CN108130546A - A kind of preparation method of room temperature low-corrosiveness carbon steel rust remover - Google Patents
A kind of preparation method of room temperature low-corrosiveness carbon steel rust remover Download PDFInfo
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- CN108130546A CN108130546A CN201711491968.9A CN201711491968A CN108130546A CN 108130546 A CN108130546 A CN 108130546A CN 201711491968 A CN201711491968 A CN 201711491968A CN 108130546 A CN108130546 A CN 108130546A
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- carbon steel
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
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Abstract
The present invention relates to a kind of preparation methods of room temperature low-corrosiveness carbon steel rust remover, belong to metal-derusting technical field.The present invention is first using the red bayberry that is rich in organic acid and flavone compound and grape as raw material, the two is blended and is fermented, obtain self-control fruit wine, then it chooses the tealeaves rich in tea polyphenols and the tea seed rich in Tea Saponin grinds and digests, by enzymolysis product and rich lanolated wool blending, again with the lanolin in the tea polyphenols and Tea Saponin and wool in the self-control fruit wine extraction enzymolysis product after heating, it finally obtains and contains organic acid and flavone compound simultaneously, tea polyphenols, lanolin, the extracting solution of Tea Saponin and alcohols, extracting solution and hydrochloric acid blending finally be can be prepared by into room temperature low-corrosiveness carbon steel rust remover, energy consumption needed for room temperature low-corrosiveness carbon steel rust remover produced by the present invention is small, it is and small to steel substrate corrosivity, acid mist is few, and it derusts, the speed to descale is fast, it has broad application prospects.
Description
Technical field
The present invention relates to a kind of preparation methods of room temperature low-corrosiveness carbon steel rust remover, belong to metal-derusting technical field.
Background technology
Straight carbon steel is widely used general, bicycle rack, front fork, mud guard, clothing branch in bicycle, electric bicycle industry
The parts such as frame are using common carbon steel material, and this kind of metal parts later stage is required for making external coating or plating processing, usually
It needs to make component surface the processing such as oil removing, derusting, scale removal, to increase deep layer binding force and antirust ability, so part
Surface cleaning problem is always one of domestic bicycle trade focus of attention problem.
And most common straight carbon steel rust remover is inorganic acid at present, and straight carbon steel is washed with strong acid under the high temperature conditions
It washs, the defects of this method is that required energy consumption is big, and strong acid is big to steel substrate corrosivity, acid mist is more, and is derusted, except oxidation
The speed of skin is slower.
Therefore, invention is a kind of can just work at normal temperatures, and, derusting fireballing environmental protection small to steel substrate corrosivity
Type carbon steel rust remover has positive meaning to metal-derusting technical field.
Invention content
Present invention mainly solves the technical issues of, be inorganic acid for common carbon steel rust remover at present, in high temperature item
Straight carbon steel is washed with strong acid under part, the defects of this method is that required energy consumption is big, and strong acid corrodes steel substrate
Property it is big, acid mist is more, and derusts, the slow defect that descales, provide a kind of room temperature low-corrosiveness carbon steel rust remover
Preparation method.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of preparation method of room temperature low-corrosiveness carbon steel rust remover, it is characterised in that specifically preparation process is：
（1）Red bayberry and new fresh grape are weighed, is put into tissue pulverizer after being rinsed 1~2 time with deionized water, crushing 20~
30min obtains mixed powder and minces, then mixed powder is minced and obtains fermentation substrate with after glucose mixing；
（2）Fermentation substrate is fitted into fermentation tank, control charge weight is the 4/5 of fermenter volume, after loading, uses cork
Fermentation tank mouth is clogged, is sealed by fermentation 25~30 days, after fermentation, is separated by filtration to obtain filtrate, it is spare；
（3）By mass ratioes is waited to weigh tealeaves and tea seed, tealeaves and tea seed are put into mortar, 20~30min is ground and obtains
Crushed material is fitted into after mixing crushed material, water and cellulase and pectase in enzymatic vessel, and heat preservation 8~10h of enzymolysis is obtained
Enzymolysis product；
（4）It is fitted into the three-necked flask with blender, uses after above-mentioned enzymolysis product and wool and spare filtrate are mixed
Stopper clogs the bottleneck of three-necked flask, then three-necked flask is moved into oil bath pan, heat temperature raising, starts blender stirring extraction；
（5）After treating said extracted, by three-necked flask extract move into centrifuge in, centrifugal treating, it is isolated on
Layer liquid, by the mixed in hydrochloric acid that upper liquid and mass fraction are 30%, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
Step（1）Described in red bayberry and new fresh grape mass ratio be 1:2, the mass ratio that mixed powder minces with glucose
It is 5:1.
Step（2）Described in sealing and fermenting temperature be 22~25 DEG C.
Step（3）Described in crushed material, water and cellulase and pectase mass ratio be 10:20:1:1, heat preservation
The temperature of enzymolysis is 30~35 DEG C.
Step（4）Described in enzymolysis product and wool and the mass ratio of spare filtrate be 1:1:10, heat temperature raising
Temperature for 100~120 DEG C, the rotating speed for stirring extraction is 100~200r/min, and the time for stirring extraction is 20~30min.
Step（5）Described in centrifugal treating rotating speed for 2000~3000r/min, time of centrifugal treating for 15~
The hydrochloric acid volume mass ratio that 20min, upper liquid and mass fraction are 30% is 3:1.
The beneficial effects of the invention are as follows：
（1）The two is blended first using the red bayberry for being rich in organic acid and flavone compound and grape as raw material by the present invention
Fermentation, obtains self-control fruit wine, then chooses the tealeaves rich in tea polyphenols and the tea seed rich in Tea Saponin grinds and digests, will
Enzymolysis product is blended with rich lanolated wool, then tea polyphenols and tea in enzymolysis product are extracted with the self-control fruit wine after heating
Lanolin in saponin and wool finally obtains and contains organic acid and flavone compound, tea polyphenols, lanolin, tea simultaneously
Extracting solution and hydrochloric acid blending finally can be prepared by room temperature low-corrosiveness carbon steel rust remover, this hair by saponin and the extracting solution of alcohols
Bright obtained room temperature low-corrosiveness carbon steel rust remover can derust work at normal temperatures, and required low energy consumption；
（2）Contain natural surfactant Tea Saponin and lanolin in room temperature low-corrosiveness carbon steel rust remover produced by the present invention,
Wherein lanolin has good cohesive force to metal surface, and the two natural surfactant can promote cleaning agent and Metal Substrate
The wetting in body surface face by soaking, emulsifying, destroying or weakening the adhesive force of metal surface greasy dirt, ensures derusting organic acid and salt
Sour component can be in direct contact with metal, so as to improve the efficiency of derusting, in addition contain organic acid in fruit wine, its energy and straight carbon steel
The iron ion on surface generates coordination, accelerates the dissolving of iron rust oxide skin, has shortened the derusting time, realized to the disposable of straight carbon steel
Oil removing, the effect for derusting, descaling；
（3）During the use of room temperature low-corrosiveness carbon steel rust remover of the present invention, on the one hand produced by during wine fermentation
Raw free property carboxyl and the oxide of straight carbon steel matrix surface chemically react, and straight carbon steel gold is removed in the form of metallic soap
The oxidation film of metal surface, another aspect organic acid and metal oxide form metal salts of organic acids, and by the moisture in rust remover
Dissolving removal, and the remaining acid ingredient for remaining in straight carbon steel surface then can completely be waved under the action of the alcohols material in fruit wine
Hair or activity are greatly lowered, and are kept inertia under atmospheric environment, are reduced the corrosivity to straight carbon steel surface, and are dissolved in fruit wine
Tea polyphenols and flavone compound have splendid inoxidizability, can be sent out to avoid the straight carbon steel matrix after being derusted by organic acid
Raw secondary oxidation, has broad application prospects.
Specific embodiment
It is 1 in mass ratio:2 weigh red bayberry and new fresh grape, and tissue pulverizer is put into after being rinsed 1~2 time with deionized water
In, 20~30min of crushing obtains mixed powder and minces, then it is 5 in mass ratio that mixed powder, which is minced with glucose,:It is obtained after 1 mixing
Fermentation substrate；Fermentation substrate is fitted into fermentation tank, control charge weight is the 4/5 of fermenter volume, after loading, uses cork
Fermentation tank mouth is clogged, is sealed by fermentation 25~30 days at being 22~25 DEG C in temperature, after fermentation, is separated by filtration and is filtered
Liquid, it is spare；By mass ratioes is waited to weigh tealeaves and tea seed, tealeaves and tea seed are put into mortar, 20~30min is ground and obtains
Crushed material, water and cellulase and pectase are 10 in mass ratio by crushed material:20:1:It is fitted into enzymatic vessel after 1 mixing,
8~10h of heat preservation enzymolysis, obtains enzymolysis product at 30~35 DEG C；Enzymolysis product and wool and spare filtrate are pressed into quality
Than being 1:1:The bottleneck for clogging three-necked flask in the three-necked flask with blender with stopper is fitted into, then by three mouthfuls after 10 mixing
Flask is moved into oil bath pan, is heated to 100~120 DEG C, is started blender and is stirred extraction with the rotating speed of 100~200r/min
20~30min；After to be extracted, the extract in three-necked flask is moved into centrifuge, and with 2000~3000r/min's
15~20min of rotating speed centrifugal treating, isolated upper liquid are in mass ratio 3:1 by salt that upper liquid and mass fraction are 30%
Acid mixing, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
Example 1
It is 1 in mass ratio:2 weigh red bayberry and new fresh grape, are put into tissue pulverizer after being rinsed 1 time with deionized water, crush
20min obtains mixed powder and minces, then it is 5 in mass ratio that mixed powder, which is minced with glucose,:Fermentation substrate is obtained after 1 mixing；It will
Fermentation substrate is fitted into fermentation tank, and control charge weight is the 4/5 of fermenter volume, and after loading, fermentation is clogged with cork
Tank mouth is sealed by fermentation 25 days at being 22 DEG C in temperature, after fermentation, is separated by filtration to obtain filtrate, spare；Claim by mass ratioes are waited
Tealeaves and tea seed are taken, tealeaves and tea seed are put into mortar, 20min is ground and obtains crushed material, by crushed material, water and fiber
Plain enzyme and pectase are 10 in mass ratio:20:1:It is fitted into enzymatic vessel after 1 mixing, heat preservation enzymolysis 8h, obtains enzyme at 30 DEG C
Solve product；It is 1 in mass ratio by enzymolysis product and wool and spare filtrate:1:Three with blender are packed into after 10 mixing
In mouth flask, the bottleneck of three-necked flask is clogged with stopper, then three-necked flask is moved into oil bath pan, be heated to 100 DEG C, open
Dynamic blender is with the rotating speed stirring extraction 20min of 100r/min；After to be extracted, by the extract in three-necked flask move into from
In scheming, and with the rotating speed centrifugal treating 15min of 2000r/min, isolated upper liquid is in mass ratio 3:1 by upper liquid
With the mixed in hydrochloric acid that mass fraction is 30%, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
Example 2
It is 1 in mass ratio:2 weigh red bayberry and new fresh grape, are put into tissue pulverizer after being rinsed 1 time with deionized water, crush
25min obtains mixed powder and minces, then it is 5 in mass ratio that mixed powder, which is minced with glucose,:Fermentation substrate is obtained after 1 mixing；It will
Fermentation substrate is fitted into fermentation tank, and control charge weight is the 4/5 of fermenter volume, and after loading, fermentation is clogged with cork
Tank mouth is sealed by fermentation 28 days at being 23 DEG C in temperature, after fermentation, is separated by filtration to obtain filtrate, spare；Claim by mass ratioes are waited
Tealeaves and tea seed are taken, tealeaves and tea seed are put into mortar, 25min is ground and obtains crushed material, by crushed material, water and fiber
Plain enzyme and pectase are 10 in mass ratio:20:1:It is fitted into enzymatic vessel after 1 mixing, heat preservation enzymolysis 9h, obtains enzyme at 33 DEG C
Solve product；It is 1 in mass ratio by enzymolysis product and wool and spare filtrate:1:Three with blender are packed into after 10 mixing
In mouth flask, the bottleneck of three-necked flask is clogged with stopper, then three-necked flask is moved into oil bath pan, be heated to 110 DEG C, open
Dynamic blender is with the rotating speed stirring extraction 25min of 150r/min；After to be extracted, by the extract in three-necked flask move into from
In scheming, and with the rotating speed centrifugal treating 18min of 2500r/min, isolated upper liquid is in mass ratio 3:1 by upper liquid
With the mixed in hydrochloric acid that mass fraction is 30%, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
Example 3
It is 1 in mass ratio:2 weigh red bayberry and new fresh grape, are put into tissue pulverizer after being rinsed 2 times with deionized water, crush
30min obtains mixed powder and minces, then it is 5 in mass ratio that mixed powder, which is minced with glucose,:Fermentation substrate is obtained after 1 mixing；It will
Fermentation substrate is fitted into fermentation tank, and control charge weight is the 4/5 of fermenter volume, and after loading, fermentation is clogged with cork
Tank mouth is sealed by fermentation 30 days at being 25 DEG C in temperature, after fermentation, is separated by filtration to obtain filtrate, spare；Claim by mass ratioes are waited
Tealeaves and tea seed are taken, tealeaves and tea seed are put into mortar, 30min is ground and obtains crushed material, by crushed material, water and fiber
Plain enzyme and pectase are 10 in mass ratio:20:1:It is fitted into enzymatic vessel after 1 mixing, heat preservation enzymolysis 10h, obtains at 35 DEG C
Enzymolysis product；It is 1 in mass ratio by enzymolysis product and wool and spare filtrate:1:It is packed into after 10 mixing with blender
In three-necked flask, the bottleneck of three-necked flask is clogged with stopper, then three-necked flask is moved into oil bath pan, is heated to 120 DEG C,
Start blender with the rotating speed stirring extraction 30min of 200r/min；After to be extracted, the extract in three-necked flask is moved into
In centrifuge, and with the rotating speed centrifugal treating 20min of 3000r/min, isolated upper liquid is in mass ratio 3:1 by upper strata
Liquid and the mixed in hydrochloric acid that mass fraction is 30%, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
Reference examples
Using traditional hydrochloride derusting agent as reference examples
The derusting effect of hydrochloride derusting agent in room temperature low-corrosiveness carbon steel rust remover produced by the present invention and reference examples is carried out
Detection, testing result are as shown in table 1：
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Derust temperature（℃） | 20~40 | 20~40 | 20~40 | 70~90 |
| It derusts the time（min） | 8 | 7 | 6 | 45 |
| Rate of corrosion（g/dm2） | 0.040 | 0.038 | 0.035 | 0.418 |
| Corrosion inhibition rate（%） | 92 | 94 | 95 | 80 |
| Derusting rate（%） | 100 | 100 | 100 | 100 |
As detection data in upper table it is found that energy consumption needed for room temperature low-corrosiveness carbon steel rust remover produced by the present invention is small and right
Steel substrate corrosivity is small, acid mist is few, and derust, the speed that descales it is fast, have broad application prospects.
Claims (6)
1. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover, it is characterised in that specifically preparation process is：
（1）Red bayberry and new fresh grape are weighed, is put into tissue pulverizer after being rinsed 1~2 time with deionized water, crushing 20~
30min obtains mixed powder and minces, then mixed powder is minced and obtains fermentation substrate with after glucose mixing；
（2）Fermentation substrate is fitted into fermentation tank, control charge weight is the 4/5 of fermenter volume, after loading, uses cork
Fermentation tank mouth is clogged, is sealed by fermentation 25~30 days, after fermentation, is separated by filtration to obtain filtrate, it is spare；
（3）By mass ratioes is waited to weigh tealeaves and tea seed, tealeaves and tea seed are put into mortar, 20~30min is ground and obtains
Crushed material is fitted into after mixing crushed material, water and cellulase and pectase in enzymatic vessel, and heat preservation 8~10h of enzymolysis is obtained
Enzymolysis product；
（4）It is fitted into the three-necked flask with blender, uses after above-mentioned enzymolysis product and wool and spare filtrate are mixed
Stopper clogs the bottleneck of three-necked flask, then three-necked flask is moved into oil bath pan, heat temperature raising, starts blender stirring extraction；
（5）After treating said extracted, by three-necked flask extract move into centrifuge in, centrifugal treating, it is isolated on
Layer liquid, by the mixed in hydrochloric acid that upper liquid and mass fraction are 30%, up to room temperature low-corrosiveness carbon steel rust remover after tinning.
2. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover according to claim 1, it is characterised in that：Step
（1）Described in red bayberry and new fresh grape mass ratio be 1:2, it is 5 that mixed powder, which minces with the mass ratio of glucose,:1.
3. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover according to claim 1, it is characterised in that：Step
（2）Described in sealing and fermenting temperature be 22~25 DEG C.
4. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover according to claim 1, it is characterised in that：Step
（3）Described in crushed material, water and cellulase and pectase mass ratio be 10:20:1:1, the temperature for keeping the temperature enzymolysis is
30~35 DEG C.
5. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover according to claim 1, it is characterised in that：Step
（4）Described in enzymolysis product and wool and the mass ratio of spare filtrate be 1:1:10, the temperature of heat temperature raising for 100~
120 DEG C, the rotating speed for stirring extraction is 100~200r/min, and the time for stirring extraction is 20~30min.
6. a kind of preparation method of room temperature low-corrosiveness carbon steel rust remover according to claim 1, it is characterised in that：Step
（5）Described in centrifugal treating rotating speed for 2000~3000r/min, time of centrifugal treating is 15~20min, upper liquid and
The hydrochloric acid volume mass ratio that mass fraction is 30% is 3:1.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112410795A (en) * | 2019-08-20 | 2021-02-26 | 上海湜清新材料科技有限公司 | Shoveling liquid and preparation process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105908197A (en) * | 2016-06-22 | 2016-08-31 | 山西艾尔德添加剂新技术有限公司 | Pickling additive for surface oxide scale of stainless steel material and preparation method therefor and pickling method thereof |
| CN105925993A (en) * | 2016-06-02 | 2016-09-07 | 安徽开林新材料股份有限公司 | Steel surface waterborne treatment agent and production method |
| CN106086902A (en) * | 2016-08-05 | 2016-11-09 | 宁波高新区斯汀环保科技有限公司 | A kind of preparation method of environmental type water base metal cleaning agent |
| CN106191875A (en) * | 2016-07-13 | 2016-12-07 | 吴迪 | A kind of preparation method of environment-friendly type composition metal abluent |
| CN106400033A (en) * | 2016-11-11 | 2017-02-15 | 中北大学 | Sunflower head corrosion inhibitor extract and method for preparing metal acid-pickling solution using the same |
| CN106637236A (en) * | 2016-10-19 | 2017-05-10 | 广西钱隆投资管理有限公司 | Domestic rust remover |
-
2017
- 2017-12-30 CN CN201711491968.9A patent/CN108130546A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925993A (en) * | 2016-06-02 | 2016-09-07 | 安徽开林新材料股份有限公司 | Steel surface waterborne treatment agent and production method |
| CN105908197A (en) * | 2016-06-22 | 2016-08-31 | 山西艾尔德添加剂新技术有限公司 | Pickling additive for surface oxide scale of stainless steel material and preparation method therefor and pickling method thereof |
| CN106191875A (en) * | 2016-07-13 | 2016-12-07 | 吴迪 | A kind of preparation method of environment-friendly type composition metal abluent |
| CN106086902A (en) * | 2016-08-05 | 2016-11-09 | 宁波高新区斯汀环保科技有限公司 | A kind of preparation method of environmental type water base metal cleaning agent |
| CN106637236A (en) * | 2016-10-19 | 2017-05-10 | 广西钱隆投资管理有限公司 | Domestic rust remover |
| CN106400033A (en) * | 2016-11-11 | 2017-02-15 | 中北大学 | Sunflower head corrosion inhibitor extract and method for preparing metal acid-pickling solution using the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112410795A (en) * | 2019-08-20 | 2021-02-26 | 上海湜清新材料科技有限公司 | Shoveling liquid and preparation process thereof |
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