CN108102787A - A kind of Damask Rose tobacco aromaticss and its preparation method and application - Google Patents
A kind of Damask Rose tobacco aromaticss and its preparation method and application Download PDFInfo
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- CN108102787A CN108102787A CN201810038174.5A CN201810038174A CN108102787A CN 108102787 A CN108102787 A CN 108102787A CN 201810038174 A CN201810038174 A CN 201810038174A CN 108102787 A CN108102787 A CN 108102787A
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- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 244000061176 Nicotiana tabacum Species 0.000 title abstract 3
- 239000000243 solution Substances 0.000 claims abstract description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 39
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000010521 absorption reaction Methods 0.000 claims abstract description 18
- 238000010828 elution Methods 0.000 claims abstract description 15
- 238000000605 extraction Methods 0.000 claims abstract description 15
- 239000012046 mixed solvent Substances 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 238000010790 dilution Methods 0.000 claims abstract description 13
- 239000012895 dilution Substances 0.000 claims abstract description 13
- 241000220317 Rosa Species 0.000 claims abstract description 8
- 239000003205 fragrance Substances 0.000 claims abstract description 6
- 239000000796 flavoring agent Substances 0.000 claims abstract description 5
- 235000019634 flavors Nutrition 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000002250 absorbent Substances 0.000 claims abstract description 4
- 230000002745 absorbent Effects 0.000 claims abstract description 4
- 241000208125 Nicotiana Species 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- 235000019441 ethanol Nutrition 0.000 claims description 18
- 239000012153 distilled water Substances 0.000 claims description 15
- 239000012141 concentrate Substances 0.000 claims description 10
- 239000003480 eluent Substances 0.000 claims description 10
- 238000011010 flushing procedure Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000002137 ultrasound extraction Methods 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims 1
- 239000000284 extract Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 4
- 238000001256 steam distillation Methods 0.000 abstract description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003546 flue gas Substances 0.000 abstract description 3
- 239000002304 perfume Substances 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract description 2
- 235000011449 Rosa Nutrition 0.000 description 6
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 1
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- ULDHMXUKGWMISQ-VIFPVBQESA-N (S)-(+)-Carvone Natural products CC(=C)[C@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-VIFPVBQESA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 240000004784 Cymbopogon citratus Species 0.000 description 1
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- -1 ethylalbenzene Chemical compound 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 229940043259 farnesol Drugs 0.000 description 1
- 229930002886 farnesol Natural products 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
- A24B15/303—Plant extracts other than tobacco
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/022—Refining
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Botany (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
A kind of Damask Rose tobacco aromaticss and its preparation method and application, it is characterized in that, the fragrance is using Damask Rose as raw material, it adds in after mixed solvent and carries out extracting solution extraction, concentration, dilution, absorption, elution and enrichment process again, Damask Rose tobacco aromaticss are made, compared with traditional extracting method, use mixed solvent ultrasonic wave extraction Damask Rose, greatly reduce heating time, / 10th of only traditional steam distillation, recovery rate is also obviously improved, and significantly reduces the production cost of rose extract；It is separated with reference to the elution of macroporous absorbent resin, reducing has cigarette smoke in extract the content of negative effect ingredient, improve the quality and purity of active ingredient, think through smokeing panel test, the product can be promoted cigarette flavor matter, cigarette perfume alcohol and exquisiteness, flue gas moisture feeling and pleasant impression aspect also have clear improvement.
Description
Technical field
The present invention relates to cigarette additive technical field more particularly to a kind of Damask Rose tobacco aromaticss and its preparations
Methods and applications.
Background technology
Damask Rose originates in Syria, starts in 14th century widely to plant in France, and Damask Rose is to protect to add
The main rose variety and universally acknowledged high-quality rose variety of Leah plantation.Blade is celadon, is had on scape hard
Hair；Hose-in-hose is opened, petal edge color is slightly shallow, there is the texture as silks and satins；Purely, the careful fragrance of a flower makes its hat pressure beautiful and fragrant flowers, becomes
Top grade in rose for oil is widely cultivated to extract Rosa Damascana at present at home.
The chemical composition of Rosa Damascana is one of most complicated essential oil of ingredient, it is known that ingredient is more than more than 300 kinds.Rosa Damascana
Main chemical composition includes citronellol, phenylethanol, geraniol, nerol, ethylalbenzene, farnesol（Fanesol）, rose
Rare wax, micro nonyl alcohol, linalool, aldehyde C-9, citral, carvol, acetic acid lemongrass, methyleugenol, eugenol.Its energy
The immune and nervous system with landman is stimulated, while helps to improve the secretion of incretory, organ sclerosis is removed, repairs carefully
Born of the same parents.
Rosa Damascana is the essential oil of most expensive in the world, and per kilogram price is up to more than 20,000 U.S. dollars.Traditional Rosa Damascana is adopted
It is produced with steam distillation, expends substantial amounts of manpower and materials, and yield is extremely low, it is difficult to be widely used in perfuming cigarette technique
In, only have a small amount of application in the essence of high-grade cigarette at present, the aroma quality of cigarette flavor can be promoted, make cigarette perfume alcohol and it is fine and smooth,
It also has clear improvement in terms of flue gas moisture feeling and pleasant impression, therefore according to the characteristics of perfuming cigarette, exploitation low price, the extraction of applicable rose
Object has a vast market prospect, is subject to the extensive concern of tobacco aromaticss insider.
The content of the invention
The technical problems to be solved by the invention are, for current traditional Rosa Damascana steam distillation use to produce with
Tobacco aromaticss are made and there is the problem of of high cost, low output, a kind of Damask Rose tobacco aromaticss and its preparation side are provided
Method and application.
A kind of Damask Rose tobacco aromaticss, which is characterized in that the fragrance is using Damask Rose as raw material, is added in
Extracting solution extraction, concentration, dilution, absorption, elution and enrichment process again are carried out after mixed solvent, with obtained Damask Rose cigarette
Use fragrance.
Preferably, the Damask Rose raw material is Damask Rose of the moisture in 8wt% -12wt%.
The present invention also provides a kind of preparation methods of Damask Rose tobacco aromaticss, it is characterised in that the preparation
The step of method, is as follows：
（1）Damask Rose petal is added in ultrasonic extraction tank, it is molten to add in the mixing being made of ethyl alcohol, propylene glycol, water
The feed liquid weight ratio of agent, Damask Rose petal and mixed solvent is 1:4—1:10, open ultrasonic extraction tank, ultrasonic wave
Frequency is 50-200kHz, and temperature is maintained at 40-60 DEG C, and 30-60 minutes extraction times extracting solution is made, stopped operation,
Extracting solution is poured out after slightly cooling down, is filtered with strainer, collection obtains first time extracting solution, collects remaining residue, remaining residue
It repeats the above method and carries out second of extraction, be collected by filtration to obtain second of extracting solution；
（2）After mixing first time extracting solution and second of extracting solution, extracting solution is poured into rotary evaporator and is concentrated, concentrated
Temperature is 45-55 DEG C, and vacuum degree is 0.005-0.01Mpa, concentrate is made；
（3）The obtained concentrate distilled water of 10-15 times of weight is diluted, dilution is made；
（4）Dilution is passed to DM301 types large pore resin absorption column to carry out absorption process with the flow velocity of 1.5BV/h, absorption
After, resin column is rinsed with the flow velocity of 1.0BV/h with 10L distilled water, after flushing, with the flow velocity of 1.0-1.5BV/h, is used
The ethanol water elution agent elution of 20wt%-60wt% of 1.5-2.0BV, collects eluent；
（5）By step（4）The eluent of middle collection, which is poured into rotary evaporator, to be concentrated, 45-55 DEG C of thickening temperature, vacuum
0.005-0.01Mpa is spent, is concentrated into density as 1.100-1.250 to get to Damask Rose tobacco aromaticss.
Preferably, the step（1）In mixed solvent contained by ethyl alcohol be 20-30 mass parts, propylene glycol is 10-20 matter
Amount part, water are:40-60 mass parts.
Preferably, the step（4）In Dm301 types macroporous absorbent resin with after 95% ethyl alcohol soaked overnight, with distillation
Water is rinsed to no ethanol flavor, then impregnates 4h with the solution of 4%NaOH, with distilled water flushing to neutrality；It is finally molten with 4% HCl
Liquid impregnates 4h, and with distilled water flushing to neutrality, dress column is spare, and cylinder specification is 10cm × 60cm.
The present invention also provides a kind of applications of Damask Rose tobacco aromaticss, which is characterized in that wherein presses
0.03wt% -0.1wt% of cigarette shreds weighs Damask Rose tobacco aromaticss, after being dissolved with 30wt% ethanol waters, spray
It is added in flue-cured tobacco pipe tobacco.
A kind of Damask Rose tobacco aromaticss of the present invention and its preparation method and application, with traditional extracting method phase
Than using mixed solvent ultrasonic wave extraction Damask Rose, greatly reducing heating time, being only traditional steam distillation
1/10th, recovery rate is also obviously improved, and significantly reduces the production cost of rose extract；With reference to macroporous absorbent resin
Elution separation, reduce the content for having negative effect ingredient in extract to cigarette smoke, improve the quality of active ingredient
And purity, think through smokeing panel test, which can make the promotion of cigarette flavor matter, cigarette perfume alcohol and exquisiteness, flue gas moisture feeling and pleasant impression aspect
Also have clear improvement.
Specific embodiment
With reference to specific embodiment, the present invention will be described in further detail.
Embodiment 1：
A kind of the step of Damask Rose tobacco aromaticss, the tobacco aromaticss preparation method, is as follows：
（1）1000g Damask Rose petals are added in ultrasonic extraction tank, addition weight ratio is ethyl alcohol：Propylene glycol：Water=
30:10:The feed liquid weight ratio of 60 mixed solvent, Damask Rose petal and mixed solvent is 1:10, it opens ultrasonic wave and carries
Tank, ultrasonic frequency 50Hz are taken, temperature is maintained at 45 DEG C, and 50 minutes extraction times extracting solution is made, stopped operation, slightly
Extracting solution is poured out after cooling, is filtered with strainer, collection obtains first time extracting solution, collects remaining residue, remaining residue weight
The multiple above method carries out second and extracts, and is collected by filtration to obtain second of extracting solution；
（2）After mixing first time extracting solution and second of extracting solution, extracting solution is poured into rotary evaporator and is concentrated, concentrated
Temperature is 55 DEG C, vacuum degree 0.005Mpa, concentrate is made；
（3）Obtained concentrate is diluted with 10 times of distilled water, dilution is made；
（4）Dilution is passed to DM301 types large pore resin absorption column to carry out absorption process with the flow velocity of 1.5BV/h, absorption
After, resin column is rinsed with the flow velocity of 1.0BV/h with 10L distilled water, after flushing, with the flow velocity of 1.5BV/h, is used
The ethanol water elution agent elution of the 20wt% of 1.5BV, collects eluent；
（5）By step（4）The eluent of middle collection, which is poured into rotary evaporator, to be concentrated, 50 DEG C of thickening temperature, vacuum degree
0.005Mpa is concentrated into density as 1.150 to get to Damask Rose tobacco aromaticss.
The Damask Rose tobacco aromaticss of gained by the 0.03wt% of cigarette shreds are weighed, are dissolved with 30% ethyl alcohol,
It is uniformly sprayed onto in pipe tobacco, cigarette, which is made, to pipe tobacco smokes panel test, and smoking result is as shown in table 1：
Embodiment 2：
A kind of the step of Damask Rose tobacco aromaticss, the tobacco aromaticss preparation method, is as follows：
（1）1000g Damask Rose petals are added in ultrasonic extraction tank, addition weight ratio is ethyl alcohol：Propylene glycol：Water=
20:20:The feed liquid weight ratio of 60 mixed solvent, Damask Rose petal and mixed solvent is 1:6, open ultrasonic wave extraction
Tank, ultrasonic frequency 100Hz, temperature are maintained at 50 DEG C, and 40 minutes extraction times extracting solution is made, stopped operation, slightly cold
But extracting solution is poured out afterwards, is filtered with strainer, and collection obtains first time extracting solution, collects remaining residue, and remaining residue repeats
The above method carries out second and extracts, and is collected by filtration to obtain second of extracting solution；
（2）After mixing first time extracting solution and second of extracting solution, extracting solution is poured into rotary evaporator and is concentrated, concentrated
Temperature is 55 DEG C, vacuum degree 0.01Mpa, concentrate is made；
（3）Obtained concentrate is diluted with 15 times of distilled water, dilution is made；
（4）Dilution is passed to DM301 types large pore resin absorption column to carry out absorption process with the flow velocity of 1.5BV/h, absorption
After, resin column is rinsed with the flow velocity of 1.0BV/h with 10L distilled water, after flushing, with the flow velocity of 1.0BV/h, is used
The ethanol water elution agent elution of the 40wt% of 2.0BV, collects eluent；
（5）By step（4）The eluent of middle collection, which is poured into rotary evaporator, to be concentrated, 55 DEG C of thickening temperature, vacuum degree
0.01Mpa is concentrated into density as 1.20 to get to Damask Rose tobacco aromaticss.
The Damask Rose tobacco aromaticss of gained by the 0.03wt% of cigarette shreds are weighed, are dissolved with 30% ethyl alcohol,
It is uniformly sprayed onto in pipe tobacco, cigarette, which is made, to pipe tobacco smokes panel test, and smoking result is as shown in table 2：
Embodiment 3：
A kind of the step of Damask Rose tobacco aromaticss, the tobacco aromaticss preparation method, is as follows：
（1）1000g Damask Rose petals are added in ultrasonic extraction tank, addition weight ratio is ethyl alcohol：Propylene glycol：Water=
30:20:The feed liquid weight ratio of 50 mixed solvents, Damask Rose petal and mixed solvent is 1:4, open ultrasonic wave extraction
Tank, ultrasonic frequency 200Hz, temperature are maintained at 60 DEG C, and 60 minutes extraction times extracting solution is made, stopped operation, slightly cold
But extracting solution is poured out afterwards, is filtered with strainer, and collection obtains first time extracting solution, collects remaining residue, and remaining residue repeats
The above method carries out second and extracts, and is collected by filtration to obtain second of extracting solution；
（2）After mixing first time extracting solution and second of extracting solution, extracting solution is poured into rotary evaporator and is concentrated, concentrated
Temperature is 55 DEG C, vacuum degree 0.005Mpa, concentrate is made；
（3）Obtained concentrate is diluted with 15 times of distilled water, dilution is made；
（4）Dilution is passed to DM301 types large pore resin absorption column to carry out absorption process with the flow velocity of 1.5BV/h, absorption
After, resin column is rinsed with the flow velocity of 1.0BV/h with 10L distilled water, after flushing, with the flow velocity of 1.5BV/h, is used
The ethanol water elution agent elution of the 60wt% of 2.0BV, collects eluent；
（5）By step（4）The eluent of middle collection, which is poured into rotary evaporator, to be concentrated, 55 DEG C of thickening temperature, vacuum degree
0.005Mpa is concentrated into density as 1.250 to get to Damask Rose tobacco aromaticss.
The Damask Rose tobacco aromaticss of gained by the 0.03wt% of cigarette shreds are weighed, are dissolved with 30% ethyl alcohol,
It is uniformly sprayed onto in pipe tobacco, cigarette, which is made, to pipe tobacco smokes panel test, and smoking result is as shown in table 3：
Claims (6)
1. a kind of Damask Rose tobacco aromaticss, which is characterized in that the fragrance is using Damask Rose as raw material, is added in mixed
Extracting solution extraction, concentration, dilution, absorption, elution and enrichment process again are carried out after bonding solvent, Damask Rose cigarette use is made
Fragrance.
A kind of 2. Damask Rose tobacco aromaticss according to claim 1, it is characterised in that Damascus rose
Rare raw material is Damask Rose of the moisture in 8wt% -12wt%.
3. a kind of preparation method of Damask Rose tobacco aromaticss, it is characterised in that the step of described preparation method is as follows：
（1）Damask Rose petal is added in ultrasonic extraction tank, it is molten to add in the mixing being made of ethyl alcohol, propylene glycol, water
The feed liquid weight ratio of agent, Damask Rose petal and mixed solvent is 1:4—1:10, open ultrasonic extraction tank, ultrasonic wave
Frequency is 50-200kHz, and temperature is maintained at 40-60 DEG C, and 30-60 minutes extraction times extracting solution is made, stopped operation,
Extracting solution is poured out after slightly cooling down, is filtered with strainer, collection obtains first time extracting solution, collects remaining residue, remaining residue
It repeats the above method and carries out second of extraction, be collected by filtration to obtain second of extracting solution；
（2）After mixing first time extracting solution and second of extracting solution, extracting solution is poured into rotary evaporator and is concentrated, concentrated
Temperature is 45-55 DEG C, and vacuum degree is 0.005-0.01Mpa, concentrate is made；
（3）The obtained concentrate distilled water of 10-15 times of weight is diluted, dilution is made；
（4）Dilution is passed to DM301 types large pore resin absorption column to carry out absorption process with the flow velocity of 1.5BV/h, absorption
After, resin column is rinsed with the flow velocity of 1.0BV/h with 10L distilled water, after flushing, with the flow velocity of 1.0-1.5BV/h, is used
The ethanol water elution agent elution of 20wt%-60wt% of 1.5-2.0BV, collects eluent；
（5）By step（4）The eluent of middle collection, which is poured into rotary evaporator, to be concentrated, 45-55 DEG C of thickening temperature, vacuum
0.005-0.01Mpa is spent, is concentrated into density as 1.100-1.250 to get to Damask Rose tobacco aromaticss.
4. the preparation method of a kind of Damask Rose tobacco aromaticss according to claim 3, it is characterised in that described
Step（1）In mixed solvent contained by ethyl alcohol be 20-30 mass parts, propylene glycol is 10-20 mass parts, water is:40-60 mass
Part.
5. the preparation method of a kind of Damask Rose tobacco aromaticss according to claim 3, it is characterised in that described
Step（4）In Dm301 types macroporous absorbent resin with after 95% ethyl alcohol soaked overnight, after distilled water flushing to no ethanol flavor, then
4h is impregnated with the solution of 4%NaOH, with distilled water flushing to neutrality；4h finally is impregnated with 4% HCl solution, uses distilled water flushing
To neutrality, dress column is spare, and cylinder specification is 10cm × 60cm.
6. a kind of application of Damask Rose tobacco aromaticss, which is characterized in that wherein by cigarette shreds 0.03wt%-
0.1wt% weighs Damask Rose tobacco aromaticss, and after being dissolved with 30wt% ethanol waters, spray is added in flue-cured tobacco pipe tobacco.
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