CN108103514A - A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof - Google Patents
A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof Download PDFInfo
- Publication number
- CN108103514A CN108103514A CN201711427431.6A CN201711427431A CN108103514A CN 108103514 A CN108103514 A CN 108103514A CN 201711427431 A CN201711427431 A CN 201711427431A CN 108103514 A CN108103514 A CN 108103514A
- Authority
- CN
- China
- Prior art keywords
- hop
- barley
- cleaning agent
- industrial cleaning
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Abstract
The present invention provides a kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof, and specific preparation method is：It is saccharified being soaked in after barley pulverization in water, treats the barley solution that barley germination is germinateed；The pistil of fresh hop is impregnated in ethanol solution, filtering contracting post processing obtains hop pistil extract；Hop pistil extract is added in the form of spraying in the barley solution of germination, is added in water, heating stirring, obtains malt/hop composite pulp；Malt/hop composite pulp is passed through oxygen, adds in wild yeasts for fermentation, filtrate is transferred to wooden barrel relaying supervention ferment, is passed through carbon dioxide, plant based cleaning agent is obtained by filtration by filtering；Finally auxiliary agent will be added in plant based cleaning agent, obtain the plant base industrial cleaning agent based on barley and hop.Industrial cleaning agent prepared by the present invention is combined using beer raw material as primary raw material, through biofermentation with physical technique is prepared the good industrial cleaning agent of environmentally protective detergency ability.
Description
Technical field
The invention belongs to industrial cleaning agent field of material technology, and in particular to a kind of plant base based on barley and hop
Industrial cleaning agent and preparation method thereof.
Background technology
With the continuous improvement of environmental consciousness and power conservation requirement, the nearly more than ten years, the rapid development that industry cleaning link liquid obtains, and
And constantly develop to green and multifunctional direction, it penetrated into machinery industry, textile printing and dyeing industry, petroleum chemical industry, adopted
Ore deposit smelting industry, chemical industry, Surface Processing Industry, instrument and meter industry, electronics industry, semicon industry, clock and watch are first
Multiple industry fields such as industry, biological industry, optics industry are adornd, ensure that and carry out production strictly in line with rules and regulations and product quality, but industry at present
For cleaning solution there are no specific standard, fabricating technology is also not mature enough.
Industrial cleaning agent can be divided into chemical cleaning, physical cleaning and micro-organism washing according to the raw material of cleaning action.China
A kind of multifunctional green aqueous cleaning agent and preparation method thereof disclosed in patent CN 105273857A, the cleaning agent are by the pungent last of the ten Heavenly stems
The transparence solution that base glucoside, fatty acid methyl ester ethoxylate, coconut oil diethanol amide and water are prepared, this is clear
Lotion major function material be three kinds of degradable nonionic surfactant raw materials, can not only effectively remove vegetable oil room,
Animal oil spot, industrial buffing wax spot, mineral oil spot etc., and it is environmentally protective.This chemical is to utilize chemistry
Medicament dissolves the substances such as greasy soils, reduces the combination power between substances itself particles such as greasy soils, reaches decontamination
Process.But this chemical reagent is difficult to thoroughly decompose grease and spot, and it is prepared by the chemical reagent used
It a degree of can also damage in journey to environment.
It is a kind of for removing the cleaning agent to remove grease disclosed in Chinese patent CN 107354041A, including Fructus Gleditsiae Abnormalis extract, carbon
Sour sodium, sodium phosphate, oleic acid, diethanol amine, sodium soap, sucrose fatty ester, neopelex, ethyl alcohol, cellulose
Methyl ether, pomelo peel abstract, polyetherimide, active silver nano-grain, graphene oxide, antifoaming agent and deionized water.This is clear
Plant extracts is combined to obtain by lotion with nano material and auxiliary agent, and the cleaning agent of preparation removes industrial oil stain and vegetable and animals oils
Dirty ability is strong, and foam is low, does not pollute the environment, and has certain antirust function to metal.It, will from the above-mentioned prior art
Active ingredient in plant extracts acts synergistically with other active principles, in industrial cleaning agent, ensure it is environmentally protective
It is technical, good clean effect, good combination property can also be obtained.The present invention is using barley and hop as active principle
Raw material is combined through biotechnology with physical technique, and environmentally protective, the strong plant base industry cleaning link of dirt-removing power is prepared
Agent.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of plant base industrial cleaning agent based on barley and hop and
Its preparation method, the present invention are faintly acid by the industrial cleaning agent that barley and hop are prepared by primary raw material, containing carbonic acid and
Acetate component and substantial amounts of vitamin and mineral, find when being cleaned to surface of aluminum plate, and cleaning performance is better than general
Industrial cleaning agent, and the vitamin and mineral contained in the industrial cleaning agent prepared due to the present invention will not be to cleaning
Staff causes any harm, and totally nontoxic is harmless, does not hurt hands, really environmentally protective without chemical bad smell.
In order to solve the above technical problems, the technical scheme is that：
A kind of preparation method of the plant base industrial cleaning agent based on barley and hop, it is characterised in that：Including following
Step：
(1) 36-48h in water after barley pulverization, will be completely soaked to be saccharified, after barley germination, take out, germinateed
Barley solution；
(2) pistil of fresh hop is picked, be impregnated in the ethanol solution of 70-75%, filter and remove residue is dense
Contracting post processing, obtains hop pistil extract；
(3) hop pistil extract prepared by step (2) is added to the barley of step (1) germination in the form of spraying
It in solution, adds in water, heating stirring is cooled to room temperature, and obtains malt/hop composite pulp；
(4) malt/hop composite pulp prepared by step (3) is passed through oxygen, adds in wild yeasts for fermentation 8-12h, mistake
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through carbon dioxide, plant based cleaning agent is obtained by filtration by filter；
(5) auxiliary agent is added in the plant based cleaning agent for preparing step (4), be uniformly mixed, obtained based on barley and golden hop
The plant base industrial cleaning agent of grass.
As the preferred of above-mentioned technical proposal, in the step (1), the grain size of barley is 100-300 μm after crushing.
As the preferred of above-mentioned technical proposal, in the step (1), 40-50 DEG C of the temperature of saccharification.
As the preferred of above-mentioned technical proposal, in the step (1), malt concentration is 55- in the barley solution of germination
60%, the content of α-amino nitrogen is 180-200mg/100g wheat juice.
As the preferred of above-mentioned technical proposal, in the step (2), the pistil of hop and the materials ratio of ethanol solution are
1-2g：5-10mL.
As the preferred of above-mentioned technical proposal, in the step (2), hop pistil extract extracts for hop pistil
Object is pellet, glue or essential oil shape.
As the preferred of above-mentioned technical proposal, in the step (3), the temperature of heating stirring is 60-70 DEG C, and the time is
30-60min, the solid content of malt/hop composite pulp is 34-45wt%.
As the preferred of above-mentioned technical proposal, in the step (4), the throughput of oxygen is 0.2-0.4mL/min, dioxy
The throughput for changing carbon is 0.3-0.5mL/min.
As the preferred of above-mentioned technical proposal, in the step (4), auxiliary agent for higher fatty acid salt, hydrochlorate, sulfonate,
One or several kinds in sulfuric acid ester salt, phosphate ester salt or fatty acyl.
As the preferred of above-mentioned technical proposal, any one described above is based on the industry of the plant base of barley and hop
Product prepared by the preparation method of cleaning agent.
Compared with prior art, the invention has the advantages that：
(1) active ingredient in the plant base industrial cleaning agent based on barley and hop for preparing of the present invention for barley and
Hop pistil, barley and hop are traditional beer raw material, and the present invention prepares barley and hop for primary raw material
Industry cleaning link is faintly acid, containing carbonic acid and acetate component and substantial amounts of vitamin and mineral, is carried out to surface of aluminum plate
It is found during cleaning, industrial cleaning agent prepared by the present invention can effectively infiltrate through the inside of dirt, go to decontaminate from internal softening
Dirt can also change the acid-base property of grease, lower the combination power between grease macromolecular, cleaning performance is better than industry generally
Cleaning agent, and the vitamin and mineral contained in the industrial cleaning agent prepared due to the present invention will not be to the staff of cleaning
It causes any harm, totally nontoxic is harmless, does not hurt hands, really environmentally protective without chemical bad smell.
(2) preparation method of the plant base industrial cleaning agent based on barley and hop of the invention, using barley malt
The enzyme of middle dormant state carries out barley saccharification processing, and the enzyme in malt is by the Starch Conversion in barley into glucose, glucose
Carbon dioxide and alcohol are resolved into again, and the barley fermentation process after pulverization process is more abundant, is conducive to obtain high concentration
Barley solution, the hop extract that the pistil of hop is concentrated to formation after ethyl alcohol extracts contains lupulones, humulus grass two
Ketenes, humulone, laurene, Huang Shi glucosides, Kaempferol, different certain herbaceous plants with big flowers skin glucoside, leucodelphindin, tanning isoreactivity ingredient, by golden hop
Careless extract is distributed in the form of spraying in the barley solution of high concentration, is prevented the reunion of hop extract, is conducive to snake
Numb grass extract is uniformly dispersed, and the barley solution of high concentration can form one due to concentration height on the surface that hop is extracted
Kind dense film after wild yeasts secondary fermentation, is more advantageous to the concerted reaction of the two, makes group in the industrial cleaning agent of preparation
Scattered more uniform, clean effect is more notable.
(3) in addition, height can also be added in the plant base industrial cleaning agent based on barley and hop prepared by the present invention
Grade soap, hydrochlorate, sulfonate, sulfuric acid ester salt, phosphate ester salt or fatty acyl, by plant extracts and Green Chemistry reagent
It is combined, on the basis of guarantee is environmentally protective, further improves clean effect.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1：
(1) by the powder that barley pulverization to grain size is 100 μm, the saccharification processing 36h in 40 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 55% in the barley solution of germination, α-amino nitrogen
Content be 180mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 1g according to materials ratio：5mL, be impregnated in 70% ethyl alcohol it is molten
In liquid, 8h, filter and remove residue are impregnated at 40 DEG C, concentration post processing obtains the hop pistil extract of pellet.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 30min, is cooled to room temperature at 60 DEG C, obtains malt/hop composite pulp that solid content is 34wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.2mL/min, adds in wild yeasts for fermentation 8h, is filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through the carbon dioxide of 0.3mL/min, plant based cleaning agent is obtained by filtration.
(5) higher fatty acid salt will be added in plant based cleaning agent, is uniformly mixed, obtains the plant based on barley and hop
Object base industrial cleaning agent, the wherein content of plant base active ingredient are 20wt%.
Embodiment 2：
(1) by the powder that barley pulverization to grain size is 300 μm, the saccharification processing 48h in 50 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 60% in the barley solution of germination, α-amino nitrogen
Content be 200mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 2g according to materials ratio：10mL is impregnated in 75% ethyl alcohol
In solution, 10h, filter and remove residue are impregnated at 70 DEG C, concentration post processing obtains the hop pistil extract of essential oil shape.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 60min, is cooled to room temperature at 70 DEG C, obtains malt/hop composite pulp that solid content is 45wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.4mL/min, adds in wild yeasts for fermentation 12h, is filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through the carbon dioxide of 0.5mL/min, plant based cleaning agent is obtained by filtration.
(5) hydrochlorate and sulfonate will be added in plant based cleaning agent, is uniformly mixed, obtains the plant based on barley and hop
Object base industrial cleaning agent, the wherein content of plant base active ingredient are 40wt%.
Embodiment 3：
(1) by the powder that barley pulverization to grain size is 200 μm, the saccharification processing 42h in 45 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 58% in the barley solution of germination, α-amino nitrogen
Content be 190mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 1.5g according to materials ratio：6mL is impregnated in 73% ethyl alcohol
In solution, 9.5h, filter and remove residue are impregnated at 50 DEG C, concentration post processing obtains gelatinous hop pistil extract.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 45min, is cooled to room temperature at 65 DEG C, obtains malt/hop composite pulp that solid content is 38wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.3mL/min, adds in wild yeasts for fermentation 10h, is filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through the carbon dioxide of 0.4mL/min, plant based cleaning agent is obtained by filtration.
(5) sulfuric acid ester salt, phosphate ester salt and fatty acyl will be added in plant based cleaning agent, be uniformly mixed, obtained based on big
Wheat and the plant base industrial cleaning agent of hop, the wherein content of plant base active ingredient are 35wt%.
Embodiment 4：
(1) by the powder that barley pulverization to grain size is 150 μm, the saccharification processing 38h in 42 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 57% in the barley solution of germination, α-amino nitrogen
Content be 190mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 1.5g according to materials ratio：8mL is impregnated in 72% ethyl alcohol
In solution, 9h, filter and remove residue are impregnated at 55 DEG C, concentration post processing obtains the hop pistil extract of essential oil shape.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 40min, is cooled to room temperature at 65 DEG C, obtains malt/hop composite pulp that solid content is 40wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.25mL/min, adds in wild yeasts for fermentation 10h, is filtered,
Filtrate is transferred to wooden barrel relaying supervention ferment, the carbon dioxide of 0.45mL/min is passed through, plant based cleaning agent is obtained by filtration.
(5) higher fatty acid salt and sulfuric acid ester salt will be added in plant based cleaning agent, will be uniformly mixed, obtain based on barley and
The plant base industrial cleaning agent of hop, the wherein content of plant base active ingredient are 25wt%.
Embodiment 5：
(1) by the powder that barley pulverization to grain size is 200 μm, the saccharification processing 48h in 40 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 55% in the barley solution of germination, α-amino nitrogen
Content be 200mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 1g according to materials ratio：10mL is impregnated in 70% ethyl alcohol
In solution, 8h, filter and remove residue are impregnated at 70 DEG C, concentration post processing obtains the hop pistil extract of pellet.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 60min, is cooled to room temperature at 60 DEG C, obtains malt/hop composite pulp that solid content is 40wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.2mL/min, adds in wild yeasts for fermentation 8h, is filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through the carbon dioxide of 0.5mL/min, plant based cleaning agent is obtained by filtration.
(5) sulfonate and fatty acyl will be added in plant based cleaning agent, will be uniformly mixed, will be obtained based on barley and hop
Plant base industrial cleaning agent, the wherein content of plant base active ingredient are 28wt%.
Embodiment 6：
(1) by the powder that barley pulverization to grain size is 300 μm, the saccharification processing 48h in 40 DEG C of water is completely soaked, is treated big
After wheat germination, take out, the barley solution to be germinateed, wherein, malt concentration is 60% in the barley solution of germination, α-amino nitrogen
Content be 180mg/100g wheat juice.
(2) pistil of fresh hop is picked, is 2g according to materials ratio：5mL, be impregnated in 75% ethyl alcohol it is molten
In liquid, 10h, filter and remove residue are impregnated at 40 DEG C, concentration post processing obtains gelatinous hop pistil extract.
(3) hop pistil extract is added in the form of spraying in the barley solution of germination, added in water,
Heating stirring 55min, is cooled to room temperature at 62 DEG C, obtains malt/hop composite pulp that solid content is 40wt%.
(4) malt/hop composite pulp is passed through to the oxygen of 0.3mL/min, adds in wild yeasts for fermentation 11h, is filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through the carbon dioxide of 0.3mL/min, plant based cleaning agent is obtained by filtration.
(5) hydrochlorate and sulfuric acid ester salt will be added in plant based cleaning agent, will be uniformly mixed, will be obtained based on barley and hop
Plant base industrial cleaning agent, the wherein content of plant base active ingredient are 35wt%.
Reference《The test method of water base metal cleaning agent》：After aluminium sheet is cleaned, 1h is dried at 120 DEG C, uses glass bar
Mineral oil is coated in strip, dirt quality control is in 0.24-0.26g/ pieces, and dry 10min, is transferred to 45 at 200 DEG C
DEG C constant temperature oven in aging 3h, with the embodiment 1-6 plant base industrial cleaning agents based on barley and hop prepared and
Industrial cleaning agent (CN 105273857A) cleaning of the prior art, after testing its detergency, to the irritation of skin, degradable
The result of property and antibiotic property is as follows：
As seen from the above table, the cleaning performance of the plant base industrial cleaning agent based on barley and hop that prepared by the present invention is not
Chemical industry cleaning agent is second to, and it is completely non-stimulated to skin, degradable rate is high, can be to work also with certain antibiotic property
Industry device surface carries out long-effective protection, functional good.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of preparation method of the plant base industrial cleaning agent based on barley and hop, which is characterized in that including following step
Suddenly：
(1) 36-48h in water after barley pulverization, will be completely soaked to be saccharified, after barley germination, taken out, the barley to be germinateed
Solution；
(2) pistil of fresh hop is picked, be impregnated in the ethanol solution of 70-75%, filter and remove residue, after concentration
Processing, obtains hop pistil extract；
(3) hop pistil extract prepared by step (2) is added to the barley solution of step (1) germination in the form of spraying
In, it adds in water, heating stirring is cooled to room temperature, and obtains malt/hop composite pulp；
(4) malt/hop composite pulp prepared by step (3) is passed through oxygen, adds in wild yeasts for fermentation 8-12h, filtered, it will
Filtrate is transferred to wooden barrel relaying supervention ferment, is passed through carbon dioxide, plant based cleaning agent is obtained by filtration；
(5) auxiliary agent will be added in the plant based cleaning agent for preparing step (4), be uniformly mixed, obtained based on barley and hop
Plant base industrial cleaning agent.
2. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (1), the grain size of barley is 100-300 μm after crushing.
3. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (1), 40-50 DEG C of the temperature of saccharification.
4. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (1), malt concentration is 55-60% in the barley solution of germination, and the content of α-amino nitrogen is 180-
200mg/100g wheat juice.
5. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (2), the pistil of hop and the materials ratio of ethanol solution are 1-2g：5-10mL.
6. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (2), hop pistil extract is that hop pistil extract is pellet, glue or essential oil
Shape.
7. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (3), the temperature of heating stirring is 60-70 DEG C, time 30-60min, and malt/hop is compound
The solid content of slurry is 34-45wt%.
8. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (4), the throughput of oxygen is 0.2-0.4mL/min, and the throughput of carbon dioxide is 0.3-
0.5mL/min。
9. a kind of preparation method of plant base industrial cleaning agent based on barley and hop according to claim 1,
It is characterized in that：In the step (4), auxiliary agent is higher fatty acid salt, hydrochlorate, sulfonate, sulfuric acid ester salt, phosphate ester salt or fat
One or several kinds in fat acyl.
10. the preparation method of any one plant base industrial cleaning agent based on barley and hop described in claim 1-9
The product of preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711427431.6A CN108103514A (en) | 2017-12-26 | 2017-12-26 | A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711427431.6A CN108103514A (en) | 2017-12-26 | 2017-12-26 | A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108103514A true CN108103514A (en) | 2018-06-01 |
Family
ID=62213251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711427431.6A Pending CN108103514A (en) | 2017-12-26 | 2017-12-26 | A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108103514A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096509A (en) * | 1994-01-15 | 1994-12-21 | 沈阳佳源国际医疗科技有限公司 | The method for preparing tetrahydro-iso-humulone by hop extract |
| CN104024395A (en) * | 2011-11-11 | 2014-09-03 | 红黎明Ip控股有限公司 | Improved process for the manufacture of alcoholic beverages and products produced by such process |
| CN105695148A (en) * | 2016-02-24 | 2016-06-22 | 江阴市佐恩精品衣物洗涤护理有限公司 | Environment-friendly solid cleaner composition |
-
2017
- 2017-12-26 CN CN201711427431.6A patent/CN108103514A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096509A (en) * | 1994-01-15 | 1994-12-21 | 沈阳佳源国际医疗科技有限公司 | The method for preparing tetrahydro-iso-humulone by hop extract |
| CN104024395A (en) * | 2011-11-11 | 2014-09-03 | 红黎明Ip控股有限公司 | Improved process for the manufacture of alcoholic beverages and products produced by such process |
| CN105695148A (en) * | 2016-02-24 | 2016-06-22 | 江阴市佐恩精品衣物洗涤护理有限公司 | Environment-friendly solid cleaner composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103695214B (en) | A kind of washing composition containing gingko ferment and preparation method thereof | |
| CN105255601A (en) | Coconut oil fruit and vegetable cleaning agent | |
| CN101962601A (en) | Environment-friendly orange peel extract limonene degumming and decontaminating agent and preparation method thereof | |
| CN103242978A (en) | Natural plant cleaning agent for cleaning heavy oil in kitchen and preparation method of natural plant cleaning agent | |
| CN102533436A (en) | Method for processing health-care camellia oil | |
| CN108103514A (en) | A kind of plant base industrial cleaning agent based on barley and hop and preparation method thereof | |
| CN106675858A (en) | Taxus chinensis toilet soap and preparation method thereof | |
| CN104844683A (en) | Method for extracting peony saponin from peony seed meal | |
| CN111073779A (en) | Soap powder prepared from kitchen waste grease and preparation method thereof | |
| CN107177643B (en) | Tremella residue fermentation product, skin-care washing product containing fermentation product and preparation method of skin-care washing product | |
| CN104479930A (en) | Fruit surface cleaning agent and preparation method thereof | |
| CN107190332A (en) | A kind of silk degumming method of high-efficiency environment friendly | |
| CN108048225A (en) | A kind of environment friendly and pollution-free washing powder and preparation method thereof | |
| CN106883938A (en) | Environmental protection floor cleaning agent | |
| CN102796207A (en) | Method for extracting pectin from tangerine peel | |
| CN112126272A (en) | Peculiar smell remover for water-based paint and preparation method thereof | |
| CN110405225A (en) | The preparation method of one Plant Extracts nano materials | |
| CN111481479A (en) | Method for extracting antioxidant component from cannabis sativa leaves and application of antioxidant component | |
| CN1190121A (en) | Preparation of plant composition detergent | |
| CN109330926A (en) | Moisturizing and nourishing hand lotion and preparation method thereof | |
| CN110257195A (en) | A kind of natural tea handmade soap and preparation method thereof | |
| CN104498197A (en) | Oil stain removal spray and preparation method thereof | |
| CN109251796A (en) | A kind of energy-saving and environment-friendly detergent | |
| KR102262517B1 (en) | Method for manufacturing eco-friendly detergent composition | |
| CN114588657B (en) | Extraction method of torreya grandis bark active ingredient |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180601 |
|
| RJ01 | Rejection of invention patent application after publication |