CN107955248A - A kind of interior enhancing composite board made using Chinese medicine dreg and preparation method thereof - Google Patents
A kind of interior enhancing composite board made using Chinese medicine dreg and preparation method thereof Download PDFInfo
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- CN107955248A CN107955248A CN201711188297.9A CN201711188297A CN107955248A CN 107955248 A CN107955248 A CN 107955248A CN 201711188297 A CN201711188297 A CN 201711188297A CN 107955248 A CN107955248 A CN 107955248A
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- chinese medicine
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- compound material
- medicine dreg
- material layer
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- 239000002131 composite material Substances 0.000 title claims abstract description 163
- 239000003814 drug Substances 0.000 title claims abstract description 117
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 141
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 133
- 150000001875 compounds Chemical class 0.000 claims abstract description 123
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 75
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 75
- 239000002245 particle Substances 0.000 claims abstract description 33
- 229920003023 plastic Polymers 0.000 claims abstract description 33
- 239000004033 plastic Substances 0.000 claims abstract description 33
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 30
- FUPMSLTYEIZSLZ-UHFFFAOYSA-N cobalt;naphthalene-1-carboxylic acid Chemical compound [Co].C1=CC=C2C(C(=O)O)=CC=CC2=C1 FUPMSLTYEIZSLZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 22
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 18
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 18
- 239000008108 microcrystalline cellulose Substances 0.000 claims abstract description 17
- 229940016286 microcrystalline cellulose Drugs 0.000 claims abstract description 17
- 238000000465 moulding Methods 0.000 claims abstract description 16
- 239000003513 alkali Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000005096 rolling process Methods 0.000 claims abstract description 13
- 239000013078 crystal Substances 0.000 claims abstract description 11
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 11
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 229920000098 polyolefin Polymers 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 8
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005530 etching Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 53
- 229920005989 resin Polymers 0.000 claims description 42
- 239000011347 resin Substances 0.000 claims description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 238000000748 compression moulding Methods 0.000 claims description 30
- -1 polyethylene Polymers 0.000 claims description 25
- 239000011159 matrix material Substances 0.000 claims description 20
- 238000004382 potting Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 239000000320 mechanical mixture Substances 0.000 claims description 18
- 239000002023 wood Substances 0.000 claims description 14
- 239000004744 fabric Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000013019 agitation Methods 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 10
- 238000007654 immersion Methods 0.000 claims description 10
- 238000005453 pelletization Methods 0.000 claims description 10
- 238000003825 pressing Methods 0.000 claims description 10
- 239000012779 reinforcing material Substances 0.000 claims description 10
- 239000008399 tap water Substances 0.000 claims description 10
- 235000020679 tap water Nutrition 0.000 claims description 10
- 238000005553 drilling Methods 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- UHZLTTPUIQXNPO-UHFFFAOYSA-N 2,6-ditert-butyl-3-methylphenol Chemical class CC1=CC=C(C(C)(C)C)C(O)=C1C(C)(C)C UHZLTTPUIQXNPO-UHFFFAOYSA-N 0.000 claims description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 7
- 235000013539 calcium stearate Nutrition 0.000 claims description 7
- 239000008116 calcium stearate Substances 0.000 claims description 7
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 240000008564 Boehmeria nivea Species 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 2
- 238000010074 rubber mixing Methods 0.000 claims 1
- 239000002699 waste material Substances 0.000 abstract description 5
- 239000002893 slag Substances 0.000 abstract description 4
- 238000009408 flooring Methods 0.000 abstract description 3
- 150000002978 peroxides Chemical class 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 229920001587 Wood-plastic composite Polymers 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000011155 wood-plastic composite Substances 0.000 description 5
- ZGBSOTLWHZQNLH-UHFFFAOYSA-N [Mg].S(O)(O)(=O)=O Chemical compound [Mg].S(O)(O)(=O)=O ZGBSOTLWHZQNLH-UHFFFAOYSA-N 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 3
- 235000013495 cobalt Nutrition 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 229920000426 Microplastic Polymers 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 229940126678 chinese medicines Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention relates to a kind of interior enhancing composite board made using Chinese medicine dreg and preparation method thereof, plate is made of three layers of thermoplastic composite layer and two layers of porous same with thermosetting compound material layer, is one layer of porous same with thermosetting compound material layer per between two layers of thermoplastic composite layer.Thermoplastic composite layer is by polyolefin plastics particle, Chinese medicine slag, maleic anhydride, stearate, antioxidant, alkali magnesium sulfate crystal whisker and microcrystalline cellulose through mixing, extruding, rolling and form；Porous same with thermosetting compound material layer by unsaturated polyester resin, naphthoic acid cobalt, methyl ethyl ketone peroxide, Chinese medicine slag and burlap handle paste, molding and drill, surface galling, alkaline etching form.The present invention is convenient for production, and cost is low, environmental-friendly, and modulus is high, creep resistant, can carry out waste utilization to Chinese medicine slag.Flooring, railing can be fabricated to, wallboard, photo frame, picture frame, skirting, withhold the products such as plate, be widely used in many occasions such as office building, auditoriums, hotels, telecommuting, municipal gardens.
Description
Technical field
The invention discloses a kind of composite board, is answered more particularly to a kind of interior enhancing made using Chinese medicine dreg
Plywood material and its production method.
Background technology
In many occasions such as office building, auditoriums, hotels, telecommuting, municipal gardens, often using various floorings, railing, wallboard, phase
Frame, picture frame, skirting, withhold the products such as plate, traditionally, these products be generally plank, plastic plate, marble slab etc. make and
Into, but these plates have some limitations during production or use, such as, plank is easy to crack, easily damages by worms, cost
Height, and need to fall trees in process, it is unfavorable for water and soil conservation and environmental protection；Plastic plate degradability is poor, discards
The waste material produced afterwards will pollute the generations such as soil, water body, and yielding, colour fading easy to aging of plastic plate etc. mostly；Marble slab
Heaviness, transport, installation are inconvenient, and sense of touch is poor, and modifiability is poor etc..In recent years, the research of wood plastic composite is with answering
With the concern for receiving height, it has excellent anti-corrosion and waterproof, anticracking and antifouling property, without secondary operation, installation side
Just, without toxic chemicals, low-carbon environment-friendly, without japanning, polishing, easy to maintain, more easy to clean, heat-insulating sound-insulating etc., thus
It is various to can be widely applied to interior/exterior decoration, Garden Engineering construction, workshop antiseptic project, marine anticorrosion engineering, environment sanitation facility etc.
Occasion.But at present production wood plastic composite used in plant fiber substantially on all use wood powder or bran powder, using wood powder without
Substantial amounts of timber will be expended by doubting, and China's timber resources is in short supply, and annual timber supply and demand notch is up to 60,000,000 m3；And bran powder source
It is relatively in short supply, and be the important feed of domestic animal, it is a large amount of to be equivalent to take grain by force from domestic animal mouthful using bran powder.So utilize it
The fiber powder of his resource makes the forward position that wood plastic composite is countries in the world research, and necessity of China's wood moulding industry development
Approach.
China is Chinese medicine production and is expected its Chinese Medicine Industry annual growth in 20- using big country, whole nation major part provinces and cities
Between 25%, drug in some provinces is estimated more than 30%, and Chinese herbal medicine industry is quickly grown.It will be produced during Chinese medicine is prepared a large amount of solid
Body Chinese medicine dreg, traditionally, these Chinese medicine dregs are abandoned generally as discarded object or burnt as fuel, resource wave
Take than more serious.
So substituting traditional plant fiber production wood plastic composite using discarded Chinese medicine dreg, it can meet market
Needs, while can also turn waste into wealth, it is very necessary.
The content of the invention
It is an object of the invention to the Chinese medicine dreg of China's abundant is carried out recycling recycling, there is provided one kind utilizes Chinese medicine
The interior enhancing composite board and its production method that the dregs of a decoction make.
A kind of interior enhancing composite board made using Chinese medicine dreg, takes following scheme to realize：
A kind of interior enhancing composite board using Chinese medicine dreg making is porous by three layers of thermoplastic composite layer and two layers
Same with thermosetting compound material layer is formed, and is one layer of porous same with thermosetting compound material layer per between two layers of thermoplastic composite layer.
Three layers of thermoplastic composite layer composition and structure are identical, by polyolefin plastics particle, Chinese medicine dreg, horse
Come acid anhydrides, stearate, antioxidant, alkali magnesium sulfate crystal whisker and microcrystalline cellulose through mixing, extruding, rolling and form；More than two layers
Hole same with thermosetting compound material layer composition and structure are identical, by unsaturated polyester resin, naphthoic acid cobalt, methyl ethyl ketone peroxide,
Chinese medicine dreg and burlap handle paste, molding and drill, surface galling, alkaline etching form.
The polyolefin plastics particle is one kind in polyethylene or polypropylene.
The Chinese medicine dreg particle diameter is 40-120 mesh.
The stearate is one kind in calcium stearate or zinc stearate.
The antioxidant is 2,6- di-tert-butyl methyl phenols or 4, in 4 '-methylene bis (2,6- DI-tert-butylphenol compounds)
One kind.
The microcrystalline cellulose particle diameter is 20-230 mesh.
The unsaturated polyester resin is one kind in adjacent benzene-type or metaphenylene unsaturated polyester resin.
The burlap is one kind in ramie cloth, linen, etramee or gunny cloth.
A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polyolefin plastics particle, maleic anhydride, stearate, antioxidant, alkali magnesium sulfate crystal whisker and microcrystalline cellulose
Plain 100: 5-15: 1-2: 0.8-1.2: 5-15: 5-15 mechanical mixture in mass ratio uniformly after extruding pelletization, obtain composite plastic grain
Son, 170-190 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg in mass ratio 100: 30-50 mechanical mixture, utilize
Twin-screw extruder is rolled into thermoplastic composite layer, 165-185 DEG C of rolling temperature, thermoplastic composite layer thickness
0.6-1cm；
(2) in mass ratio 100: 0.5-1.5: 0.5-1.5: 10-20: 10-30 unsaturated polyester resin, naphthoic acid are weighed respectively
Cobalt, methyl ethyl ketone peroxide, Chinese medicine dreg and burlap, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, add peroxide
Change methyl ethyl ketone and stir evenly, then add Chinese medicine dreg and be again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally adopt
With laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base and answer
Condensation material plate, after molding pressure 30-90Pa, cold curing 12-24h, by burlap reinforced resin matrix composite sheet at 75-85 DEG C
In the range of solidify afterwards processing 2-4h, be cooled to room temperature to obtain same with thermosetting compound material layer, it is compound in thermosetting property using cobalt hole equipment
Lower through-hole is drilled out in material layer, perforation same with thermosetting compound material layer is obtained, afterwards to same with thermosetting compound material layer surface of perforating
Plucking is carried out, obtains plucking perforation same with thermosetting compound material layer, then to be put into quality dense by plucking perforation same with thermosetting compound material layer
Spend in the NaOH solution for 2-10% after immersion treatment 24-48h, take out, rinsed to neutrality, dried with tap water, obtained porous
Same with thermosetting compound material layer, porous same with thermosetting compound material layer thickness 0.6-3cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, wherein, three layers of thermoplastic composite layer thickness are mutually the same, two layers
Porous same with thermosetting compound material layer thickness is mutually the same, heats mould, its temperature is risen to 30-50 DEG C, and is vented 5-15min,
Molding, after preheating 10-20min in the range of 170-190 DEG C, using the pressure compression molding of 10-50MPa, is made a kind of utilization
The interior enhancing composite board that Chinese medicine dreg makes.
A kind of interior enhancing composite board made using Chinese medicine dreg of the present invention, it is convenient to manufacture, and is answered using traditional
Its production and processing can be achieved in condensation material production technology, and mechanization degree is higher in production process, and production cost is low.A kind of profit
The interior enhancing composite board made of Chinese medicine dreg is compared with common plastics plate, and amount of plastic used reduces, more friendly to environment
It is good, modulus higher, more creep resistant, while waste utilization can be carried out to Chinese medicine dreg, it can not only reduce environmental pollution, but also can reduce
Products material cost；A kind of interior enhancing composite board made using Chinese medicine dreg is compared with wood-plastic composite board, intensity
Higher, substitutes wood powder or rice husk meal with Chinese medicine dreg, can reduce deforestation amount, be conducive to water and soil conservation and environmental protection,
Grain will not be taken by force from livestock mouthful, be conducive to the cultivation of domestic animal.A kind of interior enhancing composite board and glass made using Chinese medicine dreg
Glass steel board is compared, and thermosetting resin amount used is less, substitutes glass-fiber-fabric with flaxen fiber cloth, degradability is stronger, and environment is more
Close friend, and using techniques such as porous, surface galling and alkaline etchings so that combined more firmly between different laminates, comprehensive performance is more
Add excellent.In addition, manufacturing composite material using Chinese medicine dreg, the use value of Chinese medicine dreg can be also improved, is turned waste into wealth,
It may advantageously facilitate the benign development of Chinese Medicine Industry.A kind of interior enhancing composite board made using Chinese medicine dreg can be widely applied to
Many occasions such as office building, auditoriums, hotels, telecommuting, municipal gardens, can be fabricated to flooring, railing, wallboard, photo frame, picture frame, skirt
Line, withhold the products such as plate.
Brief description of the drawings
Below with reference to attached drawing, the invention will be further described.
Fig. 1 is a kind of interior enhancing plywood sheet structure schematic diagram made using Chinese medicine dreg.
Fig. 2 is the structure diagram of porous same with thermosetting compound material layer in Fig. 1.
Fig. 3 is A-A cross-sectional views in Fig. 2.
1- thermoplastic composite layers, the porous same with thermosetting compound material layers of 2-, 3- polyolefin plastics particles, 4- Chinese medicines
Slag, 5- maleic anhydrides, 6- stearate, 7- antioxidant, 8- alkali magnesium sulfate crystal whiskers, 9- microcrystalline celluloses, 10- unsaturated polyester (UP)s
Resin, 11- naphthoic acid cobalts, 12- methyl ethyl ketone peroxides, 13- burlaps, lower through-hole on 14- borders, lower through-hole on 15- centers.
Embodiment
1, attached drawing 2 and attached drawing 3 referring to the drawings, a kind of interior enhancing composite board made using Chinese medicine dreg is by three layers of thermoplastic
Property composite layer 1 and two layers of porous same with thermosetting compound material layer 2 form, per being one between two layers of thermoplastic composite layer 1
The porous same with thermosetting compound material layer 2 of layer.
Three layers of thermoplastic composite layer 1 form and structure is identical, by polyolefin plastics particle 3, Chinese medicine dreg
4th, maleic anhydride 5, stearate 6, antioxidant 7, alkali magnesium sulfate crystal whisker 8 and microcrystalline cellulose 9 through mix, extrude, roll and
Into；Two layers of porous same with thermosetting compound material layer 2 forms and structure is identical, by unsaturated polyester resin 10, naphthoic acid cobalt 11,
Methyl ethyl ketone peroxide 12, Chinese medicine dreg 4 and burlap 13 handle paste, molding and drill, surface galling, alkaline etching form.
The polyolefin plastics particle is one kind in polyethylene or polypropylene.
The Chinese medicine dreg particle diameter is 40-120 mesh.
The stearate is one kind in calcium stearate or zinc stearate.
The antioxidant is 2,6- di-tert-butyl methyl phenols or 4, in 4 '-methylene bis (2,6- DI-tert-butylphenol compounds)
One kind.
The microcrystalline cellulose particle diameter is 20-230 mesh.
The unsaturated polyester resin is one kind in adjacent benzene-type or metaphenylene unsaturated polyester resin.
The burlap is one kind in ramie cloth, linen, etramee or gunny cloth.
Embodiment 1：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polyethylene, maleic anhydride, calcium stearate, 2,6- di-tert-butyl methyl phenols, alkali magnesium sulfate crystal whisker and
Microcrystalline cellulose (125 mesh) 100: 10: 1.5: 1: 10: 10 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain composite plastic
Expect particle, 180 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg (80 mesh) 100: 40 mechanical mixtures in mass ratio, profit
Thermoplastic composite layer, 175 DEG C of rolling temperature, thermoplastic composite layer thickness are rolled into twin-screw extruder
0.8cm；
(2) in mass ratio 100: 1: 1: 15: 20 m-phthalate unsaturated polyester resin, naphthoic acid cobalt, peroxidating first are weighed respectively
Ethyl ketone, Chinese medicine dreg (80 mesh) and ramie cloth, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, add peroxidating
Methyl ethyl ketone simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally use
Laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base it is compound
Plate of material, after molding pressure 60Pa, cold curing 18h, burlap reinforced resin matrix composite sheet is handled in 80 DEG C of solidify afterwards
3h, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out on same with thermosetting compound material layer using drilling device and led to up and down
Hole, obtains perforation same with thermosetting compound material layer, and obtaining plucking to perforation same with thermosetting compound material layer surface progress plucking afterwards wears
Hole same with thermosetting compound material layer, then plucking perforation same with thermosetting compound material layer is put into the NaOH solution that mass concentration is 6%
After immersion treatment 36h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, porous thermosetting
Property composite layer thickness 1.8cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 40 DEG C, and is vented 10min, closes
Mould, after 180 DEG C preheat 15min, using the pressure compression molding of 30MPa, is made a kind of interior increasing made using Chinese medicine dreg
Strong composite board.
Embodiment 2：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polypropylene, maleic anhydride, zinc stearate, 4,4 '-methylene bis (2,6- DI-tert-butylphenol compounds), alkali formula sulfuric acid
Magnesium whisker and microcrystalline cellulose (20 mesh) 100: 5: 1: 0.8: 5: 5 mechanical mixtures in mass ratio uniformly after extruding pelletization, answered
Close plastic pellet, 170 DEG C of extrusion temperature；By composite plastic particle, Chinese medicine dreg (40 mesh) 100: 30 mechanical mixtures in mass ratio
Afterwards, thermoplastic composite layer, 165 DEG C of rolling temperature, thermoplastic composite thickness are rolled into using twin-screw extruder
Spend 0.6cm；
(2) in mass ratio 100: 0.5: 0.5: 10: 10 metaphenylene unsaturated polyester resin, naphthoic acid cobalt, peroxide are weighed respectively
Change methyl ethyl ketone, Chinese medicine dreg (40 mesh) and linen, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, added
Methyl Ethyl Ketone Oxidation simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally
Using laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base
Composite panel, after molding pressure 30Pa, cold curing 12h, by burlap reinforced resin matrix composite sheet in 75 DEG C of solidify afterwards
2h is handled, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out using drilling device on same with thermosetting compound material layer
Lower through-hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards is drawn
Hair perforation same with thermosetting compound material layer, then by plucking perforation same with thermosetting compound material layer be put into mass concentration be 2% NaOH it is molten
In liquid after immersion treatment 24h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, it is porous
Same with thermosetting compound material layer thickness 0.6cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 30 DEG C, and is vented 5min, molds,
After 170 DEG C preheat 10min, using the pressure compression molding of 10MPa, a kind of interior enhancing made using Chinese medicine dreg is made and answers
Plywood material.
Embodiment 3：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polyethylene, maleic anhydride, calcium stearate, 4,4 '-methylene bis (2,6- DI-tert-butylphenol compounds), alkali formula sulfuric acid
Magnesium whisker and microcrystalline cellulose (230 mesh) 100: 15: 2: 1.2: 15: 15 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain
To composite plastic particle, 190 DEG C of extrusion temperature；By composite plastic particle, the machinery of Chinese medicine dreg (120 mesh) in mass ratio 100: 50
After mixing, thermoplastic composite layer, 185 DEG C of rolling temperature, thermoplastic composite are rolled into using twin-screw extruder
Layer thickness 1cm；
(2) in mass ratio 100: 1.5: 1.5: 20: 30 m-phthalate unsaturated polyester resin, naphthoic acid cobalt, peroxide are weighed respectively
Change methyl ethyl ketone, Chinese medicine dreg (120 mesh) and etramee, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, added
Methyl Ethyl Ketone Oxidation simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally
Using laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base
Composite panel, after molding pressure 90Pa, cold curing 24h, by burlap reinforced resin matrix composite sheet in 85 DEG C of solidify afterwards
4h is handled, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out using drilling device on same with thermosetting compound material layer
Lower through-hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards is drawn
Hair perforation same with thermosetting compound material layer, then by plucking perforation same with thermosetting compound material layer be put into mass concentration be 10% NaOH it is molten
In liquid after immersion treatment 48h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, it is porous
Same with thermosetting compound material layer thickness 3cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 50 DEG C, and is vented 15min, closes
Mould, after 190 DEG C preheat 20min, using the pressure compression molding of 50MPa, is made a kind of interior increasing made using Chinese medicine dreg
Strong composite board.
Embodiment 4：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polypropylene, maleic anhydride, zinc stearate, 2,6- di-tert-butyl methyl phenols, alkali magnesium sulfate crystal whisker and
Microcrystalline cellulose (20 mesh) 100: 10: 2: 0.8: 10: 15 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain composite plastic
Particle, 170 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg (80 mesh) 100: 50 mechanical mixtures in mass ratio, utilize
Twin-screw extruder is rolled into thermoplastic composite layer, 165 DEG C of rolling temperature, thermoplastic composite layer thickness 0.8cm；
(2) in mass ratio 100: 1.5: 0.5: 15: 30 metaphenylene unsaturated polyester resin, naphthoic acid cobalt, peroxide are weighed respectively
Change methyl ethyl ketone, Chinese medicine dreg (40 mesh) and gunny cloth, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, added
Methyl Ethyl Ketone Oxidation simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally
Using laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base
Composite panel, after molding pressure 60Pa, cold curing 24h, by burlap reinforced resin matrix composite sheet in 75 DEG C of solidify afterwards
3h is handled, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out using drilling device on same with thermosetting compound material layer
Lower through-hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards is drawn
Hair perforation same with thermosetting compound material layer, then by plucking perforation same with thermosetting compound material layer be put into mass concentration be 10% NaOH it is molten
In liquid after immersion treatment 24h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, it is porous
Same with thermosetting compound material layer thickness 1.8cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 50 DEG C, and is vented 5min, molds,
After 180 DEG C preheat 20min, using the pressure compression molding of 10MPa, be made-kind of the interior enhancing made using Chinese medicine dreg answered
Plywood material.
Embodiment 5：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polypropylene, maleic anhydride, calcium stearate, 4,4 '-methylene bis (2,6- DI-tert-butylphenol compounds), alkali formula sulfuric acid
Magnesium whisker and microcrystalline cellulose (125 mesh) 100: 15: 1: 1: 15: 5 mechanical mixtures in mass ratio uniformly after extruding pelletization, answered
Close plastic pellet, 180 DEG C of extrusion temperature；By composite plastic particle, Chinese medicine dreg (120 mesh) 100: 30 mechanical mixtures in mass ratio
Afterwards, thermoplastic composite layer, 175 DEG C of rolling temperature, thermoplastic composite thickness are rolled into using twin-screw extruder
Spend 1cm；
(2) in mass ratio 100: 0.5: 1: 20: 10 m-phthalate unsaturated polyester resin, naphthoic acid cobalt, peroxidating are weighed respectively
Methyl ethyl ketone, Chinese medicine dreg (120 mesh) and ramie cloth, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, add peroxide
Change methyl ethyl ketone and stir evenly, then add Chinese medicine dreg and be again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally adopt
With laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base and answer
Condensation material plate, after molding pressure 60Pa, cold curing 24h, by burlap reinforced resin matrix composite sheet at 80 DEG C of solidify afterwards
4h is managed, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out up and down on same with thermosetting compound material layer using drilling device
Through hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards obtains plucking
Perforation same with thermosetting compound material layer, then plucking perforation same with thermosetting compound material layer is put into the NaOH solution that mass concentration is 2%
After middle immersion treatment 36h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, porous heat
Solidity composite layer thickness 3cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 30 DEG C, and is vented 10min, closes
Mould, after 190 DEG C preheat 10min, using the pressure compression molding of 30MPa, is made a kind of interior increasing made using Chinese medicine dreg
Strong composite board.
Embodiment 6：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polyethylene, maleic anhydride, zinc stearate, 2,6- di-tert-butyl methyl phenols, alkali magnesium sulfate crystal whisker and
Microcrystalline cellulose (230 mesh) 100: 5: 2: 1.2: 5: 15 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain composite plastic
Particle, 170 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg (120 mesh) 100: 30 mechanical mixtures in mass ratio, profit
Thermoplastic composite layer, 165 DEG C of rolling temperature, thermoplastic composite layer thickness 1cm are rolled into twin-screw extruder；
(2) in mass ratio 100: 0.5: 1.5: 10: 20 metaphenylene unsaturated polyester resin, naphthoic acid cobalt, peroxide are weighed respectively
Change methyl ethyl ketone, Chinese medicine dreg (40 mesh) and linen, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, added
Methyl Ethyl Ketone Oxidation simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally
Using laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base
Composite panel, after molding pressure 90Pa, cold curing 12h, by burlap reinforced resin matrix composite sheet in 85 DEG C of solidify afterwards
2h is handled, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out using drilling device on same with thermosetting compound material layer
Lower through-hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards is drawn
Hair perforation same with thermosetting compound material layer, then by plucking perforation same with thermosetting compound material layer be put into mass concentration be 6% NaOH it is molten
In liquid after immersion treatment 48h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, it is porous
Same with thermosetting compound material layer thickness 0.6cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 40 DEG C, and is vented 15min, closes
Mould, after preheating 15min in the range of 170 DEG C, using the pressure compression molding of 50MPa, is made one kind and is made using Chinese medicine dreg
Interior enhancing composite board.
Embodiment 7：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polypropylene, maleic anhydride, zinc stearate, 4,4 '-methylene bis (2,6- DI-tert-butylphenol compounds), alkali formula sulfuric acid
Magnesium whisker and microcrystalline cellulose (20 mesh) 100: 10: 1.5: 0.8: 15: 10 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain
To composite plastic particle, 180 DEG C of extrusion temperature；By composite plastic particle, the machinery of Chinese medicine dreg (80 mesh) in mass ratio 100: 40
After mixing, thermoplastic composite layer, 185 DEG C of rolling temperature, thermoplastic composite are rolled into using twin-screw extruder
Layer thickness 1cm；
(2) in mass ratio 100: 1.5: 1: 10: 30 metaphenylene unsaturated polyester resin, naphthoic acid cobalt, peroxidating are weighed respectively
Methyl ethyl ketone, Chinese medicine dreg (80 mesh) and etramee, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, add peroxide
Change methyl ethyl ketone and stir evenly, then add Chinese medicine dreg and be again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally adopt
With laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base and answer
Condensation material plate, after molding pressure 60Pa, cold curing 18h, by burlap reinforced resin matrix composite sheet at 75 DEG C of solidify afterwards
3h is managed, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out up and down on same with thermosetting compound material layer using drilling device
Through hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards obtains plucking
Perforation same with thermosetting compound material layer, then plucking perforation same with thermosetting compound material layer is put into the NaOH solution that mass concentration is 2%
After middle immersion treatment 48h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, porous heat
Solidity composite layer thickness 0.6cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 40 DEG C, and is vented 15min, closes
Mould, after preheating 10min in the range of 180 DEG C, using the pressure compression molding of 50MPa, is made one kind and is made using Chinese medicine dreg
Interior enhancing composite board.
Embodiment 8：A kind of preparation method of the interior enhancing composite board made using Chinese medicine dreg, its preparation process are：
(1) by polypropylene, maleic anhydride, calcium stearate, 2,6- di-tert-butyl methyl phenols, alkali magnesium sulfate crystal whisker and
Microcrystalline cellulose (200 mesh) 100: 8: 1.6: 0.9: 12: 9 mechanical mixtures in mass ratio uniformly after extruding pelletization, obtain composite plastic
Expect particle, 178 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg (60 mesh) 100: 35 mechanical mixtures in mass ratio, profit
Thermoplastic composite layer, 180 DEG C of rolling temperature, thermoplastic composite layer thickness are rolled into twin-screw extruder
0.7cm；
(2) in mass ratio 100: 0.8: 0.9: 18: 18 m-phthalate unsaturated polyester resin, naphthoic acid cobalt, peroxide are weighed respectively
Change methyl ethyl ketone, Chinese medicine dreg (100 mesh) and gunny cloth, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, added
Methyl Ethyl Ketone Oxidation simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally
Using laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base
Composite panel, after molding pressure 70Pa, cold curing 15h, by burlap reinforced resin matrix composite sheet in 78 DEG C of solidify afterwards
2.4h is handled, is cooled to room temperature to obtain same with thermosetting compound material layer, is drilled out using drilling device on same with thermosetting compound material layer
Upper lower through-hole, obtains perforation same with thermosetting compound material layer, and carrying out plucking to perforation same with thermosetting compound material layer surface afterwards obtains
Plucking perforation same with thermosetting compound material layer, then plucking perforation same with thermosetting compound material layer is put into the NaOH that mass concentration is 4%
In solution after immersion treatment 30h, take out, rinsed to neutrality, dried with tap water, obtain porous same with thermosetting compound material layer, it is more
Hole same with thermosetting compound material layer thickness 2.1cm；
(3) according to the size of compression molding mold cavity, cut thermoplastic composite layer and porous thermosetting property is compound
Material layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, porous same with thermosetting compound material layer
In have on border the upper lower through-hole of lower through-hole and center；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then lays 1 layer on it
Porous same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous thermosetting property composite wood successively on it
The bed of material, finally repaves and puts 1 layer of thermoplastic composite layer, heats mould, its temperature is risen to 38 DEG C, and is vented 12min, closes
Mould, after preheating 18min in the range of 178 DEG C, using the pressure compression molding of 40MPa, is made one kind and is made using Chinese medicine dreg
Interior enhancing composite board.
The effect of the embodiment of the present invention 1 is proved below by way of detection, its testing result is as follows：
Static bending strength：35.66MPa, quiet song modulus：2.28GPa tensile strength：28.58MPa unnotched impact strength：
18.31kJ/m2, hardness：61D.
Result above shows that the plate of embodiment 1 has good intensity, modulus and hardness, and index of correlation substantially surpasses
Cross the requirement of People's Republic of China (PRC) forestry industry standard LY/T 1613-2004.
Claims (9)
1. a kind of interior enhancing composite board made using Chinese medicine dreg is by three layers of thermoplastic composite layer and two layers of porous heat
Solidity composite layer is formed, and is one layer of porous same with thermosetting compound material layer per between two layers of thermoplastic composite layer；Three layers
Thermoplastic composite layer forms and structure is identical, by polyolefin plastics particle, Chinese medicine dreg, maleic anhydride, tristearin
Hydrochlorate, antioxidant, alkali magnesium sulfate crystal whisker and microcrystalline cellulose are through mixing, extruding, rolling and form；Two layers of porous thermosetting property is compound
Material layer forms and structure is identical, by unsaturated polyester resin, naphthoic acid cobalt, methyl ethyl ketone peroxide, Chinese medicine dreg and fiber crops
Cloth handle paste, molding and drill, surface galling, alkaline etching form.
2. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Polyolefin plastics particle be one kind in polyethylene or polypropylene.
3. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Chinese medicine dreg particle diameter be 40-120 mesh.
4. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Stearate be one kind in calcium stearate or zinc stearate.
5. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Antioxidant for 2,6- di-tert-butyl methyl phenols or 4, one kind in 4 '-methylene bis (2,6- DI-tert-butylphenol compounds).
6. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Microcrystalline cellulose particle diameter be 20-230 mesh.
7. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Unsaturated polyester resin be one kind in adjacent benzene-type or metaphenylene unsaturated polyester resin.
8. a kind of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is characterised in that described
Burlap be ramie cloth, linen, etramee or gunny cloth in one kind.
9. a kind of production method of interior enhancing composite board made using Chinese medicine dreg according to claim 1, it is special
Sign is that its production method comprises the following steps：
(1) polyolefin plastics particle, maleic anhydride, stearate, antioxidant, alkali magnesium sulfate crystal whisker and microcrystalline cellulose are pressed
100: 5-15: 1-2: 0.8-1.2: 5-15: 5-15 mechanical mixture of mass ratio uniformly after extruding pelletization, obtain composite plastic particle,
170-190 DEG C of extrusion temperature；After composite plastic particle, Chinese medicine dreg in mass ratio 100: 30-50 mechanical mixture, double roller is utilized
Rubber mixing machine is rolled into thermoplastic composite layer, 165-185 DEG C of rolling temperature, thermoplastic composite layer thickness 0.6-
1cm；
(2) in mass ratio 100: 0.5-1.5: 0.5-1.5: 10-20: 10-30 weigh respectively unsaturated polyester resin, naphthoic acid cobalt,
Methyl ethyl ketone peroxide, Chinese medicine dreg and burlap, by unsaturated polyester resin, naphthoic acid cobalt mechanical agitation it is uniform after, add peroxidating
Methyl ethyl ketone simultaneously stirs evenly, and then adds Chinese medicine dreg and is again stirring for uniformly, obtaining Chinese medicine dreg potting resin paste；Finally use
Laying mould pressing process, using burlap be reinforcing material, Chinese medicine dreg potting resin paste for matrix, make burlap reinforced resin base it is compound
Plate of material, after molding pressure 30-90Pa, cold curing 12-24h, by burlap reinforced resin matrix composite sheet in 75-85 DEG C of model
Interior solidify afterwards processing 2-4h is enclosed, is cooled to room temperature to obtain same with thermosetting compound material layer, using drilling device in thermosetting property composite wood
Lower through-hole is drilled out on the bed of material, obtain perforation same with thermosetting compound material layer, afterwards to perforation same with thermosetting compound material layer surface into
Row plucking, obtains plucking perforation same with thermosetting compound material layer, then plucking perforation same with thermosetting compound material layer is put into mass concentration
After immersion treatment 24-48h in the NaOH solution of 2-10%, take out, rinsed to neutrality, dried with tap water, obtain porous heat
Solidity composite layer, porous same with thermosetting compound material layer thickness 0.6-3cm；
(3) according to the size of compression molding mold cavity, thermoplastic composite layer and porous same with thermosetting compound material are cut
Layer, makes its length and width size consistent with the length and width size of mold cavity respectively, wherein, have in porous same with thermosetting compound material layer
The upper lower through-hole of lower through-hole and center on border；
(4) 1 layer of thermoplastic composite layer is placed in the bottom of compression molding die cavity, then 1 layer of lay is porous on it
Same with thermosetting compound material layer, then lay 1 layer of thermoplastic composite layer and 1 layer of porous same with thermosetting compound material successively on it
Layer, finally repaves and puts 1 layer of thermoplastic composite layer, wherein, three layers of thermoplastic composite layer thickness are mutually the same, more than two layers
Hole same with thermosetting compound material layer thickness is mutually the same, heats mould, its temperature is risen to 30-50 DEG C, and is vented 5-15min, closes
Mould, after preheating 10-20min in the range of 170-190 DEG C, using the pressure compression molding of 10-50MPa, is made in a kind of utilize
The interior enhancing composite board that the medicine dregs of a decoction make.
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| CN201711188297.9A CN107955248B (en) | 2017-11-21 | 2017-11-21 | Internal reinforced composite board prepared from traditional Chinese medicine dregs and preparation method thereof |
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| CN201711188297.9A CN107955248B (en) | 2017-11-21 | 2017-11-21 | Internal reinforced composite board prepared from traditional Chinese medicine dregs and preparation method thereof |
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| CN201711188297.9A Expired - Fee Related CN107955248B (en) | 2017-11-21 | 2017-11-21 | Internal reinforced composite board prepared from traditional Chinese medicine dregs and preparation method thereof |
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| CN114193842A (en) * | 2021-11-30 | 2022-03-18 | 江苏福瑞森塑木科技股份有限公司 | Plastic-wood composite material plate with ultralow surface adhesion performance and preparation method thereof |
| CN114407444A (en) * | 2022-01-28 | 2022-04-29 | 南京林业大学 | Bearing structure material made of agricultural and forestry waste and manufacturing method thereof |
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Application publication date: 20180424 Assignee: SUZHOU ZHONGTE ELECTRIC MATERIAL Co.,Ltd. Assignor: NANJING FORESTRY University Contract record no.: X2020320000062 Denomination of invention: The invention relates to an inner reinforced composite plate made of Chinese medicine dregs and a preparation method thereof Granted publication date: 20200630 License type: Common License Record date: 20200819 Application publication date: 20180424 Assignee: NANJING DAYUAN ECOLOGICAL CONSTRUCTION GROUP Co.,Ltd. Assignor: NANJING FORESTRY University Contract record no.: X2020320000063 Denomination of invention: The invention relates to an inner reinforced composite plate made of Chinese medicine dregs and a preparation method thereof Granted publication date: 20200630 License type: Common License Record date: 20200819 |
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