CN108128879B - Oxidizing gas synergistic system - Google Patents
Oxidizing gas synergistic system Download PDFInfo
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- CN108128879B CN108128879B CN201711416653.8A CN201711416653A CN108128879B CN 108128879 B CN108128879 B CN 108128879B CN 201711416653 A CN201711416653 A CN 201711416653A CN 108128879 B CN108128879 B CN 108128879B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F7/00—Magnets
- H01F7/06—Electromagnets; Actuators including electromagnets
- H01F7/20—Electromagnets; Actuators including electromagnets without armatures
- H01F7/202—Electromagnets for high magnetic field strength
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- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses an oxidizing gas synergistic system, which comprises an oxidizing gas input device, an electromagnetic fluid treatment device, a water input device, a gas-liquid mixing device, an oxidation reaction device and a gas flow regulating valve, wherein the oxidizing gas input device is connected with the electromagnetic fluid treatment device; the oxidation reaction device is provided with a gas-liquid input end and a water outlet end; the gas output end of the oxidizing gas input device is communicated with the gas inlet end of the gas-liquid mixing device through a gas flow regulating valve and an electromagnetic fluid processing device, and the water output end of the water input device is communicated with the water inlet end of the gas-liquid mixing device; the gas-liquid output end of the gas-liquid mixing device is communicated with the gas-liquid input end of the oxidation reaction device; the electromagnetic fluid processing device comprises a metal tube, a wire winding coil wound on the metal tube and an electromagnetic pulse generator electrically connected with the wire winding coil; the electromagnetic pulse generator is used for generating an analog variable frequency direct current pulse signal. The invention can improve the water treatment effect of the oxidizing gas, reduce the consumption of the oxidizing gas and further reduce the water treatment cost.
Description
Technical Field
The invention relates to the technical field of water treatment, in particular to an oxidizing gas synergistic system.
Background
With the rapid development of modern industry, the quantity and the variety of organic compounds are increased day by day, which causes a great amount of water pollution; after industrial wastewater, domestic sewage and farmland drainage flow into a water body, serious pollution can be caused, and the health of people is harmed. In the prior art, water treatment is usually realized by the reaction of oxidizing gas and organic matters in water, ozone catalytic oxidation and aeration oxidation are two common technologies, and ozone or oxygen is added into water to react the organic matters in the water with the ozone or the oxygen, so that the pollution of the water body is reduced. However, the water treatment effect by using the oxidizing gas is poor, the consumption of the oxidizing gas is high, the utilization rate is low, and the water treatment cost is always kept at a high level.
Disclosure of Invention
The inventors have found that when water is treated with an oxidizing gas, the degree of binding between the oxidizing gas and water is not so high that the oxidizing gas does not react sufficiently with water, which causes problems such as a large amount of oxidizing gas consumed, an inferior water treatment effect, and high water treatment costs.
The technical problem to be solved by the invention is to provide an oxidizing gas synergistic system, which can effectively improve the water purification treatment effect of the oxidizing gas, reduce the consumption of the oxidizing gas and further reduce the water treatment cost in the reaction of oxidizing molecules and water.
In order to solve the above technical problem, an embodiment of the present invention provides an oxidizing gas synergistic system, including an oxidizing gas input device, an electromagnetic fluid processing device, a water input device, a gas-liquid mixing device, an oxidation reaction device, and a gas flow regulating valve;
the oxidation reaction device is provided with a gas-liquid input end for allowing a gas-liquid mixture of water to be treated and oxidizing gas to enter the oxidation reaction device and a water outlet end for allowing the water subjected to oxidation treatment to flow out of the oxidation reaction device;
the gas output end of the oxidizing gas input device is communicated with the gas inlet end of the gas-liquid mixing device sequentially through the gas flow regulating valve and the electromagnetic fluid processing device, and the water output end of the water input device is communicated with the water inlet end of the gas-liquid mixing device; the gas-liquid output end of the gas-liquid mixing device is communicated with the gas-liquid input end of the oxidation reaction device;
the electromagnetic fluid processing device comprises a metal tube, a wire winding coil wound on the metal tube and an electromagnetic pulse generator electrically connected with the wire winding coil; the electromagnetic pulse generator is used for generating an analog variable frequency direct current pulse signal.
In an alternative embodiment, the oxidizing gas supply device is used for supplying ozone, oxygen or air.
In an alternative embodiment, the gas-liquid mixing device is a venturi or a dissolved air pump.
In an alternative embodiment, the wire winding coil includes several groups of coils having the same winding direction and the same winding wire.
In order to achieve the same purpose, the invention also provides another oxidizing gas synergistic system, which comprises an oxidizing gas input device, an electromagnetic fluid treatment device, an aeration device, an oxidation reaction device and a gas flow regulating valve;
the oxidation reaction device is provided with a gas input end for allowing oxidizing gas to enter and a water outlet end for allowing water subjected to oxidation treatment to flow out;
the gas output end of the oxidizing gas input device is communicated with the gas input end of the oxidation reaction device sequentially through the gas flow regulating valve and the electromagnetic fluid processing device;
the aeration device is arranged in the oxidation reaction device; the input end of the aeration device is connected with the gas input end of the oxidation reaction device;
the electromagnetic fluid processing device comprises a metal tube, a wire winding coil wound on the metal tube and an electromagnetic pulse generator electrically connected with the wire winding coil; the electromagnetic pulse generator is used for generating an analog variable frequency direct current pulse signal.
In an optional embodiment, the system further comprises a water input device, and the oxidation reaction device is also provided with a water inlet end for allowing water to be treated to enter; and the water output end of the water input device is communicated with the water inlet end of the oxidation reaction device.
In an alternative embodiment, the aeration device comprises a gas conveying pipeline and a plurality of aeration heads arranged on the gas conveying pipeline; and the gas input end of the gas conveying pipe is connected with the input end of the aeration device.
In an alternative embodiment, the oxidizing gas supply device is used for supplying ozone, oxygen or air.
In an alternative embodiment, the wire winding coil includes several groups of coils having the same winding direction and the same winding wire.
In an optional embodiment, the electromagnetic pulse generator comprises a positive direct current output pulse end and a negative direct current output pulse end, wherein the positive direct current output pulse end is electrically connected with one end of the wire winding coil, and the negative direct current output pulse end is electrically connected with the other end of the wire winding coil.
Compared with the prior art, the oxidizing gas synergy system provided by the embodiment of the invention has the beneficial effects that: the oxidizing gas before entering the oxidation reaction device is pretreated, so that the oxidizing gas is subjected to the action of a variable-frequency direct-current pulse electromagnetic field when passing through the electromagnetic fluid treatment device, the intermolecular acting force is reduced, the association degree of molecular groups in the oxidizing gas is reduced, the molecular groups are reduced, free single molecules are increased, the mixing degree of the oxidizing gas and water is higher, and the improvement of the gas-liquid reaction of the oxidizing gas and the water is facilitated; meanwhile, after the oxidizing gas passes through the electromagnetic fluid treatment device, under the action of a pulse electric field, external electrons of the oxidizing gas deviate, the polarity is enhanced, polar molecules are favorable for being associated with water molecules with the same polarity, the association degree of the oxidizing gas and water is improved, and the gas-liquid reaction of the oxidizing gas and the water is more sufficient. Therefore, the embodiment of the invention can effectively improve the water purification effect of the oxidizing gas, reduce the consumption of the oxidizing gas and further reduce the water treatment cost.
Drawings
In order to more clearly illustrate the technical solution of the present invention, the drawings used in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained based on these drawings without creative efforts.
FIG. 1 is a schematic structural view of a first embodiment of an oxidizing gas enhancement system of the present invention;
FIG. 2 is a schematic diagram of an electromagnetic fluid treatment apparatus in an oxidizing gas enhancement system according to the present invention;
FIG. 3 is a schematic structural view of a second embodiment of an oxidizing gas enhancing system of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1 and fig. 2, fig. 1 is a schematic structural diagram of a first embodiment of an oxidizing gas synergistic system of the present invention, and fig. 2 is a schematic structural diagram of an electromagnetic fluid processing apparatus in the oxidizing gas synergistic system of the present invention. The embodiment of the invention provides an oxidizing gas synergy system, which comprises an oxidizing gas input device 11, an electromagnetic fluid treatment device 12, a water input device 13, a gas-liquid mixing device 14, an oxidation reaction device 15 and a gas flow regulating valve 16;
the oxidation reaction device 15 is provided with a gas-liquid input end for allowing a gas-liquid mixture of water to be treated and oxidizing gas to enter the oxidation reaction device and a water outlet end for allowing water subjected to oxidation treatment to flow out of the oxidation reaction device;
the gas output end of the oxidizing gas input device 11 is communicated with the gas inlet end of the gas-liquid mixing device 14 sequentially through the gas flow regulating valve 16 and the electromagnetic fluid processing device 12, and the water output end of the water input device 13 is communicated with the water inlet end of the gas-liquid mixing device 14; the gas-liquid output end of the gas-liquid mixing device 14 is communicated with the gas-liquid input end of the oxidation reaction device 15;
the electromagnetic fluid processing device 12 comprises a metal tube 121, a wire winding coil 122 wound on the metal tube 121 and an electromagnetic pulse generator 123 electrically connected with the wire winding coil 122; the electromagnetic pulse generator 123 is configured to generate an analog variable frequency dc pulse signal.
It should be understood that the gas output end of the oxidizing gas input device 11 is communicated with the gas inlet end of the gas-liquid mixing device 14 sequentially through the gas flow regulating valve 16 and the electromagnetic fluid processing device 12, specifically: the gas output end of the oxidizing gas input device 11 is communicated with the gas inlet end of the gas-liquid mixing device 14 sequentially through the gas flow regulating valve 16 and the metal pipe 121.
The working principle of the electromagnetic fluid treatment device 12 is as follows: the electromagnetic pulse generator 123 generates an analog variable frequency direct current pulse signal and transmits the analog variable frequency direct current pulse signal to the wire winding coil 122, and the wire winding coil 122 generates electromagnetic induction according to the analog variable frequency direct current pulse signal to generate a variable frequency direct current pulse electromagnetic field, and the variable frequency direct current pulse electromagnetic field is conducted to the oxidizing gas through the metal tube 121. When the oxidizing gas flows through the electromagnetic fluid treatment device 12, the variable frequency direct current pulse electromagnetic field weakens the intermolecular action of the oxidizing gas molecular groups, so that the oxidizing gas molecular groups become small, the free single molecules are increased, and the contact between the oxidizing gas and water is more sufficient; meanwhile, after the oxidizing gas molecules pass through the variable-frequency direct-current pulse electromagnetic field, under the action of the pulse electric field, external electrons of the oxidizing gas molecules generate deviation, meanwhile, the polarity is enhanced, polar molecules are favorable for being associated with water molecules with the same polarity, the association degree of the oxidizing gas and water is improved, and the gas-liquid reaction of the oxidizing gas and the water is more sufficient.
The working principle of the embodiment of the invention is as follows: the oxidizing gas input device 11 is used for outputting oxidizing gas, the gas flow of the oxidizing gas entering the oxidation reaction device is controlled by the gas flow regulating valve 16, and the oxidizing gas enters the gas-liquid mixing device 14 through the gas inlet end after being treated by the electromagnetic fluid treatment device 12; the water is output by the water input device 13 and is connected to the water inlet end of the gas-liquid mixing device 14; the oxidizing gas and water are mixed and then enter the oxidation reaction device 15 for reaction, so that the water quality purification treatment is realized. Because the oxidizing gas is pretreated before gas-liquid mixing, the intermolecular force of the oxidizing gas molecules is weakened and the molecular groups are reduced under the action of a pulse electric field, and if the gas belongs to polar molecules, such as ozone, the property of the gas presents polarity, so that the gas-liquid reaction of the oxidizing gas and water is more sufficient, and the water quality purification treatment effect is improved.
In an alternative embodiment, the oxidizing gas supply device 11 is used for supplying ozone, oxygen or air. Specifically, the oxidizing gas input means 11 may be, but is not limited to, an ozone generator, an oxygen generator, or an air compressor. Ozone and oxygen both have oxidability, can generate oxidation reaction with water, purify water, and the promotion efficiency of the ozone serving as polar molecules is superior to that of oxygen of non-polar molecules.
In an alternative embodiment, the gas-liquid mixing device 14 is a venturi or a dissolved air pump.
In an alternative embodiment, the wire winding coil 122 includes several groups of coils with the same winding direction and the same winding wire. Preferably, the number of the coil groups is even, and each two groups of the coils form a mutual induction coil, so that the mutual induction effect between the coils is increased, and the conversion efficiency of electromagnetic energy can be effectively enhanced.
In an alternative embodiment, the electromagnetic pulse generator 123 includes a positive dc output pulse terminal electrically connected to one end of the wire winding coil 122 and a negative dc output pulse terminal electrically connected to the other end of the wire winding coil 122.
Correspondingly, the electromagnetic pulse generator 123 has a plurality of sets of positive and negative dc output pulse terminals, and each set of positive and negative dc output pulse terminals is correspondingly connected to two ends of a set of wire winding coils 122.
In an alternative embodiment, the electromagnetic pulse generator 123 further comprises an ac power input 124. The ac power input terminal 124 is used for supplying power to the electromagnetic pulse generator 123. Specifically, the ac power input 124 may be connected to a standard 220V ac power source.
In the embodiment, the electromagnetic fluid treatment device 12 is used for pretreating the oxidizing gas, so that when the oxidizing gas is air or oxygen, the water treatment efficiency can be improved by 10-20%; when the oxidizing gas is ozone, the water treatment efficiency can be improved by 20-80%.
Referring to fig. 2 and fig. 3, fig. 3 is a schematic structural diagram of a second embodiment of an oxidizing gas boosting system according to the present invention. Since the structure of the electromagnetic fluid treatment apparatus in this embodiment is the same as that of the electromagnetic fluid treatment apparatus in the first embodiment, please refer to fig. 2 for a schematic structural diagram of the electromagnetic fluid treatment apparatus in this embodiment. The embodiment of the invention provides another oxidizing gas synergistic system, which comprises an oxidizing gas input device 21, an electromagnetic fluid treatment device 22, an aeration device 23, an oxidation reaction device 24 and a gas flow regulating valve 25;
the oxidation reaction device 24 is provided with a gas input end for allowing oxidizing gas to enter and a water outlet end for allowing water after oxidation treatment to flow out;
the gas output end of the oxidizing gas input device 21 is communicated with the gas input end of the oxidation reaction device 24 sequentially through the gas flow regulating valve 25 and the electromagnetic fluid processing device 22;
the aeration device 23 is arranged in the oxidation reaction device 24; the input end of the aeration device 23 is connected with the gas input end of the oxidation reaction device 24;
the electromagnetic fluid processing device 22 comprises a metal tube 121, a wire winding coil 122 wound on the metal tube 121 and an electromagnetic pulse generator 123 electrically connected with the wire winding coil 122; the electromagnetic pulse generator 123 is configured to generate an analog variable frequency dc pulse signal.
The working principle of the solenoid fluid treatment device 22 in the embodiment of the present invention is the same as that of the solenoid fluid treatment device 22 in the first embodiment, and will not be described herein.
The working principle of the embodiment of the invention is as follows: the oxidizing gas input device 21 is used for outputting oxidizing gas, the gas flow rate of the oxidizing gas entering the oxidation reaction device is controlled by the gas flow rate regulating valve 25, the oxidizing gas enters the aeration device 23 through the gas input end after being treated by the electromagnetic fluid treatment device 22, and the oxidizing gas is dissolved in water through the aeration device 23 to play a role in water treatment. Because the oxidizing gas is pretreated before gas-liquid mixing, the intermolecular force of the oxidizing gas molecules is weakened and the molecular groups are reduced under the action of the pulse electric field, and if the oxidizing gas belongs to polar molecules, the gas has polarity, so that the gas-liquid reaction of the oxidizing gas and water is more sufficient, and the water quality purification treatment effect is improved.
In the present embodiment, the water in the oxidation reaction device 24 is treated in a static state, and it is understood that the gas input end of the oxidation reaction device 24 may be located at the upper end portion of the oxidation reaction device 24.
In an alternative embodiment, the system further comprises a water input device 26; the oxidation reaction device 24 is also provided with a water inlet end for allowing water to be treated to enter; the water output end of the water input device 26 is communicated with the water inlet end of the oxidation reaction device 24. Water is input through the water input device 26, and dynamic water treatment is achieved.
In an alternative embodiment, the aeration device 23 comprises a gas delivery pipe and a plurality of aeration heads 231 disposed on the gas delivery pipe; the gas input end of the gas delivery pipe is connected with the input end of the aeration device 23. The oxidizing gas is dissolved into the water by the plurality of aeration heads 231, which is advantageous for increasing the water treatment rate.
In an alternative embodiment, the oxidizing gas supply device 21 is used for supplying ozone, oxygen or air. Specifically, the oxidizing gas input means 21 may be, but is not limited to, an ozone generator, an oxygen generator, or an air compressor. Ozone and oxygen both have oxidability, can generate oxidation reaction with water, purify water, and the promotion efficiency of the ozone serving as polar molecules is superior to that of oxygen of non-polar molecules.
In an alternative embodiment, the wire winding coil 122 includes several groups of coils with the same winding direction and the same winding wire. Preferably, the number of the coil groups is even, and each two groups of the coils form a mutual induction coil, so that the mutual induction effect between the coils is increased, and the conversion efficiency of electromagnetic energy can be effectively enhanced.
In an alternative embodiment, the electromagnetic pulse generator 123 includes a positive dc output pulse terminal electrically connected to one end of the wire winding coil 122 and a negative dc output pulse terminal electrically connected to the other end of the wire winding coil 122.
Correspondingly, the electromagnetic pulse generator 123 has a plurality of sets of positive and negative dc output pulse terminals, and each set of positive and negative dc output pulse terminals is correspondingly connected to two ends of a set of wire winding coils 122.
In an alternative embodiment, the electromagnetic pulse generator 123 further comprises an ac power input. The input end of the alternating current power supply is used for supplying power to the electromagnetic pulse generator 123. Specifically, the alternating current power supply input end can be connected with a standard 220V alternating current power supply.
In the embodiment, the electromagnetic fluid treatment device 22 is used for pretreating the oxidizing gas, so that when the oxidizing gas is air or oxygen, the water treatment efficiency can be improved by 10-20%; when the oxidizing gas is ozone, the water treatment efficiency can be improved by 20-80%.
Compared with the prior art, the oxidizing gas synergy system provided by the embodiment of the invention has the beneficial effects that: the oxidizing gas before entering the oxidation reaction device is pretreated, so that the oxidizing gas is subjected to the action of a variable-frequency direct-current pulse electromagnetic field when passing through the electromagnetic fluid treatment device, the intermolecular acting force is reduced, the association degree of molecular groups in the oxidizing gas is reduced, the molecular groups are reduced, free single molecules are increased, the mixing degree of the oxidizing gas and water is higher, and the improvement of the gas-liquid reaction of the oxidizing gas and the water is facilitated; meanwhile, after the oxidizing gas passes through the electromagnetic fluid treatment device, under the action of a pulse electric field, external electrons of the oxidizing gas deviate, the polarity is enhanced, polar molecules are favorable for being associated with water molecules with the same polarity, the association degree of the oxidizing gas and water is improved, and the gas-liquid reaction of the oxidizing gas and the water is more sufficient. Therefore, the embodiment of the invention can effectively improve the water purification effect of the oxidizing gas, reduce the consumption of the oxidizing gas and further reduce the water treatment cost.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (10)
1. An oxidizing gas synergy system is characterized by comprising an oxidizing gas input device, an electromagnetic fluid treatment device, a water input device, a gas-liquid mixing device, an oxidation reaction device and a gas flow regulating valve;
the oxidation reaction device is provided with a gas-liquid input end for allowing a gas-liquid mixture of water to be treated and oxidizing gas to enter the oxidation reaction device and a water outlet end for allowing the water subjected to oxidation treatment to flow out of the oxidation reaction device;
the gas output end of the oxidizing gas input device is communicated with the gas inlet end of the gas-liquid mixing device sequentially through the gas flow regulating valve and the electromagnetic fluid processing device, and the water output end of the water input device is communicated with the water inlet end of the gas-liquid mixing device; the gas-liquid output end of the gas-liquid mixing device is communicated with the gas-liquid input end of the oxidation reaction device;
the electromagnetic fluid processing device comprises a metal tube, a wire winding coil wound on the metal tube and an electromagnetic pulse generator electrically connected with the wire winding coil; the electromagnetic pulse generator is used for generating an analog variable frequency direct current pulse signal.
2. The oxidizing gas boosting system of claim 1 wherein said oxidizing gas input means is for inputting ozone, oxygen or air.
3. The oxidizing gas boosting system according to claim 1, wherein said gas-liquid mixing means is a venturi tube or a dissolved gas pump.
4. The oxidizing gas synergistic system of claim 1, wherein the wire winding coil comprises a plurality of groups of coils wound in the same direction and having the same winding wire.
5. An oxidizing gas synergy system is characterized by comprising an oxidizing gas input device, an electromagnetic fluid treatment device, an aeration device, an oxidation reaction device and a gas flow regulating valve;
the oxidation reaction device is provided with a gas input end for allowing oxidizing gas to enter and a water outlet end for allowing water subjected to oxidation treatment to flow out;
the gas output end of the oxidizing gas input device is communicated with the gas input end of the oxidation reaction device sequentially through the gas flow regulating valve and the electromagnetic fluid processing device;
the aeration device is arranged in the oxidation reaction device; the input end of the aeration device is connected with the gas input end of the oxidation reaction device;
the electromagnetic fluid processing device comprises a metal tube, a wire winding coil wound on the metal tube and an electromagnetic pulse generator electrically connected with the wire winding coil; the electromagnetic pulse generator is used for generating an analog variable frequency direct current pulse signal.
6. The oxidizing gas boosting system according to claim 5, further comprising a water inlet means, said oxidation reaction means further having a water inlet port for allowing water to be treated to enter therein; and the water output end of the water input device is communicated with the water inlet end of the oxidation reaction device.
7. The oxidizing gas enhancement system according to claim 5, wherein the aeration device comprises a gas delivery conduit and a plurality of aeration heads disposed on the gas delivery conduit; and the gas input end of the gas conveying pipe is connected with the input end of the aeration device.
8. The oxidizing gas boosting system according to claim 5, wherein said oxidizing gas input means is for inputting ozone, oxygen or air.
9. The oxidizing gas synergistic system of claim 5, wherein the wire winding coil comprises a plurality of groups of coils wound in the same direction and having the same winding wire.
10. The oxidizing gas boosting system according to claim 5, wherein said electromagnetic pulse generator comprises a positive DC output pulse terminal and a negative DC output pulse terminal, said positive DC output pulse terminal is electrically connected to one end of said wire winding coil, said negative DC output pulse terminal is electrically connected to the other end of said wire winding coil.
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| CN111053259A (en) * | 2019-12-30 | 2020-04-24 | 西安泰金工业电化学技术有限公司 | Incomplete all-in-one of handling of portable farming |
| CN112340934A (en) * | 2020-09-02 | 2021-02-09 | 广州昭合环保科技有限公司 | Method for denitrifying sewage by ion beam superposition biological method |
| CN112340903A (en) * | 2020-09-02 | 2021-02-09 | 广州昭合环保科技有限公司 | Method for treating refractory and high-ammonia nitrogen wastewater by ion beam superposition biological method |
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