C of water, line is rubbed 40 minutes, after taking-up Squezzing is dried, and drying temperature is 90 DEG C, and finished product is because of wire base fabric characteristic, and the full three-dimensional sense of leather surface decorative pattern is strong, decorative pattern Fixed effect is good.
7)Product inspection.
Embodiment 3
1)Wet-mixing dispensing:7kg dimethylformamides and 1.2kg mill bases are stirred 90 minutes, mixture is then obtained by filtration A, for use.110kg dimethylformamides and 25kg wood powders are stirred 25 minutes, and are fully swollen 35 minutes, is then added in mixed It closes object A to stir evenly, obtains mixture B, for use.100kg polyurethane wet resins are added to the mixture B of step b formation In, stirring 35 minutes, deaeration 45 minutes obtain slurry C.
2)Wet method bass produces:Slurry C painting is scraped on weaving measuring fiber, immerses the diformazan that mass percentage concentration is 20% Solidified in base formyl amine aqueous solution then by least one of squezzing process, washed again and obtain wet method after being dried Bass D, centerline velocities are 19 meters/min.
3)Dry mixed dispensing:By 100kg polyurethane dry method resin, 17kg dimethylformamides, 17kg butanone, 18kg first High-speed stirred after benzene, 0.8kg auxiliary agents and the mixing of 4kg toners, mixing time is 12 minutes, obtains slurry E.
4)Dry method veneer:Slurry E paintings are scraped in release paper, by adhesive bonding wet method bass D, by dry heel Release paper detaches, and obtains semi-finished product F, and in drying process, oven temperature is 100 DEG C, and the speed of baking oven is 22 meters/min.
5)Embossing:Semi-finished product F is heated, is then utilized in the knurling rolls with nickel roller or silica gel by 4 DEG C of chilled waters Hydraulic pressure is acted on the semi-finished product F heated, obtains semi-finished product G;Wherein, F heating temperatures be 175 DEG C, speed for 14 meters/ min。
6)Water is rubbed:Semi-finished product G is divided into 35 meters/section, is put into the boarding machine of 50 DEG C of water, line is rubbed 30 minutes, after taking-up Squezzing is dried, and drying temperature is 80 DEG C, and finished product is because of wire base fabric characteristic, and the full three-dimensional sense of leather surface decorative pattern is strong, decorative pattern Fixed effect is good.
7)Product inspection.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of memory leather, it is characterized in that, including base cloth layer, the side of the base cloth layer, which is fixed, is fitted with wet method bass layer;Institute Wet method bass layer is stated equipped with dry method overlay coating;The dry method overlay coating fixation fits in wet method bass layer backwards to the one of base cloth layer The surface of side;Surface skin lamina is provided on the dry method overlay coating, the surface skin lamina fixation fits in dry method overlay coating Backwards to the surface of the side of wet method bass layer;The raw material of the wet method bass layer uses the textile fibre cloth of comprising metal wire ingredient.
2. a kind of production method for remembering leather, it is characterized in that, include the following steps:
1)Wet-mixing dispensing:
A, 5-10kg dimethylformamides and 0.5-2kg mill bases are stirred 80-100 minutes, mixture A is then obtained by filtration, treats With;
B, 100-120kg dimethylformamides and 20-30kg wood powders are stirred 20-30 minutes, and fully 30-40 points of swelling Then clock adds in the mixture A and stirs evenly, obtains mixture B, for use;
C, 100kg polyurethane wet resins are added in mixture B, stirring 30-40 minutes, deaeration 40-50 minutes are starched Expect C;
2)Wet method bass produces:Slurry C painting is scraped on the textile fibre cloth of comprising metal wire ingredient, immerses dimethylformamide water Solidified in solution then by squezzing process, washed again and obtain wet method bass D after being dried;
3)Dry mixed dispensing:By 100kg polyurethane dry method resin, 15-20kg dimethylformamides, 15-20kg butanone, 15- It is stirred after 20kg toluene, 0.5-1.0kg levelling agents and the mixing of 3-5kg toners, obtains slurry E;
4)Dry method veneer:Slurry E paintings are scraped in release paper, it is release by dry heel by adhesive bonding wet method bass D Paper detaches, and obtains semi-finished product F;
5)Embossing:Semi-finished product F is heated, then acts on what is heated using hydraulic pressure by chilled water in knurling rolls On semi-finished product F, semi-finished product G is obtained;
6)Water is rubbed:Semi-finished product G is divided into 30-40 meters/section, is put into the boarding machine of 40-60 DEG C of water, squezzing after line takes out is rubbed and dries It is dry;
7)Finished product inspection.
A kind of 3. production method for remembering leather according to claim 2, which is characterized in that the step(2)In, dimethyl The mass percentage concentration of formyl amine aqueous solution is 18-22%.
A kind of 4. production method for remembering leather according to claim 3, which is characterized in that the step(2)In, squezzing work Sequence is at least provided with together.
A kind of 5. production method for remembering leather according to claim 4, which is characterized in that the step(2)In, linear velocity For 18-20m/min.
A kind of 6. production method for remembering leather according to claim 2, which is characterized in that the step(3)In, during stirring Between be 10-15 minutes.
A kind of 7. production method for remembering leather according to claim 2, which is characterized in that the step(4)In, baking oven temperature It is 90-110 DEG C to spend, and the speed of baking oven is 20-25 meters/min.
A kind of 8. production method for remembering leather according to claim 2, which is characterized in that the step(5)In, F heating Temperature is 170-180 DEG C, and speed is 12-15 meters/min.
A kind of 9. production method for remembering leather according to claim 8, which is characterized in that the step(5)In, knurling rolls To carry the knurling rolls of nickel roller or silica gel, the temperature of cooling water is 3-5 DEG C.
A kind of 10. production method for remembering leather according to claim 2, which is characterized in that the step(6)In, rub line Time is 20-40 minutes, and drying temperature is 70-90 DEG C.
CN201711383686.7A 2017-12-20 2017-12-20 A kind of memory leather and its production method Pending CN108130744A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108978240A (en) * 2018-08-20 2018-12-11 福建华夏合成革有限公司 A kind of Stretch leather and preparation method thereof
CN108978241A (en) * 2018-08-20 2018-12-11 福建华夏合成革有限公司 A kind of metal silk protein ultra-soft leather
CN109349707A (en) * 2018-12-06 2019-02-19 昆山协孚新材料股份有限公司 A kind of conductive glove leather and its production method
CN109385907A (en) * 2018-12-06 2019-02-26 昆山协孚新材料股份有限公司 A kind of free-floride hydrolysis embossing clothing leather and its production method

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Publication number Priority date Publication date Assignee Title
GB1396188A (en) * 1971-12-07 1975-06-04 Ockhardt K Process of producing leather fibre materials
JPH1025668A (en) * 1996-07-09 1998-01-27 Achilles Corp Synthetic leather and its production
CN203185744U (en) * 2013-04-28 2013-09-11 温州致富皮业有限公司 Composite leather with formation layer
CN104141236A (en) * 2013-05-10 2014-11-12 昆山协孚人造皮有限公司 Creased embossed leather production method
CN203960642U (en) * 2013-12-24 2014-11-26 浙江高盛合成革有限公司 The clothes synthetic leather that a kind of novel metal is synthetic
CN204780056U (en) * 2015-06-02 2015-11-18 浙江金奥实业有限公司 Leather base cloth of containing metal silk

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1396188A (en) * 1971-12-07 1975-06-04 Ockhardt K Process of producing leather fibre materials
JPH1025668A (en) * 1996-07-09 1998-01-27 Achilles Corp Synthetic leather and its production
CN203185744U (en) * 2013-04-28 2013-09-11 温州致富皮业有限公司 Composite leather with formation layer
CN104141236A (en) * 2013-05-10 2014-11-12 昆山协孚人造皮有限公司 Creased embossed leather production method
CN203960642U (en) * 2013-12-24 2014-11-26 浙江高盛合成革有限公司 The clothes synthetic leather that a kind of novel metal is synthetic
CN204780056U (en) * 2015-06-02 2015-11-18 浙江金奥实业有限公司 Leather base cloth of containing metal silk

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108978240A (en) * 2018-08-20 2018-12-11 福建华夏合成革有限公司 A kind of Stretch leather and preparation method thereof
CN108978241A (en) * 2018-08-20 2018-12-11 福建华夏合成革有限公司 A kind of metal silk protein ultra-soft leather
CN109349707A (en) * 2018-12-06 2019-02-19 昆山协孚新材料股份有限公司 A kind of conductive glove leather and its production method
CN109385907A (en) * 2018-12-06 2019-02-26 昆山协孚新材料股份有限公司 A kind of free-floride hydrolysis embossing clothing leather and its production method

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Application publication date: 20180608