CN108128011A - A kind of preparation method and its fiberboard of non-woven fabrics fiber plate - Google Patents

A kind of preparation method and its fiberboard of non-woven fabrics fiber plate Download PDF

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Publication number
CN108128011A
CN108128011A CN201711360900.7A CN201711360900A CN108128011A CN 108128011 A CN108128011 A CN 108128011A CN 201711360900 A CN201711360900 A CN 201711360900A CN 108128011 A CN108128011 A CN 108128011A
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China
Prior art keywords
resin
woven fabrics
cloth
preparation
fiber
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CN201711360900.7A
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Chinese (zh)
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戴久永
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Individual
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Priority to CN201711360900.7A priority Critical patent/CN108128011A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of preparation method and its fiberboard of non-woven fabrics fiber plate, are related to composite board field, processing step includes:1) resin mixes;2) cloth is spread;3) starching infiltrates;4) it flattens;5) hot pressing can effectively reduce technology difficulty, produce each size, high, pollution-free, stay in grade the fiberboard of intensity, and energy secondary recovery utilizes, less waste pollution.

Description

A kind of preparation method and its fiberboard of non-woven fabrics fiber plate
Technical field
The present invention relates to composite board fields, and in particular to a kind of preparation method and its fiberboard of non-woven fabrics fiber plate.
Background technology
Fiberboard is initiated by the artificial board of nineteen nineties, using plant fiber as raw material, addition bonding Agent is suppressed under conditions of heating is pressurizeed.It has many advantages, such as fine and closely woven even structure, material, impact resistance and easy processing;Extensively It is general to be used for the fields such as building materials, furniture, household electrical appliance, musical instrument, vehicle and shipbuilding, and use scope expands year by year.
However, the density of traditional plant fibre density plate is big, same volume density board weight is several times of common wood;Stablize Property is poor, not corrosion-resistant, easily mildews and is destroyed by insect, moisture resistance is poor;Primary raw material is plant fiber and bonding glue, is easily fired It burns;It needs that a large amount of timber is used to consume greatly environmental resource, production link is more, and production cost is also higher as Raw material processing;It is raw Largely the harmful substance such as benzene, formaldehyde can be discharged in later stage use for a long time, long-term damage makes using binder during production User's health;Production link is more and can generate a large amount of waste water, exhaust gas, pollutes environment.
Non-woven fabrics (English name:Non Woven Fabric or Nonwoven cloth) nonwoven fabric is also known as, it is by orienting Or random fiber and form, be environment-friendly materials of new generation, cloth be called due to the appearance with cloth and certain performances.Nonwoven Cloth have it is moisture-proof, ventilative, flexible, light, not combustion-supporting, easy decompose, it is nontoxic it is nonirritant, rich in color, cheap, can follow The features such as ring is used again.Synthetic fibers of the polyester that polyester fiber is formed as organic dibasic acid and dihydric alcohol polycondensation obtained by through spinning. There is light, soft, nontoxic non-stimulated, antibiotic property and anti-chemical agent is good, physical durability is good.
Invention content
In order to solve the above problem of the prior art, the present invention provides a kind of preparation method of non-woven fabrics fiber plate, can Technology difficulty is effectively reduced, produces each size, high, pollution-free, stay in grade the fiberboard of intensity, and energy secondary recovery profit With less waste pollution.
A kind of preparation method of non-woven fabrics fiber plate, processing step include:
1) Pioloform, polyvinyl acetal phenol-formaldehyde resin modified with unsaturated-resin is mixed, adds in curing agent, stir and evenly mix, must set Fat batch mixing;
2) by non-woven fabrics and glass fabric/carbon cloth, stack paving is several layer of cloths;
3) using resin batch mixing obtained by step 1), layer of cloth starching as obtained by high pressure implanter by step 2) simultaneously infiltrates, Obtain resin infiltration layer of cloth;
4) by gained resin infiltration layer of cloth, Excess resin batch mixing is squeezed out by extruder, through calender by resin infiltration cloth Layer leveling;
5) press heating pressurization is answered by high temperature, resin batch mixing is immersed in glass fabric and nonwoven layer, and glass Fiber cloth melting combines together with resin, and solidifies and combine under curing agent effect;Cooling.
Wherein, glass fabric/carbon cloth refers to glass fabric, carbon cloth and glass fiber-carbon fiber and interweaves At least one of cloth.
The method of the present invention uses Pioloform, polyvinyl acetal phenol-formaldehyde resin modified that can significantly improve resin to glass fibre Cohesive force improves the brittleness of resin or carbon fibre is promoted to be merged with the physics of non-woven fabrics fiber as strand bridge, increases compound The mechanical strength of material, and solidification rate is further reduced so as to advantageously reduce hot melting temperature and briquetting pressure.As modification The preferred phenol formaldehyde resin of the phenolic resin.
Preferably, in step 1), the Pioloform, polyvinyl acetal phenol-formaldehyde resin modified, unsaturated-resin mixing and curing agent Weight ratio be 1:(0.1-0.2):(0.01-0.05).
Preferably, in step 2), the layer of cloth laying sequence is non-woven fabrics-glass fabric/carbon cloth-nonwoven Cloth-glass fabric/carbon cloth-non-woven fabrics, and each non-woven fabrics area layer of cloth is laid with one or more layers non-woven fabrics.
Preferably, in step 3), the starching material quantity of the resin batch mixing is (1-1.5) kg/m2
Preferably, the sheet metal thickness of non-woven fabrics fiber plate is controlled by the total number of plies of non-woven fabrics and determined;Non-woven fabrics fiber plate The number of plies ratio that plank hardness is laminated by glass fabric with non-woven fabrics is adjusted, (glass-fiber-fabric/carbon fiber cloth) and nonwoven layer Number is than being preferably (1-3):1.Glass/carbon fibre and non-woven fibre number of plies ratio are bigger, and fiberboard hardness of the present invention is higher.The nonwoven Cloth provides certain toughness, heat preservation and sound insulation value for fiberboard of the present invention.
Preferably, the curing agent is phenolic resin NL curing agent.
Preferably, in step 5), pressurization pressure is 600-800 tons/m2, heating temperature is 110-130 DEG C, the duration ≥3min。
The unsaturated-resin is fiberglass often with unsaturated-resin matrix, preferably unsaturated polyester (UP), epoxy resin or Unsaturated phenolic resin.When the unsaturated-resin heat or initiator under the action of, be solidified into the insoluble macromolecule not melted Network polymers, and the addition of modified resin and the enhancing of hybridized fiber skeleton, the various aspects such as heatproof, burn into mechanical strength It can be greatly improved compared with ordinary resin casting matrix.
Preferably, the non-woven fabrics is polyester fiber non-woven fabric.
Preferably, processing step further includes after cooling, one or more of Length-fixing cutting, edging, stacking, storage.
The present invention brings resultant effect to include:
1. the non-woven fabrics fiber plate of the present invention, it is small to compare traditional wood-fiber board density, easy processing;2. non-woven fabrics and glass fibers For Wei Bu/carbon cloth as compound skeleton, sheet forming intensity, toughness are high;3. non-woven fibre substituted plant fiber, and pass through nothing Machine glass fibre is composite modified, and stability is good, corrosion-resistant, be not easy raw bacterium, it is infested, go mouldy;4. Pioloform, polyvinyl acetal modified phenolic Resin improves carbon-forming performance, good anti-flammability is provided for plank under the premise of fusion performance is improved, since polyvinyl alcohol contracts The addition of aldehyde, makes the concentration of phenolic resin in resin compound accordingly reduce, and has slowed down the solidification rate of resin, reduces molding pressure Power, and pass through organic-inorganic interpenetrating skeleton and ensure heat resistance and anti-flammability;5. nonwoven cloth skeleton cures through resin infiltration hanging Fusion forms hydridization interpenetrating networks, and the hydrolysis of good waterproof performance difficulty, bubble is without influence;6. it is not binded by traditional adhesive, it is formaldehydeless Etc. harmful substances, and digestion period is long, and no small molecule volatilization is overflowed;7. production procedure is simple, cost is relatively low, in production link not Generate sewage, exhaust gas the like waste;8. because of its stronger chemistry and thermal stability, the non-woven fabrics fiber plate after use is recyclable, The binders hot pressing such as resin are added in after smashing, to make the life such as hard well lid, dustbin, external wall layer, building or industrial material Material, secondary use.
Description of the drawings
Fig. 1 is the technological process of production schematic diagram of 1 preparation method of the embodiment of the present invention.
Wherein, the identical reference numeral of component identical in the accompanying drawings;Attached drawing is not drawn according to practical ratio.
Specific embodiment
It further illustrates the present invention with reference to the accompanying drawings and examples.
Embodiment 1
A kind of preparation method of non-woven fabrics fiber plate, as shown in Figure 1, processing step includes:
1) Pioloform, polyvinyl acetal phenol-formaldehyde resin modified with unsaturated-resin is mixed, adds in phenolic resin NL curing agent, stir Mixing is mixed, obtains resin batch mixing.It is phenol formaldehyde resin as the modified phenolic resin.The Pioloform, polyvinyl acetal is modified phenol The weight ratio of urea formaldehyde, unsaturated-resin mixing and curing agent is 10:1.5:0.3.This step uses Pioloform, polyvinyl acetal to be modified Phenolic resin can significantly improve cohesive force of the resin to glass fibre, improve the brittleness of resin or promote as strand bridge Merged into carbon fibre with the physics of non-woven fabrics fiber, increase the mechanical strength of composite material, and further reduce solidification rate so as to Advantageously reduce briquetting pressure.
The unsaturated-resin is the unsaturated phenolic resin of fiberglass.When the unsaturated-resin is warm or initiator Under effect, the insoluble macromolecule network polymers not melted, and the addition of modified resin and the enhancing of hybridized fiber skeleton are solidified into, The various aspects of performance such as its heatproof, burn into mechanical strength are greatly improved compared with ordinary resin casting matrix.
2) it by non-woven fabrics and glass fabric/carbon cloth, is laid with and is laminated for 4 groups of layer of cloths.Layer of cloth described in every group is laid with It is sequentially non-woven fabrics-glass fabric/carbon cloth-non-woven fabrics-glass fabric/carbon cloth-non-woven fabrics, and single group In layer of cloth, each non-woven fabrics area is laid with layer of non-woven fabric, and the layer of cloth in glass fibre/carbon cloth area is laid with two layers, makes its (glass Cloth/carbon fiber cloth):The non-woven fabrics number of plies is than 2:1.Overall thickness 20mm is laminated in every group of ply gage 5mm.The present embodiment non-woven fabrics fiber The sheet metal thickness of plate is controlled by the total number of plies of non-woven fabrics and determined;The plank hardness of non-woven fabrics fiber plate passes through glass fabric and nothing The number of plies ratio that woven fabric is laminated is adjusted.Non-woven fabrics and (glass-fiber-fabric/carbon fiber cloth) number of plies ratio are bigger, and fiberboard hardness of the present invention is got over It is high.The non-woven fabrics provides certain toughness, heat preservation and sound insulation value for fiberboard of the present invention.The non-woven fabrics is polyester fiber Non-woven fabrics.
3) using resin batch mixing obtained by step 1), by epoxy polyurethane mixing weighing high pressure implanter, by step 2) institute The layer of cloth starching obtained, the starching material quantity of resin batch mixing is 1.2kg/m2.5min is infiltrated, obtains resin infiltration layer of cloth.
4) by gained resin infiltration layer of cloth, Excess resin batch mixing is squeezed out by extruder, through calender by resin infiltration cloth Layer leveling;
5) press heating pressurization is answered by 600-1000 tonnes of high temperature crawler type, pressurization pressure is 600 tons/m2, heating temperature It is 110-130 DEG C to spend, duration 3min, resin batch mixing is immersed in glass fabric and nonwoven layer, and glass fabric Melting combines together with resin, and solidifies and combine under the effect of phenolic resin NL curing agent, and sheet forming thickness is 10mm.
6) it after fiberboard cooling, using cutting machine Length-fixing cutting, using sander to cutting mouth edging, stacks, arrange And it stores.
Wherein, glass fabric/carbon cloth, abbreviation glass-fiber-fabric/carbon fiber cloth, refer to glass fabric, carbon cloth and At least one of glass fiber-carbon fiber interwoven.In the present embodiment, glass fabric/carbon cloth uses glass Fiber and carbon fiber interwoven.
After testing:Non-woven fabrics fiber plate is made in the present embodiment, and thermal conductivity factor 0.0358W/mK, sound-proofing reach 28 points Shellfish meets high-speed EMUs vehicle environmental protection tests standard.Unit board density is 180kg/m3,40 times smaller than steel plate, aluminium sheet is small by 14 Again, wood plywood is 7 times small, acid and alkali-resistance, waterproof, and cold and hot stability is strong.It is linear swollen also, between+30 DEG C and -30 DEG C Swollen coefficient is 25*10-6(mm*k)-1, show that temperature change is small on the influence variation of its structure, deformability is low.Meanwhile material work The superiority of skill determine entire production process without waste water, without exhaust gas, without dust, without waste, and process remaining corner and give up Material can crush recycling and reuse, and setting is compressed to the products such as inspection well cover.
Embodiment 2
The present embodiment is implemented using 1 the method for embodiment, and the difference lies in the alternately laminated layer of cloth is 8 Group, (glass-fiber-fabric/carbon fiber cloth):The non-woven fabrics number of plies is than 1:Overall thickness 40mm is laminated, in step 5) in 1, every group of ply gage 5mm Heating temperature is 80 DEG C, 800 tons/m of pressurization pressure2, sheet forming thickness 20mm.
Above with reference to preferred embodiment, invention has been described, but protection scope of the present invention is not restricted to This, any all technical solutions fallen within the scope of the appended claims are within the scope of the present invention.This hair is not being departed from In the case of bright range, various improvement can be carried out to it and component therein can be replaced with equivalent.Especially, only Otherwise there are structural conflict, items technical characteristic mentioned in the various embodiments can be combined in any way.

Claims (10)

1. a kind of preparation method of non-woven fabrics fiber plate, which is characterized in that processing step includes:
1) Pioloform, polyvinyl acetal phenol-formaldehyde resin modified with unsaturated-resin is mixed, adds in curing agent, stir and evenly mix, obtain resin and mix Material;
2) by non-woven fabrics and glass fabric/carbon cloth, stack paving is several layer of cloths;
3) using resin batch mixing obtained by step 1), layer of cloth starching as obtained by high pressure implanter by step 2) simultaneously infiltrates, and must set Fat infiltrates layer of cloth;
4) by gained resin infiltration layer of cloth, Excess resin batch mixing is squeezed out by extruder, it is through calender that resin infiltration layer of cloth is whole It is flat;
5) press heating pressurization is answered by high temperature, resin batch mixing is immersed in glass fabric and nonwoven layer, and glass fibre Cloth melting combines together with resin, and solidifies and combine under curing agent effect;Cooling;
Wherein, glass fabric/carbon cloth refers in glass fabric, carbon cloth and glass fiber-carbon fiber interwoven At least one.
2. preparation method according to claim 1, it is characterised in that:In step 1), the Pioloform, polyvinyl acetal is modified The weight ratio of phenolic resin, unsaturated-resin mixing and curing agent is 1:(0.1-0.2):(0.01-0.05).
3. preparation method according to claim 2, it is characterised in that:In step 2), the layer of cloth laying sequence is nothing Woven fabric-glass fabric/carbon cloth-non-woven fabrics-glass fabric/carbon cloth-non-woven fabrics, and each non-woven fabrics area Layer of cloth is laid with one or more layers non-woven fabrics.
4. preparation method according to claim 3, it is characterised in that:The sheet metal thickness of non-woven fabrics fiber plate passes through non-woven fabrics Total number of plies control determines;The number of plies ratio that the plank hardness of non-woven fabrics fiber plate is laminated by glass fabric with non-woven fabrics is adjusted Section, the number of plies ratio of (glass-fiber-fabric/carbon fiber cloth) and non-woven fabrics is preferably (1-3):1.
5. preparation method according to claim 2, it is characterised in that:In step 3), the starching of the resin batch mixing is used Doses is (1-1.5) kg/m2
6. preparation method according to any one of claims 1-5, it is characterised in that:In step 5), pressurization pressure is 600-800 tons/m2, heating temperature is 110-130 DEG C, the duration >=3min.
7. preparation method according to claim 6, it is characterised in that:In step 5), further include after cooling, scale is cut Cut, edging, stacking, storage one or more of.
8. preparation method according to any one of claims 1-5, it is characterised in that:The curing agent is phenolic resin NL Curing agent, the unsaturated-resin are preferably unsaturated polyester (UP), epoxy resin or unsaturated phenolic resin;.
9. preparation method according to any one of claims 1-5, it is characterised in that:The non-woven fabrics for polyester fiber without Woven fabric.
10. a kind of non-woven fabrics fiber plate, which is characterized in that carried out by the preparation method as described in any one of claim 1-9 It prepares.
CN201711360900.7A 2017-12-18 2017-12-18 A kind of preparation method and its fiberboard of non-woven fabrics fiber plate Pending CN108128011A (en)

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CN201711360900.7A CN108128011A (en) 2017-12-18 2017-12-18 A kind of preparation method and its fiberboard of non-woven fabrics fiber plate

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112356199A (en) * 2020-11-10 2021-02-12 贵州正安娜塔莎乐器制造有限公司 Preparation method of guitar material
CN112406253A (en) * 2020-11-18 2021-02-26 同高纺织化纤(深圳)有限公司 Preparation method of non-woven fabric fiberboard and fiberboard thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102909935A (en) * 2012-11-13 2013-02-06 沈阳信达信息科技有限公司 Processing method of glass fiber composite board
CN103707610A (en) * 2013-12-24 2014-04-09 唐地源 Preparation method of fiber-reinforced composite board and obtained composite board

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102909935A (en) * 2012-11-13 2013-02-06 沈阳信达信息科技有限公司 Processing method of glass fiber composite board
CN103707610A (en) * 2013-12-24 2014-04-09 唐地源 Preparation method of fiber-reinforced composite board and obtained composite board

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112356199A (en) * 2020-11-10 2021-02-12 贵州正安娜塔莎乐器制造有限公司 Preparation method of guitar material
CN112356199B (en) * 2020-11-10 2022-03-25 贵州正安娜塔莎乐器制造有限公司 Preparation method of guitar material
CN112406253A (en) * 2020-11-18 2021-02-26 同高纺织化纤(深圳)有限公司 Preparation method of non-woven fabric fiberboard and fiberboard thereof

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