CN108118541B - Method for prefabricating and transferring printing of fiber fabric - Google Patents
Method for prefabricating and transferring printing of fiber fabric Download PDFInfo
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- CN108118541B CN108118541B CN201611065974.3A CN201611065974A CN108118541B CN 108118541 B CN108118541 B CN 108118541B CN 201611065974 A CN201611065974 A CN 201611065974A CN 108118541 B CN108118541 B CN 108118541B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5228—Polyalkenyl alcohols, e.g. PVA
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
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- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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Abstract
The invention relates to a method for prefabricating and transferring printing of fiber fabrics, which comprises the following steps: (1) printing the active ink on a film with a release layer by a gravure printing machine to prepare a transfer printing film; (2) coating the fiber fabric with a coating liquid through a coating machine, attaching the coated fiber fabric to a transfer printing film, closely attaching the coated fiber fabric to the transfer printing film through rolling, and heating and pressurizing to realize printing; (3) after the printing is finished, stripping the printing film, and fixing the color of the fiber fabric finished by the printing, wherein the step of fixing the color is to use a wetting agent to pass through a coating machine to wet the fiber fabric finished by the printing, and the fiber fabric after being wetted is dried. The fiber fabric prefabrication transfer printing method provided by the invention has the advantages of less material consumption, accurate application, no waste generation, no waste water, no waste gas discharge, extremely low energy consumption, simple operation and convenient use in the aspect of prefabricated film and reactive dye.
Description
Technical Field
The invention belongs to the technical field of printing and dyeing industry, and particularly relates to a method for prefabricating and transferring printing on fiber fabrics.
Background
The traditional reactive dye printing paste is prepared by the reactive dye with stronger activity and an active catalyst together. Therefore, the slurry has short use time, large waste amount, much slurry consumption and serious pollution. The traditional reactive dye printing adopts a drop printing mode, and because the mode cannot pressurize with a drop printing mould net, the reactive dye printing only can leak from holes of a net mould by the gravity principle. This again results in inaccurate dosage and therefore in overprinting, for which reason a large amount of paste cannot be combined with the textile. Finally, the excessive sizing agent on the textile can be washed off only by water and then is dried in a row. A large amount of sewage is generated, and a large amount of heat energy is also needed for drying textiles.
Disclosure of Invention
The invention aims to provide a fiber fabric prefabrication transfer printing method, which is used for prefabricating a film and reactive dyes, has the advantages of less material consumption, accurate application, no waste generation, no waste water, waste gas discharge, extremely low energy consumption, simple operation and convenient use.
In order to achieve the above object, the technical solution of the present invention is as follows:
the invention aims to provide a method for prefabricating and transferring printing of a fiber fabric, which comprises the following steps:
(1) the active printing ink is printed on a film with a release layer by a single-color or multi-color rotary printing through a gravure printing machine to prepare a transfer printing film;
(2) coating a fiber fabric with a coating liquid through a coating machine, attaching the coated fiber fabric to the transfer printing film prepared in the step (1), rolling through a single rolling machine or a multi-rolling machine to enable the coated fiber fabric to be closely attached to the transfer printing film, and rolling, and keeping the temperature at 60-80 ℃ for 1-3 hours to realize printing;
(3) after printing is finished, stripping the printing film, and then carrying out color fixing treatment on the printed fiber fabric, wherein the color fixing treatment comprises the steps of wetting the printed fiber fabric by using a wetting agent through a coating machine, and drying the wetted fiber fabric;
the active ink in the step (1) comprises the following components in parts by mass: 10-30 parts of reactive dye, 0.4-2.3 parts of thickening adhesive, 0.35-1 part of deliquescent agent, 0.3-0.8 part of electrolyte, 0.3-0.6 part of leveling agent, 70-90 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent and 0.05 part of emulsifier, wherein the thickening adhesive comprises 0.1-0.5 part of polyvinyl alcohol, 0.1-0.5 part of hydroxymethyl cellulose, 0.1-0.3 part of organic bentonite and 0.1-1 part of polyvinylpyrrolidone, the deliquescent agent comprises 0.05-0.2 part of glycerol and 0.3-0.8 part of urea, the electrolyte is sulfuric acid decahydrate, and the leveling agent is polyoxyethylene ether;
the coating liquid in the step (2) comprises the following components in parts by mass: 0.1-0.5 part of sodium carbonate, 0.1-1 part of sodium bicarbonate, 0.01-0.5 part of sodium silicate, 85-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.01-0.3 part of cationic polyacrylamide, 0.1-0.8 part of polyaluminium chloride, 0.1-0.3 part of silane coupling agent, 0.5-1 part of amino silicone emulsion, 80-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent.
In the invention, the total silane coupling agent in the step (2) is gamma-aminopropyl triethoxysilane.
The steps of the method for prefabricating and transferring the textile fabric are all carried out at normal temperature, wherein the printing pressure of the gravure printing machine in the step (1) is 4-6 kg/cm2(ii) a The rolling pressure of the single roller press or the multiple roller presses in the step (2) is 10-80 kg/cm2(ii) a The coating pressure of the coating machine in the step (3) is 1-3 kg/cm2。
The process flow of the method for prefabricating the transfer printing provided by the invention is as follows:
the plastic film coated with the release layer is used for carrying out single-color or multi-color rotary continuous printing on an intaglio printing machine, the printing ink used for printing is active printing ink made of active dye, a template used by the intaglio printing machine is formed by precisely engraving by a computer, the printed product has exquisite patterns, rich colors, clear layers and extremely high quality, and the plastic film with the release layer and printed with high-quality patterns is stored for later use. The storage period of the plastic film with the release layer can reach more than one year.
Coating the fiber fabric by a coating machine, wherein the wetting agent is prepared from raw materials such as an adhesive, an electrolyte, an alkaline agent and the like; and (3) superposing the coated fiber fabric and the plastic film with the release layer printed with the high-quality pattern, and rolling by a single-roller or multi-roller press to ensure that the plastic film with the release layer printed with the high-quality pattern is tightly attached to the wet fiber fabric. The pattern printed on the film is completely adhered to the fiber fabric under the adhesion action of the wetting agent, and the active group of the active dye reacts with the fiber of the fiber fabric under the action of the auxiliary agents such as electrolyte, alkali agent and the like to form a common bond combination, so that the active ink is fixed on the fiber fabric. And after the reaction is finished, the film is separated from the fiber fabric, and the release layer on the film can easily and completely separate the film from the fiber fabric, so that the fiber fabric printed with the exquisite pattern is obtained.
In the second step of operation, the printed fiber fabric still has a small amount of alkaline agent and trace amount of reactive dye molecules in the wetting agent and has hydrophilicity, so that further color fixing treatment is needed, the color fixing treatment is completed by coating the wetting agent in multiple directions at one time, and the wetting agent consists of polyaluminium chloride, cationic polyacrylamide, silane coupling agent, amino silicone oil and aqueous solution of other surfactants. And (4) wetting the fiber fabric printed in the second step by using a coating machine, and then drying the fiber fabric in a tunnel furnace.
Preferably, the film in step (1) is a plastic film, and the plastic film is selected from one of a PET film, a PP film or a nylon film.
Preferably, the reactive ink in the step (1) comprises the following components in parts by mass: 15-25 parts of reactive dye, 0.9-0.15 part of thickening adhesive, 0.6-0.8 part of deliquescent agent, 0.4-0.6 part of electrolyte, 0.4-0.5 part of leveling agent and 70-90 parts of water.
Furthermore, the thickening adhesive comprises, by mass, 0.2-0.3 part of polyvinyl alcohol, 0.2-0.3 part of hydroxymethyl cellulose, 0.1-0.3 part of organic bentonite and 0.4-0.6 part of polyvinylpyrrolidone.
Preferably, the coating liquid comprises, by mass, 0.3 part of sodium carbonate, 0.5 part of sodium bicarbonate, 0.3 part of sodium silicate, 98 parts of water, 0.03 part of leveling agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent.
Preferably, the coating liquid in the step (2) is prepared by the following steps: dissolving 0.01-0.5 part of sodium silicate in 1-10 parts of water to form a sodium silicate solution for later use, adding 1-5 parts of sodium carbonate and 1-10 parts of sodium bicarbonate into 75-97 parts of water, stirring until the sodium carbonate and the sodium bicarbonate are completely dissolved, wherein the pH value is 9.5-12, adding 0.03 part of a flatting agent, 0.03 part of a penetrating agent, 0.03 part of an emulsifying agent and 0.05 part of a defoaming agent, and finally adding the sodium silicate solution and stirring uniformly to obtain the coating liquid.
Preferably, the wetting agent in the step (3) comprises the following components in parts by mass: 0.15 part of cationic polyacrylamide, 0.45 part of polyaluminium chloride, 0.2 part of silane coupling agent, 0.8 part of emulsified amino silicone oil, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
Preferably, the wetting agent described in step (3) is prepared by the following steps: dissolving 0.1-0.3 part of cationic polyacrylamide in 1-10 parts of water for later use, dissolving 0.1-0.3 part of silane coupling agent and 0.1-0.8 part of polyaluminum chloride solution in 70-97 parts of water, wherein the pH value is 4-5, sequentially adding 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent, 0.05 part of defoaming agent and 0.5-1 part of emulsified amino silicone oil, stirring uniformly, adding the dissolved cationic polyacrylamide, and stirring uniformly to obtain the wetting agent.
Preferably, the fiber fabric is selected from one of cellulose fiber, protein fiber or viscose fiber.
Preferably, the leveling agent in the step (2) and the step (3) is HR-3302, the penetrating agent is JFC-4.0, the emulsifier is diglycerol polypropylene glycol ether, and the defoaming agent is an aqueous defoaming agent. The leveling agent in the step (2) and the step (3) is HR-3302 which is purchased from Hongrui chemical engineering, and the penetrating agent can greatly improve the wettability, permeability and leveling property of the coating liquid on the surface of the coating, the penetrating agent used in the invention is JFC-4.0 which is purchased from Liaoning chemical engineering, the emulsifying agent is diglycerol polypropylene glycol ether which is purchased from creative chemical engineering, and the defoaming agent is TEGO Foamex 810 which is purchased from three-liter chemical engineering.
The invention has the beneficial effects that: the fiber fabric prefabrication transfer printing method provided by the invention has the advantages of less material consumption, accurate application, no waste generation, no waste water, no waste gas discharge, extremely low energy consumption, simple operation and convenient use in the aspect of prefabricated film and reactive dye.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are only for illustrating the present invention and are not intended to limit the scope of the present invention. In practice, the technical personnel according to the invention make improvements and modifications, which still belong to the protection scope of the invention.
The equipment and reagents used in the present invention are, unless otherwise specified, conventional commercial products in the art.
A method for prefabricating and transferring printing of fiber fabrics comprises the following steps:
(1) the active printing ink is printed on a film with a release layer by a single-color or multi-color rotary printing through a gravure printing machine to prepare a transfer printing film;
(2) coating a fiber fabric with a coating liquid through a coating machine, attaching the coated fiber fabric to the transfer printing film prepared in the step (1), rolling through a single rolling machine or a multi-rolling machine to enable the coated fiber fabric to be closely attached to the transfer printing film, and rolling, and keeping the temperature at 60-80 ℃ for 1-3 hours to realize printing;
(3) after printing is finished, stripping the printing film, and then carrying out color fixing treatment on the printed fiber fabric, wherein the color fixing treatment comprises the steps of wetting the printed fiber fabric by using a wetting agent through a coating machine, and drying the wetted fiber fabric;
the active ink in the step (1) comprises the following components in parts by mass: 10-30 parts of reactive dye, 0.4-2.3 parts of thickening adhesive, 0.35-1 part of deliquescent agent, 0.3-0.8 part of electrolyte, 0.3-0.6 part of leveling agent, 70-90 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent and 0.05 part of emulsifier, wherein the thickening adhesive comprises 0.1-0.5 part of polyvinyl alcohol, 0.1-0.5 part of hydroxymethyl cellulose, 0.1-0.3 part of organic bentonite and 0.1-1 part of polyvinylpyrrolidone, the deliquescent agent comprises 0.05-0.2 part of glycerol and 0.3-0.8 part of urea, the electrolyte is sulfuric acid decahydrate, and the leveling agent is polyoxyethylene ether;
the coating liquid in the step (2) comprises the following components in parts by mass: 0.1-0.5 part of sodium carbonate, 0.1-1 part of sodium bicarbonate, 0.01-0.5 part of sodium silicate, 85-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.01-0.3 part of cationic polyacrylamide, 0.1-0.8 part of polyaluminium chloride, 0.1-0.3 part of silane coupling agent, 0.5-1 part of amino silicone emulsion, 80-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent.
Example 1
A method for prefabricating and transferring printing of fiber fabrics comprises the following steps:
(1) the active printing ink is printed on a film with a release layer by a single-color or multi-color rotary printing through a gravure printing machine to prepare a transfer printing film;
(2) coating a fiber fabric with a coating liquid through a coating machine, attaching the coated fiber fabric to the transfer printing film prepared in the step (1), rolling through a single rolling machine or a multi-rolling machine to enable the coated fiber fabric to be closely attached to the transfer printing film, and keeping the temperature at 60 ℃ for 1h to realize printing;
(3) after the printing is finished, the printing film is peeled off, the fiber fabric which is finished through the printing is subjected to color fixing treatment, the color fixing treatment is carried out by using a wetting agent through a coating machine, the fiber fabric which is finished through the printing is wetted, and the fiber fabric which is wetted is dried.
The steps of the method for prefabricating and transferring the fiber fabrics are all carried out at normal temperature, wherein the step (1) is carried out by gravure printingThe printing pressure of the brushing machine is 4-6 kg/cm2(ii) a The rolling pressure of the single roller press or the multiple roller presses in the step (2) is 10-80 kg/cm2(ii) a The coating pressure of the coating machine in the step (3) is 1-3 kg/cm2。
The active ink in the step (1) comprises the following components in parts by mass: 10 parts of reactive dye, 0.4 part of thickening adhesive, 0.35 part of deliquescent agent, 0.3 part of sulfuric acid decahydrate, 0.3 part of polyoxyethylene ether, 70 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent and 0.05 part of emulsifying agent, wherein the thickening adhesive comprises 0.1 part of polyvinyl alcohol, 0.1 part of hydroxymethyl cellulose, 0.1 part of organic bentonite and 0.1 part of polyvinylpyrrolidone, and the deliquescent agent comprises 0.05 part of glycerol and 0.3 part of urea;
the coating liquid in the step (2) comprises the following components in parts by mass: 0.1 part of sodium carbonate, 0.1 part of sodium bicarbonate, 0.01 part of sodium silicate, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.01 part of cationic polyacrylamide, 0.1 part of polyaluminium chloride, 0.1 part of silane coupling agent, 0.5 part of emulsified amino silicone oil, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
The reactive ink of the step (1) is prepared by the following steps: adding 0.05 part of glycerol and 0.3 part of urea into 50 parts of water at the temperature of 90 ℃, uniformly stirring, adding 10 parts of reactive dye, stirring until the reactive dye is completely dissolved, cooling to the temperature below 40 ℃, then adding 20 parts of polyvinyl alcohol, 0.1 part of hydroxymethyl cellulose, 0.1 part of organic bentonite and 0.1 part of polyvinylpyrrolidone, stirring, and after the slurry is uniform, sequentially adding 0.3 part of decahydrated sulfuric acid, 0.3 part of polyoxyethylene ether and a proper amount of auxiliary agent to obtain the reactive ink, wherein the auxiliary agent comprises 0.03 part of flatting agent, 0.03 part of penetrating agent and 0.03-0.05 part of emulsifying agent, and the auxiliary agent is the same as the flatting agent, the penetrating agent and the emulsifying agent used in the step (2) and the step (3).
The leveling agent in the step (2) and the step (3) is HR-3302 which is purchased from Hongrui chemical engineering, and the penetrating agent can greatly improve the wettability, permeability and leveling property of the coating liquid on the surface of the coating, the penetrating agent used in the invention is JFC-4.0 which is purchased from Liaoning chemical engineering, the emulsifying agent is diglycerol polypropylene glycol ether which is purchased from creative chemical engineering, and the defoaming agent is TEGO Foamex 810 which is purchased from three-liter chemical engineering.
The coating liquid in the step (2) is prepared by the following steps: dissolving 0.01 part of sodium silicate by 1 part of water to form a sodium silicate solution for standby, adding 1 part of sodium carbonate and 1 part of sodium bicarbonate into 97 parts of water, stirring until the sodium silicate solution is completely dissolved, wherein the pH value is 9.5-12, then adding 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent, and finally adding the sodium silicate solution and stirring uniformly to obtain the coating liquid.
The wetting agent in the step (3) is prepared by the following steps: dissolving 0.1 part of cationic polyacrylamide by using 1 part of water for standby, dissolving 0.1 part of silane coupling agent and 0.1 part of polyaluminium chloride solution in 97 parts of water, wherein the pH value is 4-5, sequentially adding 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent, 0.05 part of defoaming agent and 0.5 part of emulsified amino silicone oil, uniformly stirring, then adding the dissolved cationic polyacrylamide, and uniformly stirring to obtain the wetting agent.
Example 2
The same as example 1, except that:
keeping the temperature at 70 ℃ for 2h in the step (2) to realize printing;
the active ink in the step (1) comprises the following components in parts by mass: 15 parts of reactive dye, 0.9 part of thickening adhesive, 0.6 part of deliquescent agent, 0.4 part of sulfuric acid decahydrate, 0.4 part of polyoxyethylene ether and 70 parts of water; the thickening adhesive comprises 0.2 part of polyvinyl alcohol, 0.2 part of hydroxymethyl cellulose, 0.1 part of organic bentonite and 0.4 part of polyvinylpyrrolidone, and the deliquescent agent comprises 0.2 part of glycerol and 0.4 part of urea;
the coating liquid in the step (2) comprises the following components in parts by mass: 0.3 part of sodium carbonate, 0.5 part of sodium bicarbonate, 0.3 part of sodium silicate, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.15 part of cationic polyacrylamide, 0.45 part of polyaluminium chloride, 0.2 part of silane coupling agent, 0.8 part of emulsified amino silicone oil, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
Example 3
The same as example 1, except that:
keeping the temperature at 70 ℃ for 2h in the step (2) to realize printing;
the active ink in the step (1) comprises the following components in parts by mass: 25 parts of reactive dye, 1.5 parts of thickening adhesive, 0.8 part of deliquescent agent, 0.6 part of sulfuric acid decahydrate, 0.5 part of polyoxyethylene ether and 90 parts of water; the deliquescent agent comprises 0.2 part of glycerol and 0.6 part of urea; the thickening adhesive comprises 0.3 part of polyvinyl alcohol, 0.3 part of hydroxymethyl cellulose, 0.3 part of organic bentonite and 0.6 part of polyvinylpyrrolidone.
The coating liquid in the step (2) comprises the following components in parts by mass: 0.3 part of sodium carbonate, 0.5 part of sodium bicarbonate, 0.3 part of sodium silicate, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.15 part of cationic polyacrylamide, 0.45 part of polyaluminium chloride, 0.2 part of silane coupling agent, 0.8 part of emulsified amino silicone oil, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
Example 4
The same as example 1, except that:
keeping the temperature at 80 ℃ for 3h in the step (2) to realize printing;
the active ink in the step (1) comprises the following components in parts by mass: 30 parts of reactive dye, 2.3 parts of thickening adhesive, 1 part of deliquescent agent, 0.8 part of sulfuric acid decahydrate, 0.6 part of polyoxyethylene ether and 90 parts of water; the deliquescent agent comprises 0.2 part of glycerol and 0.8 part of urea; the thickening adhesive comprises 0.5 part of polyvinyl alcohol, 0.5 part of hydroxymethyl cellulose, 0.3 part of organic bentonite and 1 part of polyvinylpyrrolidone.
The coating liquid in the step (2) comprises the following components in parts by mass: 0.5 part of sodium carbonate, 1 part of sodium bicarbonate, 0.5 part of sodium silicate, 85 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.3 part of cationic polyacrylamide, 0.8 part of polyaluminium chloride, 0.3 part of silane coupling agent, 1 part of emulsified amino silicone oil, 80 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
The printed fiber fabrics obtained in the embodiments 1 to 4 have an exhaustion rate of more than 99%, especially the printed fiber fabrics obtained in the embodiments 2 and 3 have an exhaustion rate of 99.9%, and are comfortable in hand feeling, and no waste materials or waste gases are generated, thereby realizing the effects of low consumption and environmental protection.
1-10 g of active printing ink solid used per square meter in the step (1) of prefabricated printing; in the step (2), rolling transfer printing is carried out, because the action transfer rate of the parting agent on the plastic film can reach 100%, the printing ink transferred on the textile is dissolved in the coating liquid, a prefabricated color is formed on the surface of the textile, the redundant active printing ink permeates downwards, the back of the printing surface of the textile with a bright color is formed without a color, and thus the dye uptake can reach 99.9%, and no floating color exists; in the step (3), under the action of the wetting agent, the hydrophilic groups of the active printing ink are closed, the hydrophilic groups and the fiber molecule reticular structure are formed, the pH value is 6-8, and the emulsified amino silicone oil enables the textile to feel smooth.
The fiber fabric prefabrication transfer printing method provided by the invention has the advantages of less material consumption, accurate application, no waste generation, no waste water, no waste gas discharge, extremely low energy consumption, simple operation and convenient use in the aspect of prefabricated film and reactive dye.
While the present invention has been described in detail with reference to the preferred embodiments thereof, the principles and embodiments of the present invention are illustrated in the accompanying drawings, which are used to explain the principles of the invention and the core concept thereof, it should be understood that various changes and modifications can be made therein by those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (10)
1. A method for prefabricating and transferring printing of fiber fabrics is characterized by comprising the following steps:
(1) the active printing ink is printed on a film with a release layer by a single-color or multi-color rotary printing through a gravure printing machine to prepare a transfer printing film;
(2) coating a fiber fabric with a coating liquid through a coating machine, attaching the coated fiber fabric to the transfer printing film prepared in the step (1), rolling through a single rolling machine or a multi-rolling machine to enable the coated fiber fabric to be closely attached to the transfer printing film, and rolling, and keeping the temperature at 60-80 ℃ for 1-3 hours to realize printing;
(3) after printing is finished, stripping the printing film, and then carrying out color fixing treatment on the printed fiber fabric, wherein the color fixing treatment comprises the steps of wetting the printed fiber fabric by using a wetting agent through a coating machine, and drying the wetted fiber fabric;
the active ink in the step (1) comprises the following components in parts by mass: 10-30 parts of reactive dye, 0.4-2.3 parts of thickening adhesive, 0.35-1 part of deliquescent agent, 0.3-0.8 part of electrolyte, 0.3-0.6 part of leveling agent, 70-90 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent and 0.05 part of emulsifier, wherein the thickening adhesive comprises 0.1-0.5 part of polyvinyl alcohol, 0.1-0.5 part of hydroxymethyl cellulose, 0.1-0.3 part of organic bentonite and 0.1-1 part of polyvinylpyrrolidone, the deliquescent agent comprises 0.05-0.2 part of glycerol and 0.3-0.8 part of urea, the electrolyte is sulfuric acid decahydrate, and the leveling agent is polyoxyethylene ether;
the coating liquid in the step (2) comprises the following components in parts by mass: 0.1-0.5 part of sodium carbonate, 0.1-1 part of sodium bicarbonate, 0.01-0.5 part of sodium silicate, 85-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent;
the wetting agent in the step (3) comprises the following components in parts by mass: 0.01-0.3 part of cationic polyacrylamide, 0.1-0.8 part of polyaluminium chloride, 0.1-0.3 part of silane coupling agent, 0.5-1 part of amino silicone emulsion, 80-98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifier and 0.05 part of defoaming agent.
2. A method of pre-forming transfer printing a fibre fabric according to claim 1, characterised in that: the film in the step (1) is a plastic film, and the plastic film is selected from one of a PET film, a PP film or a nylon film.
3. The method for prefabricating and transfer printing of fiber fabrics according to claim 1 or 2, characterized in that the reactive ink in the step (1) comprises the following components in parts by mass: 15-25 parts of reactive dye, 0.9-1.5 parts of thickening adhesive, 0.6-0.8 part of deliquescent agent, 0.4-0.6 part of electrolyte, 0.4-0.5 part of leveling agent and 70-90 parts of water.
4. A method of pre-forming transfer printing a fibre fabric according to claim 3, characterised in that: the thickening adhesive comprises, by mass, 0.2-0.3 part of polyvinyl alcohol, 0.2-0.3 part of hydroxymethyl cellulose, 0.1-0.3 part of organic bentonite and 0.4-0.6 part of polyvinylpyrrolidone.
5. A method of pre-forming transfer printing of a fibre fabric according to claim 1 or 4, characterised in that: the coating liquid comprises, by mass, 0.3 part of sodium carbonate, 0.5 part of sodium bicarbonate, 0.3 part of sodium silicate, 98 parts of water, 0.03 part of a leveling agent, 0.03 part of a penetrating agent, 0.03 part of an emulsifier and 0.05 part of a defoaming agent.
6. A method of pre-forming transfer printing of a fibre fabric according to claim 1 or 4, characterised in that: the coating liquid in the step (2) is prepared by the following steps: dissolving 0.01-0.5 part of sodium silicate in 1-10 parts of water to form a sodium silicate solution for later use, adding 1-5 parts of sodium carbonate and 1-10 parts of sodium bicarbonate into 75-97 parts of water, stirring until the sodium carbonate and the sodium bicarbonate are completely dissolved, wherein the pH value is 9.5-12, adding 0.03 part of a flatting agent, 0.03 part of a penetrating agent, 0.03 part of an emulsifying agent and 0.05 part of a defoaming agent, and finally adding the sodium silicate solution and stirring uniformly to obtain the coating liquid.
7. A method of pre-forming transfer printing a fibre fabric according to claim 1, characterised in that: the wetting agent in the step (3) comprises the following components in parts by mass: 0.15 part of cationic polyacrylamide, 0.45 part of polyaluminium chloride, 0.2 part of silane coupling agent, 0.8 part of emulsified amino silicone oil, 98 parts of water, 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent and 0.05 part of defoaming agent.
8. A method of pre-forming transfer printing a fibre fabric according to claim 1, characterised in that: the wetting agent in the step (3) is prepared by the following steps: dissolving 0.1-0.3 part of cationic polyacrylamide in 1-10 parts of water for later use, dissolving 0.1-0.3 part of silane coupling agent and 0.1-0.8 part of polyaluminum chloride solution in 70-97 parts of water, wherein the pH value is 4-5, sequentially adding 0.03 part of flatting agent, 0.03 part of penetrating agent, 0.03 part of emulsifying agent, 0.05 part of defoaming agent and 0.5-1 part of emulsified amino silicone oil, stirring uniformly, adding the dissolved cationic polyacrylamide, and stirring uniformly to obtain the wetting agent.
9. A method of pre-forming transfer printing a fibre fabric according to claim 1, characterised in that: the fiber fabric is cellulose fiber or protein fiber.
10. A method of pre-forming transfer printing a fibre fabric according to claim 1, characterised in that: in the step (2) and the step (3), the flatting agent is HR-3302, the penetrating agent is JFC-4.0, the emulsifier is diglycerol polypropylene glycol ether, and the defoaming agent is a water-based defoaming agent.
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| CN108749385A (en) * | 2018-06-13 | 2018-11-06 | 和峻（广州）胶管有限公司 | A kind of method of outer textured fiber line hose transfer lettering |
| CN109594371A (en) * | 2018-12-17 | 2019-04-09 | 苏州极数印花科技有限公司 | A kind of method for transfer printing |
| CN115216979A (en) * | 2022-07-20 | 2022-10-21 | 临清三和纺织集团有限公司 | Pearlescent powder multicolor simultaneous printing process |
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Effective date of registration: 20200401 Address after: Room 703, block 10, Sydney 1, Nanguo Olympic Park, Panyu District, Guangzhou, Guangdong 511495 Patentee after: Lv Yong Address before: 511495 Sydney, Guangzhou, Guangdong, Panyu District, 10 Sydney 1 District 703 Patentee before: GUANGZHOU BASIBA TECHNOLOGY RESEARCH AND DEVELOPMENT Co.,Ltd. |